,,little ,,blue ,,book ,,no4 #fgi ,edited by ,e4 ,haldeman-,julius ,chemistry ,for ,beginners ,hereward ,carrington1 ,ph4,d4 ,author of the following ,little ,blue ,books3 ,no4 #dia1 8,psychology for ,beginners20 ,no4 #dai1 8,life3 ,its ,origin and ,nature20 ,no4 #ebd1 8,death and ,its ,problems20 ,no4 #dic1 8,new ,discoveries in ,science20 ,nos4 #dde-ddf1 8,psychical ,research0 7#b vols471 etc41 etc4 ,,haldeman-,,julius ,,company ,,girard1 ,,kansas ,copyright1 #aibd ,haldeman-,julius ,company ,,printed ,,in ,,the ,,united ,,states ,,of ,,america ,,chemistry ,,for ,,beginners ,,contents ,,part ,i ,page ,introductory #f ,alchemy #g ,modern ,chemistry #h ,medival ,chemistry #aj ,john ,dalton #ac ,the ,atomic ,theory #ad ,the ,elements #ae ,atomic ,weights #af ,valency #ag ,the ,periodic ,law #ah ,earlier ,discoveries #bj ,analysis and ,synthesis #ba ,formul and ,equations #bb ,organic vs4 ,inorganic ,chemistry #bc ,organic ,compounds #be ,catalysis #bf ,enzymes #bg ,hormones #bg ,chemistry of the ,earth #bh ,the ,spectroscope #bi ,astro-,physics and ,chemistry #ca ,spectrum ,analysis #ca ,industrial ,chemistry #cc ,instruments of ,research #cf ,salinity of the ,oceans #cg ,the ,newer ,chemistry #ch ,radio-,activity #ci ,intra-,atomic ,energy #ci ,the ,electrical ,theory of ,matter #dj ,within the ,atom #db ,electrons #dc ,the ,nature of ,matter #dd ,,part ,,ii ,the ,elements #df ,radio-,activity #di ,the ,origin of ,life #ea ,creation of ,life #eb ,the ,ether #ec ,chemistry and ,metaphysics #ee ,,chemistry ,,for ,,beginners ,,part ,i ,the ancient ,greeks1 when they looked about them on the world in which they lived1 came to the definite conclusion that everything is in a constant state of flux1 or change4 ,things animate and inanimate gradually disintegrated and tended either to disappear 7apparently7 or to change into other forms of matter4 ,with their true sthetic sense1 they felt it necessary that there should be some one permanent thing in the world1 underlying all the changes which they saw going on about them1 and many of their early speculations were devoted to the nature and constitution of this one 8permanent thing40 ,thales1 of ,myletus1 who flourished about #ehe ,b4 ,c41 and who was1 perhaps1 the first great philosopher and physicist1 contended that the essential principle of things1--the substance1 or stuff1 of all things1--must be water4 ,he held the view that1 by condensation and rarefaction of water all things rise1 and he actually attempted an evolutionary account of the ,genesis of ,man1 ,plants and ,animals1 with this idea as a basis for his thought4 ,anaximenes said that air1 or ether1 must be the substance of things4 ,heraclitus regarded fire as the most primary element in the universe1--from which all else arises4 ,anaximander said that the 8unlimited0--a sort of boundless1 animated mass--is the ultimate substance4 ,plato1 as we know1 contended that the permanent reality of things was not anything material at all1 but was mind1 or spirit4 ,empedocles1 7#die-dce ,b4 ,c47 advanced the theory that there are four elements--,earth1 ,air1 ,fire and ,water4 ,anaxagoras contended that nothing changed of itself1 but that it is caused or made to change1 and that that which produces these changes is the permanent reality4 ,this he believed to be a sort of mind or universal intelligence 7,nous71 but he regarded this mind as strictly impersonal1 as well as immaterial1 and did not attempt to answer the difficulty as to how mind can affect matter in any detailed manner4 ,it was only natural that1 prior to the discovery of the laws of the indestructibility of matter and energy1 that this sense of 8change0 should have struck these early thinkers very forcibly1 since they had no means of ascertaining that1 when matter disappears from our sight1 it is not actually destroyed4 ,we now know that1 when we burn a candle1 the candle disappears1 but that the elements composing the candle are merely changed into invisible gaseous compounds1 which are no longer visible to the human eye4 ,lacking delicate instruments of precision1 the ancients could not know this2 to them1 the matter of the candle would have disappeared4 ,hence1 it was only natural that they should seek the ultimate reality behind these changes1 and speculate as to its origin and nature4 ,,alchemy ,the modern science of chemistry is relatively new4 ,it gradually emerged from alchemy1 which practically constituted the chemistry of the middle ages4 ,the objects of alchemy were various3 7#a7 the transmutation of the base metals into gold1 by means of the so-called 8,philosopher's ,stone02 7#b7 ,the fixation of ,mercury2 7#c7 ,the discovery of the elixir of ,life1 etc4 ,these were the purely chemical aspects of alchemy1 but we now know that the alchemists had much more than this in mind1 in their experimental work1 and that they hinted at their true meaning in many of their veiled writings4 ,many of the higher types of alchemists were also mystics1 and when they wrote in chemical symbols1 they really concealed their inner meaning2 they referred1 very largely1 to the inner spirit of man1 and the methods by which this could be changed or transformed into some higher spiritual being4 7,see 8,alchemy ,ancient and ,modern10 by ,h4 ,stanley ,redgrove2 8,alchemy1 ,its ,scope and ,romance10 by the ,rev4 ,j4 ,e4 ,mercer1 etc47 ,mr4 ,foster ,damon has lately published a series of articles in which he has brought forward a mass of evidence tending to prove that the alchemists were also deep students of psychic phenomena1 and that their experiments relative to the 8,first ,matter0 were really experiments in so-called 8,materialization60 ,he has published his findings in a series of articles in the 8,occult ,review40 ,,modern ,,chemistry ,modern chemistry may be said to begin with ,robert ,boyle 7#afbf-afia74 ,he defined an element as a substance which could not be decomposed1 but which could enter into combination with other elements1 giving compounds capable of decomposition into these original elements4 ,the number of elements which were thought to exist varied greatly1--some contending that they were but few in number1 others that they were numerous4 ,it must be remembered that all this was before the time of ,dalton1 and that the atomic theory had not yet been advanced as a scientific hypothesis1 since the days of the ancient ,greeks1 when ,democritus and ,epicurus had defended this view4 ,the swing of science1 at that time was1 therefore1 toward the materialism of those older writers1 and the atomic theories which they had then proposed4 ,chemistry is that branch of science which investigates the nature and properties of matter in all its forms4 ,it is1 perhaps1 the most materialistic of all the sciences1 since it deals essentially with matter4 ,physics deals with forces or energies1 or the energies manifested by and through matter1 but the two are more or less inter-related--especially of late years1 as we shall see4 ,chemistry is essentially an experimental science1 and practically everything which has been learned about it has been acquired by means of laboratory experimentation4 ,but here as elsewhere theories have woven together the mass of separate facts1 and of them made a consistent and philosophical science4 ,there are two main divisions of chemistry--inorganic and organic2 that is to say1 the chemistry of 8dead0 matter1 and the chemistry of 8living0 or organic substances4 ,chemical experiments may be for the purpose of analysis--discovering the constituents of a given substance2 synthesis1 in which a compound substance is 8created0 from several simpler ones2 or purely experimental1 in which certain tests are made1 and the results or rections noted4 ,,mediaeval ,,chemistry ,as before stated1 ,chemistry is more or less the direct child of ,alchemy2 but before the modern1 scientific period of chemical research had been reached1 two transitional stages were first of all passed through4 ,these were 7#a7 ,the so-called 8,iatro-,chemical0 period--the period of medical mysticism2 and 7#b7 the 8phlogistic0 period4 ,a few words will be necessary to explain each of these terms1 and the period of chemical development which they covered4 ,as may be inferred from the name1 the iatro-chemical period was one in which attempts were made to combine chemistry and medicine1 and make the former serve the latter4 ,all kinds of weird concoctions were tried1 and attempts were made to explain1 on chemical principles1 all the changes and reactions occurring in the body--an attempt which was necessarily futile for the chemistry of that day4 ,however1 many important results were achieved1 as the consequence of experimentation1 and chemical science was on the whole enriched1 even though the workers of that day were inspired by totally erroneous views4 ,the ,phlogistic ,period takes its name from a hypothetical substance denominated 8phlogiston40 ,this was supposed to be an invisible principle or entity1 constituting the basis of ,fire1 and corresponds to the 8pure fire0 of ,zoroaster4 ,the ,phlogiston theory was propounded and championed by ,stahl1 and it was defined by him as follows3 8,phlogiston is 444 a very subtle matter1 capable of penetrating the most dense substances2 it neither burns1 nor glows1 nor is visible2 it is agitated by an igneous motion1 and it is capable of communicating its motion to material particles apt to receive it4 ,the particles when indued with this rapid motion constitute visible fire44440 ,this conception dominated the whole scientific world for many years4 ,the experimental work undertaken by ,scheele and ,priestly1 however1 finally enabled ,lavoisier to discover the true nature of 8fire0--combustion4 ,in a famous 8,memoir10 published in #aghc1 entitled 8,reflections ,concerning ,phlogiston10 he showed that all the observed phenomena could be accounted for without the presence of any hypothetical phlogiston2 in fact1 as he himself says1 they 8can be better explained without phlogiston than by means of it40 ,his discovery of oxygen1 in the atmosphere1 was a fundamentally important step in modern chemical science4 ,hitherto1 the air was thought to be a single gas1 or a mixture of various gases2 but oxygen was unknown as its most important constituent4 ,lavoisier's discovery finally disposed of the phlogiston idea1 and ushered in the new era of scientific chemistry4 ,it may be thought that undue space has been devoted to this theory of ,phlogiston2 but anyone reading the history of ,chemistry will realize the extent to which this idea completely dominated the minds of men at that time1 and how all chemical researches were perverted by it4 ,the discovery of the true nature of combustion was one of the fundamental turning-points in the history of scientific thought4 ,the material world in which we live is very evidently composed of a variety of substances4 ,at least some of these were soon seen to exist in at least three different states--solid1 liquid and gaseous4 ,these seemed to differ radically from one another2 ice1 water and steam are as different as one can imagine2 and yet1 somehow1 they were the same thing after all2 for ice melts and becomes water1 and water1 when heated1 becomes steam4 ,on the contrary1 steam cools and becomes water again1 and when it is sufficiently cold1 will again form ice4 ,there must be some fundamental ,thing1 therefore1 of which water is composed4 ,what is this ,thing8 ,how many such ,things are there in the world8 ,are there a limitless number1 or only a few8 ,if a certain1 limited number1 how many8 ,and how discover them8 ,these were questions which naturally occupied the minds of men throughout the ages4 ,no answer was found1 however1 and it remained for ,john ,dalton to discover and formulate the ,law which enabled men to obtain their first glimpse of the nature of the ultimate constitution of matter4 ,,john ,,dalton ,john ,dalton 7#agff-ahdd7 was born in ,eaglesfield1 in ,cumberland 7,england71 and was the son of a poor weaver4 ,endowed with natural aptitude and an indomitable will1 he utilized all possible opportunities for the study of mathematics and natural philosophy4 ,he taught school1 while devoting all his spare time to his beloved scientific researches4 ,in fact1 he earned his living as a private teacher to the end of his life1 never having enough money to pursue his investigations unhampered by material considerations4 ,it was1 of course1 well known that mere mixtures were entirely different things from chemical compounds4 ,we can mix sand and sugar together1 but they remain sand and sugar1 and can be separated again1 having undergone no change4 ,or we can mix together two liquids or two gases1 and they also can again be separated by suitable means4 ,but when two substances chemically combine one with another1 then we have some third thing which is entirely different from the original two1 and which possesses properties dissimilar from either4 ,now1 what has happened when substances thus combine8 ,what are the laws of such combinations8 ,and what are the ultimate constituents of matter1 which render these combinations possible8 ,dalton was the first to undertake an explanation of these phenomena1 backed up by experimental evidence4 ,the historic importance of this cannot be overestimated4 ,as ,dr4 ,raphael ,meldola says1 in his 8,chemistry03-- 8,the doctrine of equivalence1 even in its most elastic form1 is still nothing more than a quantitative expression of the facts of chemical composition4 ,of course1 there must be some underlying principle--some explanation of this simplicity of multiplicity4 ,such explanation was first definitely formulated in #ahjg-jh by ,john ,dalton1 who not only discovered the law of ,multiple ,proportions1 but suggested a theory1 the introduction of which marks one of the greatest epochs in the history of ,chemistry4 ,the reason why combination takes place in definite proportions by weight1 and why1 when the same element has more than one equivalent the principle of integral multiples is maintained is1 according to ,dalton's explanation1 because the combination is between the ultimate particles of which elementary matter is composed4 ,this is the notion of the discontinuity or discreteness of matter4 ,the 8particles0 of which matter is composed--whatever its state of aggregation--are1 from ,dalton's point of view1 ultimate in the sense of being indivisible4 ,for this reason he called them atoms40 ,,the ,,atomic ,,theory ,here1 then1 we have at last the ,atomic ,theory--the theory1 that is1 that all matter1 in all its stages1 is built-up of extremely small particles which are so small1 indeed1 that they can no longer be sub-divided4 ,they are the ultimate of matter--the 8building stones of the ,universe0--of which everything1 animate and inanimate1 is composed4 ,these atoms were held to be spherical in shape1 of a certain definite weight and figure1 according to the element or substance in question4 ,thus3 8every particle of water is like every other particle of water1 every particle of hydrogen is like every other particle of hydrogen1 etc40 ,these ultimate particles--atoms--were held to be indestructible4 ,these atoms all had their own particular weights1 which might be denoted by number4 ,hence 8atomic weight40 ,these atoms1 then1 combine1 forming molecules1 or compounds of atoms2 and molecules make up matter as we see and know it4 ,further1 most of the matter in the world is composed of a variety of elementary substances1 limited in number4 ,when more complex bodies are analyzed or broken-down1 these elementary substances are always found4 ,the number of those in ,dalton's day was unknown2 but they had long been known as elements4 ,elements were1 of course1 composed of their own particular atoms2 while all other substances were made-up of combinations of elements4 ,,the ,,elements ,dalton's views ushered in a new era in chemistry4 ,prolonged researches were at once undertaken1 in order to determine the precise atomic weights--investigations which are being carried on even today4 ,the exact size1 shape1 texture1 etc41 of the atom was subject to endless investigation4 ,the nature of chemical combinations 7how two elements combine with one another7 held the fascinated attention of chemists for a hundred years1 and it is only within the past few years that a definite solution has been found1 and this has only been rendered possible by the newer views of matter1 entirely different from those maintained during the past century4 ,during the hundred years which have elapsed since ,dalton's time1 a number of new elements have been discovered1 and there are reasons for supposing that there are some yet to discover4 ,it is now believed1 however1 that there are #ib primary elements1 of which ,hydrogen has the lowest atomic weight1 and ,uranium the highest4 ,typical elements are3 ,oxygen1 ,iron1 ,fluorine1 ,silver1 ,sodium1 ,sulphur1 ,gold1 ,zinc1 ,copper1 etc4 ,a complete list may be found in any standard ,chemistry4 ,,atomic ,,weights ,when work was undertaken1 to discover the exact atomic weights of these various elements1 it was soon found that these could not be expressed in exact1 whole numbers4 ,fractions or decimal numbers were nearly always found to exist4 ,thus1 the atomic weight of ,hydrogen was not exactly #a1 but #a4jjh2 copper was #fc4eg1 etc4 ,for long it was thought that these variations were due to errors of experiment1 and renewed attempts were made to reach more accurate conclusions1 in which these apparently annoying fractions were absent4 ,but the most painstaking experimental work only served to confirm these results1 and still later researches have shown us why this is so4 ,it would take us too far afield1 however1 to go into that question at present4 ,the various elements were given symbols for the sake of brevity2 some of these represented the first letters of the name of the element2 some were the first letters of the ,latin word for that element4 ,thus1 ,co ,cobalt1 ,s ,sulphur1 ,ne ,neon1 ,bi ,bismuth4 ,on the other hand1 ,fe ,iron 7,latin1 ferrum71 etc4 ,this served greatly to abbreviate chemical language1 and at the same time simplified chemical formul and equations4 ,,valency ,we must now explain one or two terms which are extremely important for understanding what is to follow4 ,the first of these is ,valency4 ,we know that chemical combinations take place in fixed proportions by weight2 this is known as the 8,constancy of ,composition40 ,there is always an equivalence noted4 ,this doctrine of equivalence is merely the numerical expression of the definiteness of chemical change4 ,calculations are made from the point-of-view of combining with a unit-weight of hydrogen 7the ,unit element74 ,in chemical compounds1 then1 the doctrine of equivalence says that these atomic weights represent quantities of different elementary substances which are of the same chemical value as measured by their capacity for displacing the same weight of hydrogen4 ,a new property of the atom is thus brought out1 viz41 its value as measured by the number of atoms with which it can combine4 ,this property is appropriately described as the 8,valency0 of the atom4 ,if the atomic weight contains the equivalent once1 i4 e41 if the equivalent and atomic weight are identical1 that atom can combine only with one atom of hydrogen1 or of chlorine1 bromine1 etc4 ,the formul of the compounds1 ,h,cl1 ,h,br1 etc41 expresses this fact4 ,if the equivalent is contained twice in the atomic weight1 then that atom can obviously combine with two atoms of hydrogen1 chlorine1 etc42 if it is contained three times in the atomic weight1 the combining capacity or valency of the atom is three2 and so forth4 ,,the ,,periodic ,,law ,the work which had been done upon the atomic weights rendered possible one of the most brilliant generalizations of modern times1 in this field4 ,this was the ,periodic ,law4 ,in the year #ahfd1 ,newlands published a ,table containing the various elements arranged in the order of their atomic weights4 ,in a side column the differences between these weights were given1 each being deducted from the one next higher in the scale4 ,the next year1 ,newlands announced his 8law of octaves10 which he deduced from his arrangement of the elements4 ,he said in part that3 8,if the elements are arranged in the order of their equivalents1 with a few slight transpositions 444 it will be observed that elements1 belonging to the same group usually appear on the same horizontal line4444 ,it will also be seen that the number of analogous elements generally differ either by seven or by some multiple of seven2 in other words1 members of the same group stand to each other in the same relation as the extremities of one or more octaves in music40 ,this pioneer work of ,newlands rendered possible the ,periodic ,law1 as finally formulated and worked out in detail by ,mendeleeff4 ,briefly1 the ,law states that 8the properties of an element are a periodic function of its atomic weight40 ,this is merely another way of saying that if you know the atomic weight of an element1 you also know its properties1 since these are fixed or invariable4 ,mendeleeff arranged the elements in various 8,groups10 according to their atomic weights1 and it was found that the properties of the elements periodically recur as the weights of the atoms rise4 ,there were certain empty spaces in ,mendeleeff's ,table1 waiting for new elements which should fit into these empty spaces1 if discovered4 ,at the time they had not been discovered2 but several of them have been since1 and it is a remarkable fact that they invariably fit into his table exhibiting all the properties which they should theoretically exhibit1 and might have been predicted to1 years before4 ,this is one of the surest confirmations of the accuracy of ,mendeleeff's general ,law1 and is one of the finest generalizations ever made in science4 ,the conclusion which we may draw from this ,law is that there is a definite relationship between the chemical elements4 ,how or why this relationship existed was not known at the time1 and only became clear half a century later1 when the newer discoveries concerning the ultimate constitution of matter rendered this clear4 ,,earlier ,,discoveries ,mendeleeff's ,law could not have been formulated had not an immense amount of research work preceded it1 and a number of new elements been discovered4 ,such was1 however1 the case4 ,immediately following the great work of ,lavoisier1 a host of brilliant chemists appeared1 and rapid and important advances were made in consequence4 ,cadmium was discovered by ,stromeyer in #ahag2 lithium in the same year by ,arfvedson4 ,silicon was isolated in #ahaj by ,berzelius4 ,in #ahbg1 ,wohler isolated aluminum2 and the same scientist also isolated beryllium the following year4 ,bromine was discovered by ,balard in #ahbf2 iodine1 in #ahaa1 by ,courtois4 ,tellurium had been discovered by ,muller von ,reichenstein in #aghb2 ,berzelius discovered an element closely analogous to it--selenium--in #ahag4 ,elements continued to be added to the list--and then no more6 ,had every element been discovered8 ,some were inclined to think so4 ,with the discovery of ,radium1 by the ,curies1 however1 another whole list of elements was brought to light--all of which have been added to the ,table of the ,periodic ,law4 ,meanwhile1 further discoveries of the curious properties of matter were being made4 ,for example1 it had been noticed that at least three distinct varieties of sulphur existed3 7#a7 ,a pale yellow1 brittle solid2 7#b7 translucent needles2 and 7#c7 soft and rubber-like sulphur4 ,these were all different physical varieties of one and the same substance--nevertheless they are all sulphur6 ,this element1 then1 can assume more than one form1 and because of this1 the term 8allotropic0 has been applied1 to signify the varieties of appearance which the same substance can be made to assume4 ,a good example of this afforded by charcoal1 graphite 7or black-lead7 and diamond1--which would hardly be suspected of being all the same substance2 and yet they are6 ,,analysis ,,and ,,synthesis ,compounds may be broken up into their constituents1 during the process of analysis1 or they may be made to combine one with another1 in synthesis4 ,all the resources of modern science have been brought to bear1 in efforts to effect these various alterations or changes4 ,great heat1 extreme cold1 chemical regents1 enormous pressures1 high vacua1 electrical currents and sparks1 bombardment with radio-activity1 etc4--all have been employed in these chemical investigations4 ,suitable laboratories have been constructed1 encasing immense boilers1 huge refrigeration machines1 electrical contrivances of all kinds1 etc4 ,what tremendous strides have been made in this field during the past century--from the simple glass retorts1 flasks and apparatus of a century ago6 ,but this only shows us how tremendous would be our progress could men but learn to work together1 in harmony1 welded together by a common interest1--instead of butchering one another1 or wasting their precious lives and energies in scandals and political intrigues6 ,but let us return to earth again--to matter--the subject of chemistry6 ,,formulae ,,and ,,equations ,we have seen that the various chemical elements combine with one another in certain proportions4 ,in order to express these varied reactions1 chemical formul have been devised1 which can be read at a glance1 showing the changes which have taken place in any given combination4 ,when one atom of one element combines with one atom of another1 the letters signifying these elements are simply written side by side1 thus3 ,h,cl4 ,when1 however1 two atoms of one element combine with one of another1 a small figure is placed under and to the right of the element1 thus3 ,h,o4 ,here we see at a glance that two atoms of hydrogen have combined with one of oxygen1 forming water4 ,this is the simplest type of formula1 and is often known as the empirical formula4 ,there is1 however1 another way of writing a formula1 which is more expressive1 thus3 ,b ,a,c ,b ,this is known as a structural or constitutional formula1 and from it we can see at a glance that ,a is bivalent1 ,c is quadrivalent1 and ,b univalent4 ,this type of formula shows us more readily than the other the structure of the molecule in question4 ,the complexity of such formul naturally increases with the complexity of the molecules1 and in many cases may be extremely intricate4 ,ordinary chemical formul1 however1 are written empirically4 ,any chemical changes which take place as the result of some reaction are expressed in this manner4 ,,organic ,,vs4 ,,inorganic ,,chemistry ,as before stated1 chemistry has been divided into two categories--organic and inorganic4 ,it was stated at the time that these divisions represented the chemistry of living and dead matter1 respectively4 ,as a matter-of-fact1 this description is not quite accurate4 ,this was the older view of the observed facts1 because it was believed that some mysterious 8vitality0 was responsible for the peculiar substances found in living bodies1 but the chemist has now succeeded in making1 in the laboratory1 a number of these substances which were thought to be the result of life only2 and in addition has succeeded in making great numbers of organic compounds not found in the living body4 ,over #aej1jjj 8organic0 compounds are now known to the chemist1 only a small fraction of which are known to be the product of 8vitality40 ,all living things--animal and vegetable--contain carbon1 as their most important constituent1 so that the modern view of organic chemistry is that it is1 very largely1 the chemistry of carbon compounds4 ,whether or not any form of 8vitality0 exists aside from the living matter studied is a question usually passed over by chemists as beyond their province4 ,there is no doubt1 however1 that the human body presents many problems still unexplained by modern chemistry4 ,take1 for example1 the miracle of digestion4 ,a potato1 a cabbage1 an apple1 a chicken running about the yard1 a piece of candy--all these are eaten by little ,mary ,jones1 and are somehow turned into the body of little ,mary ,jones1 making hair1 teeth1 eyes1 lungs1 liver1 nerves1 brain1 etc4 ,the food material is somehow transformed into the living body of the person eating it6 ,much has been discovered as to the innumerable changes which the food undergoes during the various stages of digestion1 but the final result--how this pabulum is converted into bodily tissue--is still largely a mystery4 ,we know1 for example1 that proteins are broken-up into simpler compounds1 the most important of which are the amino-acids4 ,fats are broken up into fatty acids and glycerine1 and substances resembling soaps are formed in the body4 ,carbohydrates are resolved into levulose1 glucose1 maltose1 etc41 which are utilizable by the human system4 ,but just how these substances are converted into bodily tissue is still largely a problem4 ,,organic ,,compounds ,the living matter of the body is composed of a variety of substances1 of which protoplasm may be taken as typical4 ,this is highly complex1 and while it can be imitated by the chemist1 its living properties have not been reproduced4 7,see my book on 8,life3 ,its ,origin and ,nature10 in the present series47 ,the various secretions and excretions of the body have been studied exhaustively by physiological chemists4 ,plants have also been studied minutely from a similar point-of-view4 ,a number of important discoveries have resulted from this work1 however1 and nearly all the essential animal and vegetable substances are at present accessible to artificial synthesis from their very elements4 ,even protein matter seems to have lost much of its mystery since we have learned from ,emil ,fischer's work that amino-acids can be combined in the same way as they occur in protein4 ,compounds of ,amino-acids can be obtained1 which show all the main reactions of protein substances4 ,emil ,fischer1 of ,berlin1 was the same chemist who1 in #ahhf1 discovered how to prepare grape-sugar from glycerine4 ,a considerable number of plant alkaloids have also been artificially prepared in the course of the last five or six decades4 ,the most important coloring matters of plants--for instance1 alizarin and indigotin1--are no longer extracted from plants for technical purposes1 but are accessible from the products of coal-tar4 ,,catalysis ,we now come to a remarkable series of chemical phenomena1 which have been much studied during the past century1 and which have a bearing upon both organic and inorganic chemistry4 ,more than a century ago1 it was discovered that certain chemical substances1 which will not normally combine with one another1 can be made to do so1 if another substance is brought into contact with them4 ,this third substance does not in any way enter into the combination1 or share in the reaction2 its mere presence seems to bring it about4 ,thus1 oxygen and hydrogen may be mixed together2 but if a small amount of 8platinum black0 be introduced1 an explosion of the gases at once occurs4 ,hydroperoxide is rapidly split into oxygen and water when in contact with 8platinum black10 etc4 ,these contact-effects are very curious1 and have engaged the attention of chemists for a long time4 ,berzelius is responsible for the term now generally used--catalysis4 ,we now speak of catalytic power1 catalytic reactions1 and so forth4 ,these catalytic rections soon became very important factors in organic chemistry and biology1 as well as in the field of inorganic chemistry4 ,in #ahcc1 ,payen and ,persoz in ,paris made the discovery that germinating seeds contain a peculiar contact-substance1 which transforms starch into sugar4 ,this substance they named ,diastase4 ,similar effects were noted to occur elsewhere1--particularly in the protein digestion in the stomach of man and the higher animals4 ,we now know that many such rections occur in the living cells1 and the chemical phenomena of life have had an entirely new light thrown upon them by these findings4 ,,enzymes ,they led1 in short1 to the discovery of the so-called ,enzymes4 ,until relatively recently1 the expression 8,ferment0 was used1 as the phenomena were akin to fermentation4 ,soluble ferments are termed ,enzymes1 and the phenomena connected with living protoplasm are now known to be largely due to the action of a group of ,enzymes4 ,these are catalytic substances1 are of a limited field of action1 of colloidal nature1 and very little resistant to heat4 ,when injected into the veins of animals1 other substances are at once manufactured1 which have been called 8anti-enzymes10 which have the effect of offsetting their action4 ,sunlight and ultra-violet light destroy enzymes4 ,their importance in the field of biology may be discerned when it is stated that researches have shown us that1 e4 g41 the amount of protein digested in a certain time is not proportional to the quantity of the enzyme itself1 but to the square root of the quantity of the enzyme4 ,,hormones ,these enzymes must not be confused with other internal secretions1 such as the hormones4 ,these are substances generated by the so-called ductless glands1--such as the thyroid1 the pituitary1 the adrenals1 etc4 ,these ductless glands secrete substances which when absorbed into the blood-stream greatly affect the life of the body1 its functions1 its structure and its growth1 and to a certain extent at least the mental life4 ,researches in this field are of relatively recent origin1 but of extreme importance4 ,i have mentioned this subject at greater length in my little book on 8,life3 ,its ,origin and ,nature10 in the present series1 and the interested reader may refer to such a work as ,dr4 ,louis ,berman's 8,the ,glands ,regulating ,personality10 for further details4 ,there is no matter anywhere in the universe1 living or dead1 which modern chemistry does not attempt to analyze4 ,not only in the laboratory are these tests undertaken1 with minute particles of matter4 ,the very earth on which we dwell has been subjected to chemical analysis1 and so have the stars1 the planets and suns which circle around us in space1--perhaps separated from us by many millions of miles4 ,the ability to do this is assuredly one of the greatest achievements of the mind of man1 and represents one of the greatest conquests over nature1 over time and space4 ,,chemistry ,,of ,,the ,,earth ,the water constituting our seas1 lakes1 rivers and oceans2 the air constituting our atmosphere2 the materials of the earth on which we dwell--clay1 rock1 mud1 granite1 metals--all have been analyzed1 and their chemical composition accurately determined4 ,it has even been possible to measure the density and weight of our earth1 and to calculate its age1 from the salinity of its oceans4 7,of this more anon47 ,but when it comes to ascertaining with great accuracy the chemical constitution of distant stars1 that seems a feat well-nigh impossible1 and unless the process by means of which it is accomplished were explained1 it might very well be disbelieved4 ,how1 then1 can this be accomplished8 ,for our explanation1 we must go back to a classical experiment made by ,sir ,isaac ,newton4 ,he proved that white light1 when made to pass through a glass prism1 is split up into a variety of colors4 ,there are seven primary colors1 constituting the visible spectrum4 ,these are red1 orange1 yellow1 green1 blue1 indigo and violet4 ,we now know that there are both 8ultra-violet0 and 8infra-red0 rays1 invisible to the eye1 above and below the spectrum1 but this was not known until long after4 ,the essential fact is that light1 when passed through a prism1 is split up into its primary colors4 ,,the ,,spectroscope ,the instruments employed were necessarily soon refined1 and the modern 8spectroscope0 resulted1--a piece of apparatus of great delicacy1 capable of studying these effects with exactitude4 ,the function of the spectroscope is to receive a sample of light and to separate its different components4 ,in a broad sense1 everything that can be seen has a spectrum--flame1 blue sky1 red hot metal1 the sun1 the electric spark1 etc4 ,we can at once divide these things into two classes1 7#a7 those that are visible because they emit light of their own2 7#b7 those that can be seen only by virtue of their reflecting1 diffusing or transmitting light that falls upon them from other sources4 ,the former are called 8emission spectra0 and the latter 8absorption spectra40 ,now1 when practically any spectrum be examined in this way1 it will be seen that certain bands of shadow1 or dark lines1 cut across the light spectrum1 in absorption spectra1 these are the things which are studied4 ,thus1 when we observe the spectrum of the sun1 or of many of the stars1 we find that the spectrum may be described as a continuous spectrum1 from which a number of narrow lines are omitted4 ,the lines consequently appear dark on a bright ground4 ,these are called 8absorption lines40 ,just why these dark lines appear would take us too far afield to explain here2 suffice it to say that every chemical element has been found to yield a different spectrum2 that is to say1 the number and arrangement of these dark lines will indicate the presence of the element in question4 ,whenever certain lines appear on the spectrum1 we may be sure that such-and-such an element is present4 ,thus1 ,kirchhoff first proved that two of these dark lines were caused by the white light of the solar photosphere having suffered absorption at the sun1 by passing through a stratum of glowing sodium vapor4 ,sodium was thus shown to be present in the sun4 ,other elements were similarly identified1 not only in the sun1 but in the millions of stars in the heavens4 ,by means of spectrum analysis1 therefore1 it has been possible to detect and identify the various chemical elements present in any given sun or star in space4 ,,astro-,,physics ,,and ,,chemistry ,in this manner1 about forty terrestrial elements have been shown to exist in the sun4 ,carbon1 oxygen1 iron1 silicon1 nickel1 etc41 exist in the sun just as they do on our earth4 ,on the other hand1 many elements1 such as mercury1 nitrogen1 sulphur1 and boron do not appear1 although they are found in abundance on the earth4 ,yet several elements were shown to exist in the sun which up to that time had not been discovered here4 ,helium is an example4 7,from the ,greek1 ,helios1 the ,sun74 ,and yet1 when attention was directed to this element1 it was soon found in our earth1 and is today so common that helium gas is employed to inflate balloons1 in preference to hydrogen1 on account of its non-combustibility4 ,,spectrum ,,analysis ,spectrum analysis1 then1 tells us the precise chemical constitution of the various suns1 or stars1 in space1 and it also tells us that these stars are incapable of supporting life such as we know it4 ,as ,dr4 ,e4 ,walter ,maunder says1 in his book1 8,are the ,planets ,inhabited803 8,the application of the spectroscope to astronomy is not confined to the sun1 but reaches much further4 ,the stars also yield their spectra1 and we are compelled to recognize that they also are suns2 intensely heated globes of glowing gas1 rich in the same elements as those familiar to us on the ,earth and known by their spectral lines to be present on the sun4 ,the stars1 therefore1 cannot themselves be inhabited worlds any more than the sun1 and at a stroke the whole of the celestial luminaries within the furthest range of our most powerful telescopes are removed from our present search 7i4 e41 whether or not life may exist upon them74 ,only those members of our solar system that shine by reflecting the light of the sun can be cool enough for habitation1 the true stars cannot be inhabited1 for1 whatever their quality and order1 they are all suns1 and must necessarily be in far too highly heated a condition to be the abode of life4 ,many of them may1 perhaps1 be a source of light and heat to attendant planets1 but there is no single instance in which such a planet has been directly observed2 no dark1 non-luminous body has ever been actually seen in attendance on a star4 ,many double or multiple stars are known1 but these are all instances in which one sun-like body is revolving round another of the same order4 ,we see no body shining by reflected light outside the limits of the solar system4 ,planets to the various stars may exist in countless numbers1 but they are invisible to us44440 ,thus has the science of chemistry been wafted across hundreds of millions of miles of space1 and has enabled us to tell1 not only the composition of these distant bodies1 but also the degree of their habitability1 and their possible sources as abodes of life4 ,,industrial ,,chemistry ,but if all this is of purely theoretical interest1 the chemistry of our earth and its products is of immense practical importance4 ,it may be applied1 and the day of 8industrial chemistry0 is here4 ,by studying the chemistry of soils1 the farmer has been enabled to increase both the quality and the quantity of his crops4 ,by employing artificial fertilizers1 production has been greatly increased4 ,an analysis of the earth's strata has thrown great light upon geology4 ,analytical chemistry has proved of service in criminology1--by enabling experts to detect poisons1 blood-stains1 etc4 7,unfortunately1 it has also been applied detrimentally1 in the manufacture of explosives1 poison gases1 etc41 employed in war47 ,dentistry and surgery have been rendered painless by the discovery of ansthetics4 ,the wholesale manufacture of illuminating gas has been instrumental in lighting millions of homes4 ,the manufacture of steel1 paper1 ink1 dyes1 stains1 paints1 perfumes1 bread1 and a thousand-and-one useful articles of our daily lives has been rendered possible by the progress of chemical research4 ,artificial preservatives have enabled us to keep food-stuffs for long periods of time4 ,by the discovery of the nature of iron rust1 bridges1 buildings1 etc41 have been preserved intact4 ,our food1 our clothes1 our very lives themselves1 may be said to depend upon modern chemistry for their maintenance and preservation4 ,let us pass in rapid summary a few of these results4 ,let us take1 for example1 glass4 ,glass is made from silica4 ,what is silica8 ,it is a substance of remarkable infusibility1 and is the oxide of silicon1 which is a near neighbor of carbon4 ,glass is made by mixing sand1 limestone and carbonate of soda or potash in large pots1 and melting them together at a temperature of #c1ejj ,f4 ,the sand1 being silica1 combines with the lime of the carbonate of lime1 to give silicate of lime1 and with the soda 7or potash7 of the carbonate of soda 7or potash7 to give silicate or soda 7or potash74 ,these two silicates become intimately fused and form the glass1 which remains liquid in the pot4 ,it is then blown into various shapes or rolled into thin sheets for window glass4 ,we know what an effect windows have had upon the comforts of modern life6 ,by mixing together several metals1 alloys are obtained which very often have properties quite different from those of the substances which compose them4 ,thus3 ,bronze is a mixture of copper and tin2 plumber's solder is an alloy of lead and tin2 brass is an alloy of copper and zinc2 ferro-silicon is a union of silicon and iron1 etc4 ,many of these alloys are of great utility in the various arts and sciences1 as well as in manufacture4 ,gilding1 silvering and electroplating have been rendered possible by modern chemistry4 ,alumina and porcelain have been produced4 ,alumina is the oxide of aluminum4 ,one variety of clay known as 8kaolin0 is employed in the manufacture of porcelain4 ,china and earthenware are made by very similar processes4 ,alcohol1 wine and beer have depended upon scientific chemistry for their production4 ,ice can be manufactured artificially by means of freezing mixtures4 ,the manufacture of oxygen gas has rendered possible high altitude flights by aviators4 ,camphor can now be manufactured1 instead of depending upon nature's resources for this valuable substance4 ,wood-pulp1 starch and sugar owe much to modern chemistry4 ,artificial silk is manufactured on a large scale4 ,soaps and fats have likewise been developed in vast quantities4 ,the perfume milady uses has been developed by the chemist4 ,colors and dyes now constitute an enormous industry4 ,for our medicines we depend upon the chemist1 when visiting the nearest drug store4 ,these are but a few examples1 which might be lengthened almost indefinitely1 illustrating the extent to which we are dependent upon modern chemistry1 in our daily lives4 ,and chemistry is capable of explaining many things which would be unintelligible without its aid4 ,let us take a simple example by way of illustration4 ,you have probably noticed that a frozen potato has a characteristic sugary taste4 ,the cause of it is this3 the potato contains in its tissues a great quantity of starch1 as well as a diastase capable of transforming this starch at the moment of its sprouting4 ,these two substances are kept apart by the membrane of the tissue4 ,but if a frost occurs1 the ice tears this membrane1 and the starch comes in contact with this diastase and is1 therefore1 transformed into sugar1 just as it is when the sprouting of the potato begins4 ,,instruments ,,of ,,research ,these applications of chemistry have been rendered possible by improved methods of investigation1 a greater knowledge of the nature of matter itself1 and the perfection of scientific instruments of precision4 ,these instruments are so much finer and more delicate than our senses that they have been the means of disclosing the actual constitution of matter4 ,a man might sit and 8meditate0 upon the nature of matter for years1 but he would be no nearer an actual proof as to its constitution than he was at the beginning4 ,it is generally conceded that ,aristotle possessed one of the finest minds the world has ever known2 yet any school boy today knows more of the ultimate constitution of matter than did ,aristotle4 ,the reason for this is that instrumental methods of research have enabled us to see and measure the ultimate properties of matter1--which our unaided senses would never permit us to do4 ,the development of science in other fields1 therefore1 has rendered possible the rapid growth of chemistry1 during the past century2 and chemistry1 in turn1 has assisted the other sciences4 ,thus does all knowledge work hand in hand1 when co-operation is rendered possible6 ,,salinity ,,of ,,the ,,oceans ,i referred some time ago to the calculations which had been made as to the age of the earth1 based upon researches as to the salinity of the ocean4 ,as we know1 the water of all the oceans is salt water2 only that of rivers and lakes is 8fresh40 ,but the degree of the ocean's saltness is not quite constant4 ,it varies1 since evaporation is constantly taking place2 sediments are deposited2 and above all vast quantities of water are being poured into the ocean by the hundreds of rivers which flow into it1 carrying all kinds of earthy deposits which have been washed away by their passage through the river-beds over which they flow4 ,in #agae1 the famous astronomer ,edmund ,halley published a paper entitled 8,a ,short ,account of the ,saltness of the ,ocean4444 ,with a ,proposal by ,help ,thereof to ,discover the ,age of the ,world40 ,no definite progress was made1 however1 until #ahii1 when ,joly pointed out that of the many elements which enter into the composition of salt water1 sodium alone tends to accumulate4 ,all the others are sooner or later rejected1 associating themselves with the detrital sediments1 or forming chemical or organic sediments by their ultimate precipitation4 ,he accordingly used sodium as the index of the age of the oceans4 ,he assumed that the annual increase of sodium has been more or less constant1 being added to every year by the quantity washed into the ocean by the rivers4 ,how long a period of time would it require to reach its present degree of saltness8 ,taking all the oceans as one1 the volume of the ocean is approximately #cbj1jjj1jjj cubic miles4 ,its density 7according to ,murray7 is #a4jbf4 ,on the basis of these figures1 ,joly1 and after him ,sollas and others1 calculated that it would require from #hj to #aej million years for the present degree of salinity to be reached4 ,ninety or a hundred million years would be a fair estimate4 ,indirectly therefore1 the study of the salinity of the oceans has thrown light upon the age of our earth1 and its chemical constitution throughout geological ages4 ,,the ,,newer ,,chemistry ,it will be seen1 therefore1 that chemistry has not only proved of the utmost practical value to mankind1 but that it has been instrumental in solving some of the greatest enigmas confronting the mind of man1 and in settling some philosophical and even theological questions4 7,the age of the earth1 the composition and habitability of distant stars1 etc47 ,attempts have been made to account for life itself along purely physico-chemical lines4 ,and all this was attempted--and in part even rendered possible--before the ultimate constitution of matter was known6 ,during the present generation1 an entirely new light has been thrown upon this central problem1 and the ideas of centuries have been discarded4 ,let us trace the final steps of research in this direction1 and see how the latest findings of modern science have thrown light upon the world-old problem of the ultimate constitution of matter4 ,,radio-,,activity ,we saw at the very beginning of this little book that1 from time immemorial1 something corresponding to ,atoms were regarded as the ultimate 8building stones0 of the universe--tiny particles1 incapable of diversion1 beyond which it was impossible to go4 ,beginning with ,epicurus and ,democritus1 this idea took scientific form2 it was held by many philosophers throughout the ages2 it formed the basis of ,dalton's atomic theory1 and was assumed by the ,periodic ,law4 ,it was not until the last years of the preceding century that this idea was called into question4 ,the discovery of radium1 by the ,curies1 caused a sensation in the scientific world4 ,how account for the phenomena observed8 ,radium seemed to give off energy continuously1 without losing any2 heat was constantly being radiated without lessening the original amount4 ,had the secret of perpetual motion been discovered8 ,what was happening8 ,the discovery of other radio-active elements only tended to increase the problem1 instead of solving it4 ,here was some new property of matter1 hitherto unsuspected1 going on before the eyes of chemists1 which they could not understand or explain4 ,,intra-,,atomic ,,energy ,professor ,e4 ,rutherford1 of ,m',gill ,university1 ,canada1 was among the first to propose a new and startling theory4 ,he said3 ,suppose that the atoms are not indivisible8 ,suppose that they are capable of being split-up into something still smaller and finer8 ,if the atoms themselves are being disintegrated1 immense quantities of energy would probably be available--8intra-atomic energy0--which would account for the results obtained4 ,it is true that we should no longer have our stable atoms2 they would vanish and be represented by something else4 ,and that 8something0 would no longer be matter1 in the sense that we now understand it2 but we could account for the observed facts 7radio-activity1 etc471 and we can then endeavor to discover what atoms are resolved into later on4 ,this theory was soon proved to be true2 atoms were shown to be divisible1 and capable of being split-up into something still smaller1 which were no longer 8matter0 in the old sense4 ,matter1 in short1 had technically disappeared1 and had been resolved into its component parts4 ,this being so1 the question at once arose3 ,of what is matter 7the atom7 composed8 ,,the ,,theory ,,of ,,matter ,without going into great detail1 or attempting to trace the history of the various discoveries which led up to it1 it may now be stated definitely that matter is built-up of electricity4 ,for the proof of this1 the scientific world has to thank ,sir ,j4 ,j4 ,thomson1 who first popularized this view in his book 8,electricity and ,matter40 ,he was closely seconded by ,sir ,oliver ,lodge1 ,sir ,william ,crookes1 and many other eminent scientists4 ,on this view1 matter totally disappears1 as such2 it becomes super-sensible2 it is resolved into energy4 ,electricity and the ether somehow are responsible for matter1 but just how was not at the time understood4 ,it took many years of patient research to arrive at definite conclusions2 in fact1 it may be said that definite conclusions have not even yet been reached1--though more or less unanimity of opinion exists as to the structure of atoms4 ,the new theory of matter is that each atom is built up of negative 8electrons10 and positive 8protons0--the former revolving round the latter in orbits analogous to those of our solar system4 ,the protons1 positively charged1 remain in the center of the atom2 the electrons1 negatively charged1 circle about them1 just as our planets circle about the sun4 ,the number of these protons and electrons varies according to the nature of the element4 ,hydrogen representing unity1 has but one electron revolving around a single proton2 helium comes next1 with two2 and so on1 up the scale1 until we reach uranium1 which has ninety-two4 ,the positive and the negative charges balance one another in all stable atoms2 and when this is not the case1 the atom tends to go to pieces or disintegrate2 electrons are shot off1 which join some other atom1 and radio-activity results4 ,the nature of the element itself is accordingly changed1 and may even be so fundamentally changed by this process that it turns into something else2 i4 e41 the transmutation of one element into another has taken place1 as dreamed of by the alchemists6 ,hence we often hear of the 8new alchemy40 ,this1 in rough outline1 is the modern conception of the atom1 and of the constitution of matter generally4 ,,within ,,the ,,atom ,let us now endeavor to analyze the atom more closely1 in the light of these newer researches4 ,we have seen that the electrons revolve round the central protons4 ,these protons are probably composed of electrons and hydrogen nuclei4 ,the total central 8sun0--to use the astronomical analogy--is known as the nucleus4 ,the relative sizes of these bodies may be appreciated when it is stated that they have been compared to the sizes of the planets1 relative to the distances separating them from the sun4 ,vast spaces exist1 therefore1 within the atom1 in which the electrons revolve4 ,yet the atoms themselves are inconceivably small6 ,the following quotation from ,bertrand ,russell's 8,a4 ,b4 ,c4 of ,atoms0 will perhaps make this clear4 ,he says3 8,it will help us to picture the world of atoms if we have1 to begin with1 some idea of the size of these units4 ,let us begin with a gramme of hydrogen 7#a_/dec of a pound71 which is not a very large quantity4 ,how many atoms will it contain8 ,if the atoms were made up into bundles of a million-million1 and then into a million-million of these bundles1 we should have about a gramme and a half of hydrogen4 ,that is to say1 the weight of one atom of hydrogen is about a million-millionth of a million-millionth of a gramme and a half4 ,other atoms weigh more than the atom of hydrogen1 but not enormously more2 an atom of oxygen weighs sixteen times as much1 an atom of lead rather more than #bjj times as much4 ,per contra1 an electron weighs very much less than a hydrogen atom2 it takes about #a1hej electrons to weigh as much as one hydrogen atom40 ,,electrons ,the inner rings of electrons give rise to ,x-rays when they are disturbed1 and it is chiefly by means of ,x-rays that their constitution is studied4 ,the nucleus itself is the source of radio-activity4444 ,the most complex atom known is that of uranium1 which has1 in its normal state1 #ib electrons revolving round the nucleus1 while the nucleus itself probably consists of #bch hydrogen nuclei and #adf electrons4444 ,under normal conditions1 when the hydrogen atom is unelectrified1 the electron simply continues to go round and round the nucleus1 just as the earth continues to go round and round the sun4 ,the electron may move in any one of a certain set of orbits1 some larger1 some smaller1 some circular1 some elliptical4 ,but when the atom is undisturbed1 it has a preference for the smallest of the circular orbits1 in which the distance between the nucleus and the electron is about half a hundred-millionth of a centimetre4 ,it goes round in this tiny orbit with very great rapidity2 in fact its velocity is about a hundred-and-thirty-fourth of the velocity of light1 which is #ahf1jjj miles a second4 ,thus the electron manages to cover about #a1djj miles in every second4 ,to do this1 it has to go round its tiny orbit about seven thousand million times in a millionth of a second2 that is to say1 in a millionth of a second it has to live through about seven thousand million of its 8years06 ,such figures1 such facts1 stagger the imagination4 ,the mind of man cannot really conceive them4 ,and yet we know that they are not fanciful2 calculations and indirect measurements have been made with the utmost exactitude4 ,and1 after all1 the infinitely little is no more staggering than the infinitely great4 ,for in astronomy we know that stars billions of miles distant from us in space have been seen1 measured1 photographed and analyzed4 ,tens of thousands of 8light-years0 separate us from them 7i4 e41 space which would be travelled by light1 speeding at #ahf1jjj miles a second74 ,and yet the structure of the atom closely resembles the planetary system6 ,is the whole ,universe1 great and small1 built according to the same plan1 according to the same model8 ,it would appear so6 ,it will be seen from the above that the modern science of chemistry overlaps other sciences in many directions--physics1 biology1 astronomy1 etc4 ,these sciences are to a certain extent now inter-woven and inter-blended4 ,where the one ends and the other begins it is hard to say4 ,again we see the importance of co-operation in these various fields of inquiry6 ,,the ,,nature ,,of ,,matter ,these newer researches in chemistry have finally enabled us to realize the ultimate constitution of matter2 we have seen that it is composed of atoms1 but these atoms themselves are complex things2 they in turn are composed of electrons1 and in the last analysis matter may be said to be non-existent6 ,it has been resolved into electricity4 ,but this conception of matter has also enabled us to explain many things before inexplicable--chemical combination1 radio-activity1 and what not4 ,the world-old problem as to the nature of matter has at last been solved4 ,it now devolves upon the physicist to explain the ultimate nature of electricity6 ,matter1 then1 in a sense1 can dissociate1 disintegrate1 dematerialize4 ,it can also integrate1 materialize1 come into existence4 ,matter can be made to vanish and reappear4 ,the old law of the 8indestructibility of matter0 is not valid1 as generally understood4 ,matter can be resolved into energy4 ,and this energy is radiated into space1 or converted into other modes of energy1 and finally into heat1 which is in turn radiated into the surrounding medium4 ,the whole universe seems to resemble a clock1 which has been wound-up1 and is slowly running down4 ,even the law of the 8conservation of energy0 has been called into question 7,see ,le,bon1 8,the ,evolution of ,matter10 and 8,the ,evolution of ,forces074 ,is the whole ,universe in some mysterious manner also being wound-up8 ,or does it move in vast cycles1 of alternate action and inaction1 as the ,hindu philosophers have always contended8 ,these are ultimate questions which only the science of the future can solve6 ,,part ,,ii ,we have now made a rapid survey of the history of chemistry1 and traced the evolution of thought which has rendered possible the newer conceptions of the constitution of matter4 ,we must now say a few words as to the nature of the various elements themselves1 and give a brief account of some modern researches4 ,a few practical hints as to experiments may also be of interest to the reader4 ,we have seen that when two chemical elements combine1 some third substance is formed1 quite different in properties from the original two4 ,thus1 water seems to us entirely different from the two invisible gases which compose it--oxygen and hydrogen4 ,yet a simple experiment will prove that such is the case4 ,we can decompose water by means of an electric current1 when the original gases are given off1 in the proportion of two to one--hydrogen collecting at the negative pole1 and oxygen at the positive4 ,this process can be kept up until all the water has been decomposed1 and only hydrogen and oxygen gases remain4 ,this process of electrical decomposition is known as electrolysis4 ,,the ,,elements ,hydrogen is the lightest of all gases1 and1 as we have seen1 the simplest of the elements1 in its constitution4 ,like all gases1 it can be liquefied1 and even frozen solid into a hard lump1 like ice4 ,on the other hand1 even the densest of substances can be liquefied1 and even turned into gas or vapor at a sufficiently high temperature4 7,gases are rendered liquid or solid at a very low temperature47 ,liquid air1 for example1 is so cold that when a can of it is set upon a block of ice the liquid air boils and gives off 8steam06 ,oxygen gas constitutes about one-fifth of our atmospheric air 7the other four parts being nitrogen7 and is the most essential element in supporting life4 ,without it1 life would at once become extinct4 ,all forms of combustion take place very rapidly in oxygen1 and the combustion going on within the human body is no exception to this rule4 ,the atmospheric nitrogen acts as a sort of dilutant1 being an inert gas4 ,if a mouse be placed under a jar of pure oxygen gas1 it will often run round and round until it drops dead with exhaustion4 ,in an atmosphere of pure oxygen1 we should soon burn up1 and live our lives too rapidly4 ,oxygen has a great tendency to combine with various other elements1 particularly metals4 ,thus1 iron rust is due to the combination of oxygen with iron2 the blackening and tarnishing of cooking pots is due to the slow oxidation of copper1 etc4 ,in breathing1 we take in oxygen from the air1 which combines with the gases in the lungs1 forming carbon dioxide4 ,curiously enough1 plants thrive upon this gas1 which is so poisonous to human beings1 and in turn give off oxygen4 ,hence the value of plants and flowers in the room1 or in any densely inhabited area4 ,nitrogen is a very important element1 entering into many chemical combinations4 ,it forms the basis of explosives1 used in war4 ,until relatively recently1 this element had to be obtained from substances dug out of the ground1 but during the late war1 methods were devised for obtaining it from the air4 8,nitrogen fixation0 became possible4 ,if it had not been for this discovery1 ,germany would have had to give up the war in #aiaf1 at the latest4 ,nitrogen combines with hydrogen1 to form ammonia2 with oxygen and water1 to form nitric acid2 with nitric acid and potash to form gunpowder1 etc4 ,certain oxides combine with water1 to form what are known as bases4 ,bases can combine with acids1 giving rise to salts4 ,carbon is an essential element for all living matter2 it combines with oxygen1 to yield carbonic acid2 with hydrogen1 giving rise to a great number of compounds1 such as benzene1 turpentine1 etc4 ,marsh gas1 illuminating gas1 acetylene1 etc41 are compounds of carbon4 ,chlorine is a very important element1 combining with sodium to form common salt4 ,as we have seen1 the saltness of the sea is due to this substance4 ,owing to its great affinity for hydrogen1 chlorine decomposes water1 setting free oxygen4 ,the result of this is that a mixture of chlorine and water has strong bleaching qualities4 ,chlorine also combines with hydrogen to form hydrochloric acid4 ,on the other hand1 it shows little sympathy for oxygen1 forming but few stable compounds4 ,chloroform1 so long useful in surgical anaesthesia1 is a compound of chlorine1 carbon and hydrogen4 ,sulphur can assume a variety of appearances 7allotrophic variation7 as we have seen4 ,sulphuric acid1 etc41 are its compounds4 ,the latter substance is used for bleaching violets1 but the flowers become violet again when put into an ammonia solution4 ,sodium is a metal1 which burns when thrown into water4 ,it is the other constituent of common salt1 and enters into a great variety of combinations4 ,carbonate of soda is one of these4 ,many of the elements--iron1 nickel1 gold1 platinum1 silver1 etc41--are too well known to necessitate more than a brief note4 ,it is interesting to notice1 however1 that there are certain 8family relations0 among a number of the elements4 ,thus1 sodium and potassium are 8related02 and so are barium1 strontium and calcium4 ,again1 oxygen and sulphur have a number of points in common1--although one is a solid and the other a gas6 ,gold stands rather apart from the rest4 ,two very interesting groups should be mentioned in this place4 ,the first is the group of rare gases--argon1 neon1 etc41--most of which have been discovered only recently4 ,they are inert1 and partly on account of this1 and partly on account of their rarity1 their discovery was so long delayed4 ,,radio-,,activity ,the second list is the radio-active group of elements1--uranium1 radium1 thorium1 actinium1 etc4 ,these all possess their characteristic properties in varying degrees1--giving off alpha1 beta and gamma rays4 ,a certain mysterious 8emanation0 is also emitted by radio-active elements1 but the study of these rays and their influence would take us into the realm of 8physics10 and would more properly belong to a book on physics than in the present1 dealing with chemistry4 ,one very interesting fact should1 however1 be mentioned in this connection1 and that is the evolution of matter which has been observed1 as the result of spectrum analysis4 ,we have heard much of organic evolution1 meaning the evolution of life upon our planet4 ,it is equally true that there is an inorganic evolution1 in which the gradual development of chemical elements may similarly be traced4 ,thus1 it has been noticed that1 in the hottest stars1 7gaseous7 the fewest chemical elements exist2 in those of medium temperature 7metallic71 more elements are found1 while in those having the lowest temperature 7carbon stars7 the greatest number of chemical elements are to be distinguished4 ,this seems to prove that the higher the temperature1 the fewer the elements1 which in turn leads to the conclusion that all elements are perhaps ultimately ,,one--as ,sir ,william ,crookes suggested many years ago4 ,as these stars cool1 more and more elements seem to be 8crystallized out10 so to say1--the many being formed from the fewer4 ,the newer researches on the constitution of matter render this idea all the more plausible4 ,,the ,,origin ,,of ,,life ,just here1 it might be well to point out the late place occupied by life1 in this process of inorganic evolution4 ,the ,absolute ,zero of inter-stellar space is about -#bgc;,c4 ,on the other hand1 the temperature of the hottest stars is more than #cj1jjj6 7,argo1 ,alnitam1 etc47 ,the temperature must fall from this to a few degrees above ,zero 7the boiling point of water71 before life can become manifest at all4 ,life as we know it can only exist between the boiling and the freezing points of water4 ,this point is only reached towards the very end of the scale4 ,it has therefore been said that1 cosmically speaking1 life is only a 8flash in the pan between two eternities0--but for us that flash in the pan is everything6 ,the question of the origin of life upon our planet has been discussed at some length in my little book on 8,life3 ,its ,origin and ,nature10 in the present series4 ,it may be of interest to mention here1 however1 a few of the experiments which have been made upon the artificial creation of life1 by means of inorganic chemicals1 since these properly fall into place in a book devoted to chemistry4 ,dr4 ,h4 ,charlton ,bastian1 of ,england1 conducted many years ago a series of experiments of this character1 in which he claimed to have made living matter from sterilized chemicals4 ,he placed these in a glass bottle which had been sterilized1 heated the contents until steam issued from the mouth of the flask1 and then instantly sealed up the bottle1 preventing the entrance of air4 ,the flasks were then put away for several days1 and at the end of that time were found1 upon examination1 to contain living organisms4 8,,creation0 ,,of ,,life ,the reader will probably be interested in knowing the precise chemical formul employed for obtaining these astonishing results4 ,several such formul are given in ,dr4 ,bastian's book1 8,the ,evolution of ,life10 of which the following are samples3 ,sodium silicate1 two1 or three1 drops4 ,ammonium phosphate1 four1 or six1 grains4 ,dilute phosphoric acid1 four1 or six1 drops4 ,distilled water1 one fluid ounce4 ,another formula is the following3 ,sodium silicate1 three drops4 ,liquor ferri pernitratis1 eight drops4 ,distilled water1 one fluid ounce4 ,the reader can try the experiment for himself4 ,it should be said1 however1 that although ,dr4 ,bastian's results were undoubted1 they failed to carry conviction to the scientific world as a whole1 since they contended that some experimental error must have crept in1 to render these results possible2 and it is significant1 in this connection1 that the same experiments repeated by other men failed to yield the same striking results4 ,chemistry1 then1 enters into practically every field of inquiry--the constitution of human beings1 no less than that of metals1 earths or distant nebul4 ,everything material in the ,universe is composed of elements1 of atoms1 and these atoms are built-up1 as we have seen1 of electrons1 which are not matter at all1 but bundles of energy4 ,no two particles of matter in the world actually touch1 or come near to touching one another4 ,it is an interesting thought1 when one stops to think of it that1 for instance1 the steel pillar supporting a 8sky-scraper10 upon which rests an enormous weight 7the whole of the superstructure7 is not really dense and solid1 as it appears1 but is actually tenuous and shadowy1 and that no two of its atoms ever touch one another2 they are separated by relatively vast spaces1 filled only with the hypothetical 8ether40 ,the whole weight of the building may be said to rest upon nothing1--or at most upon ether1 which thus bears its strain6 ,,the ,,ether ,and what is this ether8 ,is it matter in some subtle form1 or is it something else8 ,we do not know2 certainly it is no form of matter known to us1 and its reality has even been called into question of late4 ,hckel1 as we know1 contended 78,the ,riddle of the ,universe07 that the ether must be like some extremely attenuated jelly1 and that a sphere of it the size of the earth would probably weigh about #bej pounds6 ,such crude conceptions have long since been given up4 ,it is far more subtle than this4 ,is it analogous to the finest gas8 ,some have thought so2 and yet ,sir ,oliver ,lodge1 one of the greatest authorities upon the ether1 has contended that it is more dense and solid than platinum or gold1 and that matter represents mere 8bubbles0 within this dense medium1 capable of moving freely through it4 ,in support of this view1 he has cited 7in his 8,ether of ,space07 the enormous gravitational pull of the earth upon the moon1 e4 g41 or of the sun upon the earth4 ,the mass of the earth is approximately #f1jjj trillion tons2 that of the moon one-eightieth of this4 ,from these data1 the gravitational pull of the earth upon the moon can be calculated2 and1 regarding this1 ,sir ,oliver says3 8,a pillar of steel which could transmit this force1 provided it could sustain a tension of #dj tons to the square inch1 would have a diameter of about #djj miles4444 ,if this force were to be transmitted by a forest of weightless pillars1 each a square foot in cross section1 with a tension of #cj tons to the square inch throughout1 there would have to be #e million million of them40 ,calculating the gravitational pull of the sun on the earth1 in a similar manner1 it was calculated that the strain in this case would have to be borne by 8a million million round rods or pillars each thirty feet in diameter40 ,it may readily be seen1 then1 from these figures1 that something enormously dense1 apparently1 must exist in order to bear this strain1 and this must be the ether4 ,and yet no physical experiments have proved to us the existence of the ether2 we only infer its presence1 and say that it must exist1 in order to account for certain phenomena observed in physics4 ,it was1 ,i think1 ,lord ,kelvin who remarked that no man could believe in the ether without at the same time believing it to possess opposite and contradictory properties6 ,indeed1 it would seem so6 ,,chemistry ,,and ,,meta-,,physics ,such speculations as these lead us far afield1 into the realm of mathematics1 metaphysics and ultimate realities4 ,even the most material of all the sciences--chemistry--leads thither when pushed to its final analysis4 ,the visible1 sensible universe vanishes1 and is replaced by the invisible1 the super-sensible4 ,yet science has been our guide throughout4 ,william ,james once remarked that metaphysics is merely 8persistently clear thinking40 ,it endeavors to find the ultimate causes of things1 the noumena behind phenomena1 the reality behind appearances4 ,the physical world in which we live is a world of phenomena only2 real in a sense1 and for all practical purposes1 and yet the greatest of all unrealities in another sense4 ,it is a mere world of appearances2 a phantasmagoria of fleeting shapes and shadows4 ,we feel that reality must exist somehow1 somewhere2 yet we can never find it4 ,we can no more find it by chemical analysis than we can discover the mind and soul of man by dissecting the brains of corpses1--or even by vivisection6 ,something always escapes us--the ,soul of ,things1 the ,ultimate ,reality1 the ,great ,unknown4 ,such thoughts and speculations as these1 however1 need not occupy the mind of the practical chemist4 ,for him1 atoms exist1 so do elements1 so does 8matter40 ,for practical1 daily life1 we certainly have to live as if matter existed1 and the chemist has to proceed with his work upon the assumption that matter actually does exist--it is 8real40 ,certain it is that the practical furtherance and application of this science can come about in no other way4 ,chemistry has revolutionized our lives2 it has penetrated all fields of commerce and industry1 and its practical application has rendered possible and pleasant the lives of countless thousands of persons now living upon our planet4 ,we owe more to chemistry than we can ever repay--or rather to those brilliant and unselfish men who have built up the modern science of chemistry4 ,it is my hope that the present little book may in some degree have helped to emphasize this fact4 ,transcriber's ,notes ,punctuation1 hyphenation1 and spelling were made consistent when a predominant preference was found in the original book2 otherwise they were not changed4 ,simple typographical errors were corrected2 unbalanced quotation marks were remedied when the change was obvious1 and otherwise left unbalanced4 ,this book uses both 8reactions0 and 8rections04 ,page #ag3 8,cobalt0 was printed as 8,cobolt02 changed here4 ,page #bc3 ,the 8constitutional0 formula in the original book was printed with the two 8,b0s stacked1 one above the other1 and in a smaller font that could fit both of them on one line of normal-sized text4 ,page #di3 8allotrophic0 was printed that way2 probably should be 8allotropic04