,the ,growth of a ,crystal ,,being ,,the ,,eighteenth ,,robert ,,boyle ,,lecture ,,delivered ,,before ,,the ,,oxford ,,university ,,junior ,,scientific ,,club ,on the #bjth of ,may1 #aiaa ,,by ,,henry ,a4 ,,miers1 ,m4,a41 ,d4,,sc4 7,,oxon471 ,f4,r4,s4 ,,principal ,,of ,,london ,,university ,,london3 ,,henry ,,frowde1 ,,amen ,,corner1 ,e4,c4 ,,edinburgh3 #ab ,,frederick ,,street4 ,,glasgow3 #ajd ,,west ,,george ,,street ,,oxford3 #aaf ,,high ,,street ,,new ,,york3 #bi-ce ,,west #cb,,nd ,,street ,,toronto3 #be-bg ,,richmond ,,street ,,west ,,melbourne3 ,,cathedral ,,buildings1 #bje ,,flinders ,,lane #aiaa ---------------------------------------- -------------------------------- ,,oxford3 ,,horace ,,hart ,,printer ,,to ,,the ,,university ---------------------------------------- -------------------------------- ,,the ,,growth ,,of ,a ,,crystal ,when this date was fixed by your ,secretary for the delivery of the ,,boyle ,lecture1 ,i discovered that it happened to be the fifteenth anniversary of the very day on which ,i was first called upon to address a general audience in ,oxford4 ,on ,may #bj1 #ahif1 ,i delivered an inaugural lecture as ,waynflete ,professor of ,mineralogy2 when ,i look back upon the happy years spent here in teaching and studying a science which is dear to me1 ,i feel that the present lecture should be an opportunity for expressing gratitude for those peaceful years1 not unmingled with regret that they led to no such worthy achievement on my part as might have brought great credit to the ,university and so have repaid something of the debt which ,i owe to her4 ,looking back from the busier world of ,london1 it is easy to see how ideal are the conditions under which an ,oxford ,professor conducts his work2 especially if his subject be one which does not overwhelm him with students who pursue it only for the purpose of passing an examination4 ,those who are attracted to his ,laboratory probably come because they have some natural taste for the subject2 he finds it a pleasure to devote his time to them2 while his vacations and the conditions of ,oxford life give him unique opportunities for his own researches4 ,it is true that those who have most leisure not infrequently waste most time4 ,it is true also that the custom of ,oxford is to burden her students and scholars in addition to their teaching1 with the conduct of affairs which could be managed as well by persons specially appointed for the purpose4 ,still it is also certain that to those who enter into the genius of the place1 and are animated by the spirit of ,learning1 ,oxford is prodigal of opportunity1 and enables them to live the ,academic ,life in a way which is scarcely possible elsewhere4 ,i know that the doors of the ,university are being opened to all the newer studies1 and that many a student spends most of his time in acquiring the useful knowledge that is to equip him for his profession and for the direct purpose of that profession2 knowledge which is to fit him to become lawyer1 doctor1 minister1 engineer1 or teacher2 yet an ,oxford ,professor may always maintain the pursuit of ,learning for its own sake and keep this purpose before his students even in their most technical work4 ,now ,mineralogy is one of those sciences whose practical applications are clear2 it is necessary to the miner and the engineer2 indeed1 it sprang from their needs2 even ,crystallography 7that is1 the study of ,crystals71 which has always hitherto1 though with little reason1 been treated for ,university purposes as a branch of ,mineralogy1 has also become part of the necessary equipment of the practical chemist and geologist2 but both ,sciences are1 in their general aspects1 very far removed from the turmoil of practical life2 it is with these aspects that ,i would fain deal1 and especially in relation to the study of crystals4 ,in this connexion1 a passage which ,i quoted from ,,goethe fifteen years ago will bear repetition3 #8,there is a flavour1' he says1 #8of the ,monk or of the old ,bachelor about ,crystallography and therefore it is self-sufficient4 ,practical application in life it has none2 its rarest objects1 the crystallized precious stones1 have to be cut and polished before we can adorn our ladies with them4' ,in fact1 this lecture1 which ,i was constrained to prepare during a brief holiday in ,italy1 was written in the midst of surroundings where it was easier to think of ,science as cultivated in the quiet of the ,laboratory1 rather than in the restless scenes of its practical applications1 although ,i am familiar with both4 ,writing at a window overlooking the mediaeval town and ancient walls of ,perugia1 with the view of peaceful ,assisi and the snowy cap of ,monte ,subasio across the plain1 it was easier to recall the hours of quiet toil and reflection spent in one's ,laboratory at ,oxford than visits to ,mining ,camp1 or ,metallurgical ,works4 ,accordingly when1 under these circumstances1 ,i set about choosing a subject for the present occasion1 it occurred to me that ,i might be allowed to take up my discourse where ,i laid it down in #ahif and in some sense to continue and conclude the remarks which ,i then made to the ,university2 and1 considering how recently ,i have left you1 ,i might regard this as my farewell address corresponding to the opening lecture which ,i then delivered4 ,in that address1 ,i recollect1 ,i began with an inquiry into the resemblances and differences between minerals and other objects of nature in respect of their beauty1 especially as regards the beauty of form which is so specially characteristic of minerals4 ,some minerals1 indeed1 are found in delicate fronds and leaflets1 and in mossy tufts1 which1 in their form and texture1 in their sheen and lustre1 so closely resemble plants that they are often mistaken for them4 ,those who heard ,,ruskin',s lectures will remember the delight with which he described these beauties of the mineral kingdom and the affection which he felt for them4 ,i pointed out1 ,i remember1 that these delicate forms are1 like the frost patterns on a window-pane1 really expressions of the crystalline shape and symmetry of the mineral2 each mineral consists of crystals1 and therefore has its own peculiar crystalline shape which is one of its inherent properties2 moreover1 this persists unchanging through the ages1 and under all conditions1 and is in no way dependent upon the environment in which the mineral is situated4 ,the shape of a crystal does not depend like that of the animal or the plant upon the life which its forefathers have led or the conditions under which they have grown4 ,there are indeed other features in which a mineral or any crystal may resemble a living thing in a way even more surprising than in its form4 ,two of the most remarkable are these3 it grows out of a solution as though it were alive2 and1 if it is wounded or broken1 it heals itself and replaces the missing part just as a living organism may do4 ,but1 as ,i pointed out1 there is this radical difference4 ,the crystal is not responsive to the change of its surroundings2 its form is not the result of external forces2 it does not adapt itself to its environment2 it is not undergoing any progressive evolution2 but remains fixed and unchanging4 ,its form is the expression of its permanent composition1 and so far as we know has always been the same4 ,indeed1 until it has been converted into its constituent elements and destroyed1 it is in a sense not only unchanging1 but imperishable4 ,for1 take a crystal and break or dissolve it away until only the tiniest fragment remains2 that fragment 7e4 g4 sugar71 though it may be only an invisible speck1 will1 if immersed in the appropriate solution1 continue to grow again and will once more assume the form of a perfect crystal4 ,neither does it make any difference if the crystal fragment has been kept for years or even centuries2 it will1 when supplied with nourishment from the appropriate solution1 heal itself and continue to grow as though the process had never been suspended4 ,in a sense it is immortal1 for1 if not destroyed1 it never loses the mysterious power of growth1 and is therefore more imperishable than any seed or germ of life4 ,the main conclusion of my lecture was that1 having been led by analogy to compare the growing crystal with the growing plant1 one finds the growth and life of the crystal to be totally unlike the growth and life of any organism4 ,its life is only an unchanging persistence without the display of any struggle for existence1 any movement1 any adaptation1 or response to environment2 its growth is only the addition of new material on the surface of the old1 without assimilation1 so that the crystal remains uniform and increases in size2 there is no distinction of any one part from any other2 the crystal grows1 therefore1 without the development of any organs4 ,one appears to be left with the conclusion that the crystal should be regarded rather as a type of death than of immortality4 ,,schopenhauer expressed this idea when he said3 #8,the crystal has only one manifestation of life1 crystallization1 which afterwards has its fully adequate and exhaustive expression in the rigid form--the corpse of that momentary life4' ,this1 however1 is not the conclusion which ,i would have you draw from the facts2 and ,i shall ask you on the present occasion to accompany me in pursuing a little further the inquiry into what we may call the vitality of a crystal and the manner in which it is displayed2 although this vitality is not to be confounded in any way with that of a living plant or creature4 ,it is1 ,i hope1 not unfitting that the subject of crystal growth should be dealt with in a ,,boyle ,lecture1 for ,,robert ,,boyle was himself one of the first to treat it in a scientific spirit4 ,he was the exact contemporary of ,,nicolas ,,steno1 the famous ,danish physician who laid the foundation of modern crystallography2 and ,,boyle1 in his treatise on the origin and virtues of gems1 was the first to express the conviction which was almost simultaneously expressed by ,,steno--that gems must have solidified from the liquid state4 ,one of his reasons for thinking so was their crystalline form1 which resembles that of salts which crystallize from solutions4 ,let me quote his exact words3 #8,the origin assigned to gems may be countenanced by the external figuration of divers of them4 ,for we plainly see that the corpuscles of nitre1 alum1 vitriol1 and even common salt1 being suffered to coagulate in the liquors they swam in before1 will convene into crystals of curious and determinate shapes4' ,and then he points out that when a salt such as nitre crystallizes in a vessel it is only where it is free to grow in the liquid1 and away from contact with the sides of the vessel1 that it can acquire this shape4 ,these crystals 7he says71 #8having a fluid ambient to shoot in1 will have those parts of their bodies that are contiguous to the liquor curiously formed into such prismatical shapes as are proper to nitre4' ,when ,,boyle wrote these words he had not seen the work of ,,steno1 which had just been published4 ,i may1 therefore1 claim that he was the first person to deal in a scientific spirit with the subject which ,i have chosen for this lecture1 the #8,growth of a ,crystal4' ,three years before ,i came back to ,oxford--on ,may #afth1 #ahic1 the subject of crystal structure had been treated in the second ,,boyle ,lecture in a most original and masterly manner by no less a person than ,,lord ,,kelvin4 ,i well remember that ,lecture1 at which ,i had the good fortune to be present2 and to one who was already interested in crystals it was a wonderfully illuminating and inspiring address4 ,on that occasion my venerable predecessor and teacher1 ,professor ,,story ,,maskelyne1 conducted ,,lord ,,kelvin to the lecture table4#a ,footnote #a3 ,it is with the deepest regret that ,i add that my old friend and revered teacher died on the very day on which these words were spoken4--,h4 ,a4 ,m4 ,at that time1 however1 there was no laboratory in ,oxford for mineralogical and crystallographical research2 the ,professor only had a lecture-room1 he did not reside in ,oxford1 and his scientific work was necessarily carried on elsewhere4 ,to-day ,i am more fortunate in being able to draw upon the resources of the well-equipped laboratory of my successor1 and former pupil1 ,professor ,,bowman1 and upon his still more valuable personal assistance and that of ,mr4 ,,barker2 so that1 though ,i only have to deal with ideas that are simple compared with those which issued with fiery vigour from the fertile brain of the ,,boyle ,lecturer of #ahic1 ,i have a better opportunity of showing to an ,oxford audience to-day the actual things of which ,i am speaking1 and may help to make my meaning clear to those who cannot know much from personal experience concerning the growth of crystals4#b ,when ,i delivered my own inaugural lecture ,i had no means of making visible to an audience the astonishing features of crystal growth4 ,beautiful effects may easily be witnessed by anyone with a few drops of common solution and a magnifying glass1 yet ,i believe that they are witnessed by comparatively few persons4 ,footnote #b3 ,this lecture was beautifully illustrated by excellent slides showing the actual growth of crystals4--,,ed4 ,i have alluded to laws of crystalline structure1 to which ,,lord ,,kelvin had directed attention3 these are the laws of geometrical arrangement which prove crystals to be constructed in an entirely different manner from the living plants which they may so closely resemble2 these laws1 however1 were not established by observations or experiments upon the growth of crystals4 ,they were the result of a century of patient measurements of the external shape of countless crystals2 more than a century of accurate determinations of what happens when heat and light are transmitted through them and of numberless other experiments made by physicists2 and1 added to this1 the labours of mathematicians who studied the manner in which solid particles could be arranged so as to correspond to the geometrical and physical proportions thus determined by experiment4 ,but all these were experiments and reasoning upon matter which appears to be as nearly as possible inert2 they entirely ignore the power of growth possessed by crystals2 indeed1 no such power is contemplated by the ordinary theories of crystal structure or could be predicted from them4 ,so far1 then1 we may regard the comparison of crystals with plants and all the fanciful ideas concerning their connexion with the origin of life which were suggested by that comparison as only one more example of the dangers of reasoning from analogy4 ,the recollections that ,i retain of the allusions to that process--in text-books of logic and treatises on ,science alike--give me the impression that examples of reasoning from analogy are generally quoted only as instances of its danger and futility4 ,that1 indeed1 might seem to be the conclusion of my own inaugural lecture2 for1 when we come to examine the growth and structure of crystals1 so far from finding that there is any real likeness to the life and structure of the plants which they resemble1 we find nothing but a profound difference4 ,that1 however1 is not my real opinion1 and was not my opinion fifteen years ago4 ,on the contrary1 ,i have the greatest belief in analogy as one of the most useful guides to discovery1 and as the means by which in practice new lines of investigation are most frequently opened and new hypotheses suggested4 ,in fact1 ,i think that most of the advances which are made in science1 and especially in scientific theory1 have been made with the help of analogies4 ,if an explanation of any fact in ,nature consists in correlating it with some apparently distinct fact1 and showing that the two have a common cause1 or are connected in a definite manner1 how often has the explanation of a new occurrence been suggested by the analogy of some other known occurrence which is brought to mind by the memory2 not by a conscious effort of the reason1 but by the recollection of a resemblance4 ,do not some of the standard methods which are familiar in the descriptions or criticisms of scientific discovery1 such as #8reasoning from the known to the unknown'1 #8the adoption of a working hypothesis'1 #8the scientific use of the imagination'1 often resolve themselves on analysis into the simple process of being struck by an analogy and being led by it to adopt an explanation or to try an experiment suggested by it8 ,i daresay that scientific discoverers are ashamed to confess that they may have been led to a theory by a superficial analogy just as they are ashamed to confess that they have hit upon a discovery or an invention by chance1 and have found one thing when they were looking for another4 ,but there is no need to be ashamed1 for the discoveries only come to those who have the eyes to see1 or the knowledge which enables them to remember a resemblance1 and who have further the intellectual power to make use of it4 ,science grows on the acquisition of new knowledge and we must not hesitate to grasp it where we can4 ,there is a danger lest the formulation of the methods of science may deter the inquisitive student from seeking knowledge wherever it is to be found1 and make him believe that it is only by the orthodox processes of reasoning based upon a lifetime of training that he is to discover anything new4 ,rather let him be encouraged to seek any resemblance or analogy that may point a way in the gloom4 ,it is true that in the past the argument from analogy has often proved dangerous when1 because the things possess certain attributes in common1 it was inferred that they are alike in other respects4 ,yet even here it may prove useful4 ,,newton only asserted that the diamond is inflammable because it resembles other inflammable substances in possessing a high refractive power2 and yet he turned out to be right1 although his analogy was wrong4 ,moreover1 it was the analogy which prompted the experiment4 ,to detect an analogy1 to test it1 and to find that it cannot be maintained1 may be as useful an addition to knowledge as the establishment of a real causal relationship3 it has had the effect of setting the worker on to new experiments or observations1 and every such step is necessarily an advance4 ,the conscientious search for one thing almost invariably leads to the discovery of another2 and1 even if it does not1 who shall say that it may not be as important and useful1 say1 to establish a difference as to prove the resemblance which has been suspected8 ,if1 however1 reasoning from an analogy may be fallacious when inferences are drawn from the fact that two things possess the same attributes in common1 it is1 ,i think1 a safer guide when it is used to suggest a new hypothesis2 a corpuscular theory of light may be suggested by the analogy between the reflexion of light and the rebounding of elastic bodies2 an undulatory theory by the analogy of a wave propagated along a string or on the surface of water4 ,the one theory may be found to fit the facts and the other may be condemned2 but without some analogy as a guide how are such theories to be devised8 ,what we require in science are continual stimuli to start us on new experiments1 new observations1 and new ideas1 and prevent us1 especially those who are teachers1 from constantly repeating the old ones4 ,i shall be satisfied if the present lecture is regarded as a plea for the use of reasoning from analogy1 and as an illustration of its value4 ,let me1 then1 after this exhortation1 return to my problem of the growth of crystals1 and show how ,i still think that we may be guided by analogy in seeking to understand it4 ,so far from regarding the growth of a crystal as of no further importance after it has been proved to be quite different from the growth of a plant1 we must still think of it as one of the most interesting and mysterious events1 and the one through which we may hope to get the clearest insight into the nature of the crystal itself4 ,for1 after all1 when after making physical experiments upon the solid crystal and studying its action upon heat and light we are led to speculate upon the manner in which it is constructed1 we must not forget that it grew1 and that the material was laid down under conditions which we can only understand by studying what happens on the surface as it grows4 ,,lord ,,curzon devoted his ,,romanes ,lecture to the consideration of ,frontiers1 and explained their interest and importance in the growth of nations4 ,in the study of ,science also nothing is more interesting and important than frontier problems4 ,in two senses is this true4 ,the problems which lie on the borderland between two sciences are the most fruitful of all1 because they throw light upon each science1 and1 by bringing into harmony things that were previously distinct and separate1 lead to an immediate extension of knowledge4 ,and also in a more restricted sense4 ,you will find1 ,i think1 that the scenes of the most interesting events in ,nature are generally those places where different things come into contact and where there is consequently stir and action2 where two substances meet to form a new chemical compound2 where two bodies touch and react upon each other2 at the surface of a solid or a liquid2 these are the regions in which events are taking place that we can study and measure with the prospect of discovery4 ,impressed by the analogy between the growth of crystals and of living things1 ,i have always felt that1 for a proper understanding of the things themselves1 the study of their growth is as important for the one as for the other2 that to obtain this understanding it is necessary to study what is happening on the surface of the growing crystal where the advancing solid is in actual contact with the solidifying liquid4 ,if you wish to understand a plant or an animal it is not enough to study dried specimens or specimens in spirits1 but to watch the living organisms growing under natural conditions2 and in the same way it is surely worth while to study the growing crystal surrounded by the solution which feeds it1 and even to make under these conditions the measurements and observations which are usually made upon crystals only after they have been taken out of the solution and have ceased to grow4 ,in the case of living things1 we know that growth takes place by internal processes and not only by new material added on the surface4 ,how much easier1 then1 should it be to study the growth of a crystal when we have found that it is only a surface activity1 and does not involve internal changes8 ,as ,i have already said1 when ,i came to ,oxford there was no laboratory of ,mineralogy nor any apparatus for research1 but ,i brought with me a piece of apparatus which ,i had constructed a few years previously for this exact purpose2 to measure the angles of crystals while they are growing in the solution and to ascertain whether any changes take place in those angles1 in the hope of getting some insight into the nature of the surface and what ,i have called the frontier problem4 ,many days and also nights had ,i spent with this apparatus in the absorbing pursuit of measuring growing crystals1 watching the curious changes that take place in the position of their facets1 excited by the knowledge that ,i was looking at things that had certainly not been seen before1 and by the expectation of what they might disclose4 ,i need not weary this audience with any description of these experiments1 which doubtless seem more interesting and important to their author than to anyone else4 ,but ,i wish to draw your attention to the result that came out of them4 ,i found that it was possible with the same apparatus to measure the refractive power of the liquid in absolute contact with the growing crystal and from this to calculate the exact strength of the solution at that spot4 ,it was thus possible to prove that the solution in contact with the crystal is rather stronger than at a very short distance from it1 and to know exactly how much stronger4 ,in other words1 while a crystal of1 say1 alum is growing1 the liquid in contact with it contains more particles of alum and less particles of water1 or is richer in alum1 than the liquid at a short distance from it4 ,i will ask you to bear this in mind in what follows4 ,there is another curious fact connected with this subject4 ,crystals of nitrate of soda have almost exactly the same shape and almost the same physical properties as crystals of the common mineral calcite1 which1 in its purest and most perfect form of transparent glassy crystals1 is known as ,iceland spar4 ,now1 when a perfectly clean crystal of ,iceland spar is immersed in a strong solution of nitrate of soda1 although it is not dissolved by the liquid itself and therefore cannot crystallize out of it1 the ,iceland spar actually continues to grow1 and becomes enveloped by the nitrate of soda so as to form what is apparently a single crystal4 ,it appears1 therefore1 highly probable that a crystal of nitrate of soda and a crystal of ,iceland spar behave alike in this respect when placed in a strong solution of the nitrate2 each draws to itself the liquid nitrate in the solution1 then draws it out of the solution in the solid state1 and further arranges the particles upon its own surface in a perfectly regular manner1 so that the arrangement of the particles in the shell of nitrate is the same as the arrangement of the particles in the spar which it surrounds2 just as a bricklayer sets upon the rising wall new bricks arranged in the same way as those which he has already laid4 ,i remember that on ,,lord ,,kelvin',s last visit to ,oxford1 shortly before his death1 mindful of his ,,boyle ,lecture1 ,i showed him1 in company with my pupil1 ,mr4 ,,barker1 this beautiful experiment1 with which he was at that time not familiar1 and ,i shall never forget the interest and enthusiasm with which he witnessed the beautifully regular and instantaneous growth of the nitrate crystals4 ,he always was as enthusiastic and inquiring as a boy1 and these characteristics were exhibited on that occasion in his old age4 ,it is an experiment which sets one thinking1 and ,i have no doubt that1 if ,,lord ,,kelvin1 even at that advanced age1 had set his mind to consider it1 he would have been able to deduce far more than it has yet suggested to those who have witnessed it4#c ,footnote #c3 ,the experiment was then shown1 exactly as it was shown to ,lord ,kelvin4--,,ed4 ,some two years or so before the time of which ,i am speaking1 ,mr4 ,,barker had at my suggestion made an exhaustive study of a great number of different substances in order to ascertain which of them behave towards one another like nitrate of soda and calcite1 and why they do so1 and he has really discovered the secret4 ,when two substances like nitrate of soda and calcite have nearly the same shape and resemble one another closely in their physical properties1 the geometrical laws of crystalline structure of which ,i have already spoken make it certain that they consist of particles arranged in the same way4 ,we do not know what these particles are or what is their shape or size1 but we may be sure that they are arranged in the same way4 ,i am perhaps using the word particles in a loose sense1 for they might be hollow cells or they might be the space occupied by moving particles1 or anything else1 but whatever they may be it is pretty certain that they are arranged in the same way4 ,well1 ,mr4 ,,barker has proved that1 if two crystals grow together like nitrate of soda and calcite1 their particles are not only arranged in the same way1 but they must be of the same size1 or at any rate occupy the same space4 ,in more scientific language1 the two crystals not only have the same molecular structure1 but the same molecular volume4 ,it is1 therefore1 mainly a question of fitting together1 and1 if the two structures do not fit1 they cannot grow together1 like nitrate of soda and ,iceland spar1 as a continuous crystal4 ,let me illustrate by a suggestive comparison4 ,the bee's cell is one of the most remarkable and symmetrical structures in nature4 ,its regularity is probably due to the fact that bees of the same size are1 in making it1 so closely crowded together2 there is one bee's head in each cell1 and therefore you may say that the arrangement of the bees is the same as that of the cells4 ,for example1 if you place in each cell a ball which exactly fits it and then take away the cells1 you have an arrangement of balls which is the same as that of the cells1 each being in contact with six neighbours4 ,it may be called a hexagonal arrangement4 ,you have only to push together a number of balls on a table1 and they will fall into this arrangement4 ,it was a contemporary and associate of ,,boyle1 and an ,oxford man1 ,dr4 ,,robert ,,hooke1 who pointed out that with balls piled together in this way you can build up the shapes of crystals1 and that1 for example1 a pyramid of cannon-balls stacked together in the manner that ,i have just shown1 has the shape and angles of an alum crystal4 ,now1 if two such arrangements are to fit together1 they must be of the same size1 whether they consist of bees1 or cells1 or balls1 or molecules4 ,in the same way ,mr4 ,,barker has proved that ,iceland spar and nitrate of soda must consist of materials which are not only arranged in the same way1 but are of the same size1 although we do not know in the least what that material is1 nor what its actual size may be4 ,but this1 of course1 is not the end of the whole mystery3 for not only do two such structures fit together1 as might be expected1 but each has the remarkable property of making the other crystallize and grow1 and that means1 as ,i have just explained1 that it draws the other out of the solution where it is liquid into the crystal where it becomes part of a solid structure and lays it down in the exact position in which it fits1 just as one bee's cell is added to another in the growth of the comb4 ,we have advanced a step1 but only one step1 towards the better understanding of the mystery1 and ,i would beg you to note how we are continually led on by analogies which may be quite false1 but which are at any rate fruitful4 ,now let me pass to another series of researches which were conducted by ,miss ,,isaac and myself for a few years before ,i left ,oxford and have since been carried on by her with conspicuous success4 ,still experimenting with the same apparatus1 and endeavouring to trace how a solution changes in strength while it is crystallizing1 we came across some curious and unexpected results4 ,it is1 of course1 well known that if a crystal1 say of alum1 is placed in a weak solution of alum it is dissolved1 and only has the effect of making the solution stronger1 but that at last a stage is reached at which the solution becomes #8saturated' and can dissolve no more1 just as a stage is reached at which a soaking sponge will hold no more water4 ,at this point a crystal1 if put into it1 remains unchanged4 ,but it is quite easy to make the solution still stronger1 not by adding alum to it1 but by taking water away from it by evaporation3 it then becomes oversaturated or #8supersaturated'1 and now a crystal of alum dipped into the liquid will at once begin to grow and to make the solution weaker4 ,in fact1 this is an unfailing test by which we can tell whether a solution is saturated or supersaturated2 and1 more than this1 until a bit of solid crystal gets into it the liquid does not crystallize4 ,keep it in a closed vessel so that no speck of alum can fall into it1 and it will remain liquid for weeks or years or as long as you please4 ,but let the smallest possible grain of an alum crystal fall into it1 and crystallization will be started2 inoculate it with an invisible germ of alum dust1 such as must be flying about in the air of any room where dry alum is or has been kept1 and you will see the life and growth of a crystal begin when that germ is introduced4 ,this is the most extraordinarily sensitive test1 and one that can easily be applied4 ,in many of our experiments we found that during the first day when we were working with some new substance it would not crystallize from an exposed solution2 but on the second day1 when the air of the laboratory had become impregnated with crystal germs1 an exposed solution would begin to crystallize at once4 ,dr4 ,,tutton1 one of the most accomplished investigators of crystals1 whose refined and beautiful researches were for many years carried on in ,oxford1 has fully described these effects in his two books on crystals just published1 and confirms them from his own experience4 ,now1 ,miss ,,isaac and ,i have found in the course of our researches that1 as the solution becomes stronger and stronger--say1 by the evaporation of some of its water1 it continues to be in the ordinary state of supersaturation in which it does not crystallize save by inoculation with a germ of solid alum crystal1 but at last it suddenly reaches a condition in which it can crystallize spontaneously1 and at this moment it is enough to stir or shake the solution1 and you will at once witness the birth of thousands of tiny crystals which appear as a cloud in the liquid and begin to grow rapidly4 ,a very easy way in which to make this experiment is to dip a clean needle into a drop of evaporating solution on a glass plate and to scratch the glass on which the drop lies3 for a time nothing happens1 and then suddenly1 as the liquid passes into the new condition1 a chain of tiny crystals appears along the line of scratch4 ,that this suspended crystallization has a fixed limit was suspected1 and had been predicted by the ,german chemist ,,ostwald1 but could never be proved until we made our experiments1 and it was ,mr4 ,,hartley who first helped us to interpret our results4 ,he has subsequently1 with his pupils1 made a number of investigations on the same subject4 ,i can show you the two conditions in one and the same drop by using a solution of common potassium bichromate4 ,crystals begin to grow at the edge of the drop where the liquid first becomes sufficiently strong1 and continue to grow slowly in the evaporating liquid which is only slightly supersaturated4 ,but in a few moments other parts of the drop which are thinner become so strongly supersaturated that they begin to crystallize spontaneously2 and there you can witness the birth of new crystals which grow rapidly in all directions1 because they are growing in a solution which is much stronger than that in which the first crystals are growing slowly4 ,does not all this set one thinking8 ,what is taking place we cannot tell1 but we can only think of it as in some way analogous to the birth of a cloud2 and in both instances we have to picture to ourselves minute invisible particles1 of whose shape and size we know nothing1 coming together and coalescing till they grow into a drop or a crystal that we can see4 ,but why they do not begin to coalesce as soon as the liquid is supersaturated it is difficult to say4 ,we have to conceive the alum solution as made up of moving particles of alum and of water1 and it may be that the particles are constantly coalescing into minute groups1 but as rapidly being broken up again1 until a moment arrives at which the alum particles are sufficiently dense to cohere permanently2 but how they attract one another and arrange themselves into the wonderful structure which makes a crystal1 of this we are entirely ignorant4 ,the question brings us back again to our initial mystery1 how does the crystal actually grow8 ,but this is not all4 ,i have said that all solutions seem to behave in the same way1 and among them nitrate of soda1 which we have already seen growing in perfect regularity on ,iceland spar4 ,it appears1 however1 from experiments made by ,mr4 ,,barker1 ,miss ,,isaac1 ,m4 ,,chevalier 7who was another of my pupils71 and myself1 that ,iceland spar behaves in this respect also exactly like nitrate of soda4 ,in a solution which is supersaturated1 but is not strong enough to crystallize spontaneously1 not only will inoculation with a crystal of nitrate produce instant crystallization2 but inoculation with a crystal of ,iceland spar produces the same result4 ,so we have a still more convincing proof of what ,i suggested a short time ago1 that two crystals1 which have structures so nearly identical that they can fit together1 possess also the power of drawing each other from the liquid state into the solid form of a crystal4 ,whatever it is which conditions the fitting together of two structures must then also confer upon them this extraordinary power of making each other grow4 ,if ,i had more time1 ,i should like to give an account of some of the more important discoveries that have been made about crystals during the last fifteen years1 for they would make it easier to understand the present state of our knowledge concerning them4 ,i will only refer to two3 one is an experimental fact1 and the other is a theoretical speculation1 and both are connected with the subject that ,i have been discussing4 ,it was discovered shortly before that time1 and has been found by many experiments since1 that there are certain substances which are in a real sense crystals1 although they are liquid2 that is to say1 they affect light in its passage through them just as solid crystals do4 ,these extraordinary substances1 which had been investigated by ,professor ,,lehmann1 were first shown in ,england by ,mr4 ,,bowman and ,mr4 ,,hartley1 who were then working in my laboratory1 at a conversazione at the ,royal ,society1 not long after their discovery1 and ,i can well remember the interest with which they were witnessed by ,sir ,,george ,,stokes and others4 ,we can only picture these liquids as consisting of particles which1 while they are free to move in all directions1 always continue to face the same way1 like a group of dancers who in all their evolutions continue to face the audience1 instead of turning as they move4 ,when the mechanism which renders possible this remarkable behaviour is better understood1 we may be sure that it will bring about a better understanding of the manner in which a solid crystal is constructed4 ,the interesting thing about it is that here at any rate the particles are in violent movement instead of being comparatively stationary1 as they are in a solid crystal4 ,one is naturally led to imagine that before any solution begins to crystallize in the solid form it passes into this liquid state1 and that the particles have begun to set themselves and all to face the same way before they begin to cohere and to build themselves into a solid4 ,but so far as ,i know there is no evidence in favour of this suggestion--a solution before solid crystals begin to appear does not behave like a liquid crystal1 but remains an ordinary solution up to the last moment when new crystals are born in it or are started by inoculation with a crystal germ4 ,the other discovery1 which is in the nature of a speculation1 is that of another person whom ,i am proud to reckon among my former pupils1 namely1 ,professor ,,pope of ,cambridge1 working in conjunction with ,mr4 ,,barlow4 ,mr4 ,,barlow had already been referred to by ,,lord ,,kelvin in his ,,boyle ,lecture as the author of ingenious researches upon the various ways in which materials can be packed together1 and the different arrangements and structures which result from this packing4 ,these two workers have now propounded a theory according to which1 if the various atoms which constitute a substance are represented by spheres whose sizes represent the valency of the atoms1 and if these spheres are packed together as closely as they will go1 the resulting structure will represent very nearly the structure of the crystal2 and so it may be possible for the first time from a knowledge of the chemical constitution of a substance to predict the structure of its crystals and therefore the form in which it will crystallize4 ,you remember the bee's cell arrangement and the similar arrangement of balls got by placing a ball in each cell and then removing the cells4 ,another way of getting the same arrangement is to place a number of equal balls on a table and to squeeze them together until they are packed as closely as possible4 ,this arrangement of closest packing1 the arrangement of a pyramid of cannon-balls1 is precisely the same as before1 the one in which each ball on the table is in contact with six others4 ,according to ,,pope and ,,barlow the atoms in a crystal simply pack themselves together as closely as possible1 but instead of being equal in size they have generally to be represented as of different sizes according to their valencies4 ,if we imagine the coalescence of atoms to form a crystal to be due to their mutual attraction1 it is very reasonable to suppose that they will get as close together as is possible1 and therefore that the ways of close packing are the ways of crystal structure4 ,the theory therefore suggests a reason for the growth as well as for the shape of a crystal4 ,i may remind you that the bee's cell itself1 which is in the world of life the thing that most nearly resembles crystalline structure1 is due to this same principle of close packing2 for in their efforts to get as closely together as possible the bees are constrained to get into the hexagonal arrangement4 ,the bees crowd their heads together and to each bee's head corresponds one cell4 ,on the other hand1 ,professor ,,sollas has brought forward some most suggestive and convincing speculations concerning certain crystals which are based upon the principle of open1 and not close1 packing4 ,his model of silver iodide1 for example1 is well known in ,oxford4 ,i have mentioned these recent contributions to science1 not only with the object of indicating that our knowledge of crystals is steadily increasing1 but also in order to point out that little has yet been done to explain the mysteries of their growth4 ,all that has been effected up to the present is an attempt to explain how they are constructed1 not the process by which the construction takes place4 ,it is as though we were to analyse the form and structure of animals and plants and never to watch them as they grow1 but only to study them from fossils or from museum specimens4 ,and ,i believe the reason to be this4 ,all the speculations concerning crystals persist in regarding the particles of which they consist as fixed and immovable3 the theories are all statical4 ,and yet we know that the particles of matter1 whatever they may be1 are really in lively movement4 ,is it not possible that in order to get a correct understanding of the growth of a crystal we should take account not only of the positions1 but of the movements1 of its particles8 ,without some knowledge of these we are not able to approach the problem1 or to ascertain how a crystal either of nitrate of soda or of ,iceland spar draws the nitrate of soda out of the solution and makes it grow into a solid4 ,remember that when we say we know how the particles of a crystal are arranged we really know nothing about their nature1 and can only represent them by spheres1 or solid figures1 or cells1 or even points1 in order to get a representation of their arrangement4 ,but we might arrange in the same way a number of bodies each of which is whirling in a fixed orbit1 like a planet1 about the corresponding point1 or vibrating about it like the prong of a tuning-fork1 or pulsating like a breathing animal2 and so far from the arrangement being independent of the movements it may be due to them4 ,if ,i may seek another analogy1 let me take a group of figure skaters2 their centre remains fixed at the orange1 maybe1 about which their figures are executed1 but the group of skaters is at one moment extended when they circle out to their furthest sweep1 and at another moment concentrated when they converge to the centre2 and this alternating expansion and compression occurs in a regular rhythm4 ,imagine a pond covered by a number of such groups of skaters2 the manner in which they will fit in1 and have to arrange themselves1 will depend both upon the dimensions and the rhythm of their curves1 and they may even interlace and become part of one great figure system covering the whole pond4 ,may not the growth of a crystal be something of this sort8 ,all the devices which ,i have quoted for picturing to ourselves the architecture of a crystal ,i would regard as merely models representing something that may be really quite different4 ,but ,i venture to suggest that the time has come when we should make use of moving and not stationary models4 ,one need not go further than a spinning top for an illustration of stability due to movement1 and there is nothing unreasonable in the suggestion that the rigidity of a crystal structure may be due to the motion of its parts4 ,one curious observation which ,i have made is suggestive4 ,i have many times noticed that when the appropriate crystal is introduced into a supersaturated solution1 which is not strong enough to crystallize spontaneously1 it may cause crystals to grow not only in actual contact with itself1 but at some little distance in its neighbourhood4 ,if this be so1 then the crystallizing force1 the power of propagating crystal growth1 is not merely a frontier problem1 but can be exercised through the liquid to a distance4 ,if ,i try to picture to myself what is happening1 ,i must again have recourse to analogy2 ,i can only think of the manner in which a string or a tuning-fork is set in vibration and responds to a similar string or tuning-fork which is giving out its note at the other end of the room2 and so is it not possible that the movements1 whatever they are1 vibrations or pulsations or regular oscillations of some sort1 which constitute crystalline growth may be communicated through the almost crystallizing liquid1 and culminate at some point where they set similar material vibrating1 that is to say1 crystallizing1 in the same way8 ,i remember1 when ,i first began to be interested in crystals in undergraduate days1 reading in ,nature an account of two papers which seemed to have a possible bearing on the subject4 ,one is an example of a stationary arrangement of rigid bodies4 ,the other illustrates the principle which ,i am now suggesting1 and is an arrangement of pulsating bodies whose positions are due to their movements4 ,the first was a description of ,,mayer',s experiment on floating magnets which was1 if ,i remember right1 shown here in a ,,boyle ,lecture by ,sir ,,joseph ,,thomson a few years ago2 an experiment in which magnets suspended in water by corks and with their ,north poles projecting so that they repel one another1 are brought together by the attraction of a large magnet held1 with its ,south pole downwards1 above the surface of the water2 under the joint influence of this attraction and their own mutual repulsions1 they group themselves into a number of interesting geometrical figures very suggestive of the geometrical regularity of crystal structure4 ,indeed1 attempts have been made by ,,lehmann to explain the architecture of a crystal by a grouping of magnetic systems4 ,and the other was the experiment of ,,bjerknes in #ahgf 7described in ,nature in #ahha71 in which a number of hollow elastic balls were made to expand and contract by means of air tubes attached to them4 ,these pulsating balls1 when placed in water1 attracted and repelled one another like magnets1 and arranged themselves in a regular manner2 thus suggesting that there may be many unexpected ways in which rhythmical motion can exercise an attractive and directive action such as is required to produce a crystal4 ,let me illustrate what ,i mean by another crude analogy4 ,take a room full of dancers2 if they are all dancing to different times and in different ways there will be no order or arrangement in the crowd1 and it will remain an incoherent jostling assembly of independent persons4 ,but if there are among them those who are moving to the same step and in the same manner1 and if they come together1 they can become partners and can continue to dance together2 and if the room be filled with such dancers1 then the whole assembly can grow together into an orderly movement1 and only those whose step does not fit into the dance will be ejected and left out4 ,or take another example3 soldiers marching together have not ceased to be individual men1 but when they fell into step they became in addition an organized body with a structure and a coherence that does not belong to a miscellaneous crowd4 ,even so may the particles of dissolved salt be endowed with a movement which enables them to enter into partnership and cohere1 and so to build themselves into the orderly structure which makes up a crystal4 ,and even so do crystals grow out of a mixed solution as a pure and homogeneous substance and reject the other materials which are dissolved in the liquid4 ,one other suggestion4 ,if the growth of a crystal is really the coming together of vibrating particles which cohere because they are in tune with one another and so enter into a partnership like that of the dancers or the figure skaters1 then is it not possible that we may be able to communicate these vibrations to a supersaturated solution1 which is so densely crowded that it is ready to crystallize1 by some other means than by inoculating it with the appropriate crystal8 ,i think that the time has come when we may be able to get some knowledge of the manner of these movements by experimental methods2 perhaps by studying the sort of shock or movement1 if there be any such1 which starts crystallization in a supersaturated solution2 perhaps by finding other substances1 whose movements we understand1 which are able to start the crystallization when they are introduced into certain solutions4 ,i have said that the frontier problems in science are interesting2 and that this is true not only of the events that take place when different bodies meet1 but in another and more general sense4 ,the most interesting and fruitful problems are those which deal with the borderland between two sciences1 when the difficulties of the one are enlightened by the experience of the other1 or when the same problem is looked at from two different sides4 ,let me only quote as an illustration the work connected with osmosis1 which attracted first the botanists and then the physical chemists1 and remind you of the enormous importance which it has assumed by their combined efforts4 ,i think it will be found that these problems of crystal growth are of this borderland nature4 ,and such problems can only be satisfactorily attacked by those who are more than mere specialists and can be led by the experience or the analogies of other sciences4 ,i said that ,i should like to regard this lecture as an attempt to justify the value of analogy4 ,we poor specialists grope within the confines of our own science1 and what little advance we make is made in part by the light we borrow from the other sciences4 ,in these days of increasing specialization what we need is to interest in our own problems1 not only those who are tilling the same fields with ourselves1 but even more1 those who live on the other side of the fence which surrounds us3 to call to them across the frontier1 to seek their advice and assistance and the benefit of their experience4 ,this is one of the great advantages of a ,university1 that workers and thinkers in different subjects are brought together and can make their difficulties known to each other4 ,the connecting links between them are the analogies which they perceive and which excite an interest that they would not otherwise feel in each other's work4 ,this is the reason why ,i have endeavoured to set before you a very special problem in a very elementary way and as far as possible without using technical terms4 ,it is with the hope of attracting the interest of workers in other subjects to this fascinating problem of crystal growth which1 from the time of ,,boyle to that of ,,ruskin1 and more especially1 as ,i have shown you1 in recent years1 has engaged the attention of ,oxford students of crystals4 ---------------------------------------- -------------------------------- ,transcriber's note3 ,page #h1 #8allum' changed to #8alum1' 8corpuscles of nitre1 alum1 vitriol10