,,familiar ,,letters ,,on ,,chemistry1 ,,and ,,its ,,relation ,,to ,,commerce1 ,,physiology1 ,,and ,,agriculture1 ,,by ,,justus ,,liebig1 ,m4,d41 ,,ph4 ,d41 ,f4,r4,s41 ,,professor ,,of ,,chemistry ,,in ,,the ,,university ,,of ,,giessen4 ,,edited ,,by ,,john ,,gardner1 ,m4,d41 ,,member ,,of ,,the ,,chemical ,,society4 ,second ,edition1 ,corrected4 ,,london3 ,,mdcccxliv4 ,,preface ,the ,letters contained in this little ,volume embrace some of the most important points of the science of ,chemistry1 in their application to ,natural ,philosophy1 ,physiology1 ,agriculture1 and ,commerce4 ,some of them treat of subjects which have already been1 or will hereafter be1 more fully discussed in my larger works4 ,they were intended to be mere sketches1 and were written for the especial purpose of exciting the attention of governments1 and an enlightened public1 to the necessity of establishing ,schools of ,chemistry1 and of promoting1 by every means1 the study of a science so intimately connected with the arts1 pursuits1 and social well-being of modern civilised nations4 ,for my own part ,i do not scruple to avow the conviction1 that ere long1 a knowledge of the principal truths of ,chemistry will be expected in every educated man1 and that it will be as necessary to the ,statesman1 the ,political ,economist1 and the ,practical ,agriculturist1 as it is already indispensable to the ,physician1 and the ,manufacturer4 ,in ,germany1 such of these ,letters as have been already published1 have not failed to produce some of the results anticipated4 ,new professorships have been established in the ,universities of ,goettingen and ,wuertzburg1 for the express purpose of facilitating the application of chemical truths to the practical arts of life1 and of following up the new line of investigation and research--the bearing of ,chemistry upon ,physiology1 ,medicine1 and ,agriculture1--which may be said to be only just begun4 ,my friend1 ,dr4 ,ernest ,dieffenbach1 one of my first pupils1 who is well acquainted with all the branches of ,chemistry1 ,physics1 ,natural ,history1 and ,medicine1 suggested to me that a collection of these ,letters would be acceptable to the ,english public1 which has so favourably received my former works4 ,i readily acquiesced in the publication of an ,english edition1 and undertook to write a few additional ,letters1 which should embrace some conclusions ,i have arrived at1 in my recent investigations1 in connection with the application of chemical science to the physiology of plants and agriculture4 ,my esteemed friend1 ,dr4 ,gardner1 has had the kindness to revise the manuscript and the proof sheets for publication1 for which ,i cannot refrain expressing my best thanks4 ,it only remains for me to add a hope1 that this little offering may serve to make new friends to our beautiful and useful science1 and be a remembrancer to those old friends who have1 for many years past1 taken a lively interest in all my labours4 ,,justus ,,liebig ,giessen1 ,aug4 #ahdc4 ,,contents ,,letter ,i ,the ,subject proposed4 ,materials employed for ,chemical ,apparatus3-- ,,glass--,,caoutchouc--,,cork--,,platinu m4 ,,the ,,balance4 ,the ,elements of the ,ancients1 represent the forms of matter4 ,lavoisier and his successors4 ,study of the materials composing the ,earth4 ,synthetic production of ,minerals--,,lapis ,,lazuli4 ,organic ,chemistry4 ,,letter ,,ii ,changes of ,form which every kind of ,matter undergoes4 ,conversion of ,gases into ,liquids and ,solids4 ,carbonic ,acid--its curious properties in a solid state4 ,condensation of ,gases by porous bodies4 ,by ,spongy ,platinum4 ,importance of this property in ,nature4 ,,letter ,,iii ,the ,manufacture of ,soda from ,culinary ,salt2 its importance in the ,arts and in ,commerce4 ,glass--,soap--,sulphuric ,acid4 ,silver ,refining4 ,bleaching4 ,,trade ,,in ,,sulphur4 ,,letter ,,iv ,connection of ,theory with ,practice4 ,employment of ,,magnetism as a moving power--its impracticability4 ,relation of ,coals and ,zinc as economic sources of ,force4 ,manufacture of ,beet-root ,sugar--its impolicy4 ,gas for illumination4 ,,letter ,v ,,isomerism1 or identity of composition in bodies with different chemical and physical properties4 ,,crystallisation4 ,,amorphism4 ,,isomorphism1 or similarity of properties in bodies totally different in composition4 ,,letter ,,vi ,,alliance ,,of ,,chemistry ,,with ,,physiology4 ,division of ,food into nourishment1 and materials for combustion4 ,effects of ,atmospheric ,oxygen4 ,balance of ,,carbon and ,,oxygen4 ,,letter ,,vii ,,animal ,,heat1 its laws and influence on the ,animal ,functions4 ,loss and ,,supply4 ,influence of ,climate4 ,fuel of ,animal ,heat4 ,agency of ,oxygen in ,disease4 ,respiration4 ,,letter ,,viii ,,aliments4 ,constituents of the ,blood4 ,fibrine1 ,albumen4 ,inorganic ,substances4 ,isomerism of ,fibrine1 ,albumen1 and elements of nutrition4 ,relation of animal and vegetable organisms4 ,,letter ,,ix ,growth of ,animals4 ,uses of ,butter and ,milk4 ,metamorphoses of ,tissues4 ,food of ,carnivora1 and of the ,horse4 ,,letter ,x ,application of the preceding facts to ,man4 ,division of human ,food4 ,uses of ,gelatine4 ,,letter ,,xi ,,circulation ,,of ,,matter ,,in ,,the ,,animal ,,and ,,vegetable ,,kingdoms4 ,the ,ocean4 ,,agriculture4 ,,restitution ,,of ,,an ,,equilibrium ,,in ,,the ,,soil4 ,causes of the exhaustion of ,land4 ,virginia4 ,england4 ,relief gained by importation of bones4 ,empirical farming unsatisfactory4 ,necessity for scientific principles4 ,influence of the atmosphere4 ,of ,saline and ,earthy matters of the soil4 ,,letter ,,xii ,,science ,,and ,,art ,,of ,,agriculture4 ,,necessity ,,of ,,chemistry4 ,rationale of agricultural processes4 ,washing for gold4 ,,letter ,,xiii ,,illustration ,,of ,,the ,,necessity ,,of ,,chemistry ,,to ,,advance ,,and ,,perfect ,,agriculture4 ,manner in which ,,fallow ameliorates the soil4 ,uses of ,lime4 ,effects of ,burning4 ,of ,marl4 ,,letter ,,xiv ,,nature ,,and ,,effects ,,of ,,manures4 ,animal bodies subject to constant waste4 ,parts separating--exuviae--waste vegetable matters--together contain all the elements of the soil and of food4 ,various value of excrements of different animals as manure4 ,,letter ,,xv ,,source ,,of ,,the ,,carbon ,,and ,,nitrogen ,,of ,,plants4 ,produce of ,carbon in ,forests and ,meadows supplied only with mineral aliments prove it to be from the atmosphere4 ,relations between ,mineral constituents1 and ,carbon and ,nitrogen4 ,effects of the ,carbonic ,acid and ,ammonia of ,manures4 ,necessity of inorganic constituents to the formation of aliments1 of blood1 and therefore of nutrition4 ,,necessity ,,of ,,inquiries by ,,analysis to advance ,,agriculture4 ,,letter ,,xvi ,,results ,,of ,,the ,,author',s ,,latest ,,inquiries4 ,superlative importance of the ,,phosphates ,,of ,,lime and ,,alkalies to the cultivation of the ,,cerealia4 ,sources of a ,,supply of these ,,materials4 ,,letters ,,on ,,chemistry ,,letter ,i ,my dear ,sir1 ,the influence which the science of chemistry exercises upon human industry1 agriculture1 and commerce2 upon physiology1 medicine1 and other sciences1 is now so interesting a topic of conversation everywhere1 that it may be no unacceptable present to you if ,i trace in a few familiar letters some of the relations it bears to these various sciences1 and exhibit for you its actual effect upon the present social condition of mankind4 ,in speaking of the present state of chemistry1 its rise and progress1 ,i shall need no apology if1 as a preliminary step1 ,i call your attention to the implements which the chemist employs--the means which are indispensable to his labours and to his success4 ,these consist1 generally1 of materials furnished to us by nature1 endowed with many most remarkable properties fitting them for our purposes2 if one of them is a production of art1 yet its adaptation to the use of mankind1--the qualities which render it available to us1--must be referred to the same source as those derived immediately from nature4 ,cork1 ,platinum1 ,glass1 and ,caoutchouc1 are the substances to which ,i allude1 and which minister so essentially to modern chemical investigations4 ,without them1 indeed1 we might have made some progress1 but it would have been slow2 we might have accomplished much1 but it would have been far less than has been done with their aid4 ,some persons1 by the employment of expensive substances1 might have successfully pursued the science2 but incalculably fewer minds would have been engaged in its advancement4 ,these materials have only been duly appreciated and fully adopted within a very recent period4 ,in the time of ,lavoisier1 the rich alone could make chemical researches2 the necessary apparatus could only be procured at a very great expense4 ,and first1 of ,glass3 every one is familiar with most of the properties of this curious substance2 its transparency1 hardness1 destitution of colour1 and stability under ordinary circumstances3 to these obvious qualities we may add those which especially adapt it to the use of the chemist1 namely1 that it is unaffected by most acids or other fluids contained within it4 ,at certain temperatures it becomes more ductile and plastic than wax1 and may be made to assume in our hands1 before the flame of a common lamp1 the form of every vessel we need to contain our materials1 and of every apparatus required to pursue our experiments4 ,then1 how admirable and valuable are the properties of ,cork6 ,how little do men reflect upon the inestimable worth of so common a substance6 ,how few rightly esteem the importance of it to the progress of science1 and the moral advancement of mankind6--,there is no production of nature or art equally adapted to the purposes to which the chemist applies it4 ,cork consists of a soft1 highly elastic substance1 as a basis1 having diffused throughout a matter with properties resembling wax1 tallow1 and resin1 yet dissimilar to all of these1 and termed suberin4 ,this renders it perfectly impermeable to fluids1 and1 in a great measure1 even to gases4 ,it is thus the fittest material we possess for closing our bottles1 and retaining their contents4 ,by its means1 and with the aid of ,caoutchouc1 we connect our vessels and tubes of glass1 and construct the most complicated apparatus4 ,we form joints and links of connexion1 adapt large apertures to small1 and thus dispense altogether with the aid of the brassfounder and the mechanist4 ,thus the implements of the chemist are cheaply and easily procured1 immediately adapted to any purpose1 and readily repaired or altered4 ,again1 in investigating the composition of solid bodies1--of minerals1--we are under the necessity of bringing them into a liquid state1 either by solution or fusion4 ,now vessels of glass1 of porcelain1 and of all non-metallic substances1 are destroyed by the means we employ for that purpose1--are acted upon by many acids1 by alkalies and the alkaline carbonates4 ,crucibles of gold and silver would melt at high temperatures4 ,but we have a combination of all the qualities we can desire in ,platinum4 ,this metal was only first adapted to these uses about fifty years since4 ,it is cheaper than gold1 harder and more durable than silver1 infusible at all temperatures of our furnaces1 and is left intact by acids and alkaline carbonates4 ,platinum unites all the valuable properties of gold and of porcelain1 resisting the action of heat1 and of almost all chemical agents4 ,as no mineral analysis could be made perfectly without platinum vessels1 had we not possessed this metal1 the composition of minerals would have yet remained unknown2 without cork and caoutchouc we should have required the costly aid of the mechanician at every step4 ,even without the latter of these adjuncts our instruments would have been far more costly and fragile4 ,possessing all these gifts of nature1 we economise incalculably our time--to us more precious than money6 ,such are our instruments4 ,an equal improvement has been accomplished in our laboratory4 ,this is no longer the damp1 cold1 fireproof vault of the metallurgist1 nor the manufactory of the druggist1 fitted up with stills and retorts4 ,on the contrary1 a light1 warm1 comfortable room1 where beautifully constructed lamps supply the place of furnaces1 and the pure and odourless flame of gas1 or of spirits of wine1 supersedes coal and other fuel1 and gives us all the fire we need2 where health is not invaded1 nor the free exercise of thought impeded3 there we pursue our inquiries1 and interrogate ,nature to reveal her secrets4 ,to these simple means must be added ,the ,balance1 and then we possess everything which is required for the most extensive researches4 ,the great distinction between the manner of proceeding in chemistry and natural philosophy is1 that one weighs1 the other measures4 ,the natural philosopher has applied his measures to nature for many centuries1 but only for fifty years have we attempted to advance our philosophy by weighing4 ,for all great discoveries chemists are indebted to the balance--that incomparable instrument which gives permanence to every observation1 dispels all ambiguity1 establishes truth1 detects error1 and guides us in the true path of inductive science4 ,the balance1 once adopted as a means of investigating nature1 put an end to the school of ,aristotle in physics4 ,the explanation of natural phenomena by mere fanciful speculations1 gave place to a true natural philosophy4 ,fire1 air1 earth1 and water1 could no longer be regarded as elements4 ,three of them could henceforth be considered only as significative of the forms in which all matter exists4 ,everything with which we are conversant upon the surface of the earth is solid1 liquid1 or aeriform2 but the notion of the elementary nature of air1 earth1 and water1 so universally held1 was now discovered to belong to the errors of the past4 ,fire was found to be but the visible and otherwise perceptible indication of changes proceeding within the1 so called1 elements4 ,lavoisier investigated the composition of the atmosphere and of water1 and studied the many wonderful offices performed by an element common to both in the scheme of nature1 namely1 oxygen3 and he discovered many of the properties of this elementary gas4 ,after his time1 the principal problem of chemical philosophers was to determine the composition of the solid matters composing the earth4 ,to the eighteen metals previously known were soon added twenty-four discovered to be constituents of minerals4 ,the great mass of the earth was shown to be composed of metals in combination with oxygen1 to which they are united in one1 two1 or more definite and unalterable proportions1 forming compounds which are termed metallic oxides1 and these1 again1 combined with oxides of other bodies1 essentially different to metals1 namely1 carbon and silicium4 ,if to these we add certain compounds of sulphur with metals1 in which the sulphur takes the place of oxygen1 and forms sulphurets1 and one other body1--common salt1--7which is a compound of sodium and chlorine71 we have every substance which exists in a solid form upon our globe in any very considerable mass4 ,other compounds1 innumerably various1 are found only in small scattered quantities4 ,the chemist1 however1 did not remain satisfied with the separation of minerals into their component elements1 i4e4 their analysis2 but he sought by synthesis1 i4e4 by combining the separate elements and forming substances similar to those constructed by nature1 to prove the accuracy of his processes and the correctness of his conclusions4 ,thus he formed1 for instance1 pumice-stone1 feldspar1 mica1 iron pyrites1 c4 artificially4 ,but of all the achievements of inorganic chemistry1 the artificial formation of lapis lazuli was the most brilliant and the most conclusive4 ,this mineral1 as presented to us by nature1 is calculated powerfully to arrest our attention by its beautiful azure-blue colour1 its remaining unchanged by exposure to air or to fire1 and furnishing us with a most valuable pigment1 ,ultramarine1 more precious than gold6 ,the analysis of lapis lazuli represented it to be composed of silica1 alumina1 and soda1 three colourless bodies1 with sulphur and a trace of iron4 ,nothing could be discovered in it of the nature of a pigment1 nothing to which its blue colour could be referred1 the cause of which was searched for in vain4 ,it might therefore have been supposed that the analyst was here altogether at fault1 and that at any rate its artificial production must be impossible4 ,nevertheless1 this has been accomplished1 and simply by combining in the proper proportions1 as determined by analysis1 silica1 alumina1 soda1 iron1 and sulphur4 ,thousands of pounds weight are now manufactured from these ingredients1 and this artificial ultramarine is as beautiful as the natural1 while for the price of a single ounce of the latter we may obtain many pounds of the former4 ,with the production of artificial lapis lazuli1 the formation of mineral bodies by synthesis ceased to be a scientific problem to the chemist2 he has no longer sufficient interest in it to pursue the subject4 ,he may now be satisfied that analysis will reveal to him the true constitution of minerals4 ,but to the mineralogist and geologist it is still in a great measure an unexplored field1 offering inquiries of the highest interest and importance to their pursuits4 ,after becoming acquainted with the constituent elements of all the substances within our reach and the mutual relations of these elements1 the remarkable transmutations to which the bodies are subject under the influence of the vital powers of plants and animals1 became the principal object of chemical investigations1 and the highest point of interest4 ,a new science1 inexhaustible as life itself1 is here presented us1 standing upon the sound and solid foundation of a well established inorganic chemistry4 ,thus the progress of science is1 like the development of nature's works1 gradual and expansive4 ,after the buds and branches spring forth the leaves and blossoms1 after the blossoms the fruit4 ,chemistry1 in its application to animals and vegetables1 endeavours jointly with physiology to enlighten us respecting the mysterious processes and sources of organic life4 ,,letter ,,ii ,my dear ,sir1 ,in my former letter ,i reminded you that three of the supposed elements of the ancients represent the forms or state in which all the ponderable matter of our globe exists2 ,i would now observe1 that no substance possesses absolutely any one of those conditions2 that modern chemistry recognises nothing unchangeably solid1 liquid1 or aeriform3 means have been devised for effecting a change of state in almost every known substance4 ,platinum1 alumina1 and rock crystal1 it is true1 cannot be liquified by the most intense heat of our furnaces1 but they melt like wax before the flame of the oxy-hydrogen blowpipe4 ,on the other hand1 of the twenty-eight gaseous bodies with which we are acquainted1 twenty-five may be reduced to a liquid state1 and one into a solid4 ,probably1 ere long1 similar changes of condition will be extended to every form of matter4 ,there are many things relating to this condensation of the gases worthy of your attention4 ,most aeriform bodies1 when subjected to compression1 are made to occupy a space which diminishes in the exact ratio of the increase of the compressing force4 ,very generally1 under a force double or triple of the ordinary atmospheric pressure1 they become one half or one third their former volume4 ,this was a long time considered to be a law1 and known as the law of ,marriotte2 but a more accurate study of the subject has demonstrated that this law is by no means of general application4 ,the volume of certain gases does not decrease in the ratio of the increase of the force used to compress them1 but in some1 a diminution of their bulk takes place in a far greater degree as the pressure increases4 ,again1 if ammoniacal gas is reduced by a compressing force to one-sixth of its volume1 or carbonic acid is reduced to one thirty-sixth1 a portion of them loses entirely the form of a gas1 and becomes a liquid1 which1 when the pressure is withdrawn1 assumes again in an instant its gaseous state--another deviation from the law of ,marriotte4 ,our process for reducing gases into fluids is of admirable simplicity4 ,a simple bent tube1 or a reduction of temperature by artificial means1 have superseded the powerful compressing machines of the early experimenters4 ,the cyanuret of mercury1 when heated in an open glass tube1 is resolved into cyanogen gas and metallic mercury2 if this substance is heated in a tube hermetically sealed1 the decomposition occurs as before1 but the gas1 unable to escape1 and shut up in a space several hundred times smaller than it would occupy as gas under the ordinary atmospheric pressure1 becomes a fluid in that part of the tube which is kept cool4 ,when sulphuric acid is poured upon limestone in an open vessel1 carbonic acid escapes with effervescence as a gas1 but if the decomposition is effected in a strong1 close1 and suitable vessel of iron1 we obtain the carbonic acid in the state of liquid4 ,in this manner it may be obtained in considerable quantities1 even many pounds weight4 ,carbonic acid is separated from other bodies with which it is combined as a fluid under a pressure of thirty-six atmospheres4 ,the curious properties of fluid carbonic acid are now generally known4 ,when a small quantity is permitted to escape into the atmosphere1 it assumes its gaseous state with extraordinary rapidity1 and deprives the remaining fluid of caloric so rapidly that it congeals into a white crystalline mass like snow3 at first1 indeed1 it was thought to be really snow1 but upon examination it proved to be pure frozen carbonic acid4 ,this solid1 contrary to expectation1 exercises only a feeble pressure upon the surrounding medium4 ,the fluid acid inclosed in a glass tube rushes at once1 when opened1 into a gaseous state1 with an explosion which shatters the tube into fragments2 but solid carbonic acid can be handled without producing any other effect than a feeling of intense cold4 ,the particles of the carbonic acid being so closely approximated in the solid1 the whole force of cohesive attraction 7which in the fluid is weak7 becomes exerted1 and opposes its tendency to assume its gaseous state2 but as it receives heat from surrounding bodies1 it passes into gas gradually and without violence4 ,the transition of solid carbonic acid into gas deprives all around it of caloric so rapidly and to so great an extent1 that a degree of cold is produced immeasurably great1 the greatest indeed known4 ,ten1 twenty1 or more pounds weight of mercury1 brought into contact with a mixture of ether and solid carbonic acid1 becomes in a few moments firm and malleable4 ,this1 however1 cannot be accomplished without considerable danger4 ,a melancholy accident occurred at ,paris1 which will probably prevent for the future the formation of solid carbonic acid in these large quantities1 and deprive the next generation of the gratification of witnessing these curious experiments4 ,just before the commencement of the lecture in the ,laboratory of the ,polytechnic ,school1 an iron cylinder1 two feet and a half long and one foot in diameter1 in which carbonic acid had been developed for experiment before the class1 burst1 and its fragments were scattered about with the most tremendous force2 it cut off both the legs of the assistant and killed him on the spot4 ,this vessel1 formed of the strongest cast-iron1 and shaped like a cannon1 had often been employed to exhibit experiments in the presence of the students4 ,we can scarcely think1 without shuddering1 of the dreadful calamity such an explosion would have occasioned in a hall filled with spectators4 ,when we had ascertained the fact of gases becoming fluid under the influence of cold or pressure1 a curious property possessed by charcoal1 that of absorbing gas to the extent of many times its volume1--ten1 twenty1 or even as in the case of ammoniacal gas or muriatic acid gas1 eighty or ninety fold1--which had been long known1 no longer remained a mystery4 ,some gases are absorbed and condensed within the pores of the charcoal1 into a space several hundred times smaller than they before occupied2 and there is now no doubt they there become fluid1 or assume a solid state4 ,as in a thousand other instances1 chemical action here supplants mechanical forces4 ,adhesion or heterogeneous attraction1 as it is termed1 acquired by this discovery a more extended meaning2 it had never before been thought of as a cause of change of state in matter2 but it is now evident that a gas adheres to the surface of a solid body by the same force which condenses it into a liquid4 ,the smallest amount of a gas1--atmospheric air for instance1--can be compressed into a space a thousand times smaller by mere mechanical pressure1 and then its bulk must be to the least measurable surface of a solid body1 as a grain of sand to a mountain4 ,by the mere effect of mass1--the force of gravity1--gaseous molecules are attracted by solids and adhere to their surfaces2 and when to this physical force is added the feeblest chemical affinity1 the liquifiable gases cannot retain their gaseous state4 ,the amount of air condensed by these forces upon a square inch of surface is certainly not measurable2 but when a solid body1 presenting several hundred square feet of surface within the space of a cubic inch1 is brought into a limited volume of gas1 we may understand why that volume is diminished1 why all gases without exception are absorbed4 ,a cubic inch of charcoal must have1 at the lowest computation1 a surface of one hundred square feet4 ,this property of absorbing gases varies with different kinds of charcoal3 it is possessed in a higher degree by those containing the most pores1 i4e4 where the pores are finer2 and in a lower degree in the more spongy kinds1 i4e4 where the pores are larger4 ,in this manner every porous body--rocks1 stones1 the clods of the fields1 c41--imbibe air1 and therefore oxygen2 the smallest solid molecule is thus surrounded by its own atmosphere of condensed oxygen2 and if in their vicinity other bodies exist which have an affinity for oxygen1 a combination is effected4 ,when1 for instance1 carbon and hydrogen are thus present1 they are converted into nourishment for vegetables1--into carbonic acid and water4 ,the development of heat when air is imbibed1 and the production of steam when the earth is moistened by rain1 are acknowledged to be consequences of this condensation by the action of surfaces4 ,but the most remarkable and interesting case of this kind of action is the imbibition of oxygen by metallic platinum4 ,this metal1 when massive1 is of a lustrous white colour1 but it may be brought1 by separating it from its solutions1 into so finely divided a state1 that its particles no longer reflect light1 and it forms a powder as black as soot4 ,in this condition it absorbs eight hundred times its volume of oxygen gas1 and this oxygen must be contained within it in a state of condensation very like that of fluid water4 ,when gases are thus condensed1 i4e4 their particles made to approximate in this extraordinary manner1 their properties can be palpably shown4 ,their chemical actions become apparent as their physical characteristic disappears4 ,the latter consists in the continual tendency of their particles to separate from each other2 and it is easy to imagine that this elasticity of gaseous bodies is the principal impediment to the operation of their chemical force2 for this becomes more energetic as their particles approximate4 ,in that state in which they exist within the pores or upon the surface of solid bodies1 their repulsion ceases1 and their whole chemical action is exerted4 ,thus combinations which oxygen cannot enter into1 decompositions which it cannot effect while in the state of gas1 take place with the greatest facility in the pores of platinum containing condensed oxygen4 ,when a jet of hydrogen gas1 for instance1 is thrown upon spongy platinum1 it combines with the oxygen condensed in the interior of the mass2 at their point of contact water is formed1 and as the immediate consequence heat is evolved2 the platinum becomes red hot and the gas is inflamed4 ,if we interrupt the current of the gas1 the pores of the platinum become instantaneously filled again with oxygen2 and the same phenomenon can be repeated a second time1 and so on interminably4 ,in finely pulverised platinum1 and even in spongy platinum1 we therefore possess a perpetuum mobile--a mechanism like a watch which runs out and winds itself up--a force which is never exhausted--competent to produce effects of the most powerful kind1 and self-renewed ad infinitum4 ,many phenomena1 formerly inexplicable1 are satisfactorily explained by these recently discovered properties of porous bodies4 ,the metamorphosis of alcohol into acetic acid1 by the process known as the quick vinegar manufacture1 depends upon principles1 at a knowledge of which we have arrived by a careful study of these properties4 ,,letter ,,iii ,my dear ,sir1 ,the manufacture of soda from common culinary salt1 may be regarded as the foundation of all our modern improvements in the domestic arts2 and we may take it as affording an excellent illustration of the dependence of the various branches of human industry and commerce upon each other1 and their relation to chemistry4 ,soda has been used from time immemorial in the manufacture of soap and glass1 two chemical productions which employ and keep in circulation an immense amount of capital4 ,the quantity of soap consumed by a nation would be no inaccurate measure whereby to estimate its wealth and civilisation4 ,of two countries1 with an equal amount of population1 the wealthiest and most highly civilised will consume the greatest weight of soap4 ,this consumption does not subserve sensual gratification1 nor depend upon fashion1 but upon the feeling of the beauty1 comfort1 and welfare1 attendant upon cleanliness2 and a regard to this feeling is coincident with wealth and civilisation4 ,the rich in the middle ages concealed a want of cleanliness in their clothes and persons under a profusion of costly scents and essences1 whilst they were more luxurious in eating and drinking1 in apparel and horses4 ,with us a want of cleanliness is equivalent to insupportable misery and misfortune4 ,soap belongs to those manufactured products1 the money value of which continually disappears from circulation1 and requires to be continually renewed4 ,it is one of the few substances which are entirely consumed by use1 leaving no product of any worth4 ,broken glass and bottles are by no means absolutely worthless2 for rags we may purchase new cloth1 but soap-water has no value whatever4 ,it would be interesting to know accurately the amount of capital involved in the manufacture of soap2 it is certainly as large as that employed in the coffee trade1 with this important difference as respects ,germany1 that it is entirely derived from our own soil4 ,france formerly imported soda from ,spain1--,spanish sodas being of the best quality--at an annual expenditure of twenty to thirty millions of francs4 ,during the war with ,england the price of soda1 and consequently of soap and glass1 rose continually2 and all manufactures suffered in consequence4 ,the present method of making soda from common salt was discovered by ,le ,blanc at the end of the last century4 ,it was a rich boon for ,france1 and became of the highest importance during the wars of ,napoleon4 ,in a very short time it was manufactured to an extraordinary extent1 especially at the seat of the soap manufactories4 ,marseilles possessed for a time a monopoly of soda and soap4 ,the policy of ,napoleon deprived that city of the advantages derived from this great source of commerce1 and thus excited the hostility of the population to his dynasty1 which became favourable to the restoration of the ,bourbons4 ,a curious result of an improvement in a chemical manufacture6 ,it was not long1 however1 in reaching ,england4 ,in order to prepare the soda of commerce 7which is the carbonate7 from common salt1 it is first converted into ,glauber's salt 7sulphate of soda74 ,for this purpose #hj pounds weight of concentrated sulphuric acid 7oil of vitriol7 are required to #ajj pounds of common salt4 ,the duty upon salt checked1 for a short time1 the full advantage of this discovery2 but when the ,government repealed the duty1 and its price was reduced to its minimum1 the cost of soda depended upon that of sulphuric acid4 ,the demand for sulphuric acid now increased to an immense extent2 and1 to supply it1 capital was embarked abundantly1 as it afforded an excellent remuneration4 ,the origin and formation of sulphuric acid was studied most carefully2 and from year to year1 better1 simpler1 and cheaper methods of making it were discovered4 ,with every improvement in the mode of manufacture1 its price fell2 and its sale increased in an equal ratio4 ,sulphuric acid is now manufactured in leaden chambers1 of such magnitude that they would contain the whole of an ordinary-sized house4 ,as regards the process and the apparatus1 this manufacture has reached its acme--scarcely is either susceptible of improvement4 ,the leaden plates of which the chambers are constructed1 requiring to be joined together with lead 7since tin or solder would be acted on by the acid71 this process was1 until lately1 as expensive as the plates themselves2 but now1 by means of the oxy-hydrogen blowpipe1 the plates are cemented together at their edges by mere fusion1 without the intervention of any kind of solder4 ,and then1 as to the process3 according to theory1 #ajj pounds weight of sulphur ought to produce #cjf pounds of sulphuric acid2 in practice #cjj pounds are actually obtained2 the amount of loss is therefore too insignificant for consideration4 ,again2 saltpetre being indispensable in making sulphuric acid1 the commercial value of that salt had formerly an important influence upon its price4 ,it is true that #ajj pounds of saltpetre only are required to #ajjj pounds of sulphur2 but its cost was four times greater than an equal weight of the latter4 ,travellers had observed near the small seaport of ,yquiqui1 in the district of ,atacama1 in ,peru1 an efflorescence covering the ground over extensive districts4 ,this was found to consist principally of nitrate of soda4 ,advantage was quickly taken of this discovery4 ,the quantity of this valuable salt proved to be inexhaustible1 as it exists in beds extending over more than #bjj square miles4 ,it was brought to ,england at less than half the freight of the ,east ,india saltpetre 7nitrate of potassa72 and as1 in the chemical manufacture neither the potash nor the soda were required1 but only the nitric acid1 in combination with the alkali1 the soda-saltpetre of ,south ,america soon supplanted the potash-nitre of the ,east4 ,the manufacture of sulphuric acid received a new impulse2 its price was much diminished without injury to the manufacturer2 and1 with the exception of fluctuations caused by the impediments thrown in the way of the export of sulphur from ,sicily1 it soon became reduced to a minimum1 and remained stationary4 ,potash-saltpetre is now only employed in the manufacture of gunpowder2 it is no longer in demand for other purposes2 and thus1 if ,government effect a saving of many hundred thousand pounds annually in gunpowder1 this economy must be attributed to the increased manufacture of sulphuric acid4 ,we may form an idea of the amount of sulphuric acid consumed1 when we find that #ej1jjj pounds weight are made by a small manufactory1 and from #bjj1jjj to #fjj1jjj pounds by a large one annually4 ,this manufacture causes immense sums to flow annually into ,sicily4 ,it has introduced industry and wealth into the arid and desolate districts of ,atacama4 ,it has enabled us to obtain platina from its ores at a moderate and yet remunerating price2 since the vats employed for concentrating this acid are constructed of this metal1 and cost from #ajjjl4 to #bjjjl4 sterling4 ,it leads to frequent improvements in the manufacture of glass1 which continually becomes cheaper and more beautiful4 ,it enables us to return to our fields all their potash--a most valuable and important manure--in the form of ashes1 by substituting soda in the manufacture of glass and soap4 ,it is impossible to trace1 within the compass of a letter1 all the ramifications of this tissue of changes and improvements resulting from one chemical manufacture2 but ,i must still claim your attention to a few more of its most important and immediate results4 ,i have already told you1 that in the manufacture of soda from culinary salt1 it is first converted into sulphate of soda4 ,in this first part of the process1 the action of sulphuric acid produces muriatic acid to the extent of one-and-a-half the amount of the sulphuric acid employed4 ,at first1 the profit upon the soda was so great1 that no one took the trouble to collect the muriatic acid3 indeed it had no commercial value4 ,a profitable application of it was1 however1 soon discovered3 it is a compound of chlorine1 and this substance may be obtained from it purer than from any other source4 ,the bleaching power of chlorine has long been known2 but it was only employed upon a large scale after it was obtained from this residuary muriatic acid1 and it was found that in combination with lime it could be transported to distances without inconvenience4 ,thenceforth it was used for bleaching cotton2 and1 but for this new bleaching process1 it would scarcely have been possible for the cotton manufacture of ,great ,britain to have attained its present enormous extent1--it could not have competed in price with ,france and ,germany4 ,in the old process of bleaching1 every piece must be exposed to the air and light during several weeks in the summer1 and kept continually moist by manual labour4 ,for this purpose1 meadow land1 eligibly situated1 was essential4 ,now a single establishment near ,glasgow bleaches #adjj pieces of cotton daily1 throughout the year4 ,what an enormous capital would be required to purchase land for this purpose6 ,how greatly would it increase the cost of bleaching to pay interest upon this capital1 or to hire so much land in ,england6 ,this expense would scarcely have been felt in ,germany4 ,besides the diminished expense1 the cotton stuffs bleached with chlorine suffer less in the hands of skilful workmen than those bleached in the sun2 and already the peasantry in some parts of ,germany have adopted it1 and find it advantageous4 ,another use to which cheap muriatic acid is applied1 is the manufacture of glue from bones4 ,bone contains from #cj to #cf per cent4 of earthy matter--chiefly phosphate of lime1 and the remainder is gelatine4 ,when bones are digested in muriatic acid they become transparent and flexible like leather1 the earthy matter is dissolved1 and after the acid is all carefully washed away1 pieces of glue of the same shape as the bones remain1 which are soluble in hot water and adapted to all the purposes of ordinary glue1 without further preparation4 ,another important application of sulphuric acid may be adduced2 namely1 to the refining of silver and the separation of gold1 which is always present in some proportion in native silver4 ,silver1 as it is usually obtained from mines in ,europe1 contains in #af ounces1 #f to #h ounces of copper4 ,when used by the silversmith1 or in coining1 #af ounces must contain in ,germany #ac ounces of silver1 in ,england about #ad #a_/b4 ,but this alloy is always made artificially by mixing pure silver with the due proportion of the copper2 and for this purpose the silver must be obtained pure by the refiner4 ,this he formerly effected by amalgamation1 or by roasting it with lead2 and the cost of this process was about #bl4 for every hundred-weight of silver4 ,in the silver so prepared1 about #a_/abjj to #a_/bjjjth part of gold remained2 to effect the separation of this by nitrio-hydrochloric acid was more expensive than the value of the gold2 it was therefore left in utensils1 or circulated in coin1 valueless4 ,the copper1 too1 of the native silver was no use whatever4 ,but the #a_/ajjjth part of gold1 being about one and a half per cent4 of the value of the silver1 now covers the cost of refining1 and affords an adequate profit to the refiner2 so that he effects the separation of the copper1 and returns to his employer the whole amount of the pure silver1 as well as the copper1 without demanding any payment3 he is amply remunerated by that minute portion of gold4 ,the new process of refining is a most beautiful chemical operation3 the granulated metal is boiled in concentrated sulphuric acid1 which dissolves both the silver and the copper1 leaving the gold nearly pure1 in the form of a black powder4 ,the solution is then placed in a leaden vessel containing metallic copper2 this is gradually dissolved1 and the silver precipitated in a pure metallic state4 ,the sulphate of copper thus formed is also a valuable product1 being employed in the manufacture of green and blue pigments4 ,other immediate results of the economical production of sulphuric acid1 are the general employment of phosphorus matches1 and of stearine candles1 that beautiful substitute for tallow and wax4 ,twenty-five years ago1 the present prices and extensive applications of sulphuric and muriatic acids1 of soda1 phosphorus1 c41 would have been considered utterly impossible4 ,who is able to foresee what new and unthought-of chemical productions1 ministering to the service and comforts of mankind1 the next twenty-five years may produce8 ,after these remarks you will perceive that it is no exaggeration to say1 we may fairly judge of the commercial prosperity of a country from the amount of sulphuric acid it consumes4 ,reflecting upon the important influence which the price of sulphur exercises upon the cost of production of bleached and printed cotton stuffs1 soap1 glass1 c41 and remembering that ,great ,britain supplies ,america1 ,spain1 ,portugal1 and the ,east1 with these1 exchanging them for raw cotton1 silk1 wine1 raisins1 indigo1 c41 c41 we can understand why the ,english ,government should have resolved to resort to war with ,naples1 in order to abolish the sulphur monopoly1 which the latter power attempted recently to establish4 ,nothing could be more opposed to the true interests of ,sicily than such a monopoly2 indeed1 had it been maintained a few years1 it is highly probable that sulphur1 the source of her wealth1 would have been rendered perfectly valueless to her4 ,science and industry form a power to which it is dangerous to present impediments4 ,it was not difficult to perceive that the issue would be the entire cessation of the exportation of sulphur from ,sicily4 ,in the short period the sulphur monopoly lasted1 fifteen patents were taken out for methods to obtain back the sulphuric acid used in making soda4 ,admitting that these fifteen experiments were not perfectly successful1 there can be no doubt it would ere long have been accomplished4 ,but then1 in gypsum1 7sulphate of lime71 and in heavy-spar1 7sulphate of barytes71 we possess mountains of sulphuric acid2 in galena1 7sulphate of lead71 and in iron pyrites1 we have no less abundance of sulphur4 ,the problem is1 how to separate the sulphuric acid1 or the sulphur1 from these native stores4 ,hundreds of thousands of pounds weight of sulphuric acid were prepared from iron pyrites1 while the high price of sulphur consequent upon the monopoly lasted4 ,we should probably ere long have triumphed over all difficulties1 and have separated it from gypsum4 ,the impulse has been given1 the possibility of the process proved1 and it may happen in a few years that the inconsiderate financial speculation of ,naples may deprive her of that lucrative commerce4 ,in like manner ,russia1 by her prohibitory system1 has lost much of her trade in tallow and potash4 ,one country purchases only from absolute necessity from another1 which excludes her own productions from her markets4 ,instead of the tallow and linseed oil of ,russia1 ,great ,britain now uses palm oil and cocoa-nut oil of other countries4 ,precisely analogous is the combination of workmen against their employers1 which has led to the construction of many admirable machines for superseding manual labour4 ,in commerce and industry every imprudence carries with it its own punishment2 every oppression immediately and sensibly recoils upon the head of those from whom it emanates4 ,,letter ,,iv ,my dear ,sir1 ,one of the most influential causes of improvement in the social condition of mankind is that spirit of enterprise which induces men of capital to adopt and carry out suggestions for the improvement of machinery1 the creation of new articles of commerce1 or the cheaper production of those already in demand2 and we cannot but admire the energy with which such men devote their talents1 their time1 and their wealth1 to realise the benefits of the discoveries and inventions of science4 ,for even when these are expended upon objects wholly incapable of realisation1--nay1 even when the idea which first gave the impulse proves in the end to be altogether impracticable or absurd1 immediate good to the community generally ensues2 some useful and perhaps unlooked-for result flows directly1 or springs ultimately1 from exertions frustrated in their main design4 ,thus it is also in the pursuit of science4 ,theories lead to experiments and investigations2 and he who investigates will scarcely ever fail of being rewarded by discoveries4 ,it may be1 indeed1 the theory sought to be established is entirely unfounded in nature2 but while searching in a right spirit for one thing1 the inquirer may be rewarded by finding others far more valuable than those which he sought4 ,at the present moment1 electro-magnetism1 as a moving power1 is engaging great attention and study2 wonders are expected from its application to this purpose4 ,according to the sanguine expectations of many persons1 it will shortly be employed to put into motion every kind of machinery1 and amongst other things it will be applied to impel the carriages of railroads1 and this at so small a cost1 that expense will no longer be matter of consideration4 ,england is to lose her superiority as a manufacturing country1 inasmuch as her vast store of coals will no longer avail her as an economical source of motive power4 ,we1 say the ,german cultivators of this science1 have cheap zinc1 and1 how small a quantity of this metal is required to turn a lathe1 and consequently to give motion to any kind of machinery6 ,such expectations may be very attractive1 and yet they are altogether illusory6 they will not bear the test of a few simple calculations2 and these our friends have not troubled themselves to institute4 ,with a simple flame of spirits of wine1 under a proper vessel containing boiling water1 a small carriage of #bjj to #cjj pounds weight can be put into motion1 or a weight of #hj to #ajj pounds may be raised to a height of #bj feet4 ,the same effects may be produced by dissolving zinc in dilute sulphuric acid in a certain apparatus4 ,this is certainly an astonishing and highly interesting discovery2 but the question to be determined is1 which of the two processes is the least expensive8 ,in order to answer this question1 and to judge correctly of the hopes entertained from this discovery1 let me remind you of what chemists denominate equivalents4 ,these are certain unalterable ratios of effects which are proportionate to each other1 and may therefore be expressed in numbers4 ,thus1 if we require #h pounds of oxygen to produce a certain effect1 and we wish to employ chlorine for the same effect1 we must employ neither more nor less than #ce #a_/b pounds weight4 ,in the same manner1 #f pounds weight of coal are equivalent to #cb pounds weight of zinc4 ,the numbers representing chemical equivalents express very general ratios of effects1 comprehending for all bodies all the actions they are capable of producing4 ,if zinc be combined in a certain manner with another metal1 and submitted to the action of dilute sulphuric acid1 it is dissolved in the form of an oxide2 it is in fact burned at the expense of the oxygen contained in the fluid4 ,a consequence of this action is the production of an electric current1 which1 if conducted through a wire1 renders it magnetic4 ,in thus effecting the solution of a pound weight1 for example1 of zinc1 we obtain a definite amount of force adequate to raise a given weight one inch1 and to keep it suspended2 and the amount of weight it will be capable of suspending will be the greater the more rapidly the zinc is dissolved4 ,by alternately interrupting and renewing the contact of the zinc with the acid1 and by very simple mechanical arrangements1 we can give to the iron an upward and downward or a horizontal motion1 thus producing the conditions essential to the motion of any machinery4 ,this moving force is produced by the oxidation of the zinc2 and1 setting aside the name given to the force in this case1 we know that it can be produced in another manner4 ,if we burn the zinc under the boiler of a steam-engine1 consequently in the oxygen of the air instead of the galvanic pile1 we should produce steam1 and by it a certain amount of force4 ,if we should assume1 7which1 however1 is not proved17 that the quantity of force is unequal in these cases1--that1 for instance1 we had obtained double or triple the amount in the galvanic pile1 or that in this mode of generating force less loss is sustained1--we must still recollect the equivalents of zinc and coal1 and make these elements of our calculation4 ,according to the experiments of ,despretz1 #f pounds weight of zinc1 in combining with oxygen1 develops no more heat than #a pound of coal2 consequently1 under equal conditions1 we can produce six times the amount of force with a pound of coal as with a pound of zinc4 ,it is therefore obvious that it would be more advantageous to employ coal instead of zinc1 even if the latter produced four times as much force in a galvanic pile1 as an equal weight of coal by its combustion under a boiler4 ,indeed it is highly probable1 that if we burn under the boiler of a steam-engine the quantity of coal required for smelting the zinc from its ores1 we shall produce far more force than the whole of the zinc so obtained could originate in any form of apparatus whatever4 ,heat1 electricity1 and magnetism1 have a similar relation to each other as the chemical equivalents of coal1 zinc1 and oxygen4 ,by a certain measure of electricity we produce a corresponding proportion of heat or of magnetic power2 we obtain that electricity by chemical affinity1 which in one shape produces heat1 in another electricity or magnetism4 ,a certain amount of affinity produces an equivalent of electricity in the same manner as1 on the other hand1 we decompose equivalents of chemical compounds by a definite measure of electricity4 ,the magnetic force of the pile is therefore limited to the extent of the chemical affinity1 and in the case before us is obtained by the combination of the zinc and sulphuric acid4 ,in the combustion of coal1 the heat results from1 and is measured by1 the affinity of the oxygen of the atmosphere for that substance4 ,it is true that with a very small expense of zinc1 we can make an iron wire a magnet capable of sustaining a thousand pounds weight of iron2 let us not allow ourselves to be misled by this4 ,such a magnet could not raise a single pound weight of iron two inches1 and therefore could not impart motion4 ,the magnet acts like a rock1 which while at rest presses with a weight of a thousand pounds upon a basis2 it is like an inclosed lake1 without an outlet and without a fall4 ,but it may be said1 we have1 by mechanical arrangements1 given it an outlet and a fall4 ,true2 and this must be regarded as a great triumph of mechanics2 and ,i believe it is susceptible of further improvements1 by which greater force may be obtained4 ,but with every conceivable advantage of mechanism1 no one will dispute that one pound of coal1 under the boiler of a steam-engine1 will give motion to a mass several hundred times greater than a pound of zinc in the galvanic pile4 ,our experience of the employment of electro-magnetism as a motory power is1 however1 too recent to enable us to foresee the ultimate results of contrivances to apply it2 and1 therefore1 those who have devoted themselves to solve the problem of its application should not be discouraged1 inasmuch as it would undoubtedly be a most important achievement to supersede the steam-engine1 and thus escape the danger of railroads1 even at double their expense4 ,professor ,weber of ,gottingen has thrown out a suggestion1 that if a contrivance could be devised to enable us to convert at will the wheels of the steam-carriage into magnets1 we should be enabled to ascend and descend acclivities with great facility4 ,this notion may ultimately be1 to a certain extent1 realised4 ,the employment of the galvanic pile as a motory power1 however1 must1 like every other contrivance1 depend upon the question of its relative economy3 probably some time hence it may so far succeed as to be adopted in certain favourable localities2 it may stand in the same relation to steam power as the manufacture of beet sugar bears to that of cane1 or as the production of gas from oils and resins to that from mineral coal4 ,the history of beet-root sugar affords us an excellent illustration of the effect of prices upon commercial productions4 ,this branch of industry seems at length1 as to its processes1 to be perfected4 ,the most beautiful white sugar is now manufactured from the beet-root1 in the place of the treacle-like sugar1 having the taste of the root1 which was first obtained2 and instead of #c or #d per cent41 the proportion obtained by ,achard1 double or even treble that amount is now produced4 ,and notwithstanding the perfection of the manufacture1 it is probable it will ere long be in most places entirely discontinued4 ,in the years #ahbd to #ahbg1 the prices of agricultural produce were much lower than at present1 while the price of sugar was the same4 ,at that time one malter #a of wheat was #ajs41 and one klafter #b of wood #ahs41 and land was falling in price4 ,thus1 food and fuel were cheap1 and the demand for sugar unlimited2 it was1 therefore1 advantageous to grow beet-root1 and to dispose of the produce of land as sugar4 ,all these circumstances are now different4 ,a malter of wheat costs #ahs42 a klafter of wood1 #cjs4 to #cfs4 ,wages have risen1 but not in proportion1 whilst the price of colonial sugar has fallen4 ,within the limits of the ,german commercial league1 as1 for instance1 at ,frankfort-on-the-,maine1 a pound of the whitest and best loaf sugar is #g;d42 the import duty is #ca_/;d41 or #cjs4 per cwt41 leaving #ca_/;d4 as the price of the sugar4 ,in the year #ahbg1 then1 one malter of wheat was equal to #dj lbs4 weight of sugar1 whilst at present that quantity of wheat is worth #gj lbs4 of sugar4 ,if indeed fuel were the same in price as formerly1 and #gj lbs4 of sugar could be obtained from the same quantity of the root as then yielded #dj lbs41 it might still be advantageously produced2 but the amount1 if now obtained by the most approved methods of extraction1 falls far short of this2 and as fuel is double the price1 and labour dearer1 it follows that1 at present1 it is far more advantageous to cultivate wheat and to purchase sugar4 ,there are1 however1 other elements which must enter into our calculations2 but these serve to confirm our conclusion that the manufacture of beet-root sugar as a commercial speculation must cease4 ,the leaves and residue of the root1 after the juice was expressed1 were used as food for cattle1 and their value naturally increased with the price of grain4 ,by the process formerly pursued1 #ge lbs4 weight of juice were obtained from #ajj lbs4 of beet-root1 and gave #e lbs4 of sugar4 ,the method of ,schutzenbach1 which was eagerly adopted by the manufacturers1 produced from the same quantity of root #h lbs4 of sugar2 but it was attended with more expense to produce1 and the loss of the residue as food for cattle4 ,the increased expense in this process arises from the larger quantity of fuel required to evaporate the water2 for instead of merely evaporating the juice1 the dry residue is treated with water1 and we require fuel sufficient to evaporate #ajf lbs4 of fluid instead of #ge lbs41 and the residue is only fit for manure4 ,the additional #c lbs4 of sugar are purchased at the expense of much fuel1 and the loss of the residue as an article of food4 ,if the valley of the ,rhine possessed mines of diamonds as rich as those of ,golconda1 ,visiapoor1 or the ,brazils1 they would probably not be worth the working3 at those places the cost of extraction is #bhs4 to #cjs4 the carat4 ,with us it amounts to three or four times as much--to more1 in fact1 than diamonds are worth in the market4 ,the sand of the ,rhine contains gold2 and in the ,grand ,duchy of ,baden many persons are occupied in gold-washing when wages are low2 but as soon as they rise1 this employment ceases4 ,the manufacture of sugar from beet-root1 in the like manner1 twelve to fourteen years ago offered advantages which are now lost3 instead1 therefore1 of maintaining it at a great sacrifice1 it would be more reasonable1 more in accordance with true natural economy1 to cultivate other and more valuable productions1 and with them purchase sugar4 ,not only would the state be the gainer1 but every member of the community4 ,this argument does not apply1 perhaps1 to ,france and ,bohemia1 where the prices of fuel and of colonial sugar are very different to those in ,germany4 ,the manufacture of gas for lighting1 from coal1 resin1 and oils1 stands with us on the same barren ground4 ,the price of the materials from which gas is manufactured in ,england bears a direct proportion to the price of corn3 there the cost of tallow and oil is twice as great as in ,germany1 but iron and coal are two-thirds cheaper2 and even in ,england the manufacture of gas is only advantageous when the other products of the distillation of coal1 the coke1 c41 can be sold4 ,it would certainly be esteemed one of the greatest discoveries of the age if any one could succeed in condensing coal gas into a white1 dry1 solid1 odourless substance1 portable1 and capable of being placed upon a candlestick1 or burned in a lamp4 ,wax1 tallow1 and oil1 are combustible gases in a solid or fluid form1 which offer many advantages for lighting1 not possessed by gas3 they furnish1 in well-constructed lamps1 as much light1 without requiring the expensive apparatus necessary for the combustion of gas1 and they are generally more economical4 ,in large towns1 or such establishments as hotels1 where coke is in demand1 and where losses in stolen tallow or oil must be considered1 together with the labour of snuffing candles and cleaning lamps1 the higher price of gas is compensated4 ,in places where gas can be manufactured from resin1 oil of turpentine1 and other cheap oils1 as at ,frankfort1 this is advantageous so long as it is pursued on small scale only4 ,if large towns were lighted in the same manner1 the materials would rise in price3 the whole amount at present produced would scarcely suffice for two such towns as ,berlin and ,munich4 ,but no just calculation can be made from the present prices of turpentine1 resin1 c41 which are not produced upon any large scale4 ,footnote #a3 ,malter--a measure containing several bushels1 but varying in different countries4 ,footnote #b3 ,klafter--a cord1 a stack1 measuring six feet every way4 ,,letter ,v ,my dear ,sir1 ,until very recently it was supposed that the physical qualities of bodies1 i4e4 hardness1 colour1 density1 transparency1 c41 and still more their chemical properties1 must depend upon the nature of their elements1 or upon their composition4 ,it was tacitly received as a principle1 that two bodies containing the same elements in the same proportion1 must of necessity possess the same properties4 ,we could not imagine an exact identity of composition giving rise to two bodies entirely different in their sensible appearance and chemical relations4 ,the most ingenious philosophers entertained the opinion that chemical combination is an inter-penetration of the particles of different kinds of matter1 and that all matter is susceptible of infinite division4 ,this has proved to be altogether a mistake4 ,if matter were infinitely divisible in this sense1 its particles must be imponderable1 and a million of such molecules could not weigh more than an infinitely small one4 ,but the particles of that imponderable matter1 which1 striking upon the retina1 give us the sensation of light1 are not in a mathematical sense infinitely small4 ,inter-penetration of elements in the production of a chemical compound1 supposes two distinct bodies1 ,a and ,b1 to occupy one and the same space at the same time4 ,if this were so1 different properties could not consist with an equal and identical composition4 ,that hypothesis1 however1 has shared the fate of innumerable imaginative explanations of natural phenomena1 in which our predecessors indulged4 ,they have now no advocate4 ,the force of truth1 dependent upon observation1 is irresistible4 ,a great many substances have been discovered amongst organic bodies1 composed of the same elements in the same relative proportions1 and yet exhibiting physical and chemical properties perfectly distinct one from another4 ,to such substances the term ,isomeric 7from #a_/;ao#a_/ equal and aei#a_/o#a_/ part7 is applied4 ,a great class of bodies1 known as the volatile oils1 oil of turpentine1 essence of lemons1 oil of balsam of copaiba1 oil of rosemary1 oil of juniper1 and many others1 differing widely from each other in their odour1 in their medicinal effects1 in their boiling point1 in their specific gravity1 c41 are exactly identical in composition1--they contain the same elements1 carbon and hydrogen1 in the same proportions4 ,how admirably simple does the chemistry of organic nature present itself to us from this point of view6 ,an extraordinary variety of compound bodies produced with equal weights of two elements6 and how wide their dissimilarity6 ,the crystallised part of the oil of roses1 the delicious fragrance of which is so well known1 a solid at ordinary temperatures1 although readily volatile1 is a compound body containing exactly the same elements1 and in the same proportions1 as the gas we employ for lighting our streets2 and1 in short1 the same elements1 in the same relative quantities1 are found in a dozen other compounds1 all differing essentially in their physical and chemical properties4 ,these remarkable truths1 so highly important in their applications1 were not received and admitted as sufficiently established1 without abundant proofs4 ,many examples have long been known where the analysis of two different bodies gave the same composition2 but such cases were regarded as doubtful3 at any rate1 they were isolated observations1 homeless in the realms of science3 until1 at length1 examples were discovered of two or more bodies whose absolute identity of composition1 with totally distinct properties1 could be demonstrated in a more obvious and conclusive manner than by mere analysis2 that is1 they can be converted and reconverted into each other without addition and without subtraction4 ,in cyanuric acid1 hydrated cyanic acid1 and cyamelide1 we have three such isomeric compounds4 ,cyanuric acid is crystalline1 soluble in water1 and capable of forming salts with metallic oxides4 ,hydrated cyanic acid is a volatile and highly blistering fluid1 which cannot be brought into contact with water without being instantaneously decomposed4 ,cyamelide is a white substance very like porcelain1 absolutely insoluble in water4 ,now if we place the first1--cyanuric acid1--in a vessel hermetically sealed1 and apply a high degree of heat1 it is converted by its influence into hydrated cyanic acid2 and1 then1 if this is kept for some time at the common temperature1 it passes into cyamelide1 no other element being present4 ,and1 again inversely1 cyamelide can be converted into cyanuric acid and hydrated cyanic acid4 ,we have three other bodies which pass through similar changes1 in aldehyde1 metaldehyde1 and etaldehyde2 and1 again two1 in urea and cyanuret of ammonia4 ,further1 #ajj parts of aldehyde hydrated butyric acid and acetic ether contain the same elements in the same proportion4 ,thus one substance may be converted into another without addition or subtraction1 and without the participation of any foreign bodies in the change4 ,the doctrine that matter is not infinitely divisible1 but on the contrary1 consists of atoms incapable of further division1 alone furnishes us with a satisfactory explanation of these phenomena4 ,in chemical combinations1 the ultimate atoms of bodies do not penetrate each other1 they are only arranged side by side in a certain order1 and the properties of the compound depend entirely upon this order4 ,if they are made to change their place--their mode of arrangement--by an impulse from without1 they combine again in a different manner1 and another compound is formed with totally different properties4 ,we may suppose that one atom combines with one atom of another element to form a compound atom1 while in other bodies two and two1 four and four1 eight and eight1 are united2 so that in all such compounds the amount per cent4 of the elements is absolutely equal2 and yet their physical and chemical properties must be totally different1 the constitution of each atom being peculiar1 in one body consisting of two1 in another of four1 in a third of eight1 and in a fourth of sixteen simple atoms4 ,the discovery of these facts immediately led to many most beautiful and interesting results2 they furnished us with a satisfactory explanation of observations which were before veiled in mystery1--a key to many of ,nature's most curious recesses4 ,again2 solid bodies1 whether simple or compound1 are capable of existing in two states1 which are known by the terms amorphous and crystalline4 ,when matter is passing from a gaseous or liquid state slowly into a solid1 an incessant motion is observed1 as if the molecules were minute magnets2 they are seen to repel each other in one direction1 and to attract and cohere together in another1 and in the end become arranged into a regular form1 which under equal circumstances is always the same for any given kind of matter2 that is1 crystals are formed4 ,time and freedom of motion for the particles of bodies are necessary to the formation of crystals4 ,if we force a fluid or a gas to become suddenly solid1 leaving no time for its particles to arrange themselves1 and cohere in that direction in which the cohesive attraction is strongest1 no crystals will be formed1 but the resulting solid will have a different colour1 a different degree of hardness and cohesion1 and will refract light differently2 in one word1 will be amorphous4 ,thus we have cinnabar as a red and a jet-black substance2 sulphur a fixed and brittle body1 and soft1 semitransparent1 and ductile2 glass as a milk-white opaque substance1 so hard that it strikes fire with steel1 and in its ordinary and well-known state4 ,these dissimilar states and properties of the same body are occasioned in one case by a regular1 in the other by an irregular1 arrangement of its atoms2 one is crystalline1 the other amorphous4 ,applying these facts to natural productions1 we have reason to believe that clay-slate1 and many kinds of greywacke1 are amorphous feldspar1 as transition limestone is amorphous marble1 basalt and lava mixtures of amorphous zeolite and augite4 ,anything that influences the cohesion1 must also in a certain degree alter the properties of bodies4 ,carbonate of lime1 if crystallised at ordinary temperatures1 possesses the crystalline form1 hardness1 and refracting power of common spar2 if crystallised at a higher temperature1 it has the form and properties of arragonite4 ,finally1 ,isomorphism1 or the equality of form of many chemical compounds having a different composition1 tends to prove that matter consists of atoms the mere arrangement of which produces all the properties of bodies4 ,but when we find that a different arrangement of the same elements gives rise to various physical and chemical properties1 and a similar arrangement of different elements produces properties very much the same1 may we not inquire whether some of those bodies which we regard as elements may not be merely modifications of the same substance8--whether they are not the same matter in a different state of arrangement8 ,we know in fact the existence of iron in two states1 so dissimilar1 that in the one1 it is to the electric chain like platinum1 and in the other it is like zinc2 so that powerful galvanic machines have been constructed of this one metal4 ,among the elements are several instances of remarkable similarity of properties4 ,thus there is a strong resemblance between platinum and iridium2 bromine and iodine2 iron1 manganese1 and magnesium2 cobalt and nickel2 phosphorus and arsenic2 but this resemblance consists mainly in their forming isomorphous compounds in which these elements exist in the same relative proportion4 ,these compounds are similar1 because the atoms of which they are composed are arranged in the same manner4 ,the converse of this is also true3 nitrate of strontia becomes quite dissimilar to its common state if a certain proportion of water is taken into its composition4 ,if we suppose selenium to be merely modified sulphur1 and phosphorus modified arsenic1 how does it happen1 we must inquire1 that sulphuric acid and selenic acid1 phosphoric and arsenic acid1 respectively form compounds which it is impossible to distinguish by their form and solubility8 ,were these merely isomeric1 they ought to exhibit properties quite dissimilar6 ,we have not1 ,i believe1 at present the remotest ground to suppose that any one of those substances which chemists regard as elements can be converted into another4 ,such a conversion1 indeed1 would presuppose that the element was composed of two or more ingredients1 and was in fact not an element2 and until the decomposition of these bodies is accomplished1 and their constituents discovered1 all pretensions to such conversions deserve no notice4 ,dr4 ,brown of ,edinburgh thought he had converted iron into rhodium1 and carbon or paracyanogen into silicon4 ,his paper upon this subject was published in the ,transactions of the ,royal ,society of ,edinburgh1 and contained internal evidence1 without a repetition of his experiments1 that he was totally unacquainted with the principles of chemical analysis4 ,but his experiments have been carefully repeated by qualified persons1 and they have completely proved his ignorance3 his rhodium is iron1 and his silicon an impure incombustible coal4 ,,letter ,,vi ,my dear ,sir1 ,one of the most remarkable effects of the recent progress of science is the alliance of chemistry with physiology1 by which a new and unexpected light has been thrown upon the vital processes of plants and animals4 ,we have now no longer any difficulty in understanding the different actions of aliments1 poisons1 and remedial agents--we have a clear conception of the causes of hunger1 of the exact nature of death2 and we are not1 as formerly1 obliged to content ourselves with a mere description of their symptoms4 ,it is now ascertained with positive certainty1 that all the substances which constitute the food of man must be divided into two great classes1 one of which serves for the nutrition and reproduction of the animal body1 whilst the other ministers to quite different purposes4 ,thus starch1 gum1 sugar1 beer1 wine1 spirits1 c41 furnish no element capable of entering into the composition of blood1 muscular fibre1 or any part which is the seat of the vital principle4 ,it must surely be universally interesting to trace the great change our views have undergone upon these subjects1 as well as to become acquainted with the researches from which our present knowledge is derived4 ,the primary conditions of the maintenance of animal life1 are a constant supply of certain matters1 animal food1 and of oxygen1 in the shape of atmospheric air4 ,during every moment of life1 oxygen is absorbed from the atmosphere in the organs of respiration1 and the act of breathing cannot cease while life continues4 ,the observations of physiologists have demonstrated that the body of an adult man supplied abundantly with food1 neither increases nor diminishes in weight during twenty-four hours1 and yet the quantity of oxygen absorbed into his system1 in that period1 is very considerable4 ,according to the experiments of ,lavoisier1 an adult man takes into his system from the atmosphere1 in one year1 no less than #gdf pounds weight of oxygen2 the calculations of ,menzies make the quantity amount even to #hcg pounds2 but we find his weight at the end of the year either exactly the same or different one way or the other by at most a few pounds4 ,what1 it may be asked1 has become of the enormous amount of oxygen thus introduced into the human system in the course of one year8 ,we can answer this question satisfactorily4 ,no part of the oxygen remains in the body1 but is given out again1 combined with carbon and hydrogen4 ,the carbon and hydrogen of certain parts of the animal body combine with the oxygen introduced through the lungs and skin1 and pass off in the forms of carbonic acid and vapour of water4 ,at every expiration and every moment of life1 a certain amount of its elements are separated from the animal organism1 having entered into combination with the oxygen of the atmosphere4 ,in order to obtain a basis for the approximate calculation1 we may assume1 with ,lavoisier and ,seguin1 that an adult man absorbs into his system #cb #a_/b ounces of oxygen daily1--that is1 #df1jcg cubic inches #ae1ffa grains1 ,french weight2 and further1 that the weight of the whole mass of his blood is #bd pounds1 of which #hj per cent4 is water4 ,now1 from the known composition of the blood1 we know that in order to convert its whole amount of carbon and hydrogen into carbonic acid and water1 #fd4ajb grains of oxygen are required4 ,this quantity will be taken into the system in four days and five hours4 ,whether the oxygen enters into combination directly with the elements of the blood1 or with the carbon and hydrogen of other parts of the body1 it follows inevitably--the weight of the body remaining unchanged and in a normal condition--that as much of these elements as will suffice to supply #bd pounds of blood1 must be taken into the system in four days and five hours2 and this necessary amount is furnished by the food4 ,we have not1 however1 remained satisfied with mere approximation3 we have determined accurately1 in certain cases1 the quantity of carbon taken daily in the food1 and of that which passes out of the body in the faeces and urine combined--that is1 uncombined with oxygen2 and from these investigations it appears that an adult man taking moderate exercise consumes #ac4i ounces of carbon1 which pass off through the skin and lungs as carbonic acid gas4 #a ,it requires #cg ounces of oxygen to convert #ac #i_/aj of carbon into carbonic acid4 ,again2 according to the analysis of ,boussingault1 7,annales de ,chim4 et de ,phys41 lxx4 i4 p4#acf71 a horse consumes #gi #a_/aj ounces of carbon in twenty-four hours1 a milch cow #gj #c_/d ounces2 so that the horse requires #ac pounds #c #a_/b ounces1 and the cow #aa pounds #aj #c_/d ounces of oxygen4 #b ,as no part of the oxygen taken into the system of an animal is given off in any other form than combined with carbon or hydrogen1 and as in a normal condition1 or state of health1 the carbon and hydrogen so given off are replaced by those elements in the food1 it is evident that the amount of nourishment required by an animal for its support must be in a direct ratio with the quantity of oxygen taken in to its system4 ,two animals which in equal times take up by means of the lungs and skin unequal quantities of oxygen1 consume an amount of food unequal in the same ratio4 ,the consumption of oxygen in a given time may be expressed by the number of respirations2 it is1 therefore1 obvious that in the same animal the quantity of nourishment required must vary with the force and number of respirations4 ,a child breathes quicker than an adult1 and1 consequently1 requires food more frequently and proportionably in larger quantity1 and bears hunger less easily4 ,a bird deprived of food dies on the third day1 while a serpent1 confined under a bell1 respires so slowly that the quantity of carbonic acid generated in an hour can scarcely be observed1 and it will live three months1 or longer1 without food4 ,the number of respirations is fewer in a state of rest than during labour or exercise3 the quantity of food necessary in both cases must be in the same ratio4 ,an excess of food1 a want of a due amount of respired oxygen1 or of exercise1 as also great exercise 7which obliges us to take an increased supply of food71 together with weak organs of digestion1 are incompatible with health4 ,but the quantity of oxygen received by an animal through the lungs not only depends upon the number of respirations1 but also upon the temperature of the respired air4 ,the size of the thorax of an animal is unchangeable2 we may therefore regard the volume of air which enters at every inspiration as uniform4 ,but its weight1 and consequently the amount of oxygen it contains1 is not constant4 ,air is expanded by heat1 and contracted by cold--an equal volume of hot and cold air contains1 therefore1 an unequal amount of oxygen4 ,in summer atmospheric air contains water in the form of vapour1 it is nearly deprived of it in winter2 the volume of oxygen in the same volume of air is smaller in summer than in winter4 ,in summer and winter1 at the pole and at the equator1 we inspire an equal volume of air2 the cold air is warmed during respiration and acquires the temperature of the body4 ,in order1 therefore1 to introduce into the lungs a given amount of oxygen1 less expenditure of force is necessary in winter than in summer1 and for the same expenditure of force more oxygen is inspired in winter4 ,it is also obvious that in an equal number of respirations we consume more oxygen at the level of the sea than on a mountain4 ,the oxygen taken into the system is given out again in the same form1 both in summer and winter3 we expire more carbon at a low than at a high temperature1 and require more or less carbon in our food in the same proportion2 and1 consequently1 more is respired in ,sweden than in ,sicily1 and in our own country and eighth more in winter than in summer4 ,even if an equal weight of food is consumed in hot and cold climates1 ,infinite ,wisdom has ordained that very unequal proportions of carbon shall be taken in it4 ,the food prepared for the inhabitants of southern climes does not contain in a fresh state more than #ab per cent4 of carbon1 while the blubber and train oil which feed the inhabitants of ,polar regions contain #ff to #hj per cent4 of that element4 ,from the same cause it is comparatively easy to be temperate in warm climates1 or to bear hunger for a long time under the equator2 but cold and hunger united very soon produce exhaustion4 ,the oxygen of the atmosphere received into the blood in the lungs1 and circulated throughout every part of the animal body1 acting upon the elements of the food1 is the source of animal heat4 ,footnote #a3 ,this account is deduced from observations made upon the average daily consumption of about #cj soldiers in barracks4 ,the food of these men1 consisting of meat1 bread1 potatoes1 lentils1 peas1 beans1 butter1 salt1 pepper1 c41 was accurately weighed during a month1 and each article subjected to ultimate analysis4 ,of the quantity of food1 beer1 and spirits1 taken by the men when out of barracks1 we have a close approximation from the report of the sergeant2 and from the weight and analysis of the faeces and urine1 it appears that the carbon which passes off through these channels may be considered equivalent to the amount taken in that portion of the food1 and of sour-crout1 which was not included in the estimate4 ,footnote #b3 #ag4e ounces #j4e kilogramme4 ,,letter ,,vii ,my dear ,sir1 ,the source of animal heat1 its laws1 and the influence it exerts upon the functions of the animal body1 constitute a curious and highly interesting subject1 to which ,i would now direct your attention4 ,all living creatures1 whose existence depends upon the absorption of oxygen1 possess within themselves a source of heat1 independent of surrounding objects4 ,this general truth applies to all animals1 and extends to the seed of plants in the act of germination1 to flower-buds when developing1 and fruits during their maturation4 ,in the animal body1 heat is produced only in those parts to which arterial blood1 and with it the oxygen absorbed in respiration1 is conveyed4 ,hair1 wool1 and feathers1 receive no arterial blood1 and1 therefore1 in them no heat is developed4 ,the combination of a combustible substance with oxygen is1 under all circumstances1 the only source of animal heat4 ,in whatever way carbon may combine with oxygen1 the act of combination is accompanied by the disengagement of heat4 ,it is indifferent whether this combination takes place rapidly or slowly1 at a high or at a low temperature3 the amount of heat liberated is a constant quantity4 ,the carbon of the food1 being converted into carbonic acid within the body1 must give out exactly as much heat as if it had been directly burnt in oxygen gas or in common air2 the only difference is1 the production of the heat is diffused over unequal times4 ,in oxygen gas the combustion of carbon is rapid and the heat intense2 in atmospheric air it burns slower and for a longer time1 the temperature being lower2 in the animal body the combination is still more gradual1 and the heat is lower in proportion4 ,it is obvious that the amount of heat liberated must increase or diminish with the quantity of oxygen introduced in equal times by respiration4 ,those animals1 therefore1 which respire frequently1 and consequently consume much oxygen1 possess a higher temperature than others1 which1 with a body of equal size to be heated1 take into the system less oxygen4 ,the temperature of a child 7#ajb deg7 is higher than that of an adult 7#ii #a_/b deg74 ,that of birds 7#ajd deg to #aje4d deg7 is higher than that of quadrupeds 7#ih #a_/b deg to #ajj4d deg7 or than that of fishes or amphibia1 whose proper temperature is from #b4g to #c4f deg higher than that of the medium in which they live4 ,all animals1 strictly speaking1 are warm-blooded2 but in those only which possess lungs is the temperature of the body quite independent of the surrounding medium4 ,the most trustworthy observations prove that in all climates1 in the temperate zones as well as at the equator or the poles1 the temperature of the body in man1 and in what are commonly called warm-blooded animals1 is invariably the same2 yet how different are the circumstances under which they live6 ,the animal body is a heated mass1 which bears the same relation to surrounding objects as any other heated mass4 ,it receives heat when the surrounding objects are hotter1 it loses heat when they are colder1 than itself4 ,we know that the rapidity of cooling increases with the difference between the temperature of the heated body and that of the surrounding medium2 that is1 the colder the surrounding medium the shorter the time required for the cooling of the heated body4 ,how unequal1 then1 must be the loss of heat in a man at ,palermo1 where the external temperature is nearly equal to that of the body1 and in the polar regions1 where the external temperature is from #gj deg to #ij deg lower6 ,yet1 notwithstanding this extremely unequal loss of heat1 experience has shown that the blood of the inhabitant of the arctic circle has a temperature as high as that of the native of the south1 who lives in so different a medium4 ,this fact1 when its true significance is perceived1 proves that the heat given off to the surrounding medium is restored within the body with great rapidity4 ,this compensation must consequently take place more rapidly in winter than in summer1 at the pole than at the equator4 ,now1 in different climates the quantity of oxygen introduced into the system by respiration1 as has been already shown1 varies according to the temperature of the external air2 the quantity of inspired oxygen increases with the loss of heat by external cooling1 and the quantity of carbon or hydrogen necessary to combine with this oxygen must be increased in the same ratio4 ,it is evident that the supply of the heat lost by cooling is effected by the mutual action of the elements of the food and the inspired oxygen1 which combine together4 ,to make use of a familiar1 but not on that account a less just illustration1 the animal body acts1 in this respect1 as a furnace1 which we supply with fuel4 ,it signifies nothing what intermediate forms food may assume1 what changes it may undergo in the body2 the last change is uniformly the conversion of its carbon into carbonic acid1 and of its hydrogen into water4 ,the unassimilated nitrogen of the food1 along with the unburned or unoxidised carbon1 is expelled in the urine or in the solid excrements4 ,in order to keep up in the furnace a constant temperature1 we must vary the supply of fuel according to the external temperature1 that is1 according to the supply of oxygen4 ,in the animal body the food is the fuel2 with a proper supply of oxygen we obtain the heat given out during its oxidation or combustion4 ,in winter1 when we take exercise in a cold atmosphere1 and when consequently the amount of inspired oxygen increases1 the necessity for food containing carbon and hydrogen increases in the same ratio2 and by gratifying the appetite thus excited1 we obtain the most efficient protection against the most piercing cold4 ,a starving man is soon frozen to death4 ,the animals of prey in the arctic regions1 as every one knows1 far exceed in voracity those of the torrid zone4 ,in cold and temperate climates1 the air1 which incessantly strives to consume the body1 urges man to laborious efforts in order to furnish the means of resistance to its action1 while1 in hot climates1 the necessity of labour to provide food is far less urgent4 ,our clothing is merely an equivalent for a certain amount of food4 ,the more warmly we are clothed the less urgent becomes the appetite for food1 because the loss of heat by cooling1 and consequently the amount of heat to be supplied by the food1 is diminished4 ,if we were to go naked1 like certain savage tribes1 or if in hunting or fishing we were exposed to the same degree of cold as the ,samoyedes1 we should be able with ease to consume #aj lbs4 of flesh1 and perhaps a dozen of tallow candles into the bargain1 daily1 as warmly clad travellers have related with astonishment of these people4 ,we should then also be able to take the same quantity of brandy or train oil without bad effects1 because the carbon and hydrogen of these substances would only suffice to keep up the equilibrium between the external temperature and that of our bodies4 ,according to the preceding expositions1 the quantity of food is regulated by the number of respirations1 by the temperature of the air1 and by the amount of heat given off to the surrounding medium4 ,no isolated fact1 apparently opposed to this statement1 can affect the truth of this natural law4 ,without temporary or permanent injury to health1 the ,neapolitan cannot take more carbon and hydrogen in the shape of food than he expires as carbonic acid and water2 and the ,esquimaux cannot expire more carbon and hydrogen than he takes in the system as food1 unless in a state of disease or of starvation4 ,let us examine these states a little more closely4 ,the ,englishman in ,jamaica perceives with regret the disappearance of his appetite1 previously a source of frequently recurring enjoyment2 and he succeeds1 by the use of cayenne pepper1 and the most powerful stimulants1 in enabling himself to take as much food as he was accustomed to eat at home4 ,but the whole of the carbon thus introduced into the system is not consumed2 the temperature of the air is too high1 and the oppressive heat does not allow him to increase the number of respirations by active exercise1 and thus to proportion the waste to the amount of food taken2 disease of some kind1 therefore1 ensues4 ,on the other hand1 ,england sends her sick to southern regions1 where the amount of the oxygen inspired is diminished in a very large proportion4 ,those whose diseased digestive organs have in a greater or less degree lost the power of bringing the food into the state best adapted for oxidation1 and therefore are less able to resist the oxidising influence of the atmosphere of their native climate1 obtain a great improvement in health4 ,the diseased organs of digestion have power to place the diminished amount of food in equilibrium with the inspired oxygen1 in the mild climate2 whilst in a colder region the organs of respiration themselves would have been consumed in furnishing the necessary resistance to the action of the atmospheric oxygen4 ,in our climate1 hepatic diseases1 or those arising from excess of carbon1 prevail in summer2 in winter1 pulmonary diseases1 or those arising from excess of oxygen1 are more frequent4 ,the cooling of the body1 by whatever cause it may be produced1 increases the amount of food necessary4 ,the mere exposure to the open air1 in a carriage or on the deck of a ship1 by increasing radiation and vaporisation1 increases the loss of heat1 and compels us to eat more than usual4 ,the same is true of those who are accustomed to drink large quantities of cold water1 which is given off at the temperature of the body1 #ih #a_/b deg4 ,it increases the appetite1 and persons of weak constitution find it necessary1 by continued exercise1 to supply to the system the oxygen required to restore the heat abstracted by the cold water4 ,loud and long continued speaking1 the crying of infants1 moist air1 all exert a decided and appreciable influence on the amount of food which is taken4 ,we have assumed that carbon and hydrogen especially1 by combining with oxygen1 serve to produce animal heat4 ,in fact1 observation proves that the hydrogen of the food plays a no less important part than the carbon4 ,the whole process of respiration appears most clearly developed1 when we consider the state of a man1 or other animal1 totally deprived of food4 ,the first effect of starvation is the disappearance of fat1 and this fat cannot be traced either in the urine or in the scanty faeces4 ,its carbon and hydrogen have been given off through the skin and lungs in the form of oxidised products2 it is obvious that they have served to support respiration4 ,in the case of a starving man1 #cb #a_/b oz4 of oxygen enter the system daily1 and are given out again in combination with a part of his body4 ,currie mentions the case of an individual who was unable to swallow1 and whose body lost #ajj lbs4 in weight during a month2 and1 according to ,martell 7,trans4 ,linn4 ,soc41 vol4 xi4 p4#daa71 a fat pig1 overwhelmed in a slip of earth1 lived #afj days without food1 and was found to have diminished in weight1 in that time1 more than #abj lbs4 ,the whole history of hybernating animals1 and the well-established facts of the periodical accumulation1 in various animals1 of fat1 which1 at other periods1 entirely disappears1 prove that the oxygen1 in the respiratory process1 consumes1 without exception1 all such substances as are capable of entering into combination with it4 ,it combines with whatever is presented to it2 and the deficiency of hydrogen is the only reason why carbonic acid is the chief product2 for1 at the temperature of the body1 the affinity of hydrogen for oxygen far surpasses that of carbon for the same element4 ,we know1 in fact1 that the graminivora expire a volume of carbonic acid equal to that of the oxygen inspired1 while the carnivora1 the only class of animals whose food contains fat1 inspire more oxygen than is equal in volume to the carbonic acid expired4 ,exact experiments have shown1 that in many cases only half the volume of oxygen is expired in the form of carbonic acid4 ,these observations cannot be gainsaid1 and are far more convincing than those arbitrary and artificially produced phenomena1 sometimes called experiments2 experiments which1 made as too often they are1 without regard to the necessary and natural conditions1 possess no value1 and may be entirely dispensed with2 especially when1 as in the present case1 ,nature affords the opportunity for observation1 and when we make a rational use of that opportunity4 ,in the progress of starvation1 however1 it is not only the fat which disappears1 but also1 by degrees all such of the solids as are capable of being dissolved4 ,in the wasted bodies of those who have suffered starvation1 the muscles are shrunk and unnaturally soft1 and have lost their contractibility2 all those parts of the body which were capable of entering into the state of motion have served to protect the remainder of the frame from the destructive influence of the atmosphere4 ,towards the end1 the particles of the brain begin to undergo the process of oxidation1 and delirium1 mania1 and death close the scene2 that is to say1 all resistance to the oxidising power of the atmospheric oxygen ceases1 and the chemical process of eremacausis1 or decay1 commences1 in which every part of the body1 the bones excepted1 enters into combination with oxygen4 ,the time which is required to cause death by starvation depends on the amount of fat in the body1 on the degree of exercise1 as in labour or exertion of any kind1 on the temperature of the air1 and finally1 on the presence or absence of water4 ,through the skin and lungs there escapes a certain quantity of water1 and as the presence of water is essential to the continuance of the vital motions1 its dissipation hastens death4 ,cases have occurred1 in which a full supply of water being accessible to the sufferer1 death has not occurred till after the lapse of twenty days4 ,in one case1 life was sustained in this way for the period of sixty days4 ,in all chronic diseases death is produced by the same cause1 namely1 the chemical action of the atmosphere4 ,when those substances are wanting1 whose function in the organism is to support the process of respiration1 when the diseased organs are incapable of performing their proper function of producing these substances1 when they have lost the power of transforming the food into that shape in which it may1 by entering into combination with the oxygen of the air1 protect the system from its influence1 then1 the substance of the organs themselves1 the fat of the body1 the substance of the muscles1 the nerves1 and the brain1 are unavoidably consumed4 ,the true cause of death in these cases is the respiratory process1 that is1 the action of the atmosphere4 ,a deficiency of food1 and a want of power to convert the food into a part of the organism1 are both1 equally1 a want of resistance2 and this is the negative cause of the cessation of the vital process4 ,the flame is extinguished1 because the oil is consumed2 and it is the oxygen of the air which has consumed it4 ,in many diseases substances are produced which are incapable of assimilation4 ,by the mere deprivation of food1 these substances are removed from the body without leaving a trace behind2 their elements have entered into combination with the oxygen of the air4 ,from the first moment that the function of the lungs or of the skin is interrupted or disturbed1 compounds1 rich in carbon1 appear in the urine1 which acquires a brown colour4 ,over the whole surface of the body oxygen is absorbed1 and combines with all the substances which offer no resistance to it4 ,in those parts of the body where the access of oxygen is impeded2 for example1 in the arm-pits1 or in the soles of the feet1 peculiar compounds are given out1 recognisable by their appearance1 or by their odour4 ,these compounds contain much carbon4 ,respiration is the falling weight--the bent spring1 which keeps the clock in motion2 the inspirations and expirations are the strokes of the pendulum which regulate it4 ,in our ordinary time-pieces1 we know with mathematical accuracy the effect produced on their rate of going1 by changes in the length of the pendulum1 or in the external temperature4 ,few1 however1 have a clear conception of the influence of air and temperature on the health of the human body2 and yet the research into the conditions necessary to keep it in the normal state is not more difficult than in the case of a clock4 ,,letter ,,viii ,my dear ,sir1 ,having attempted in my last letter to explain to you the simple and admirable office subserved by the oxygen of the atmosphere in its combination with carbon in the animal body1 ,i will now proceed to present you with some remarks upon those materials which sustain its mechanisms in motion1 and keep up their various functions1--namely1 the ,aliments4 ,if the increase in mass in an animal body1 the development and reproduction of its organs depend upon the blood1 then those substances only which are capable of being converted into blood can be properly regarded as nourishment4 ,in order then to ascertain what parts of our food are nutritious1 we must compare the composition of the blood with the composition of the various articles taken as food4 ,two substances require especial consideration as the chief ingredients of the blood2 one of these separates immediately from the blood when it is withdrawn from the circulation4 ,it is well known that in this case blood coagulates1 and separates into a yellowish liquid1 the serum of the blood1 and a gelatinous mass1 which adheres to a rod or stick in soft1 elastic fibres1 when coagulating blood is briskly stirred4 ,this is the fibrine of the blood1 which is identical in all its properties with muscular fibre1 when the latter is purified from all foreign matters4 ,the second principal ingredient of the blood is contained in the serum1 and gives to this liquid all the properties of the white of eggs1 with which it is indeed identical4 ,when heated1 it coagulates into a white elastic mass1 and the coagulating substance is called albumen4 ,fibrine and albumen1 the chief ingredients of blood1 contain1 in all1 seven chemical elements1 among which nitrogen1 phosphorus1 and sulphur are found4 ,they contain also the earth of bones4 ,the serum retains in solution sea salt and other salts of potash and soda1 in which the acids are carbonic1 phosphoric1 and sulphuric acids4 ,the globules of the blood contain fibrine and albumen1 along with a red colouring matter1 in which iron is a constant element4 ,besides these1 the blood contains certain fatty bodies in small quantity1 which differ from ordinary fats in several of their properties4 ,chemical analysis has led to the remarkable result1 that fibrine and albumen contain the same organic elements united in the same proportion1--i4e41 that they are isomeric1 their chemical composition--the proportion of their ultimate elements--being identical4 ,but the difference of their external properties shows that the particles of which they are composed are arranged in a different order4 7,see ,letter ,v74 ,this conclusion has lately been beautifully confirmed by a distinguished physiologist 7,denis71 who has succeeded in converting fibrine into albumen1 that is1 in giving it the solubility1 and coagulability by heat1 which characterise the white of egg4 ,fibrine and albumen1 besides having the same composition1 agree also in this1 that both dissolve in concentrated muriatic acid1 yielding a solution of an intense purple colour4 ,this solution1 whether made with fibrine or albumen1 has the very same re-actions with all substances yet tried4 ,both albumen and fibrine1 in the process of nutrition1 are capable of being converted into muscular fibre1 and muscular fibre is capable of being reconverted into blood4 ,these facts have long been established by physiologists1 and chemistry has merely proved that these metamorphoses can be accomplished under the influence of a certain force1 without the aid of a third substance1 or of its elements1 and without the addition of any foreign element1 or the separation of any element previously present in these substances4 ,if we now compare the composition of all organised parts with that of fibrine and albumen1 the following relations present themselves3-- ,all parts of the animal body which have a decided shape1 which form parts of organs1 contain nitrogen4 ,no part of an organ which possesses motion and life is destitute of nitrogen2 all of them contain likewise carbon and the elements of water2 the latter1 however1 in no case in the proportion to form water4 ,the chief ingredients of the blood contain nearly #ag per cent4 of nitrogen1 and from numerous analyses it appears that no part of an organ contains less than #ag per cent4 of nitrogen4 ,the most convincing experiments and observations have proved that the animal body is absolutely incapable of producing an elementary body1 such as carbon or nitrogen1 out of substances which do not contain it2 and it obviously follows1 that all kinds of food fit for the production either of blood1 or of cellular tissue1 membranes1 skin1 hair1 muscular fibre1 c41 must contain a certain amount of nitrogen1 because that element is essential to the composition of the above-named organs2 because the organs cannot create it from the other elements presented to them2 and1 finally1 because no nitrogen is absorbed from the atmosphere in the vital process4 ,the substance of the brain and nerves contains a large quantity of albumen1 and1 in addition to this1 two peculiar fatty acids1 distinguished from other fats by containing phosphorus 7phosphoric acid874 ,one of these contains nitrogen 7,fremy74 ,finally1 water and common fat are those ingredients of the body which are destitute of nitrogen4 ,both are amorphous or unorganised1 and only so far take part in the vital process as that their presence is required for the due performance of the vital functions4 ,the inorganic constituents of the body are1 iron1 lime1 magnesia1 common salt1 and the alkalies4 ,the nutritive process is seen in its simplest form in carnivorous animals4 ,this class of animals lives on the blood and flesh of the graminivora2 but this blood and flesh are1 in all their properties1 identical with their own4 ,neither chemical nor physiological differences can be discovered4 ,the nutriment of carnivorous animals is derived originally from blood2 in their stomach it becomes dissolved1 and capable of reaching all other parts of the body2 in its passage it is again converted into blood1 and from this blood are reproduced all those parts of their organisation which have undergone change or metamorphosis4 ,with the exception of hoofs1 hair1 feathers1 and the earth of bones1 every part of the food of carnivorous animals is capable of assimilation4 ,in a chemical sense1 therefore1 it may be said that a carnivorous animal1 in supporting the vital process1 consumes itself4 ,that which serves for its nutrition is identical with those parts of its organisation which are to be renewed4 ,the process of nutrition in graminivorous animals appears at first sight altogether different4 ,their digestive organs are less simple1 and their food consists of vegetables1 the great mass of which contains but little nitrogen4 ,from what substances1 it may be asked1 is the blood formed1 by means of which of their organs are developed8 ,this question may be answered with certainty4 ,chemical researches have shown1 that all such parts of vegetables as can afford nutriment to animals contain certain constituents which are rich in nitrogen2 and the most ordinary experience proves that animals require for their support and nutrition less of these parts of plants in proportion as they abound in the nitrogenised constituents4 ,animals cannot be fed on matters destitute of these nitrogenised constituents4 ,these important products of vegetation are especially abundant in the seeds of the different kinds of grain1 and of peas1 beans1 and lentils2 in the roots and the juices of what are commonly called vegetables4 ,they exist1 however1 in all plants1 without exception1 and in every part of plants in larger or smaller quantity4 ,these nitrogenised forms of nutriment in the vegetable kingdom may be reduced to three substances1 which are easily distinguished by their external characters4 ,two of them are soluble in water1 the third is insoluble4 ,when the newly-expressed juices of vegetables are allowed to stand1 a separation takes place in a few minutes4 ,a gelatinous precipitate1 commonly of a green tinge1 is deposited1 and this1 when acted on by liquids which remove the colouring matter1 leaves a grayish white substance1 well known to druggists as the deposite from vegetable juices4 ,this is one of the nitrogenised compounds which serves for the nutrition of animals1 and has been named vegetable fibrine4 ,the juice of grapes is especially rich in this constituent1 but it is most abundant in the seeds of wheat1 and of the cerealia generally4 ,it may be obtained from wheat flour by a mechanical operation1 and in a state of tolerable purity2 it is then called gluten1 but the glutinous property belongs1 not to vegetable fibrine1 but to a foreign substance1 present in small quantity1 which is not found in the other cerealia4 ,the method by which it is obtained sufficiently proves that it is insoluble in water2 although we cannot doubt that it was originally dissolved in the vegetable juice1 from which it afterwards separated1 exactly as fibrine does from blood4 ,the second nitrogenised compound remains dissolved in the juice after the separation of the fibrine4 ,it does not separate from the juice at the ordinary temperature1 but is instantly coagulated when the liquid containing it is heated to the boiling point4 ,when the clarified juice of nutritious vegetables1 such as cauliflower1 asparagus1 mangelwurzel1 or turnips1 is made to boil1 a coagulum is formed1 which it is absolutely impossible to distinguish from the substance which separates as a coagulum1 when the serum of blood1 or the white of an egg1 diluted with water1 are heated to the boiling point4 ,this is vegetable albumen4 ,it is found in the greatest abundance in certain seeds1 in nuts1 almonds1 and others1 in which the starch of the gramineae is replaced by oil4 ,the third nitrogenised constituent of the vegetable food of animals is vegetable caseine4 ,it is chiefly found in the seeds of peas1 beans1 lentils1 and similar leguminous seeds4 ,like vegetable albumen1 it is soluble in water1 but differs from it in this1 that its solution is not coagulated by heat4 ,when the solution is heated or evaporated1 a skin forms on its surface1 and the addition of an acid causes a coagulum1 just as in animal milk4 ,these three nitrogenised compounds1 vegetable fibrine1 albumen1 and caseine1 are the true nitrogenised constituents of the food of graminivorous animals2 all other nitrogenised compounds occurring in plants1 are either rejected by animals1 as in the case of the characteristic principles of poisonous and medicinal plants1 or else they occur in the food in such very small proportion1 that they cannot possibly contribute to the increase of mass in the animal body4 ,the chemical analysis of these three substances has led to the very interesting result that they contain the same organic elements1 united in the same proportion by weight2 and1 what is still more remarkable1 that they are identical in composition with the chief constituents of blood1 animal fibrine1 and albumen4 ,they all three dissolve in concentrated muriatic acid with the same deep purple colour1 and even in their physical characters1 animal fibrine and albumen are in no respect different from vegetable fibrine and albumen4 ,it is especially to be noticed1 that by the phrase1 identity of composition1 we do not here intend mere similarity1 but that even in regard to the presence and relative amount of sulphur1 phosphorus1 and phosphate of lime1 no difference can be observed4 ,how beautifully and admirably simple1 with the aid of these discoveries1 appears the process of nutrition in animals1 the formation of their organs1 in which vitality chiefly resides6 ,those vegetable principles1 which in animals are used to form blood1 contain the chief constituents of blood1 fibrine and albumen1 ready formed1 as far as regards their composition4 ,all plants1 besides1 contain a certain quantity of iron1 which reappears in the colouring matter of the blood4 ,vegetable fibrine and animal fibrine1 vegetable albumen and animal albumen1 hardly differ1 even in form2 if these principles be wanting in the food1 the nutrition of the animal is arrested2 and when they are present1 the graminivorous animal obtains in its food the very same principles on the presence of which the nutrition of the carnivora entirely depends4 ,vegetables produce in their organism the blood of all animals1 for the carnivora1 in consuming the blood and flesh of the graminivora1 consume1 strictly speaking1 only the vegetable principles which have served for the nutrition of the latter4 ,vegetable fibrine and albumen take the form in the stomach of the graminivorous animal as animal fibrine and albumen do in that of the carnivorous animal4 ,from what has been said1 it follows that the development of the animal organism and its growth are dependent on the reception of certain principles identical with the chief constituents of blood4 ,in this sense we may say that the animal organism gives to the blood only its form2 that it is incapable of creating blood out of other substances which do not already contain the chief constituents of that fluid4 ,we cannot1 indeed1 maintain that the animal organism has no power to form other compounds1 for we know that it is capable of producing an extensive series of compounds1 differing in composition from the chief constituents of blood2 but these last1 which form the starting-point of the series1 it cannot produce4 ,the animal organism is a higher kind of vegetable1 the development of which begins with those substances with the production of which the life of an ordinary vegetable ends4 ,as soon as the latter has borne seed1 it dies1 or a period of its life comes to a termination4 ,in that endless series of compounds1 which begins with carbonic acid1 ammonia1 and water1 the sources of the nutrition of vegetables1 and includes the most complex constituents of the animal brain1 there is no blank1 no interruption4 ,the first substance capable of affording nutriment to animals is the last product of the creative energy of vegetables4 ,the substance of cellular tissue and of membranes1 of the brain and nerves1 these the vegetable cannot produce4 ,the seemingly miraculous in the productive agency of vegetables disappears in a great degree1 when we reflect that the production of the constituents of blood cannot appear more surprising than the occurrence of the fat of beef and mutton in cocoa beans1 of human fat in olive-oil1 of the principal ingredient of butter in palm-oil1 and of horse fat and train-oil in certain oily seeds4 ,,letter ,,ix ,my dear ,sir1 ,the facts detailed in my last letter will satisfy you as to the manner in which the increase of mass in an animal1 that is1 its growth1 is accomplished2 we have still to consider a most important question1 namely1 the function performed in the animal system by substances destitute of nitrogen2 such as sugar1 starch1 gum1 pectine1 c4 ,the most extensive class of animals1 the graminivora1 cannot live without these substances2 their food must contain a certain amount of one or more of them1 and if these compounds are not supplied1 death quickly ensues4 ,this important inquiry extends also to the constituents of the food of carnivorous animals in the earliest periods of life2 for this food also contains substances1 which are not necessary for their support in the adult state4 ,the nutrition of the young of carnivora is obviously accomplished by means similar to those by which the graminivora are nourished2 their development is dependent on the supply of a fluid1 which the body of the mother secretes in the shape of milk4 ,milk contains only one nitrogenised constituent1 known under the name of caseine2 besides this1 its chief ingredients are butter 7fat71 and sugar of milk4 ,the blood of the young animal1 its muscular fibre1 cellular tissue1 nervous matter1 and bones1 must have derived their origin from the nitrogenised constituent of milk--the caseine2 for butter and sugar of milk contain no nitrogen4 ,now1 the analysis of caseine has led to the result1 which1 after the details ,i have given1 can hardly excite your surprise1 that this substance also is identical in composition with the chief constituents of blood1 fibrine and albumen4 ,nay more--a comparison of its properties with those of vegetable caseine has shown--that these two substances are identical in all their properties2 insomuch1 that certain plants1 such as peas1 beans1 and lentils1 are capable of producing the same substance which is formed from the blood of the mother1 and employed in yielding the blood of the young animal4 ,the young animal1 therefore1 receives in the form of caseine1--which is distinguished from fibrine and albumen by its great solubility1 and by not coagulating when heated1--the chief constituent of the mother's blood4 ,to convert caseine into blood no foreign substance is required1 and in the conversion of the mother's blood into caseine1 no elements of the constituents of the blood have been separated4 ,when chemically examined1 caseine is found to contain a much larger proportion of the earth of bones than blood does1 and that in a very soluble form1 capable of reaching every part of the body4 ,thus1 even in the earliest period of its life1 the development of the organs1 in which vitality resides1 is1 in the carnivorous animal1 dependent on the supply of a substance1 identical in organic composition with the chief constituents of its blood4 ,what1 then1 is the use of the butter and the sugar of milk8 ,how does it happen that these substances are indispensable to life8 ,butter and sugar of milk contain no fixed bases1 no soda nor potash4 ,sugar of milk has a composition closely allied to that of the other kinds of sugar1 of starch1 and of gum2 all of them contain carbon and the elements of water1 the latter precisely in the proportion to form water4 ,there is added1 therefore1 by means of these compounds1 to the nitrogenised constituents of food1 a certain amount of carbon2 or1 as in the case of butter1 of carbon and hydrogen2 that is1 an excess of elements1 which cannot possibly be employed in the production of blood1 because the nitrogenised substances contained in the food already contain exactly the amount of carbon which is required for the production of fibrine and albumen4 ,in an adult carnivorous animal1 which neither gains nor loses weight1 perceptibly1 from day to day1 its nourishment1 the waste of organised tissue1 and its consumption of oxygen1 stand to each other in a well-defined and fixed relation4 ,the carbon of the carbonic acid given off1 with that of the urine2 the nitrogen of the urine1 and the hydrogen given off as ammonia and water2 these elements1 taken together1 must be exactly equal in weight to the carbon1 nitrogen1 and hydrogen of the metamorphosed tissues1 and since these last are exactly replaced by the food1 to the carbon1 nitrogen1 and hydrogen of the food4 ,were this not the case1 the weight of the animal could not possibly remain unchanged4 ,but1 in the young of the carnivora1 the weight does not remain unchanged2 on the contrary1 it increases from day to day by an appreciable quantity4 ,this fact presupposes1 that the assimilative process in the young animal is more energetic1 more intense1 than the process of transformation in the existing tissues4 ,if both processes were equally active1 the weight of the body could not increase2 and were the waste by transformation greater1 the weight of the body would decrease4 ,now1 the circulation in the young animal is not weaker1 but1 on the contrary1 more rapid2 the respirations are more frequent2 and1 for equal bulks1 the consumption of oxygen must be greater rather than smaller in the young than in the adult animal4 ,but1 since the metamorphosis of organised parts goes on more slowly1 there would ensue a deficiency of those substances1 the carbon and hydrogen of which are adapted for combination with oxygen2 because1 in the carnivora1 nature has destined the new compounds1 produced by the metamorphosis of organised parts1 to furnish the necessary resistance to the action of the oxygen1 and to produce animal heat4 ,what is wanting for these purposes an ,infinite ,wisdom has supplied to the young in its natural food4 ,the carbon and hydrogen of butter1 and the carbon of the sugar of milk1 no part of either of which can yield blood1 fibrine1 or albumen1 are destined for the support of the respiratory process1 at an age when a greater resistance is opposed to the metamorphosis of existing organisms2 or1 in other words1 to the production of compounds1 which1 in the adult state1 are produced in quantity amply sufficient for the purpose of respiration4 ,the young animal receives the constituents of its blood in the caseine of the milk4 ,a metamorphosis of existing organs goes on1 for bile and urine are secreted2 the materials of the metamorphosed parts are given off in the form of urine1 of carbonic acid1 and of water2 but the butter and sugar of milk also disappear2 they cannot be detected in the faeces4 ,the butter and sugar of milk are given out in the form of carbonic acid and water1 and their conversion into oxidised products furnishes the clearest proof that far more oxygen is absorbed than is required to convert the carbon and hydrogen of the metamorphosed tissues into carbonic acid and water4 ,the change and metamorphosis of organised tissues going on in the vital process in the young animal1 consequently yield1 in a given time1 much less carbon and hydrogen in the form adapted for the respiratory process than correspond to the oxygen taken up in the lungs4 ,the substance of its organised parts would undergo a more rapid consumption1 and would necessarily yield to the action of the oxygen1 were not the deficiency of carbon and hydrogen supplied from another source4 ,the continued increase of mass1 or growth1 and the free and unimpeded development of the organs in the young animal1 are dependent on the presence of foreign substances1 which1 in the nutritive process1 have no other function than to protect the newly-formed organs from the action of the oxygen4 ,the elements of these substances unite with the oxygen2 the organs themselves could not do so without being consumed2 that is1 growth1 or increase of mass in the body1--the consumption of oxygen remaining the same1--would be utterly impossible4 ,the preceding considerations leave no doubt as to the purpose for which ,nature has added to the food of the young of carnivorous mammalia substances devoid of nitrogen1 which their organism cannot employ for nutrition1 strictly so called1 that is1 for the production of blood2 substances which may be entirely dispensed with in their nourishment in the adult state4 ,in the young of carnivorous birds1 the want of all motion is an obvious cause of diminished waste in the organised parts2 hence1 milk is not provided for them4 ,the nutritive process in the carnivora thus presents itself under two distinct forms2 one of which we again meet with in the graminivora4 ,in graminivorous animals1 we observe1 that during their whole life1 their existence depends on a supply of substances having a composition identical with that of sugar of milk1 or closely resembling it4 ,everything that they consume as food contains a certain quantity of starch1 gum1 or sugar1 mixed with other matters4 ,the function performed in the vital process of the graminivora by these substances is indicated in a very clear and convincing manner1 when we take into consideration the very small relative amount of the carbon which these animals consume in the nitrogenised constituents of their food1 which bears no proportion whatever to the oxygen absorbed through the skin and lungs4 ,a horse1 for example1 can be kept in perfectly good condition1 if he obtain as food #ae lbs4 of hay and #d #a_/b lbs4 of oats daily4 ,if we now calculate the whole amount of nitrogen in these matters1 as ascertained by analysis 7#a #a_/b per cent4 in the hay1 #b4b per cent4 in the oats71 in the form of blood1 that is1 as fibrine and albumen1 with the due proportion of water in blood 7#hj per cent471 the horse receives daily no more than #d #a_/b oz4 of nitrogen1 corresponding to about #h lbs4 of blood4 ,but along with this nitrogen1 that is1 combined with it in the form of fibrine or albumen1 the animal receives only about #ad #a_/b oz4 of carbon4 ,without going further into the calculation1 it will readily be admitted1 that the volume of air inspired and expired by a horse1 the quantity of oxygen consumed1 and1 as a necessary consequence1 the amount of carbonic acid given out by the animal1 are much greater than in the respiratory process in man4 ,but an adult man consumes daily abut #ad oz4 of carbon1 and the determination of ,boussingault1 according to which a horse expires #gi oz4 daily1 cannot be very far from the truth4 ,in the nitrogenised constituents of his food1 therefore1 the horse receives rather less than the fifth part of the carbon which his organism requires for the support of the respiratory process2 and we see that the wisdom of the ,creator has added to his food the four-fifths which are wanting1 in various forms1 as starch1 sugar1 c4 with which the animal must be supplied1 or his organism will be destroyed by the action of the oxygen4 ,it is obvious1 that in the system of the graminivora1 whose food contains so small a portion1 relatively1 of the constituents of the blood1 the process of metamorphosis in existing tissues1 and consequently their restoration or reproduction1 must go on far less rapidly than in the carnivora4 ,were this not the case1 a vegetation a thousand times more luxuriant than the actual one would not suffice for their nourishment4 ,sugar1 gum1 and starch1 would no longer be necessary to support life in these animals1 because1 in that case1 the products of the waste1 or metamorphosis of the organised tissues1 would contain enough carbon to support the respiratory process4 ,,letter ,x ,my dear ,sir1 ,let me now apply the principles announced in the preceding letters to the circumstances of our own species4 ,man1 when confined to animal food1 requires for his support and nourishment extensive sources of food1 even more widely extended than the lion and tiger1 because1 when he has the opportunity1 he kills without eating4 ,a nation of hunters1 on a limited space1 is utterly incapable of increasing its numbers beyond a certain point1 which is soon attained4 ,the carbon necessary for respiration must be obtained from the animals1 of which only a limited number can live on the space supposed4 ,these animals collect from plants the constituents of their organs and of their blood1 and yield them1 in turn1 to the savages who live by the chase alone4 ,they1 again1 receive this food unaccompanied by those compounds1 destitute of nitrogen1 which1 during the life of the animals1 served to support the respiratory process4 ,in such men1 confined to an animal diet1 it is the carbon of the flesh and of the blood which must take the place of starch and sugar4 ,but #ae lbs4 of flesh contain no more carbon than #d lbs4 of starch1 and while the savage with one animal and an equal weight of starch should maintain life and health for a certain number of days1 he would be compelled1 if confined to flesh alone1 in order to procure the carbon necessary for respiration1 during the same time1 to consume five such animals4 ,it is easy to see1 from these considerations1 how close the connection is between agriculture and the multiplication of the human species4 ,the cultivation of our crops has ultimately no other object than the production of a maximum of those substances which are adapted for assimilation and respiration1 in the smallest possible space4 ,grain and other nutritious vegetables yield us1 not only in starch1 sugar1 and gum1 the carbon which protects our organs from the action of oxygen1 and produces in the organism the heat which is essential to life1 but also in the form of vegetable fibrine1 albumen1 and caseine1 our blood1 from which the other parts of our body are developed4 ,man1 when confined to animal food1 respires1 like the carnivora1 at the expense of the matters produced by the metamorphosis of organised tissues2 and1 just as the lion1 tiger1 hyaena1 in the cages of a menagerie1 are compelled to accelerate the waste of the organised tissues by incessant motion1 in order to furnish the matter necessary for respiration1 so1 the savage1 for the very same object1 is forced to make the most laborious exertions1 and go through a vast amount of muscular exercise4 ,he is compelled to consume force merely in order to supply matter for respiration4 ,cultivation is the economy of force4 ,science teaches us the simplest means of obtaining the greatest effect with the smallest expenditure of power1 and with given means to produce a maximum of force4 ,the unprofitable exertion of power1 the waste of force in agriculture1 in other branches of industry1 in science1 or in social economy1 is characteristic of the savage state1 or of the want of knowledge4 ,in accordance with what ,i have already stated1 you will perceive that the substances of which the food of man is composed may be divided into two classes2 into nitrogenised and non-nitrogenised4 ,the former are capable of conversion into blood2 the latter are incapable of this transformation4 ,out of those substances which are adapted to the formation of blood1 are formed all the organised tissues4 ,the other class of substances1 in the normal state of health1 serve to support the process of respiration4 ,the former may be called the plastic elements of nutrition2 the latter1 elements of respiration4 ,among the former we reckon-- ,vegetable fibrine4 ,vegetable albumen4 ,vegetable caseine4 ,animal flesh4 ,animal blood4 ,among the elements of respiration in our food1 are-- ,fat4 ,pectine4 ,starch4 ,bassorine4 ,gum4 ,wine4 ,cane sugar4 ,beer4 ,grape sugar4 ,spirits4 ,sugar of milk4 ,the most recent and exact researches have established as a universal fact1 to which nothing yet known is opposed1 that the nitrogenised constituents of vegetable food have a composition identical with that of the constituents of the blood4 ,no nitrogenised compound1 the composition of which differs from that of fibrine1 albumen1 and caseine1 is capable of supporting the vital process in animals4 ,the animal organism unquestionably possesses the power of forming1 from the constituents of its blood1 the substance of its membranes and cellular tissue1 of the nerves and brain1 and of the organic part of cartilages and bones4 ,but the blood must be supplied to it perfect in everything but its form--that is1 in its chemical composition4 ,if this be not done1 a period is rapidly put to the formation of blood1 and consequently to life4 ,this consideration enables us easily to explain how it happens that the tissues yielding gelatine or chondrine1 as1 for example1 the gelatine of skin or of bones1 are not adapted for the support of the vital process2 for their composition is different from that of fibrine or albumen4 ,it is obvious that this means nothing more than that those parts of the animal organism which form the blood do not possess the power of effecting a transformation in the arrangement of the elements of gelatine1 or of those tissues which contain it4 ,the gelatinous tissues1 the gelatine of the bones1 the membranes1 the cells and the skin suffer1 in the animal body1 under the influence of oxygen and moisture1 a progressive alteration2 a part of these tissues is separated1 and must be restored from the blood2 but this alteration and restoration are obviously confined within very narrow limits4 ,while1 in the body of a starving or sick individual1 the fat disappears and the muscular tissue takes once more the form of blood1 we find that the tendons and membranes retain their natural condition1 and the limbs of the dead body their connections1 which depend on the gelatinous tissues4 ,on the other hand1 we see that the gelatine of bones devoured by a dog entirely disappears1 while only the bone earth is found in his excrements4 ,the same is true of man1 when fed on food rich in gelatine1 as1 for example1 strong soup4 ,the gelatine is not to be found either in the urine or in the faeces1 and consequently must have undergone a change1 and must have served some purpose in the animal economy4 ,it is clear that the gelatine must be expelled from the body in a form different from that in which it was introduced as food4 ,when we consider the transformation of the albumen of the blood into a part of an organ composed of fibrine1 the identity in composition of the two substances renders the change easily conceivable4 ,indeed we find the change of a dissolved substance into an insoluble organ of vitality1 chemically speaking1 natural and easily explained1 on account of this very identity of composition4 ,hence the opinion is not unworthy of a closer investigation1 that gelatine1 when taken in the dissolved state1 is again converted1 in the body1 into cellular tissue1 membrane and cartilage2 that it may serve for the reproduction of such parts of these tissues as have been wasted1 and for their growth4 ,and when the powers of nutrition in the whole body are affected by a change of the health1 then1 even should the power of forming blood remain the same1 the organic force by which the constituents of the blood are transformed into cellular tissue and membranes must necessarily be enfeebled by sickness4 ,in the sick man1 the intensity of the vital force1 its power to produce metamorphoses1 must be diminished as well in the stomach as in all other parts of the body4 ,in this condition1 the uniform experience of practical physicians shows that gelatinous matters in a dissolved state exercise a most decided influence on the state of the health4 ,given in a form adapted for assimilation1 they serve to husband the vital force1 just as may be done1 in the case of the stomach1 by due preparation of the food in general4 ,brittleness in the bones of graminivorous animals is clearly owing to a weakness in those parts of the organism whose function it is to convert the constituents of the blood into cellular tissue and membrane2 and if we can trust to the reports of physicians who have resided in the ,east1 the ,turkish women1 in their diet of rice1 and in the frequent use of enemata of strong soup1 have united the conditions necessary for the formation both of cellular tissue and of fat4 ,,letter ,,xi ,my dear ,sir1 ,in the immense1 yet limited expanse of the ocean1 the animal and vegetable kingdoms are mutually dependent upon1 and successive to each other4 ,the animals obtain their constituent elements from the plants1 and restore them to the water in their original form1 when they again serve as nourishment to a new generation of plants4 ,the oxygen which marine animals withdraw in their respiration from the air1 dissolved in sea water1 is returned to the water by the vital processes of sea plants2 that air is richer in oxygen than atmospheric air1 containing #cb to #cc per cent4 ,oxygen1 also1 combines with the products of the putrefaction of dead animal bodies1 changes their carbon into carbonic acid1 their hydrogen into water1 and their nitrogen assumes again the form of ammonia4 ,thus we observe in the ocean a circulation takes place without the addition or subtraction of any element1 unlimited in duration1 although limited in extent1 inasmuch as in a confined space the nourishment of plants exists in a limited quantity4 ,we well know that marine plants cannot derive a supply of humus for their nourishment through their roots4 ,look at the great sea-tang1 the ,fucus giganteus3 this plant1 according to ,cook1 reaches a height of #cfj feet1 and a single specimen1 with its immense ramifications1 nourishes thousands of marine animals1 yet its root is a small body1 no larger than the fist4 ,what nourishment can this draw from a naked rock1 upon the surface of which there is no perceptible change8 ,it is quite obvious that these plants require only a hold1--a fastening to prevent a change of place1--as a counterpoise to their specific gravity1 which is less than that of the medium in which they float4 ,that medium provides the necessary nourishment1 and presents it to the surface of every part of the plant4 ,sea-water contains not only carbonic acid and ammonia1 but the alkaline and earthy phosphates and carbonates required by these plants for their growth1 and which we always find as constant constituents of their ashes4 ,all experience demonstrates that the conditions of the existence of marine plants are the same which are essential to terrestrial plants4 ,but the latter do not live like sea-plants1 in a medium which contains all their elements and surrounds with appropriate nourishment every part of their organs2 on the contrary1 they require two media1 of which one1 namely the soil1 contains those essential elements which are absent from the medium surrounding them1 i4e4 the atmosphere4 ,is it possible that we could ever be in doubt respecting the office which the soil and its component parts subserve in the existence and growth of vegetables8--that there should have been a time when the mineral elements of plants were not regarded as absolutely essential to their vitality8 ,has not the same circulation been observed on the surface of the earth which we have just contemplated in the ocean1--the same incessant change1 disturbance and restitution of equilibrium8 ,experience in agriculture shows that the production of vegetables on a given surface increases with the supply of certain matters1 originally parts of the soil which had been taken up from it by plants--the excrements of man and animals4 ,these are nothing more than matters derived from vegetable food1 which in the vital processes of animals1 or after their death1 assume again the form under which they originally existed1 as parts of the soil4 ,now1 we know that the atmosphere contains none of these substances1 and therefore can replace none2 and we know that their removal from a soil destroys its fertility1 which may be restored and increased by a new supply4 ,is it possible1 after so many decisive investigations into the origin of the elements of animals and vegetables1 the use of the alkalies1 of lime and the phosphates1 any doubt can exist as to the principles upon which a rational agriculture depends8 ,can the art of agriculture be based upon anything but the restitution of a disturbed equilibrium8 ,can it be imagined that any country1 however rich and fertile1 with a flourishing commerce1 which for centuries exports its produce in the shape of grain and cattle1 will maintain its fertility1 if the same commerce does not restore1 in some form of manure1 those elements which have been removed from the soil1 and which cannot be replaced by the atmosphere8 ,must not the same fate await every such country which has actually befallen the once prolific soil of ,virginia1 now in many parts no longer able to grow its former staple productions--wheat and tobacco8 ,in the large towns of ,england the produce both of ,english and foreign agriculture is largely consumed2 elements of the soil indispensable to plants do not return to the fields1--contrivances resulting from the manners and customs of ,english people1 and peculiar to them1 render it difficult1 perhaps impossible1 to collect the enormous quantity of the phosphates which are daily1 as solid and liquid excrements1 carried into the rivers4 ,these phosphates1 although present in the soil in the smallest quantity1 are its most important mineral constituents4 ,it was observed that many ,english fields exhausted in that manner immediately doubled their produce1 as if by a miracle1 when dressed with bone earth imported from the ,continent4 ,but if the export of bones from ,germany is continued to the extent it has hitherto reached1 our soil must be gradually exhausted1 and the extent of our loss may be estimated1 by considering that one pound of bones contains as much phosphoric acid as a hundred-weight of grain4 ,the imperfect knowledge of ,nature and the properties and relations of matter possessed by the alchemists gave rise1 in their time1 to an opinion that metals as well as plants could be produced from a seed4 ,the regular forms and ramifications seen in crystals1 they imagined to be the leaves and branches of metal plants2 and as they saw the seed of plants grow1 producing root1 stem and leaves1 and again blossoms1 fruit and seeds1 apparently without receiving any supply of appropriate material1 they deemed it worthy of zealous inquiry to discover the seed of gold1 and the earth necessary for its development4 ,if the metal seeds were once obtained1 might they not entertain hopes of their growth8 ,such ideas could only be entertained when nothing was known of the atmosphere1 and its participation with the earth1 in administering to the vital processes of plants and animals4 ,modern chemistry indeed produces the elements of water1 and1 combining them1 forms water anew2 but it does not create those elements--it derives them from water2 the new-formed artificial water has been water before4 ,many of our farmers are like the alchemists of old1--they are searching for the miraculous seed1--the means1 which1 without any further supply of nourishment to a soil scarcely rich enough to be sprinkled with indigenous plants1 shall produce crops of grain a hundred-fold4 ,the experience of centuries1 nay1 of thousands of years1 is insufficient to guard men against these fallacies2 our only security from these and similar absurdities must be derived from a correct knowledge of scientific principles4 ,in the first period of natural philosophy1 organic life was supposed to be derived from water only2 afterwards1 it was admitted that certain elements derived from the air must be superadded to the water2 but we now know that other elements must be supplied by the earth1 if plants are to thrive and multiply4 ,the amount of materials contained in the atmosphere1 suited to the nourishment of plants1 is limited2 but it must be abundantly sufficient to cover the whole surface of the earth with a rich vegetation4 ,under the tropics1 and in those parts of our globe where the most genial conditions of fertility exist1--a suitable soil1 a moist atmosphere1 and a high temperature1--vegetation is scarcely limited by space2 and1 where the soil is wanting1 it is gradually supplied by the decaying leaves1 bark and branches of plants4 ,it is obvious there is no deficiency of atmospheric nourishment for plants in those regions1 nor are these wanting in our own cultivated fields3 all that plants require for their development is conveyed to them by the incessant motions of the atmosphere4 ,the air between the tropics contains no more than that of the arctic zones2 and yet how different is the amount of produce of an equal surface of land in the two situations6 ,this is easily explicable4 ,all the plants of tropical climates1 the oil and wax palms1 the sugar cane1 c41 contain only a small quantity of the elements of the blood necessary to the nutrition of animals1 as compared with our cultivated plants4 ,the tubers of the potato in ,chili1 its native country1 where the plant resembles a shrub1 if collected from an acre of land1 would scarcely suffice to maintain an ,irish family for a single day 7,darwin74 ,the result of cultivation in those plants which serve as food1 is to produce in them those constituents of the blood4 ,in the absence of the elements essential to these in the soil1 starch1 sugar and woody fibre1 are perhaps formed2 but no vegetable fibrine1 albumen1 or caseine4 ,if we intend to produce on a given surface of soil more of these latter matters than the plants can obtain from the atmosphere or receive from the soil of the same surface in its uncultivated and normal state1 we must create an artificial atmosphere1 and add the needed elements to the soil4 ,the nourishment which must be supplied in a given time to different plants1 in order to admit a free and unimpeded growth1 is very unequal4 ,on pure sand1 on calcareous soil1 on naked rocks1 only a few genera of plants prosper1 and these are1 for the most part1 perennial plants4 ,they require1 for their slow growth1 only such minute quantities of mineral substances as the soil can furnish1 which may be totally barren for other species4 ,annual1 and especially summer plants1 grow and attain their perfection in a comparatively short time2 they therefore do not prosper on a soil which is poor in those mineral substances necessary to their development4 ,to attain a maximum in height in the short period of their existence1 the nourishment contained in the atmosphere is not sufficient4 ,if the end of cultivation is to be obtained1 we must create in the soil an artificial atmosphere of carbonic acid and ammonia2 and this surplus of nourishment1 which the leaves cannot appropriate from the air1 must be taken up by the corresponding organs1 i4e4 the roots1 from the soil4 ,but the ammonia1 together with the carbonic acid1 are alone insufficient to become part of a plant destined to the nourishment of animals4 ,in the absence of the alkalies1 the phosphates and other earthy salts1 no vegetable fibrine1 no vegetable caseine1 can be formed4 ,the phosphoric acid of the phosphate of lime1 indispensable to the cerealia and other vegetables in the formation of their seeds1 is separated as an excrement1 in great quantities1 by the rind and barks of ligneous plants4 ,how different are the evergreen plants1 the cacti1 the mosses1 the ferns1 and the pines1 from our annual grasses1 the cerealia and leguminous vegetables6 ,the former1 at every time of the day during winter and summer1 obtain carbon through their leaves by absorbing carbonic acid which is not furnished by the barren soil on which they grow2 water is also absorbed and retained by their coriaceous or fleshy leaves with great force4 ,they lose very little by evaporation1 compared with other plants4 ,on the other hand1 how very small is the quantity of mineral substances which they withdraw from the soil during their almost constant growth in one year1 in comparison with the quantity which one crop of wheat of an equal weight receives in three months6 ,it is by means of moisture that plants receive the necessary alkalies and salts from the soil4 ,in dry summers a phenomenon is observed1 which1 when the importance of mineral elements to the life of a plant was unknown1 could not be explained4 ,the leaves of plants first developed and perfected1 and therefore nearer the surface of the soil1 shrivel up and become yellow1 lose their vitality1 and fall off while the plant is in an active state of growth1 without any visible cause4 ,this phenomenon is not seen in moist years1 nor in evergreen plants1 and but rarely in plants which have long and deep roots1 nor is it seen in perennials in autumn and winter4 ,the cause of this premature decay is now obvious4 ,the perfectly-developed leaves absorb continually carbonic acid and ammonia from the atmosphere1 which are converted into elements of new leaves1 buds1 and shoots2 but this metamorphosis cannot be effected without the aid of the alkalies1 and other mineral substances4 ,if the soil is moist1 the latter are continually supplied to an adequate amount1 and the plant retains its lively green colour2 but if this supply ceases from a want of moisture to dissolve the mineral elements1 a separation takes place in the plant itself4 ,the mineral constituents of the juice are withdrawn from the leaves already formed1 and are used for the formation of the young shoots2 and as soon as the seeds are developed1 the vitality of the leaves completely ceases4 ,these withered leaves contain only minute traces of soluble salts1 while the buds and shoots are very rich in them4 ,on the other hand1 it has been observed1 that where a soil is too highly impregnated with soluble saline materials1 these are separated upon the surface of the leaves4 ,this happens to culinary vegetables especially1 whose leaves become covered with a white crust4 ,in consequence of these exudations the plant sickens1 its organic activity decreases1 its growth is disturbed2 and if this state continues long1 the plant dies4 ,this is most frequently seen in foliaceous plants1 the large surfaces of which evaporate considerable quantities of water4 ,carrots1 pumpkins1 peas1 c41 are frequently thus diseased1 when1 after dry weather1 the plant being near its full growth1 the soil is moistened by short showers1 followed again by dry weather4 ,the rapid evaporation carries off the water absorbed by the root1 and this leaves the salts in the plant in a far greater quantity than it can assimilate4 ,these salts effloresce upon the surface of the leaves1 and if they are herbaceous and juicy1 produce an effect upon them as if they had been watered with a solution containing a greater quantity of salts than their organism can bear4 ,of two plants of the same species1 this disease befalls that which is nearest its perfection2 if one should have been planted later1 or be more backward in its development1 the same external cause which destroys the one will contribute to the growth of the other4 ,,letter ,,xii ,my dear ,sir1 ,having now occupied several letters with the attempt to unravel1 by means of chemistry1 some of the most curious functions of the animal body1 and1 as ,i hope1 made clear to you the distinctions between the two kinds of constituent elements in food1 and the purposes they severally subserve in sustaining life1 let me now direct your attention to a scarcely less interesting and equally important subject--the means of obtaining from a given surface of the earth the largest amount of produce adapted to the food of man and animals4 ,agriculture is both a science and an art4 ,the knowledge of all the conditions of the life of vegetables1 the origin of their elements1 and the sources of their nourishment1 forms its scientific basis4 ,from this knowledge we derive certain rules for the exercise of the ,,art1 the principles upon which the mechanical operations of farming depend1 the usefulness or necessity of these for preparing the soil to support the growth of plants1 and for removing every obnoxious influence4 ,no experience1 drawn from the exercise of the art1 can be opposed to true scientific principles1 because the latter should include all the results of practical operations1 and are in some instances solely derived therefrom4 ,theory must correspond with experience1 because it is nothing more than the reduction of a series of phenomena to their last causes4 ,a field in which we cultivate the same plant for several successive years becomes barren for that plant in a period varying with the nature of the soil3 in one field it will be in three1 in another in seven1 in a third in twenty1 in a fourth in a hundred years4 ,one field bears wheat1 and no peas2 another beans or turnips1 but no tobacco2 a third gives a plentiful crop of turnips1 but will not bear clover4 ,what is the reason that a field loses its fertility for one plant1 the same which at first flourished there8 ,what is the reason one kind of plant succeeds in a field where another fails8 ,these questions belong to ,science4 ,what means are necessary to preserve to a field its fertility for one and the same plant8--what to render one field fertile for two1 for three1 for all plants8 ,these last questions are put by ,art1 but they cannot be answered by ,art4 ,if a farmer1 without the guidance of just scientific principles1 is trying experiments to render a field fertile for a plant which it otherwise will not bear1 his prospect of success is very small4 ,thousands of farmers try such experiments in various directions1 the result of which is a mass of practical experience forming a method of cultivation which accomplishes the desired end for certain places2 but the same method frequently does not succeed1 it indeed ceases to be applicable to a second or third place in the immediate neighbourhood4 ,how large a capital1 and how much power1 are wasted in these experiments6 ,very different1 and far more secure1 is the path indicated by ,,science2 it exposes us to no danger of failing1 but1 on the contrary1 it furnishes us with every guarantee of success4 ,if the cause of failure--of barrenness in the soil for one or two plants--has been discovered1 means to remedy it may readily be found4 ,the most exact observations prove that the method of cultivation must vary with the geognostical condition of the subsoil4 ,in basalt1 graywacke1 porphyry1 sandstone1 limestone1 c41 are certain elements indispensable to the growth of plants1 and the presence of which renders them fertile4 ,this fully explains the difference in the necessary methods of culture for different places2 since it is obvious that the essential elements of the soil must vary with the varieties of composition of the rocks1 from the disintegration of which they originated4 ,wheat1 clover1 turnips1 for example1 each require certain elements from the soil2 they will not flourish where the appropriate elements are absent4 ,science teaches us what elements are essential to every species of plants by an analysis of their ashes4 ,if therefore a soil is found wanting in any of those elements1 we discover at once the cause of its barrenness1 and its removal may now be readily accomplished4 ,the empiric attributes all his success to the mechanical operations of agriculture2 he experiences and recognises their value1 without inquiring what are the causes of their utility1 their mode of action3 and yet this scientific knowledge is of the highest importance for regulating the application of power and the expenditure of capital1--for insuring its economical expenditure and the prevention of waste4 ,can it be imagined that the mere passing of the ploughshare or the harrow through the soil--the mere contact of the iron--can impart fertility miraculously8 ,nobody1 perhaps1 seriously entertains such an opinion4 ,nevertheless1 the modus operandi of these mechanical operations is by no means generally understood4 ,the fact is quite certain1 that careful ploughing exerts the most favourable influence3 the surface is thus mechanically divided1 changed1 increased1 and renovated2 but the ploughing is only auxiliary to the end sought4 ,in the effects of time1 in what in ,agriculture are technically called fallows--the repose of the fields--we recognise by science certain chemical actions1 which are continually exercised by the elements of the atmosphere upon the whole surface of our globe4 ,by the action of its oxygen and its carbonic acid1 aided by water1 rain1 changes of temperature1 c41 certain elementary constituents of rocks1 or of their ruins1 which form the soil capable of cultivation1 are rendered soluble in water1 and consequently become separable from all their insoluble parts4 ,these chemical actions1 poetically denominates the tooth of time1 destroy all the works of man1 and gradually reduce the hardest rocks to the condition of dust4 ,by their influence the necessary elements of the soil become fitted for assimilation by plants2 and it is precisely the end which is obtained by the mechanical operations of farming4 ,they accelerate the decomposition of the soil1 in order to provide a new generation of plants with the necessary elements in a condition favourable to their assimilation4 ,it is obvious that the rapidity of the decomposition of a solid body must increase with the extension of its surface2 the more points of contact we offer in a given time to the external chemical agent1 the more rapid will be its action4 ,the chemist1 in order to prepare a mineral for analysis1 to decompose it1 or to increase the solubility of its elements1 proceeds in the same way as the farmer deals with his fields--he spares no labour in order to reduce it to the finest powder2 he separates the impalpable from the coarser parts by washing1 and repeats his mechanical bruising and trituration1 being assured his whole process will fail if he is inattentive to this essential and preliminary part of it4 ,the influence which the increase of surface exercises upon the disintegration of rocks1 and upon the chemical action of air and moisture1 is strikingly illustrated upon a large scale in the operations pursued in the gold-mines of ,yaquil1 in ,chili4 ,these are described in a very interesting manner by ,darwin4 ,the rock containing the gold ore is pounded by mills into the finest powder2 this is subjected to washing1 which separates the lighter particles from the metallic2 the gold sinks to the bottom1 while a stream of water carries away the lighter earthy parts into ponds1 where it subsides to the bottom as mud4 ,when this deposit has gradually filled up the pond1 this mud is taken out and piled in heaps1 and left exposed to the action of the atmosphere and moisture4 ,the washing completely removes all the soluble part of the disintegrated rock2 the insoluble part1 moreover1 cannot undergo any further change while it is covered with water1 and so excluded from the influence of the atmosphere at the bottom of the pond4 ,but being exposed at once to the air and moisture1 a powerful chemical action takes place in the whole mass1 which becomes indicated by an efflorescence of salts covering the whole surface of the heaps in considerable quantity4 ,after being exposed for two or three years1 the mud is again subjected to the same process of washing1 and a considerable quantity of gold is obtained1 this having been separated by the chemical process of decomposition in the mass4 ,the exposure and washing of the same mud is repeated six or seven times1 and at every washing it furnishes a new quantity of gold1 although its amount diminishes every time4 ,precisely similar is the chemical action which takes place in the soil of our fields2 and we accelerate and increase it by the mechanical operations of our agriculture4 ,by these we sever and extend the surface1 and endeavour to make every atom of the soil accessible to the action of the carbonic acid and oxygen of the atmosphere4 ,we thus produce a stock of soluble mineral substances1 which serves as nourishment to a new generation of plants1 materials which are indispensable to their growth and prosperity4 ,,letter ,,xiii ,my dear ,sir1 ,having in my last letter spoken of the general principles upon which the science and art of agriculture must be based1 let me now direct your attention to some of those particulars between chemistry and agriculture1 and demonstrate the impossibility of perfecting the important art of rearing food for man and animals1 without a profound knowledge of our science4 ,all plants cultivated as food require for their healthy sustenance the alkalies and alkaline earths1 each in a certain proportion2 and in addition to these1 the cerealia do not succeed in a soil destitute of silica in a soluble condition4 ,the combinations of this substance found as natural productions1 namely1 the silicates1 differ greatly in the degree of facility with which they undergo decomposition1 in consequence of the unequal resistance opposed by their integral parts to the dissolving power of the atmospheric agencies4 ,thus the granite of ,corsica degenerates into a powder in a time which scarcely suffices to deprive the polished granite of ,heidelberg of its lustre4 ,some soils abound in silicates so readily decomposable1 that in every one or two years1 as much silicate of potash becomes soluble and fitted for assimilation as is required by the leaves and straw of a crop of wheat4 ,in ,hungary1 extensive districts are not uncommon where wheat and tobacco have been grown alternately upon the same soil for centuries1 the land never receiving back any of those mineral elements which were withdrawn in the grain and straw4 ,on the other hand1 there are fields in which the necessary amount of soluble silicate of potash for a single crop of wheat is not separated from the insoluble masses in the soil in less than two1 three1 or even more years4 ,the term fallow1 in ,agriculture1 designates that period in which the soil1 left to the influence of the atmosphere1 becomes enriched with those soluble mineral constituents4 ,fallow1 however1 does not generally imply an entire cessation of cultivation1 but only an interval in the growth of the cerealia4 ,that store of silicates and alkalies which is the principal condition of their success is obtained1 if potatoes or turnips are grown upon the same fields in the intermediate periods1 since these crops do not abstract a particle of silica1 and therefore leave the field equally fertile for the following crop of wheat4 ,the preceding remarks will render it obvious to you1 that the mechanical working of the soil is the simplest and cheapest method of rendering the elements of nutrition contained in it accessible to plants4 ,but it may be asked1 ,are there not other means of decomposing the soil besides its mechanical subdivision8--are there not substances1 which by their chemical operation will equally well or better render its constituents suitable for entering into vegetable organisms8 ,yes3 we certainly possess such substances1 and one of them1 namely1 quick-lime1 has been employed for the last century past in ,england for this purpose2 and it would be difficult to find a substance better adapted to this service1 as it is simple1 and in almost all localities cheap and easily accessible4 ,in order to obtain correct views respecting the effect of quick-lime upon the soil1 let me remind you of the first process employed by the chemist when he is desirous of analysing a mineral1 and for this purpose wishes to bring its elements into a soluble state4 ,let the mineral to be examined be1 for instance1 feldspar2 this substance1 taken alone1 even when reduced to the finest powder1 requires for its solution to be treated with an acid for weeks or months2 but if we first mix it with quick-lime1 and expose the mixture to a moderately strong heat1 the lime enters into chemical combination with certain elements of the feldspar1 and its alkali 7potass7 is set free4 ,and now the acid1 even without heat1 dissolves not only the lime1 but also so much of the silica of the feldspar as to form a transparent jelly4 ,the same effect which the lime in this process1 with the aid of heat1 exerts upon the feldspar1 it produces when it is mixed with the alkaline argillaceous silicates1 and they are for a long time kept together in a moist state4 ,common potters' clay1 or pipe-clay1 diffused through water1 and added to milk of lime1 thickens immediately upon mixing2 and if the mixture is kept for some months1 and then treated with acid1 the clay becomes gelatinous1 which would not occur without the admixture with the lime4 ,the lime1 in combining with the elements of the clay1 liquifies it2 and1 what is more remarkable1 liberates the greater part of its alkalies4 ,these interesting facts were first observed by ,fuchs1 at ,munich3 they have not only led to a more intimate knowledge of the nature and properties of the hydraulic cements1 but1 what is far more important1 they explain the effects of caustic lime upon the soil1 and guide the agriculturist in the application of an invaluable means of opening it1 and setting free its alkalies--substances so important1 nay1 so indispensable to his crops4 ,in the month of ,october the fields of ,yorkshire and ,oxfordshire look as it they were covered with snow4 ,whole square miles are seen whitened over with quicklime1 which during the moist winter months1 exercises its beneficial influence upon the stiff1 clayey soil1 of those counties4 ,according to the humus theory1 quick-lime ought to exert the most noxious influence upon the soil1 because all organic matters contained in it are destroyed by it1 and rendered incapable of yielding their humus to a new vegetation4 ,the facts are indeed directly contrary to this now abandoned theory3 the fertility of the soil is increased by the lime4 ,the cerealia require the alkalies and alkaline silicates1 which the action of the lime renders fit for assimilation by the plants4 ,if1 in addition to these1 there is any decaying organic matter present in the soil supplying carbonic acid1 it may facilitate their development2 but it is not essential to their growth4 ,if we furnish the soil with ammonia1 and the phosphates1 which are indispensable to the cerealia1 with the alkaline silicates1 we have all the conditions necessary to ensure an abundant harvest4 ,the atmosphere is an inexhaustible store of carbonic acid4 ,a no less favourable influence than that of lime is exercised upon the soil of peaty land by the mere act of burning it3 this greatly enhances its fertility4 ,we have not long been acquainted with the remarkable change which the properties of clay undergo by burning4 ,the observation was first made in the process of analysing the clay silicates4 ,many of these1 in their natural state1 are not acted on by acids1 but they become perfectly soluble if heated to redness before the application of the acid4 ,this property belongs to potters' clay1 pipe-clay1 loam1 and many different modifications of clay in soils4 ,in their natural state they may be boiled in concentrated sulphuric acid1 without sensible change2 but if feebly burned1 as is done with the pipe-clay in many alum manufactories1 they dissolve in the acid with the greatest facility1 the contained silica being separated like jelly in a soluble state4 ,potters' clay belongs to the most sterile kinds of soil1 and yet it contains within itself all the constituent elements essential to a most luxurious growth of plants2 but their mere presence is insufficient to secure this end4 ,the soil must be accessible to the atmosphere1 to its oxygen1 to its carbonic acid2 these must penetrate it1 in order to secure the conditions necessary to a happy and vigorous development of the roots4 ,the elements present must be brought into that peculiar state of combination which will enable them to enter into plants4 ,plastic clay is wanting in these properties2 but they are imparted to it by a feeble calcination4 ,at ,hardwicke ,court1 near ,gloucester1 ,i have seen a garden 7,mr4 ,baker's7 consisting of a stiff clay1 which was perfectly sterile1 become by mere burning extremely fertile4 ,the operation was extended to a depth of three feet4 ,this was an expensive process1 certainly2 but it was effectual4 ,the great difference in the properties of burnt and unburnt clay is illustrated by what is seen in brick houses1 built in moist situations4 ,in the town of ,flanders1 for instance1 where most buildings are of brick1 effloresences of salts cover the surfaces of the walls1 like a white nap1 within a few days after they are erected4 ,if this saline incrustation is washed away by the rain1 it soon re-appears2 and this is even observed on walls which1 like the gateway of ,lisle1 have been erected for centuries4 ,these saline incrustations consist of carbonates and sulphates1 with alkaline bases2 and it is well known these act an important part in vegetation4 ,the influence of lime in their production is manifested by their appearing first at the place where the mortar and brick come into contact4 ,it will now be obvious to you1 that in a mixture of clay with lime1 all the conditions exist for the solution of the silicated clay1 and the solubility of the alkaline silicates4 ,the lime gradually dissolving in water charged with carbonic acid1 acts like milk of lime upon the clay4 ,this explains also the favourable influence which marl 7by which term all those varieties of clay rich in chalk are designated7 exerts upon most kinds of soil4 ,there are marly soils which surpass all others in fertility for all kinds of plants2 but ,i believe marl in a burnt state must be far more effective1 as well as other materials possessing a similar composition2 as1 for instance1 those species of limestone which are adapted to the preparation of hydraulic cements1--for these carry to the soil not only the alkaline bases useful to plants1 but also silica in a state capable of assimilation4 ,the ashes of coals and lignite are also excellent means of ameliorating the soil1 and they are used in many places for this purpose4 ,the most suitable may be readily known by their property of forming a gelatinous mass when treated with acids1 or by becoming1 when mixed with cream of lime1 like hydraulic cement1--solid and hard as stone4 ,i have now1 ,i trust1 explained to your satisfaction1 that the mechanical operations of agriculture--the application of lime and chalk to lands1 and the burning of clay--depend upon one and the same scientific principle3 they are means of accelerating the decomposition of the alkaline clay silicates1 in order to provide plants1 at the beginning of a new vegetation1 with certain inorganic matters indispensable for their nutrition4 ,,letter ,,xiv ,my dear ,sir1 ,i treated1 in my last letter1 of the means of improving the condition of the soil for agricultural purposes by mechanical operations and mineral agents4 ,i have now to speak of the uses and effects of animal exuviae1 and vegetable matters or manures--properly so called4 ,in order to understand the nature of these1 and the peculiarity of their influence upon our fields1 it is highly important to keep in mind the source whence they are derived4 ,it is generally known1 that if we deprive an animal of food1 the weight of its body diminishes during every moment of its existence4 ,if this abstinence is continued for some time1 the diminution becomes apparent to the eye2 all the fat of the body disappears1 the muscles decrease in firmness and bulk1 and1 if the animal is allowed to die starved1 scarcely anything but skin1 tendon1 and bones1 remain4 ,this emaciation which occurs in a body otherwise healthy1 demonstrates to us1 that during the life of an animal every part of its living substance is undergoing a perpetual change2 all its component parts1 assuming the form of lifeless compounds1 are thrown off by the skin1 lungs1 and urinary system1 altered more or less by the secretory organs4 ,this change in the living body is intimately connected with the process of respiration2 it is1 in truth1 occasioned by the oxygen of the atmosphere in breathing1 which combines with all the various matters within the body4 ,at every inspiration a quantity of oxygen passes into the blood in the lungs1 and unites with its elements2 but although the weight of the oxygen thus daily entering into the body amounts to #cb or more ounces1 yet the weight of the body is not thereby increased4 ,exactly as much oxygen as is imbibed in inspiration passes off in expiration1 in the form of carbonic acid and water2 so that with every breath the amount of carbon and hydrogen in the body is diminished4 ,but the emaciation--the loss of weight by starvation--does not simply depend upon the separation of the carbon and hydrogen2 but all the other substances which are in combination with these elements in the living tissues pass off in the secretions4 ,the nitrogen undergoes a change1 and is thrown out of the system by the kidneys4 ,their secretion1 the urine1 contains not only a compound rich in nitrogen1 namely urea1 but the sulphur of the tissues in the form of a sulphate1 all the soluble salts of the blood and animal fluids1 common salt1 the phosphates1 soda and potash4 ,the carbon and hydrogen of the blood1 of the muscular fibre1 and of all the animal tissues which can undergo change1 return into the atmosphere4 ,the nitrogen1 and all the soluble inorganic elements are carried to the earth in the urine4 ,these changes take place in the healthy animal body during every moment of life2 a waste and loss of substance proceeds continually2 and if this loss is to be restored1 and the original weight and substance repaired1 an adequate supply of materials must be furnished1 from whence the blood and wasted tissues may be regenerated4 ,this supply is obtained from the food4 ,in an adult person in a normal or healthy condition1 no sensible increase or decrease of weight occurs from day to day4 ,in youth the weight of the body increases1 whilst in old age it decreases4 ,there can be no doubt that in the adult1 the food has exactly replaced the loss of substance3 it has supplied just so much carbon1 hydrogen1 nitrogen1 and other elements1 as have passed through the skin1 lungs1 and urinary organs4 ,in youth the supply is greater than the waste4 ,part of the elements of the food remain to augment the bulk of the body4 ,in old age the waste is greater than the supply1 and the body diminishes4 ,it is unquestionable1 that1 with the exception of a certain quantity of carbon and hydrogen1 which are secreted through the skin and lungs1 we obtain1 in the solid and fluid excrements of man and animals1 all the elements of their food4 ,we obtain daily1 in the form of urea1 all the nitrogen taken in the food both of the young and the adult2 and further1 in the urine1 the whole amount of the alkalies1 soluble phosphates and sulphates1 contained in all the various aliments4 ,in the solid excrements are found all those substances taken in the food which have undergone no alteration in the digestive organs1 all indigestible matters1 such as woody fibre1 the green colouring matter of leaves 7 chlorophyle71 wax1 c4 ,physiology teaches us1 that the process of nutrition in animals1 that is1 their increase of bulk1 or the restoration of wasted parts1 proceeds from the blood4 ,the purpose of digestion and assimilation is to convert the food into blood4 ,in the stomach and intestines1 therefore1 all those substances in the food capable of conversion into blood are separated from its other constituents2 in other words1 during the passage of the food through the intestinal canal there is a constant absorption of its nitrogen1 since only azotised substances are capable of conversion into blood2 and therefore the solid excrements are destitute of that element1 except only a small portion1 in the constitution of that secretion which is formed to facilitate their passage4 ,with the solid excrements1 the phosphates of lime and magnesia1 which were contained in the food and not assimilated1 are carried off1 these salts being insoluble in water1 and therefore not entering the urine4 ,we may obtain a clear insight into the chemical constitution of the solid excrements without further investigation1 by comparing the faeces of a dog with his food4 ,we give that animal flesh and bones--substances rich in azotised matter--and we obtain1 as the last product of its digestion1 a perfectly white excrement1 solid while moist1 but becoming in dry air a powder4 ,this is the phosphate of lime of the bones1 with scarcely one per cent4 of foreign organic matter4 ,thus we see that in the solid and fluid excrements of man and animals1 all the nitrogen--in short1 all the constituent ingredients of the consumed food1 soluble and insoluble1 are returned2 and as food is primarily derived from the fields1 we possess in those excrements all the ingredients which we have taken from it in the form of seeds1 roots1 or herbs4 ,one part of the crops employed for fattening sheep and cattle is consumed by man as animal food2 another part is taken directly--as flour1 potatoes1 green vegetables1 c42 a third portion consists of vegetable refuse1 and straw employed as litter4 ,none of the materials of the soil need be lost4 ,we can1 it is obvious1 get back all its constituent parts which have been withdrawn therefrom1 as fruits1 grain and animals1 in the fluid and solid excrements of man1 and the bones1 blood and skins of the slaughtered animals4 ,it depends upon ourselves to collect carefully all these scattered elements1 and to restore the disturbed equilibrium of composition in the soil4 ,we can calculate exactly how much and which of the component parts of the soil we export in a sheep or an ox1 in a quarter of barley1 wheat or potatoes1 and we can discover1 from the known composition of the excrements of man and animals1 how much we have to supply to restore what is lost to our fields4 ,if1 however1 we could procure from other sources the substances which give to the exuviae of man and animals their value in agriculture1 we should not need the latter4 ,it is quite indifferent for our purpose whether we supply the ammonia 7the source of nitrogen7 in the form of urine1 or in that of a salt derived from coal-tar2 whether we derive the phosphate of lime from bones1 apatite1 or fossil excrements 7the coprolithes74 ,the principal problem for agriculture is1 how to replace those substances which have been taken from the soil1 and which cannot be furnished by the atmosphere4 ,if the manure supplies an imperfect compensation for this loss1 the fertility of a field or of a country decreases2 if1 on the contrary1 more are given to the fields1 their fertility increases4 ,an importation of urine1 or of solid excrements1 from a foreign country1 is equivalent to an importation of grain and cattle4 ,in a certain time1 the elements of those substances assume the form of grain1 or of fodder1 then become flesh and bones1 enter into the human body1 and return again day by day to the form they originally possessed4 ,the only real loss of elements we are unable to prevent is of the phosphates1 and these1 in accordance with the customs of all modern nations1 are deposited in the grave4 ,for the rest1 every part of that enormous quantity of food which a man consumes during his lifetime 7 say in sixty or seventy years71 which was derived from the fields1 can be obtained and returned to them4 ,we know with absolute certainty1 that in the blood of a young or growing animal there remains a certain quantity of phosphate of lime and of the alkaline phosphates1 to be stored up and to minister to the growth of the bones and general bulk of the body1 and that1 with the exception of this very small quantity1 we receive back1 in the solid and fluid excrements1 all the salts and alkaline bases1 all the phosphate of lime and magnesia1 and consequently all the inorganic elements which the animal consumes in its food4 ,we can thus ascertain precisely the quantity1 quality1 and composition of animal excrements1 without the trouble of analysing them4 ,if we give a horse daily #d #a_/b pounds' weight of oats1 and #ae pounds of hay1 and knowing that oats give #d per cent4 and hay #i per cent4 of ashes1 we can calculate that the daily excrements of the horse will contain #ba ounces of inorganic matter which was drawn from the fields4 ,by analysis we can determine the exact relative amount of silica1 of phosphates1 and of alkalies1 contained in the ashes of the oats and of the hay4 ,you will now understand that the constituents of the solid parts of animal excrements1 and therefore their qualities as manure1 must vary with the nature of the creature's food4 ,if we feed a cow upon beetroot1 or potatoes1 without hay1 straw or grain1 there will be no silica in her solid excrements1 but there will be phosphate of lime and magnesia4 ,her fluid excrements will contain carbonate of potash and soda1 together with compounds of the same bases with inorganic acids4 ,in one word1 we have1 in the fluid excrements1 all the soluble parts of the ashes of the consumed food2 and in the solid excrements1 all those parts of the ashes which are insoluble in water4 ,if the food1 after burning1 leaves behind ashes containing soluble alkaline phosphates1 as is the case with bread1 seeds of all kinds1 and flesh1 we obtain from the animal by which they are consumed a urine holding in solution these phosphates4 ,if1 however1 the ashes of food contain no alkaline phosphates1 but abound in insoluble earthy phosphates1 as hay1 carrots1 and potatoes1 the urine will be free from alkaline phosphates1 but the earthy phosphates will be found in the faeces4 ,the urine of man1 of carnivorous and graminivorous animals1 contains alkaline phosphates2 that of herbivorous animals is free from these salts4 ,the analysis of the excrements of man1 of the piscivorous birds 7as the guano71 of the horse1 and of cattle1 furnishes us with the precise knowledge of the salts they contain1 and demonstrates1 that in those excrements1 we return to the fields the ashes of the plants which have served as food1--the soluble and insoluble salts and earths indispensable to the development of cultivated plants1 and which must be furnished to them by a fertile soil4 ,there can be no doubt that1 in supplying these excrements to the soil1 we return to it those constituents which the crops have removed from it1 and we renew its capability of nourishing new crops3 in one word1 we restore the disturbed equilibrium2 and consequently1 knowing that the elements of the food derived from the soil enter into the urine and solid excrements of the animals it nourishes1 we can with the greatest facility determine the exact value of the different kinds of manure4 ,thus the excrements of pigs which we have fed with peas and potatoes are principally suited for manuring crops of potatoes and peas4 ,in feeding a cow upon hay and turnips1 we obtain a manure containing the inorganic elements of grasses and turnips1 and which is therefore preferable for manuring turnips4 ,the excrement of pigeons contains the mineral elements of grain2 that of rabbits1 the elements of herbs and kitchen vegetables4 ,the fluid and solid excrements of man1 however1 contain the mineral elements of grain and seeds in the greatest quantity4 ,,letter ,,xv ,my dear ,sir1 ,you are now acquainted with my opinions respecting the effects of the application of mineral agents to our cultivated fields1 and also the rationale of the influence of the various kinds of manures2 you will1 therefore1 now readily understand what ,i have to say of the sources whence the carbon and nitrogen1 indispensable to the growth of plants1 are derived4 ,the growth of forests1 and the produce of meadows1 demonstrate that an inexhaustible quantity of carbon is furnished for vegetation by the carbonic acid of the atmosphere4 ,we obtain from an equal surface of forest1 or meadow-land1 where the necessary mineral elements of the soil are present in a suitable state1 and to which no carbonaceous matter whatever is furnished in manures1 an amount of carbon1 in the shape of wood and hay1 quite equal1 and oftimes more than is produced by our fields1 in grain1 roots1 and straw1 upon which abundance of manure has been heaped4 ,it is perfectly obvious that the atmosphere must furnish to our cultivated fields as much carbonic acid1 as it does to an equal surface of forest or meadow1 and that the carbon of this carbonic acid is assimilated1 or may be assimilated by the plants growing there1 provided the conditions essential to its assimilation1 and becoming a constituent element of vegetables1 exist in the soil of these fields4 ,in many tropical countries the produce of the land in grain or roots1 during the whole year1 depends upon one rain in the spring4 ,if this rain is deficient in quantity1 or altogether wanting1 the expectation of an abundant harvest is diminished or destroyed4 ,now it cannot be the water merely which produces this enlivening and fertilising effect observed1 and which lasts for weeks and months4 ,the plant receives1 by means of this water1 at the time of its first development1 the alkalies1 alkaline earths1 and phosphates1 necessary to its organization4 ,if these elements1 which are necessary previous to its assimilation of atmospheric nourishment1 be absent1 its growth is retarded4 ,in fact1 the development of a plant is in a direct ratio to the amount of the matters it takes up from the soil4 ,if1 therefore1 a soil is deficient in these mineral constituents required by plants1 they will not flourish even with an abundant supply of water4 ,the produce of carbon on a meadow1 or an equal surface of forest land1 is independent of a supply of carbonaceous manure1 but it depends upon the presence of certain elements of the soil which in themselves contain no carbon1 together with the existence of conditions under which their assimilation by plants can be effected4 ,we increase the produce of our cultivated fields1 in carbon1 by a supply of lime1 ashes1 and marl1 substances which cannot furnish carbon to the plants1 and yet it is indisputable1--being founded upon abundant experience1--that in these substances we furnish to the fields elements which greatly increase the bulk of their produce1 and consequently the amount of carbon4 ,if we admit these facts to be established1 we can no longer doubt that a deficient produce of carbon1 or in other words1 the barrenness of a field does not depend upon carbonic acid1 because we are able to increase the produce1 to a certain degree1 by a supply of substances which do not contain any carbon4 ,the same source whence the meadow and the forest are furnished with carbon1 is also open to our cultivated plants4 ,the great object of agriculture1 therefore1 is to discover the means best adapted to enable these plants to assimilate the carbon of the atmosphere which exists in it as carbonic acid4 ,in furnishing plants1 therefore1 with mineral elements1 we give them the power to appropriate carbon from a source which is inexhaustible2 whilst in the absence of these elements the most abundant supply of carbonic acid1 or of decaying vegetable matter1 would not increase the produce of a field4 ,with an adequate and equal supply of these essential mineral constituents in the soil1 the amount of carbonic acid absorbed by a plant from the atmosphere in a given time is limited by the quantity which is brought into contact with its organs of absorption4 ,the withdrawal of carbonic acid from the atmosphere by the vegetable organism takes place chiefly through its leaves2 this absorption requires the contact of the carbonic acid with their surface1 or with the part of the plant by which it is absorbed4 ,the quantity of carbonic acid absorbed in a given time is in direct proportion to the surface of the leaves and the amount of carbonic acid contained in the air2 that is1 two plants of the same kind and the same extent of surface of absorption1 in equal times and under equal conditions1 absorb one and the same amount of carbon4 ,in an atmosphere containing a double proportion of carbonic acid1 a plant absorbs1 under the same condition1 twice the quantity of carbon4 ,boussingault observed1 that the leaves of the vine1 inclosed in a vessel1 withdrew all the carbonic acid from a current of air which was passed through it1 however great its velocity4 7,dumas ,lecon1 p4#bc47 ,if1 therefore1 we supply double the quantity of carbonic acid to one plant1 the extent of the surface of which is only half that of another living in ordinary atmospheric air1 the former will obtain and appropriate as much carbon as the latter4 ,hence results the effects of humus1 and all decaying organic substances1 upon vegetation4 ,if we suppose all the conditions for the absorption of carbonic acid present1 a young plant will increase in mass1 in a limited time1 only in proportion to its absorbing surface2 but if we create in the soil a new source of carbonic acid1 by decaying vegetable substances1 and the roots absorb in the same time three times as much carbonic acid from the soil as the leaves derive from the atmosphere1 the plant will increase in weight fourfold4 ,this fourfold increase extends to the leaves1 buds1 stalks1 c41 and in the increased extent of the surface1 the plant acquires an increased power of absorbing nourishment from the air1 which continues in action far beyond the time when its derivation of carbonic acid through the roots ceases4 ,humus1 as a source of carbonic acid in cultivated lands1 is not only useful as a means of increasing the quantity of carbon--an effect which in most cases may be very indifferent for agricultural purposes--but the mass of the plant having increased rapidly in a short time1 space is obtained for the assimilation of the elements of the soil necessary for the formation of new leaves and branches4 ,water evaporates incessantly from the surface of the young plant2 its quantity is in direct proportion to the temperature and the extent of the surface4 ,the numerous radical fibrillae replace1 like so many pumps1 the evaporated water2 and so long as the soil is moist1 or penetrated with water1 the indispensable elements of the soil1 dissolved in the water1 are supplied to the plant4 ,the water absorbed by the plant evaporating in an aeriform state leaves the saline and other mineral constituents within it4 ,the relative proportion of these elements taken up by a plant1 is greater1 the more extensive the surface and more abundant the supply of water2 where these are limited1 the plant soon reaches its full growth1 while if their supply is continued1 a greater amount of elements necessary to enable it to appropriate atmospheric nourishment being obtained1 its development proceeds much further4 ,the quantity1 or mass of seed produced1 will correspond to the quantity of mineral constituents present in the plant4 ,that plant1 therefore1 containing the most alkaline phosphates and earthy salts will produce more or a greater weight of seeds than another which1 in an equal time has absorbed less of them4 ,we consequently observe1 in a hot summer1 when a further supply of mineral ingredients from the soil ceases through want of water1 that the height and strength of plants1 as well as the development of their seeds1 are in direct proportion to its absorption of the elementary parts of the soil in the preceding epochs of its growth4 ,the fertility of the year depends in general upon the temperature1 and the moisture or dryness of the spring1 if all the conditions necessary to the assimilation of the atmospheric nourishment be secured to our cultivated plants4 ,the action of humus1 then1 as we have explained it above1 is chiefly of value in gaining time4 ,in agriculture1 this must ever be taken into account and in this respect humus is of importance in favouring the growth of vegetables1 cabbages1 c4 ,but the cerealia1 and plants grown for their roots1 meet on our fields1 in the remains of the preceding crop1 with a quantity of decaying vegetable substances corresponding to their contents of mineral nutriment from the soil1 and consequently with a quantity of carbonic acid adequate to their accelerated development in the spring4 ,a further supply of carbonic acid1 therefore1 would be quite useless1 without a corresponding increase of mineral ingredients4 ,from a morgen of good meadow land1 #b1ejj pounds weight of hay1 according to the best agriculturists1 are obtained on an average4 ,this amount is furnished without any supply of organic substances1 without manure containing carbon or nitrogen4 ,by irrigation1 and the application of ashes or gypsum1 double that amount may be grown4 ,but assuming #b1ejj pounds weight of hay to be the maximum1 we may calculate the amount of carbon and nitrogen derived from the atmosphere by the plants of meadows4 ,according to elementary analysis1 hay1 dried at a temperature of #ajj deg ,reaumur1 contains #de4h per cent4 of carbon1 and #a #a_/b per cent4 of nitrogen4 #ad per cent4 of water retained by the hay1 dried at common temperatures1 is driven off at #ajj deg4 #b1ejj pounds weight of hay1 therefore1 corresponds to #b1aej pounds1 dried at #ajj deg4 ,this shows us1 that #ihd pounds of carbon1 and #cb4b pounds weight of nitrogen1 have been obtained in the produce of one morgen of meadow land4 ,supposing that this nitrogen has been absorbed by the plants in the form of ammonia1 the atmosphere contains #ci4a pounds weight of ammonia to every #cfdj pounds weight of carbonic acid 7#ihd carbon1 or #bg per cent471 or in other words1 to every #a1jjj pounds weight of carbonic acid1 #aj4g pounds of ammonia1 that is to about #a_/ajj1jjj1 the weight of the air1 or #a_/fj1jjj of its volume4 ,for every #ajj parts of carbonic acid absorbed by the surface of the leaves1 the plant receives from the atmosphere somewhat more than one part of ammonia4 ,with every #a1jjj pounds of carbon1 we obtain-- ,from a meadow 4 #cb #g_/aj pounds of nitrogen4 ,from cultivated fields1 ,in ,wheat 4 #ba #a_/b ,oats 4 #bb4c ,rye 4 #ae4b ,potatoes 4 #cd4a ,beetroot 4 #ci4a ,clover 4 #dd ,peas 4 #fb ,boussingault obtained from his farm at ,bechelbronn1 in ,alsace1 in five years1 in the shape of potatoes1 wheat1 clover1 turnips1 and oats1 #h1chc of carbon1 and #bej4g nitrogen4 ,in the following five years1 as beetroot1 wheat1 clover1 turnips1 oats1 and rye1 #h1aib of carbon1 and #bhd4b of nitrogen4 ,in a further course of six years1 potatoes1 wheat1 clover1 turnips1 peas1 and rye1 #aj1idi of carbon1 #cef4f of nitrogen4 ,in #af years1 #bg1dbd carbon1 #heh #a_/b nitrogen1 which gives for every #a1jjj carbon1 #ca4c nitrogen4 ,from these interesting and unquestionable facts1 we may deduce some conclusions of the highest importance in their application to agriculture4 #a4 ,we observe that the relative proportions of carbon and nitrogen1 stand in a fixed relation to the surface of the leaves4 ,those plants1 in which all the nitrogen may be said to be concentrated in the seeds1 as the cerealia1 contain on the whole less nitrogen than the leguminous plants1 peas1 and clover4 #b4 ,the produce of nitrogen on a meadow which receives no nitrogenised manure1 is greater than that of a field of wheat which has been manured4 #c4 ,the produce of nitrogen in clover and peas1 which agriculturists will acknowledge require no nitrogenised manure1 is far greater than that of a potato or turnip field1 which is abundantly supplied with such manures4 ,lastly4 ,and this is the most curious deduction to be derived from the above facts1--if we plant potatoes1 wheat1 turnips1 peas1 and clover1 7plants containing potash1 lime1 and silex17 upon the same land1 three times manured1 we gain in #af years1 for a given quantity of carbon1 the same proportion of nitrogen which we receive from a meadow which has received no nitrogenised manure4 ,on a morgen of meadow-land1 we obtain in plants1 containing silex1 lime1 and potash1 #ihd carbon1 #cb4b nitrogen4 ,on a morgen of cultivated land1 in an average of #af years1 in plants containing the same mineral elements1 silex1 lime1 and potash1 #heg carbon1 #bf4h nitrogen4 ,if we add the carbon and nitrogen of the leaves of the beetroot1 and the stalk and leaves of the potatoes1 which have not been taken into account1 it still remains evident that the cultivated fields1 notwithstanding the supply of carbonaceous and nitrogenised manures1 produced no more carbon and nitrogen than an equal surface of meadow-land supplied only with mineral elements4 ,what then is the rationale of the effect of manure1--of the solid and fluid excrements of animals8 ,this question can now be satisfactorily answered3 that effect is the restoration of the elementary constituents of the soil which have been gradually drawn from it in the shape of grain and cattle4 ,if the land ,i am speaking of had not been manured during those #af years1 not more than one-half1 or perhaps than one-third part of the carbon and nitrogen would have been produced4 ,we owe it to the animal excrements1 that it equalled in production the meadow-land1 and this1 because they restored the mineral ingredients of the soil removed by the crops4 ,all that the supply of manure accomplished1 was to prevent the land from becoming poorer in these1 than the meadow which produces #b1ejj pounds of hay4 ,we withdraw from the meadow in this hay as large an amount of mineral substances as we do in one harvest of grain1 and we know that the fertility of the meadow is just as dependent upon the restoration of these ingredients to its soil1 as the cultivated land is upon manures4 ,two meadows of equal surface1 containing unequal quantities of inorganic elements of nourishment1--other conditions being equal1--are very unequally fertile2 that which possesses most1 furnishes most hay4 ,if we do not restore to a meadow the withdrawn elements1 its fertility decreases4 ,but its fertility remains unimpaired1 with a due supply of animal excrements1 fluid and solid1 and it not only remains the same1 but may be increased by a supply of mineral substances alone1 such as remain after the combustion of ligneous plants and other vegetables2 namely1 ashes4 ,ashes represent the whole nourishment which vegetables receive from the soil4 ,by furnishing them in sufficient quantities to our meadows1 we give to the plants growing on them the power of condensing and absorbing carbon and nitrogen by their surface4 ,may not the effect of the solid and fluid excrements1 which are the ashes of plants and grains1 which have undergone combustion in the bodies of animals and of man1 be dependent upon the same cause8 ,should not the fertility1 resulting from their application1 be altogether independent of the ammonia they contain8 ,would not their effect be precisely the same in promoting the fertility of cultivated plants1 if we had evaporated the urine1 and dried and burned the solid excrements8 ,surely the cerealia and leguminous plants which we cultivate must derive their carbon and nitrogen from the same source whence the graminea and leguminous plants of the meadows obtain them6 ,no doubt can be entertained of their capability to do so4 ,in ,virginia1 upon the lowest calculation1 #bb pounds weight of nitrogen were taken on the average1 yearly1 from every morgen of the wheat-fields4 ,this would amount1 in #ajj years1 to #b1bjj pounds weight4 ,if this were derived from the soil1 every morgen of it must have contained the equivalent of #aaj1jjj pounds weight of animal excrements 7assuming the latter1 when dried1 at the temperature of boiling water1 to contain #b per cent474 ,in ,hungary1 as ,i remarked in a former ,letter1 tobacco and wheat have been grown upon the same field for centuries1 without any supply of nitrogenised manure4 ,is it possible that the nitrogen essential to1 and entering into1 the composition of these crops1 could have been drawn from the soil8 ,every year renews the foliage and fruits of our forests of beech1 oak1 and chesnuts2 the leaves1 the acorns1 the chesnuts1 are rich in nitrogen2 so are cocoa-nuts1 bread-fruit1 and other tropical productions4 ,this nitrogen is not supplied by man1 can it indeed be derived from any other source than the atmosphere8 ,in whatever form the nitrogen supplied to plants may be contained in the atmosphere1 in whatever state it may be when absorbed1 from the atmosphere it must have been derived4 ,did not the fields of ,virginia receive their nitrogen from the same source as wild plants8 ,is the supply of nitrogen in the excrements of animals quite a matter of indifference1 or do we receive back from our fields a quantity of the elements of blood corresponding to this supply8 ,the researches of ,boussingault have solved this problem in the most satisfactory manner4 ,if1 in his grand experiments1 the manure which he gave to his fields was in the same state1 i4e4 dried at #aaj deg in a vacuum1 as it was when analysed1 these fields received1 in #af years1 #a1cjj pounds of nitrogen4 ,but we know that by drying all the nitrogen escapes which is contained in solid animal excrements1 as volatile carbonate of ammonia4 ,in this calculation the nitrogen of the urine1 which by decomposition is converted into carbonate of ammonia1 has not been included4 ,if we suppose it amounted to half as much as that in the dried excrements1 this would make the quantity of nitrogen supplied to the fields #a1iej pounds4 ,in #af years1 however1 as we have seen1 only #a1eag pounds of nitrogen1 was contained in their produce of grain1 straw1 roots1 et cetera--that is1 far less than was supplied in the manure2 and in the same period the same extent of surface of good meadow-land 7one hectare a ,hessian morgen71 which received no nitrogen in manure1 #b1jfb pounds of nitrogen4 ,it is well known that in ,egypt1 from the deficiency of wood1 the excrement of animals is dried1 and forms the principal fuel1 and that the nitrogen from the soot of this excrement was1 for many centuries1 imported into ,europe in the form of sal ammoniac1 until a method of manufacturing this substance was discovered at the end of the last century by ,gravenhorst of ,brunswick4 ,the fields in the delta of the ,nile are supplied with no other animal manures than the ashes of the burnt excrements1 and yet they have been proverbially fertile from a period earlier than the first dawn of history1 and that fertility continues to the present day as admirable as it was in the earliest times4 ,these fields receive1 every year1 from the inundation of the ,nile1 a new soil1 in its mud deposited over their surface1 rich in those mineral elements which have been withdrawn by the crops of the previous harvest4 ,the mud of the ,nile contains as little nitrogen as the mud derived from the ,alps of ,switzerland1 which fertilises our fields after the inundations of the ,rhine4 ,if this fertilising mud owed this property to nitrogenised matters2 what enormous beds of animal and vegetable exuviae and remains ought to exist in the mountains of ,africa1 in heights extending beyond the limits of perpetual snow1 where no bird1 no animal finds food1 from the absence of all vegetation6 ,abundant evidence in support of the important truth we are discussing1 may be derived from other well known facts4 ,thus1 the trade of ,holland in cheese may be adduced in proof and illustration thereof4 ,we know that cheese is derived from the plants which serve as food for cows4 ,the meadow-lands of ,holland derive the nitrogen of cheese from the same source as with us2 i4e4 the atmosphere4 ,the milch cows of ,holland remain day and night on the grazing-grounds1 and therefore1 in their fluid and solid excrements return directly to the soil all the salts and earthy elements of their food3 a very insignificant quantity only is exported in the cheese4 ,the fertility of these meadows can1 therefore1 be as little impaired as our own fields1 to which we restore all the elements of the soil1 as manure1 which have been withdrawn in the crops4 ,the only difference is1 in ,holland they remain on the field1 whilst we collect them at home and carry them1 from time to time1 to the fields4 ,the nitrogen of the fluid and solid excrements of cows1 is derived from the meadow-plants1 which receive it from the atmosphere2 the nitrogen of the cheese also must be drawn from the same source4 ,the meadows of ,holland have1 in the lapse of centuries1 produced millions of hundredweights of cheese4 ,thousands of hundredweights are annually exported1 and yet the productiveness of the meadows is in no way diminished1 although they never receive more nitrogen than they originally contained4 ,nothing then can be more certain than the fact1 that an exportation of nitrogenised products does not exhaust the fertility of a country2 inasmuch as it is not the soil1 but the atmosphere1 which furnishes its vegetation with nitrogen4 ,it follows1 consequently1 that we cannot increase the fertility of our fields by a supply of nitrogenised manure1 or by salts of ammonia1 but rather that their produce increases or diminishes1 in a direct ratio1 with the supply of mineral elements capable of assimilation4 ,the formation of the constituent elements of blood1 that is1 of the nitrogenised principles in our cultivated plants1 depends upon the presence of inorganic matters in the soil1 without which no nitrogen can be assimilated even when there is a most abundant supply4 ,the ammonia contained in animal excrements exercises a favourable effect1 inasmuch as it is accompanied by the other substances necessary to accomplish its transition into the elements of the blood4 ,if we supply ammonia associated with all the conditions necessary to its assimilation1 it ministers to the nourishment of the plants2 but if this artificial supply is not given they can derive all the needed nitrogen from the atmosphere--a source1 every loss from which is restored by the decomposition of the bodies of dead animals and the decay of plants4 ,ammonia certainly favours1 and accelerates1 the growth of plants in all soils1 wherein all the conditions of its assimilation are united2 but it is altogether without effect1 as respects the production of the elements of blood where any of these conditions are wanting4 ,we can suppose that asparagin1 the active constituent of asparagus1 the mucilaginous root of the marsh-mallow1 the nitrogenised and sulphurous ingredients of mustard-seed1 and of all cruciferous plants1 may originate without the aid of the mineral elements of the soil4 ,but if the principles of those vegetables1 which serve as food1 could be generated without the co-operation of the mineral elements of blood1 without potash1 soda1 phosphate of soda1 phosphate of lime1 they would be useless to us and to herbivorous animals as food2 they would not fulfil the purpose for which the wisdom of the ,creator has destined them4 ,in the absence of alkalies and the phosphates1 no blood1 no milk1 no muscular fibre can be formed4 ,without phosphate of lime our horses1 sheep and cattle1 would be without bones4 ,in the urine and in the solid excrements of animals we carry ammonia1 and1 consequently1 nitrogen1 to our cultivated plants1 and this nitrogen is accompanied by all the mineral elements of food exactly in the same proportions1 in which both are contained in the plants which served as food to the animals1 or what is the same1 in those proportions in which both can serve as nourishment to a new generation of plants1 to which both are essential4 ,the effect of an artificial supply of ammonia1 as a source of nitrogen1 is1 therefore1 precisely analogous to that of humus as a source of carbonic acid--it is limited to a gain of time2 that is1 it accelerates the development of plants4 ,this is of great importance1 and should always be taken into account in gardening1 especially in the treatment of the kitchen-garden2 and as much as possible1 in agriculture on a large scale1 where the time occupied in the growth of the plants cultivated is of importance4 ,when we have exactly ascertained the quantity of ashes left after the combustion of cultivated plants which have grown upon all varieties of soil1 and have obtained correct analyses of these ashes1 we shall learn with certainty which of the constituent elements of the plants are constant and which are changeable1 and we shall arrive at an exact knowledge of the sum of all the ingredients we withdraw from the soil in the different crops4 ,with this knowledge the farmer will be able to keep an exact record1 of the produce of his fields in harvest1 like the account-book of a well regulated manufactory2 and then by a simple calculation he can determine precisely the substances he must supply to each field1 and the quantity of these1 in order to restore their fertility4 ,he will be able to express1 in pounds weight1 how much of this or that element he must give in order to augment its fertility for any given kind of plants4 ,these researches and experiments are the great desideratum of the present time4 ,,to ,,the ,,united ,,efforts ,,of ,,the ,,chemists ,,of ,,all ,,countries ,,we ,,may ,,confidently ,,look ,,for ,a ,,solution ,,of ,,these ,,great ,,questions1 and by the aid of ,,enlightened ,,agriculturists we shall arrive at a ,,rational system of ,,gardening1 ,,horticulture1 and ,,agriculture1 applicable to every country and all kinds of soil1 and which will be based upon the immutable foundation of ,,observed ,,facts and ,,philosophical ,,induction4 ,,letter ,,xvi ,my dear ,sir1 ,my recent researches into the constituent ingredients of our cultivated fields have led me to the conclusion that1 of all the elements furnished to plants by the soil and ministering to their nourishment1 the phosphate of lime--or1 rather1 the phosphates generally--must be regarded as the most important4 ,in order to furnish you with a clear idea of the importance of the phosphates1 it may be sufficient to remind you of the fact1 that the blood of man and animals1 besides common salt1 always contains alkaline and earthy phosphates4 ,if we burn blood and examine the ashes which remain1 we find certain parts of them soluble in water1 and others insoluble4 ,the soluble parts are1 common salt and alkaline phosphates2 the insoluble consist of phosphate of lime1 phosphate of magnesia1 and oxide of iron4 ,these mineral ingredients of the blood--without the presence of which in the food the formation of blood is impossible--both man and animals derive either immediately1 or mediately through other animals1 from vegetable substances used as food2 they had been constituents of vegetables1 they had been parts of the soil upon which the vegetable substances were developed4 ,if we compare the amount of the phosphates in different vegetable substances with each other1 we discover a great variety1 whilst there is scarcely any ashes of plants altogether devoid of them1 and those parts of plants which experience has taught us are the most nutritious1 contain the largest proportion4 ,to these belong all seeds and grain1 especially the varieties of bread-corn1 peas1 beans1 and lentils4 ,it is a most curious fact that if we incinerate grain or its flour1 peas1 beans1 and lentils1 we obtain ashes1 which are distinguished from the ashes of all other parts of vegetables by the absence of alkaline carbonates4 ,the ashes of these seeds when recently prepared1 do not effervesce with acids2 their soluble ingredients consist solely of alkaline phosphates1 the insoluble parts of phosphate of lime1 phosphate of magnesia1 and oxide of iron3 consequently1 of the very same salts which are contained in blood1 and which are absolutely indispensable to its formation4 ,we are thus brought to the further indisputable conclusion that no seed suitable to become food for man and animals can be formed in any plant without the presence and co-operation of the phosphates4 ,a field in which phosphate of lime1 or the alkaline phosphates1 form no part of the soil1 is totally incapable of producing grain1 peas1 or beans4 ,an enormous quantity of these substances indispensable to the nourishment of plants1 is annually withdrawn from the soil and carried into great towns1 in the shape of flour1 cattle1 et cetera4 ,it is certain that this incessant removal of the phosphates must tend to exhaust the land and diminish its capability of producing grain4 ,the fields of ,great ,britain are in a state of progressive exhaustion from this cause1 as is proved by the rapid extension of the cultivation of turnips and mangel wurzel--plants which contain the least amount of the phosphates1 and therefore require the smallest quantity for their development4 ,these roots contain #hj to #ib per cent4 of water4 ,their great bulk makes the amount of produce fallacious1 as respects their adaptation to the food of animals1 inasmuch as their contents of the ingredients of the blood1 i4e4 of substances which can be transformed into flesh1 stands in a direct ratio to their amount of phosphates1 without which neither blood nor flesh can be formed4 ,our fields will become more and more deficient in these essential ingredients of food1 in all localities where custom and habits do not admit the collection of the fluid and solid excrements of man1 and their application to the purposes of agriculture4 ,in a former letter ,i showed you how great a waste of phosphates is unavoidable in ,england1 and referred to the well-known fact that the importation of bones restored in a most admirable manner the fertility of the fields exhausted from this cause4 ,in the year #ahbg the importation of bones for manure amounted to #dj1jjj tons1 and ,huskisson estimated their value to be from ,l #ajj1jjj to ,l #bjj1jjj sterling4 ,the importation is still greater at present1 but it is far from being sufficient to supply the waste4 ,another proof of the efficacy of the phosphates in restoring fertility to exhausted land is afforded by the use of the guano--a manure which1 although of recent introduction into ,england1 has found such general and extensive application4 ,we believe that the importation of one hundred-weight of guano is equivalent to the importation of eight hundred-weight of wheat--the hundred-weight of guano assumes in a time which can be accurately estimated the form of a quantity of food corresponding to eight hundred-weight of wheat4 ,the same estimate is applicable in the valuation of bones4 ,if it were possible to restore to the soil of ,england and ,scotland the phosphates which during the last fifty years have been carried to the sea by the ,thames and the ,clyde1 it would be equivalent to manuring with millions of hundred-weights of bones1 and the produce of the land would increase one-third1 or perhaps double itself1 in five to ten years4 ,we cannot doubt that the same result would follow if the price of the guano admitted the application of a quantity to the surface of the fields1 containing as much of the phosphates as have been withdrawn from them in the same period4 ,if a rich and cheap source of phosphate of lime and the alkaline phosphates were open to ,england1 there can be no question that the importation of foreign corn might be altogether dispensed with after a short time4 ,for these materials ,england is at present dependent upon foreign countries1 and the high price of guano and of bones prevents their general application1 and in sufficient quantity4 ,every year the trade in these substances must decrease1 or their price will rise as the demand for them increases4 ,according to these premises1 it cannot be disputed1 that the annual expense of ,great ,britain for the importation of bones and guano is equivalent to a duty on corn3 with this difference only1 that the amount is paid to foreigners in money4 ,to restore the disturbed equilibrium of constitution of the soil1--to fertilise her fields1--,england requires an enormous supply of animal excrements1 and it must1 therefore1 excite considerable interest to learn1 that she possesses beneath her soil beds of fossil guano1 strata of animal excrements1 in a state which will probably allow of their being employed as a manure at a very small expense4 ,the coprolithes discovered by ,dr4 ,buckland1 7a discovery of the highest interest to ,geology17 are these excrements2 and it seems extremely probable that in these strata ,england possesses the means of supplying the place of recent bones1 and therefore the principal conditions of improving agriculture--of restoring and exalting the fertility of her fields4 ,in the autumn of #ahdb1 ,dr4 ,buckland pointed out to me a bed of coprolithes in the neighbourhood of ,clifton1 from half to one foot thick1 inclosed in a limestone formation1 extending as a brown stripe in the rocks1 for miles along the banks of the ,severn4 ,the limestone marl of ,lyme ,regis consists1 for the most part1 of one-fourth part of fossil excrements and bones4 ,the same are abundant in the lias of ,bath1 ,eastern and ,broadway ,hill1 near ,evesham4 ,dr4 ,buckland mentions beds1 several miles in extent1 the substance of which consists1 in many places1 of a fourth part of coprolithes4 ,pieces of the limestone rock in ,clifton1 near ,bristol1 which is rich in coprolithes and organic remains1 fragments of bones1 teeth1 c41 were subjected to analysis1 and were found to contain above #ah per cent4 of phosphate of lime4 ,if this limestone is burned and brought in that state to the fields1 it must be a perfect substitute for bones1 the efficacy of which as a manure does not depend1 as has been generally1 but erroneously supposed1 upon the nitrogenised matter which they contain1 but on their phosphate of lime4 ,the osseous breccia found in many parts of ,england deserves especial attention1 as it is highly probable that in a short time it will become an important article of commerce4 ,what a curious and interesting subject for contemplation6 ,in the remains of an extinct animal world1 ,england is to find the means of increasing her wealth in agricultural produce1 as she has already found the great support of her manufacturing industry in fossil fuel1--the preserved matter of primeval forests1--the remains of a vegetable world4 ,may this expectation be realised6 and may her excellent population be thus redeemed from poverty and misery6