material from the ,google ,print project47 ,transcriber's ,note3 ,a few typographical errors have been corrected4 ,details are given at the end of the text4 ,,heads ,,of ,,lectures ,,on ,a ,,course ,,of ,,experimental ,,philosophy1 ,,particularly ,,including ,,chemistry1 ,,delivered ,,at ,,the ,,new ,,college ,,in ,,hackney4 ,by ,,joseph ,,priestley1 ,,ll4,d4 ,f4,r4,s4 ,,ac4 ,,imp4 ,,petrop4 ,r4 ,,paris4 ,,holm4 ,,taurin4 ,,aurel4 ,,med4 ,,paris4 ,,harlem4 ,,cantab4 ,,americ4 ,,et ,,philad4 ,,soc4 ,,qui ,,docet ,,discit4--,,wm4 ,,lilly ,,london3 ,,printed ,,for ,j4 ,,johnson1 ,,no4 #gb1 ,,st4 ,,paul',s ,,church-,,yard4 #agid4 ,,the ,,preface4 ,situated1 as ,i happily am1 in the neighbourhood of the ,new ,college at ,hackney1 an institution that does honour to the ,dissenters1 an institution open to all persons without distinction#a1 and connected as ,i am by friendship with the tutors1 ,i was glad to give it every assistance in my power2 and therefore undertook to read the ,lectures on ,history and ,general ,policy which ,i had composed when ,i was tutor at ,warrington1 and also to give another course on the subject of ,experimental ,philosophy4 ,with this view ,i drew up the following ,heads of ,lectures2 and1 to save the students the trouble of transcribing them1 they are now printed4 ,to other persons they may serve as a compendious view of the most important discoveries relating to the subject4 ,footnote #a3 ,one gentleman of the ,roman ,catholic persuasion1 and several of the ,church of ,england1 are now in the ,college4 ,as it was found most convenient1 with respect to the other business of the college1 to confine this course to one lecture in a week1 ,i contrived to bring within that compass as much of the subject of experimental philosophy as ,i well could1 and especially to include the whole of what is called chemistry1 to which so much attention is now given1 and which presents so many new fields of philosophical investigation4 ,besides that the plan of the young gentlemen's studies would not admit of it1 ,i think it most advisable not to trouble beginners with more than a large outline of any branch of science4 ,by this means they are not fatigued by too long an attention to any one subject1 a greater variety of articles may be brought before them1 and in future life they may pursue any of them as much farther as their inclination may dispose1 and their ability and opportunity shall enable1 them to do it4 ,i do not give any account of the experiments introduced into the several lectures4 ,they will be sufficiently indicated by the subjects of them4 ,they were as many as ,i could conveniently make within the time2 and where the experiments themselves could not be made1 ,i usually exhibited both the different substances employed in them1 and those that were the result of them4 ,as these lectures were calculated for the use of the students at the ,new ,college1 ,i prefix an ,address to them1 the same in substance with that which ,i delivered to them at the close of the session of #agia4 ,in it may be seen a specimen of the language we hold to them on the subject of politics1 which with reasonable men will serve as an answer to the many calumnies that have been thrown out against us1 as disaffected to the government of this country4 ,such institutions will1 indeed1 always be objects of hatred and dread to bigots and the advocates for arbitrary power1 but the pride of a truly free country4 ,i therefore conclude with my earnest prayer 7the accomplishment of which the present state of the ,college does not allow us to doubt7 ,,esto ,,perpetua4 ,,the ,,dedication4 ,,to ,,the ,,students ,,at ,,the ,,new ,,college ,,in ,,hackney4 ,my young ,friends1 ,having drawn up the following ,heads of ,lectures for your use1 ,i take the liberty thus publickly to dedicate them to you2 and as ,i earnestly wish for your improvement and happiness in all respects1 excuse me if ,i take the farther liberty of making a few observations1 and giving you some advice1 of a more general nature1 adapted to your age and circumstances4 ,as you will soon leave this place of education1 and enter upon your several professions and employments1 ,i hope your conduct will demonstrate to the world the solid advantages of this institution1 and that the great expence attending it1 and the best attention of the managers1 have not been bestowed in vain4 ,many liberal friends of science1 of virtue1 and of religion1 have contributed to procure you the advantages which you enjoy4 ,they have spared no pains to provide able and careful tutors1 and you have had every other advantage for the prosecution of your studies that they could procure you1 unclogged by any subscription to articles of faith1 or obligation of any other kind1 besides such as they have deemed necessary for your own good1 and to give the institution its greatest effect4 ,this is an advantage you could not have found elsewhere1 at least in this country4 ,and in every seminary of education much more depends upon opportunity for study1 free from any obstruction1 and undue bias1 than upon the ability of tutors2 though there is an additional advantage when they are able men1 and eminent in the branches of science which they undertake to teach4 ,but this is by no means so essential as many other circumstances4 ,whatever be the qualifications of your tutors1 your improvement must chiefly depend upon yourselves4 ,they cannot think or labour for you4 ,they can only put you in the best way of thinking and labouring for yourselves4 ,if1 therefore1 you get knowledge1 you must acquire it by your own industry4 ,you must form all conclusions1 and all maxims1 for yourselves1 from premises and data collected1 and considered by yourselves4 ,and it is the great object of this institution to remove every bias the mind can lie under1 and give the greatest scope to true freedom of thinking and inquiry4 ,and provided you be intelligent and virtuous men1 and good citizens1 it will be no cause of regret to the friends of this institution1 if1 with respect to religion1 or politics1 you adopt systems of principles1 and maxims of conduct1 very different from theirs4 ,give me leave1 now that ,i am addressing you as young men1 and young students1 to suggest a caution on a subject1 of the importance of which it is hardly possible that you should be sufficiently aware1 because it is only impressed by that experience which you have not yet had4 ,i mean that degree of vanity which generally accompanies the acquirements that diligent persons of your age make in places of liberal education1 and the contempt they are too apt to entertain for those who have not made the same proficiency with themselves4 ,and ,i assure you1 that in the observations ,i shall make on this subject1 ,i have no view whatever to any thing that ,i have observed1 or heard1 of any of you in particular4 ,but ,i have been in your situation myself1 and ,i know the importance of these observations to students in general4 ,you are now at an age in which young persons usually make the most sensible advances in knowledge1 and in which the understanding appears to ripen the most rapid manner4 ,you are able to say every year1 every month1 and almost every day1 what particular advances you have made1 and how much you know more than you did before4 ,and being taught1 and accustomed1 to express your thoughts in writing1 you find yourselves qualified to do this in a manner of which you had no idea1 or expectation1 but a little time ago4 ,you also perfectly remember what you have so recently learned1 and many respects may be more particular and exact than even your tutors themselves4 ,the almost unavoidable effect of this is a high idea of your own powers and attainments1 and too often a proportionable contempt of those who1 not having had equal advantages1 cannot do what you are easily capable of4 ,a certain degree of vanity is1 therefore1 excusable in young persons2 and1 indeed1 it is by means of it that they are excited to exert themselves in a manner that they would not otherwise have done4 ,but be careful that this temper be not indulged to excess1 for it will then be found to have serious ill consequences2 the least of which is the precluding future improvement1 from being already satisfied with yourselves1 and conscious of a sufficient superiority over others4 ,the foundation of this self-conceit1 on account of literary attainments1 will be found to be extremely weak4 ,in fact1 we learn more before the period to which you are now arrived1 and ,i hope you will continue to learn more after it1 without its being so much noticed2 and the ability that is discovered in the acquirements which are the subjects of this vanity is not greater than appears on other occasions4 ,only they are not so conspicuous4 ,what we all learn in the first three years of our lives1 is much more extraordinary in its nature than all that we acquire afterwards4 ,i mean the perfect use of our limbs1 and the elements of speech4 ,what we learn in a month in that early period of life1 could not1 if we were brought up in the ignorance of it1 be learned in a year at any subsequent period4 ,but these acquirements being universal1 and what the circumstances in which we are all necessarily in compel us to learn1 it does not appear extraordinary in any particular individual4 ,also1 the proficiency that boys make at a grammar school1 in which1 in general1 the dead languages only are taught 7a knowledge of which is commonly the result of severe application7 is too common to be the cause of much self-conceit4 ,but the advances that are made at places of liberal education are both less common1 and of a more conspicuous nature4 ,you will also find1 if you continue your application to study1 that it is only the elements of science that you can acquire here1 and that if you live many years1 they will bear but a small proportion to your future acquirements4 ,but those future acquirements1 in consequence of their bearing a less proportion to your whole stock of knowledge1 will not be so conspicuous4 ,thus1 though all the buildings that in one year are added to such a city as ,london would make a pretty large country town1 they bear so small a proportion to what was built before1 that they are not much noticed2 whereas1 had half the quantity of building been erected in a place where no house had existed before1 it would have been a memorable event in the history of the country4 ,also1 as in old cities many buildings will fall to decay1 while new ones are added2 you must expect to forget much of what you now know4 ,no man can give equal attention to every object2 and as we advance in life1 we1 in general1 only learn new things at the expence of the old ones4 ,but then they are the more valuable articles of knowledge1 the more general and leading principles1 which remain with us2 while the more useless ones1 things to which we give less attention because we find them to be of less use1 disappear4 ,yet it is no uncommon thing for ingenious students to despise old scholars who are not so ready in the minutiae of literature1 though they may have forgotten more than those youths ever knew1 and may retain what they cannot acquire without forgetting as much4 ,another observation proper to lessen the conceit of literary men1 is1 that genius is not confined to them1 but is equally great1 though not equally conspicuous1 in every other line of life1 and especially in manufactures and the arts4 ,here1 however1 discoveries equal1 with respect to sagacity1 to those of ,newton1 contribute little to posthumous fame1 because the discoverers are not writers4 ,but the greatest branch of intellectual excellence with respect to which every other is nothing1 and which1 from its nature1 can never be foundation of any self-conceit1 is virtue1 or right dispositions of mind1 leading to right conduct in life4 ,proper sentiments1 and just affections of mind1 arise from just1 and often comprehensive1 views of things1 past1 present1 and to come4 ,and if the real greatness of any thought1 or action1 be estimated by the number of elements that constitute it1 and its remoteness from the dictates of sense and natural appetite1 a virtuous and pious man will appear to be a much more dignified character1 more proper to be viewed with admiration and esteem1 than the greatest scholar2 discovering1 in fact1 greater comprehension and force of mind4 ,i mean1 however1 that virtue which is the result of reflection1 of discipline1 and much voluntary exertion1 which1 though operating with equal promptness and facility1 is as much superior to mere innocence1 and what is commonly called good nature1 as motions secondarily automative are to those that are primarily so2 a comparison which you who have studied ,hartley's ,theory of the ,mind will see the force of4 ,these considerations ,i take the liberty to suggest1 as being proper to lessen that vanity which is so incident to those who distinguish themselves in the fields of literature1 and which1 operating like the acquisition of riches1 or power1 or any possession that is rare among men1 instead of enlarging1 may tend to contract the mind1 by confining its attention to itself4 ,beginning with a generous emulation1 it proceeds to envy and jealousy1 and ends in actual hatred and malignity1 against which you cannot1 surely1 be too strongly put upon your guard2 this being the greatest depravity to which human nature is subject1 and which yet1 like any other vice1 may be in full possession of the mind1 without the person himself knowing1 or suspecting it2 unless he give more attention to his feelings than most persons do4 ,if no man ever thought himself to be avaricious1 or cruel1 can it be expected that any person should ever discover that he is too self-conceited8 ,better1 however1 infinitely better1 were it to rank with the merest dunces1 than have the conceit and malignity 7produced originally from conceit7 of some who have distinguished themselves the most as linguists1 critics1 and poets4 ,even the study of nature1 though1 from its vast extent1 it is less apt to produce this baneful effect1 is not always a sufficient guard against it4 ,this is an affecting and an alarming consideration4 ,but in the intellectual1 as in the civil and commercial world1 we gain nothing but at the risk of some loss2 and in this case the possible gain is worth the risk of even this great loss4 ,for when literary1 and scientific excellence coincide with that which is of a moral nature1 it adds unspeakably to the value of a character4 ,ingenuity coupled with modesty1 and great genius with benevolence and true piety1 constitute the perfection of human character1 and is what we should ever have in view4 ,and a course of education in which both these objects are equally attended to1 is the only one that deserves to be called liberal3 but such as1 ,i hope1 you have found this to be4 ,give me leave further to observe to you1 that the time that you spend in a place of liberal education is of more importance to you than you can be at present aware of4 ,whatever be the sphere of life for which you are destined1 the probability is1 that you will hereafter have but little leisure for reading and studying1 compared to what you have now4 ,besides1 general maxims of all kinds1 such as are the foundation of all our future conduct1 in morals1 religion1 or politics1 are generally formed at your time of life4 ,from this period expect no great change in your opinions1 or conduct2 because now it is that you give particular attention to the forming your opinions on all subjects of importance2 so that very little that is materially new to you can be expected to occur to you in future life1 and almost every thing that you would choose to read will only tend to confirm you in the general principles that you will now adopt4 ,there are1 no doubt1 exceptions to this1 as well as every other general observation2 but it is wisdom to suppose1 and to act upon the supposition1 that we are constituted as the generality of mankind are1 and that we shall feel1 and act1 as they do4 ,since1 then1 so much depends on the leading principles and maxims which you will now adopt1 be it your care to form just and good ones1 and let no authority of tutors1 or others1 have any undue influence over you4 ,in all cases think and judge for yourselves1 and especially on all subjects of importance1 and with as much attention as you can give to them4 ,it may not be amiss1 in the present state of things1 to say something respecting another subject1 which now commands universal attention4 ,you cannot but be apprised1 that many persons entertain a prejudice against this ,college1 on account of the republican1 and1 as they choose to call them1 the licentious1 principles of government1 which are supposed to be taught here4 ,show1 then1 by your general conversation1 and conduct1 that you are the friends of peace and good order2 and that1 whatever may be your opinions with respect to the best form of government for people who have no previous prejudices or habits1 you will do every thing in your power for the preservation of that form of it which the generality of your countrymen approve1 and under which you live1 which is all that can be reasonably expected of any subject4 ,as it is not necessary that every good son should think his parent the wisest and best man in the world1 but it is thought sufficient if the son pay due respect and obedience to his parent2 so neither is it to be expected that every man should be of opinion that the form of government under which he happens to be born is the best of all possible forms of government4 ,it is enough that he submit to it1 and that he make no attempt to bring about any change1 except by fair reasoning1 and endeavouring to convince his countrymen1 that it is in their power to better their condition in that respect1 as well as in any other4 ,think1 therefore1 speak1 and write1 with the greatest freedom on the subject of government1 particular or general1 as well as on any other that may come before you4 ,it can only be avowed tyranny that would prevent this4 ,but at the same time submit yourselves1 and promote submission in others1 to that form of government which you find to be most approved1 in this country1 which at present unquestionably is that by ,king1 ,lords1 and ,commons4 ,as to religion1 we may1 surely1 be allowed to think and act entirely for ourselves2 in all cases obeying ,god and conscience rather than man4 ,but let us be thankful for the degree of liberty that we are allowed1 though it be not all that we are justly entitled to2 and let us not use any other means than reason and argument in order to better our condition4 ,by this peaceable and steady conduct we shall at length convince those who will hear reason1 that we are entitled to greater consideration2 and doubt not but whatever is true and right1 will finally prevail1 and be universally established4 ,that any of your tutors1 or any of the friends of this institution1 wish to promote reformation1 in church or state1 by any other means than those of reason1 and argument1 is a calumny1 utterly void of foundation1 or probability4 ,but your conduct1 dispersed as you will soon be in different parts of the country1 will be the best means of refuting it4 ,let us leave the method of proceeding by riot and tumult to those persons to whose schemes such proceedings are congenial4 ,truth stands in no need of such support1 and will always triumph when assailed by such weapons4 ,in return1 then1 for the advantages which you have enjoyed in this institution1 do it this service2 and in recommending it1 ,i trust you are doing substantial service to the cause of liberty and truth2 and conferring a most important benefit on your country1 and on mankind4 ,,contents4 ,,lecture ,i4 ,the ,introduction #a ,,lecture ,,ii4 ,of the ,properties of all ,matter #i ,of ,aeriform ,substances #ac ,,lecture ,,iii4 ,of ,atmospherical ,air #ae ,,lecture ,,iv4 ,of ,dephlogisticated ,air #ah ,of ,phlogisticated ,air #bj ,,lecture ,v4 ,of ,inflammable ,air #ba ,,lecture ,,vi4 ,of ,nitrous ,air #bc ,,lecture ,,vii4 ,of ,fixed ,air #bg ,of ,hepatic ,air #bi ,of ,phosphoric ,air #cj ,,lecture ,,viii4 ,of ,dephlogisticated ,marine ,acid ,air #ca ,of ,phlogisticated ,marine ,acid ,air #cb ,,lecture ,,ix4 ,of ,vitriolic ,acid ,air #cd ,of ,fluor ,acid ,air #cf ,,lecture ,x4 ,of ,alkaline ,air #cg ,miscellaneous ,observations relating to ,air #ch ,,lecture ,,xi4 ,of ,liquid ,substances2 and first of ,water #da ,,lecture ,,xii4 ,of the ,nitrous ,acid #de ,,lecture ,,xiii4 ,of the ,vitriolic ,acid #di ,of the ,marine ,acid #eb ,,lecture ,,xiv4 ,of the ,vegetable ,acids1 and others of a less perfect nature #ed ,,lecture ,,xv4 ,of the ,phosphoric ,acid #ei ,,lecture ,,xvi4 ,of ,alkalis #fb ,,lecture ,,xvii4 ,of ,liquid ,inflammable ,substances #ff ,of ,a,ether #fh ,,lecture ,,xviii4 ,of ,oil #gj ,,lecture ,,xix4 ,of ,solid ,substances #gf ,of ,calcareous ,earth #gg ,of ,siliceous ,earth #gi ,,lecture ,,xx4 ,of ,argillaceous ,earth #ha ,of ,terra ,ponderosa #hb ,of ,magnesia #hc ,,lecture ,,xxi4 ,of ,ores #hd ,of ,gold #hg ,,lecture ,,xxii4 ,of ,silver #ij ,of ,platina #ib ,,lecture ,,xxiii4 ,of ,mercury #id ,,lecture ,,xxiv4 ,of ,lead #ii ,of ,copper #aja ,,lecture ,,xxv4 ,of ,iron #aje ,,lecture ,,xxvi4 ,of ,tin #aji ,of the ,semi-metals #aac ,,lecture ,,xxvii4 ,of ,nickel #aae ,of ,arsenic #aaf ,of ,cobalt #aah ,of ,zinc #aai ,,lecture ,,xxviii4 ,of ,antimony #aba ,of ,manganese #abc ,of ,wolfram #abd ,of ,molybdena #abe ,of ,solid ,combustible ,substances #abf ,,lecture ,,xxix4 ,of the ,doctrine of ,phlogiston and the ,composition of ,water #abg ,,lecture ,,xxx4 ,of ,heat #ace ,,lecture ,,xxxi4 ,of ,animal ,heat #ade ,,lecture ,,xxxii4 ,of ,light #adh ,,lecture ,,xxxiii4 ,of ,magnetism #aee ,,lecture ,,xxxiv4 ,of ,electricity #afb ,,lecture ,,xxxv4 ,the same ,subject continued #agj ,,lecture ,,xxxvi4 ,the same ,subject continued #agg ,,lectures ,,on ,,experimental ,,philosophy4 ,,lecture ,i4 ,the ,introduction4 ,the object of experimental philosophy is the knowledge of nature in general1 or more strictly1 that of the properties of natural substances1 and of the changes of those properties in different circumstances4 ,this knowledge can only be attained by experiment1 or observation2 as that clay is capable of becoming hard by means of fire1 and thereby being made into bricks1 and that by the same means lime-stone can be converted into quick-lime1 and by the addition of water and sand1 make mortar4 ,it is by observation also that we discover that stones and other heavy bodies fall to the ground1 and that a magnet will attract iron4 ,in other words1 experimental philosophy is an investigation of the wisdom of ,god in the works and the laws of nature1 so that it is one of the greatest objects to the mind of man1 and opens a field of inquiry which has no bounds2 every advance we make suggesting new doubts and subjects of farther inquiry4 ,the uniformity we discover in the properties of natural substances enables us to lay down general rules1 or principles1 which1 being invariable1 we call the laws of nature2 and by our knowledge of these laws we are able to predict1 and at our own pleasure to produce1 particular results1 and this is the source of all the powers of man4 ,it is the direction we acquire of the powers of nature2 so that1 as ,lord ,bacon observed1 knowledge is power4 ,all arts and manufactures are derived from science4 ,thus the doctrine of mechanics is an application of the law of gravitation4 ,every thing we are capable of doing by means of the steam-engine is derived from our knowledge of the properties of water in steam2 all the great effects of gunpowder we owe to our knowledge of the composition1 and chemical properties1 of that substance4 ,every new appearance in nature is preceded by some new circumstance1 and to this1 or rather to something always attending it1 we say that the appearance is owing4 ,this circumstance we therefore call the cause1 and the new appearance the effect of that cause4 ,thus we say that the union of phlogiston to a particular kind of earth is the cause of its becoming a metal4 ,it is one of the principal rules of philosophizing to admit no more causes than are necessary to account for the effects4 ,thus1 if the power of gravity1 by which heavy bodies fall to the earth1 be sufficient to retain the planets in their orbits1 we are authorized to reject the ,cartesian ,vortices4 ,in other words1 we must make no more general propositions than are necessary to comprehend all the particulars contained in them4 ,thus1 after having observed that iron consists of a particular kind of earth united to phlogiston1 and that it is soluble in acids2 and that the same is true of all other metallic substances1 we say1 universally1 that all metals consist of a peculiar earth and phlogiston1 and that they are all soluble in some acid4 ,of the circumstances which occasion a change in the properties of bodies1 some are the addition of what are properly called substances1 or things that are the objects of our senses1 being visible1 tangible1 or having weight1 c4 ,thus the addition of an acid changes an alkali into a neutral salt4 ,but other changes are occasioned either by a change of texture in the substance itself1 or the addition of something that is not the object of any of our senses4 ,thus1 a piece of steel becomes a magnet by the touch of another magnet1 and a drop of glass acquires the property of flying asunder by a small fracture1 in consequence of falling when red hot into cold water4 ,such also1 in the opinion of some1 is the difference between hot and cold substances4 ,till the nature of the cause be ascertained1 it is convenient to make use of the term principle1 as including both of the above-mentioned causes of the change of properties in bodies4 ,thus1 whatever be the real cause of gravity1 or of inflammability1 we may speak of the principle of gravity1 or of inflammability2 whether1 with ,newton1 we suppose gravity to be occasioned by a fluid pervading the whole universe1 which he termed aether1 and whether inflammability be caused by the presence of a real substance called phlogiston1 or not4 ,in this manner we use the letters x and y to denote unknown quantities in algebra4 ,when changes are made in substances by the addition of other substances1 they make what is called a chemical union2 and in this case the properties of the compound cannot with any certainty be deduced from those of the component parts1 but must be ascertained by fresh experiments4 ,thus1 from the specific gravities1 or the degrees of fusibility1 of two metals1 those of the compound cannot be predicted4 ,neither water nor acid of vitriol will separately dissolve iron1 so as to produce inflammable air1 but both together will do it4 ,however1 the properties of similar compounds are similar to one another4 ,thus1 all metals dissolved in acids are precipitated by mild alkalis4 ,this chemical union of two substances we ascribe to a certain elective attraction1 or affinity that subsists between them1 in consequence of which they unite with one another whenever a proper opportunity offers1 in preference to those substances to which they were before united4 ,thus the vitriolic acid1 having a stronger affinity with the vegetable alkali which is the basis of nitre1 will unite with that alkali1 and with it form another compound1 called vitriolated tartar1 while the acid of nitre1 being detached from its base1 is collected separately4 ,when two substances compose one liquid1 and a third1 which has a stronger affinity with either of the two parts than they have with each other1 is added to them1 it will unite with that part1 and take its place in the solution1 while the other will in many cases be precipitated1 and may be collected4 ,thus the earth of alum is precipitated from a solution of alum by salt of tartar4 ,this is the case of simple affinity4 ,when both the substances are compounds1 the component parts of which have a weaker affinity with each other than they have with those of the other compound1 two new combinations are formed1 and this is called a case of double affinity4 ,thus when phlogisticated alkali is poured into a solution of green vitriol1 the acid of the vitriol unites with the alkali1 while the phlogiston joining the calx of iron makes ,prussian blue4 ,all nature lying open to our investigation1 we must consider the different parts in some order4 ,but it is not very material which we adopt1 because1 begin where we will1 the properties of the substances we first treat of will be connected with those which must be particularly considered afterwards1 the changes in one substance being occasioned by its union with another4 ,it will be impossible1 for example1 to explain the properties of metals without considering the acids1 because by their union with acids very important changes are made in their properties4 ,there have been three principal methods of arranging natural substances4 ,one is according to the three kingdoms1 as they are called1 into which they have been distributed1 viz4 the mineral1 the vegetable1 and the animal4 ,another is according to the elements which enter into their composition1 and a third according to the form in which they are usually found1 viz4 aerial1 fluid1 or solid4 ,upon the whole this last appears to me to be the most convenient1 especially as it is easy to intermix general observations concerning the other divisions when they are particularly wanted4 ,as there will be frequent occasion to speak of the component and elementary parts of all substances1 ,i shall here observe1 that1 according to the latest observations1 the following appear to be the elements which compose all natural substances1 viz4 dephlogisticated air1 or the acidifying principle2 phlogiston1 or the alkaline principle2 the different earths1 and the principles of heat1 light1 and electricity4 ,besides these1 there are the following principles which have not been proved to be substances1 viz4 attraction1 repulsion1 and magnetism4 ,by the help of these principles we are able1 according to the present state of natural knowledge1 to explain all the appearances that have yet occurred to us4 ,,lecture ,,ii4 ,of the ,properties of all ,matter4 ,before ,i consider the properties of particular substances1 it will be proper to mention those which are common to them all4 ,but ,i shall first observe1 that the term substance has no proper idea annexed to it1 but is merely a convenience in speech2 since we cannot speak of the properties of substances1 such as hard1 round1 coloured1 c4 c4 7which circumstances alone affect our senses1 and thereby give proper ideas7 without saying that they inhere in1 or belong to1 some thing1 substance1 or substratum4 ,the terms being and person are also in the same predicament4 ,one property of all substances is extension1 since they all occupy some portion of space4 ,the incapacity of any substance to change its place has been termed1 though improperly1 the vis inertiae of matter4 ,it is sufficient to say1 that neither this1 nor any other effect can be produced without a cause4 ,infinite divisibility is a necessary property of all extended substance2 and from this circumstance it will follow1 that the smallest quantity of solid matter may be made to fill the largest space1 and yet none of the pores shall exceed the smallest given magnitude2 and consequently1 that1 for any thing we know to the contrary1 all the bodies in the universe may be comprized in the smallest space4 ,another property usually ascribed to all matter is impenetrability1 or the necessary exclusion of any substance from the place occupied by another4 ,but the only proof of impenetrability is the resistance that we find to our endeavours to put one substance into the place of another2 and it is demonstrated by experiments1 that this resistance is not occasioned by the actual contact of the substances1 but by a power of repulsion acting at a real distance from their surfaces4 ,it requires a considerable force to bring two solid substances into as near contact as the particles of the same substance2 and that these are not in actual contact is evident1 from their being capable of being brought nearer by cold2 and this is most remarkable with respect to the heaviest1 that is1 the densest1 of all substances1 viz4 the metals4 ,a more positive argument for the penetrability of matter is1 that the particles of light1 after entering the densest transparent substance1 do not appear to meet with any obstruction to their progress till they come to the opposite side4 ,the powers of attraction and repulsion seem to be common to all matter1 and the component parts of all substances are kept in their places by the due balance of those opposite powers4 ,if1 by any means1 the particles of any substance be removed beyond their sphere of mutual attraction1 they repel one another1 as those of water when it becomes steam4 ,of the different kinds of attraction1 that of gravitation seems to extend to the greatest possible distance2 but that which keeps together the parts of the same substance1 thence called the attraction of cohesion1 and the different kinds of chemical attractions1 called affinities1 only act at a small distance4 ,of the causes of these attractions we are entirely ignorant4 ,of ,aeriform ,substances4 ,aeriform substances1 of which the air that we breathe is one1 though invisible1 are real substances1 as appears by their excluding other substances4 ,that the air has weight appears by actually weighing a vessel before and after it is exhausted of air by means of an air-pump 7an instrument contrived for that purpose7 by its bursting a bladder1 and various other experiments4 ,air1 being a fluid1 presses in all directions1 as in the experiment of the fountain in vacuo1 and others4 ,the weight of the air is the cause of the suspension of mercury in a barometer1 and of the action of pumps4 ,the weight of atmospherical air is to that of water in the proportion of about #a to #hjj1 so as to press with the weight of about fourteen pounds on every square inch of surface4 ,air1 being an elastic fluid1 is capable of occupying more or less space according to the pressure which it sustains1 as appears by a bladder partially filled with air being expanded when the air is drawn from a receiver in which it is put1 by means of the air-pump1 and compressed in the condensing engine1 an instrument the reverse of the air-pump4 ,air is necessary to the conveyance of sound1 to the existence of flame1 and to animal life4 ,,lecture ,,iii4 ,of ,atmospherical ,air4 ,the first species of air that offers itself to our consideration is that of the atmosphere1 which appears to consist of a mixture of two kinds of air1 of different and opposite qualities1 viz41 dephlogisticated and phlogisticated1 in the proportion of about one third of the former to two thirds of the latter4 ,it is by means of the former of these two ingredients that it is capable of supporting flame and animal life4 ,this composition of atmospherical air is proved by several substances absorbing the dephlogisticated air1 and leaving the phlogisticated4 ,all these processes have been termed phlogistic1 because the effect is not produced but by substances supposed to contain phlogiston in a volatile state2 and by the affinity between phlogiston and the dephlogisticated part of the air1 the one is separated from the other4 ,of these processes are the calcination of metals1 a mixture of iron-filings and sulphur1 liver of sulphur1 the burning of phosphorus1 and the effluvia of flowers4 ,in some cases1 however1 it is not so clear that any thing is emitted from the substance that produces this effect2 for water deprived of all air will absorb the dephlogisticated part of the atmospherical in preference to the phlogisticated part4 ,as the purity of atmospherical air1 or its fitness for respiration1 depends upon the proportion of the dephlogisticated air that it contains1 any of the above-mentioned processes will suffice to determine it4 ,the more any given quantity of air is diminished by any of them1 the purer it was before the diminution4 ,but this effect is produced the most quickly by a mixture of nitrous air1 or firing inflammable air in it1 being almost instantaneous4 ,in order to measure the purity of air1 it is convenient to take more of the nitrous or inflammable air than is necessary to saturate the dephlogisticated air it contains4 ,equal quantities of each best answer the purpose4 ,supposing a given quantity of atmospherical air to be mixed with an equal quantity of nitrous air1 and the residuum to be #a4a measure1 the proportion of dephlogisticated and phlogisticated air in it may be found by the following arithmetical operation1 it being here taken for granted that one measure of pure dephlogisticated air will saturate two measures of pure nitrous air4 #b4j viz4 one of each4 #a4a the residuum4 ----- #c7j4i the quantity that has disappeared4 #j4c the dephlogisticated air contained in the measure of the air examined4 ,and this substracted from #a leaves 4#g for the proportion of phlogisticated air in it4 ,,lecture ,,iv4 ,of ,dephlogisticated ,air4 ,dephlogisticated air1 which is one of the component parts of atmospherical air1 is a principal element in the composition of acids1 and may be extracted by means of heat from many substances which contain them1 especially the nitrous and vitriolic2 as from nitre1 red precipitate1 the vitriols1 and turbith mineral1 and also from these two acids themselves1 exposed to a red heat in an earthen tube4 ,this kind of air is also contained in several substances which had attracted it from the atmosphere1 as from precipitate per se1 minium1 manganese4 ,dephlogisticated air is likewise produced by the action of light upon green vegetables2 and this seems to be the chief means employed by nature to preserve the purity of the atmosphere4 ,it is this ingredient in atmospheric air that enables it to support combustion and animal life4 ,by means of it the most intense heat may be produced1 and in the purest of it animals will live nearly five times as long as in an equal quantity of atmospherical air4 ,in respiration1 part of this air1 passing the membrane of the lungs1 unites with the blood1 and imparts to it its florid colour1 while the remainder1 uniting with phlogiston exhaled from the venous blood1 forms fixed air4 ,it is dephlogisticated air combined with water that enables fishes to live in it4 ,dephlogisticated air is something heavier than atmospherical air1 and the purity of it measured by mixing with it two equal quantities of nitrous or inflammable air1 deducing the residuum after the diminution from the three measures employed1 and dividing the remainder by #c1 as in the process for common air4 ,of ,phlogisticated ,air4 ,the other ingredient in the composition of atmospherical air is phlogisticated air4 ,it is procured by extracting the dephlogisticated part of the common air1 as by the calcination of metals1 c4 c4 by dissolving animal substances in nitrous acid1 and also by the union of phlogiston with nitrous air1 as by heating iron in it1 and by a mixture of iron-filings and sulphur4 ,phlogisticated air extinguishes a candle1 is entirely unfit for respiration1 and is something lighter than common air4 ,it is not capable of decomposition1 except by exploding it together with a superabundance of dephlogisticated air1 and a quantity of inflammable air1 or by taking the electric spark repeatedly in a mixture of it and dephlogisticated air4 ,in these cases nitrous acid is formed4 ,,lecture ,v4 ,of ,inflammable ,air4 ,inflammable air is procured from all combustible substances by means of heat and water1 and from several of the metals1 especially iron1 zink1 and tin1 by the vitriolic and marine acids4 ,from oils and spirit of wine it is procured by the electric spark4 ,by the same means also alkaline air is converted into it4 ,that which is procured from metals1 especially by steam1 is the purest and the lightest1 about ten times lighter than common air2 in consequence of which1 if a sufficient quantity be confined in a light covering1 it is possible to make it carry up heavy weights4 ,when it is procured from animal or vegetable substances1 it is of a heavier kind1 and burns with a lambent flame1 of various colours1 according to the circumstances4 ,calces of metals heated in inflammable air are revived1 and the air absorbed2 and since all the metals are revived in the same inflammable air1 the principle of metallization1 or phlogiston1 appears to be the same in them all4 ,pure inflammable air seems to consist of phlogiston and water1 and the lambent kinds to be the same thing1 with the addition of some oily vapour diffused through it4 ,,lecture ,,vi4 ,of ,nitrous ,air4 ,nitrous air is procured by dissolving most of the metals1 especially iron1 mercury1 and copper1 in the nitrous acid2 but that from mercury seems to be the purest4 ,nitrous air produced from copper contains a mixture of phlogisticated air4 ,some nitrous air is also obtained from the solution of all vegetable substances in nitrous acid2 whereas animal substances in the same process yield chiefly phlogisticated air3 but in both these cases there is a mixture of fixed air4 ,this species of air is likewise produced by impregnating water with nitrous vapour4 ,this process continues to have this effect after the water becomes blue1 but ceases when it turns green2 there not then1 probably1 being a sufficient proportion of water4 ,nitrous air is likewise produced by volatile alkali passing over red hot manganese1 or green vitriol1 when they are yielding dephlogisticated air4 ,this shews that dephlogisticated air is one ingredient in the composition of nitrous air1 and the same thing appears by pyrophorus burning in it4 ,on the contrary1 when nitrous air is made to pass over red-hot iron1 volatile alkali is produced4 ,nitrous air is completely decomposed by a mixture of about half its bulk of dephlogisticated air1 and the produce is nitrous acid4 ,and as nitrous acid is likewise formed by the union of inflammable and dephlogisticated air1 one principal ingredient in nitrous air must be common to it and inflammable air1 or phlogiston4 ,this air is likewise decomposed by dephlogisticated nitrous acid1 which by this means becomes phlogisticated4 ,it is also decomposed by a solution of green vitriol1 which by this means becomes black1 and when exposed to the air1 or heated1 emits nitrous air1 and recovers its former colour4 ,these decompositions of nitrous air seem to be effected by depriving it of phlogiston1 and thereby reducing it to the phlogisticated air originally contained in it4 ,this kind of air is diminished to about one fourth of its bulk by a mixture of iron filings and brimstone1 or by heating iron in it1 or calcining other metals in it1 when the remainder is phlogisticated air4 ,all that iron gets in this process is an addition of weight1 which appears to be water1 but it loses its phlogiston1 so that nitrous air seems to contain more phlogiston1 and less water than phlogisticated air4 ,nitrous air and dephlogisticated air will act upon one another through a bladder1 but in this case there remains about one-fourth of the bulk of nitrous air1 and that is phlogisticated air2 so that in this case there seems to be a conversion of nitrous air into phlogisticated air without any addition of phlogiston4 ,nitrous air is decomposed by pyrophorus1 and by agitation in olive oil1 which becomes coagulated by the process4 ,it is also absorbed by spirit of turpentine1 by ether1 by spirit of wine1 and alkaline liquors4 ,it is imbibed by charcoal1 and both that air which is afterwards expelled from it by heat1 and that which remains unabsorbed1 is phlogisticated air4 ,nitrous air resists putrefaction1 but is diminished by the animal substances exposed to it to about a fourth of its bulk1 and becomes phlogisticated air4 ,it is likewise fatal to plants1 and particularly to insects4 ,when nitrous air is long exposed to iron1 it is diminished and brought into a state in which a candle will burn in it1 though no animal can breathe it4 ,but this peculiar modification of nitrous air1 called dephlogisticated nitrous air1 is produced with the greatest certainty by dissolving iron in spirit of nitre saturated with copper1 impregnating water with this air1 and then expelling it from the water by heat4 ,if bits of earthen ware be heated in this dephlogisticated nitrous air1 a great proportion of it becomes permanent air1 not miscible with water1 and nearly as pure as common air1 so that the principle of heat seems to be wanting to constitute it permanent air4 ,,lecture ,,vii4 ,of ,fixed ,air4 ,having considered the properties of those kinds of air which are not readily absorbed by water1 and therefore may be confined by it1 ,i proceed to those which are absorbed by it1 and which require to be confined by mercury4 ,there are two kinds1 however1 in a middle state between these1 being absorbed by water1 but not very readily2 a considerable time1 or agitation1 being necessary for that purpose4 ,the first of these is fixed air4 ,this kind of air is obtained in the purest state by dissolving marble1 lime-stone1 and other kinds of mild calcareous earth in any acid4 ,it is also obtained by the burning1 or the putrefaction1 of both animal and vegetable substances1 but with a mixture of both phlogisticated and inflammable air4 ,fixed air is also produced by heating together iron filings and red precipitate2 the former of which would alone yield inflammable air1 and the latter dephlogisticated4 ,fixed air is therefore a combination of these two kinds of air4 ,another fact which proves the same thing is1 that if charcoal of copper be heated in dephlogisticated air1 almost the whole of it will be converted into fixed air4 ,on the same principle fixed air is produced when iron1 and other inflammable substances1 are burned in dephlogisticated air1 and also when minium1 and other substances containing dephlogisticated air1 are heated in inflammable air4 ,that water is an essential part of fixed air is proved by an experiment upon terra ponderosa aerata1 which yields fixed air when it is dissolved in an acid1 but not by mere heat4 ,if steam1 however1 be admitted to it in that state1 it will yield as much fixed air as when it is dissolved in an acid4 ,water absorbs something more than its own bulk of fixed air1 and then becomes a proper acid4 ,iron dissolved in this water makes it a proper chalybeate2 as without iron it is of the same nature with ,pyrmont or ,seltzer water1 which by this means may be made artificially4 ,ice will not imbibe this air1 and therefore freezing expels it from water4 ,fixed air extinguishes flame1 and is fatal to animals breathing in it4 ,also water impregnated with this air is fatal to fishes1 and highly injurious to plants4 ,but water thus impregnated will prevent1 in a great measure1 the putrefaction of animal substances4 ,fixed air thrown into the intestines1 by way of glyster1 has been found to give relief in some cases of putrid disease4 ,of ,hepatic ,air4 ,another species of air absorbed by water1 but not instantly1 is termed hepatic air1 being produced by the solution of liver of sulphur1 or of sulphurated iron1 in vitriolic or marine acid4 ,water imbibes about twice its bulk of this kind of air1 and it is then the same thing with the sulphureous waters of ,harrowgate4 ,of ,phosphoric ,air4 ,phosphoric air is produced by the solution of phosphorus in caustic fixed alkali4 ,if this air be confined by mercury1 it will take fire on being admitted to atmospheric1 and much more to dephlogisticated air4 ,after agitation in water it loses this property1 and the residuum is merely inflammable air1 with no great diminution of its bulk4 ,this kind of air1 therefore1 probably consists of phosphorus dissolved in inflammable air2 though it cannot be made by melting it in inflammable air4 ,,lecture ,,viii4 ,of ,dephlogisticated ,marine ,acid ,air4 ,this species of air is produced by heating spirit of salt with manganese2 or more readily1 by pouring acid of vitriol on a mixture of salt and manganese1 in the proportion of about #af of the former to #f of the latter4 ,in this case the acid of vitriol decomposes the salt1 and the marine acid1 disengaged in the form of air1 takes dephlogisticated air from the manganese2 so that this species of air seems to consist of marine acid vapour1 and dephlogisticated air4 ,this species of air has a peculiarly pungent smell1 and is absorbed by water as readily as fixed air4 ,the water takes about twice its bulk of it2 and thereby acquires a yellowish tinge4 ,both this air1 and the water impregnated with it1 discharges vegetable colours from linen or cotton1 and is thereby useful in bleaching4 ,this air when cold coagulates into a yellowish substance4 ,it dissolves mercury1 and with it forms corrosive sublimate4 ,of ,phlogisticated ,marine ,acid ,air4 ,besides the preceding kinds of air which are slowly absorbed by water1 there are others which are absorbed by it very rapidly1 so that they cannot be confined but by mercury4 ,of this kind is phlogisticated marine acid air1 procured by the acid of vitriol and common salt2 the former seizing upon the alkaline basis of the latter1 and thereby expelling the marine acid in the form of air4 ,it is called phlogisticated to distinguish it from dephlogisticated marine acid air1 which seems to be the same thing1 with the addition of dephlogisticated air4 ,phlogisticated marine acid air is heavier than common air4 ,it extinguishes a candle with a blue flame4 ,it dissolves many substances containing phlogiston1 as iron1 dry flesh1 c4 and thereby forms a little inflammable air4 ,water absorbs #cfj times its bulk of this air1 and is then the strongest spirit of salt4 ,it absorbs one-sixth more than its bulk of alkaline air1 and with it forms the common sal ammoniac4 ,its affinity to water enables it to dissolve ice1 and to deprive borax1 nitre1 and other saline substances1 of the water that enters into their composition4 ,,lecture ,,ix4 ,of ,vitriolic ,acid ,air4 ,vitriolic acid air is procured by heating in hot acid of vitriol almost any substance containing phlogiston1 especially the metals which are soluble in that acid1 as copper1 mercury1 c4 ,this kind of air is heavier than common air1 and extinguishes a candle1 but without any particular colour of its flame4 ,it will not dislodge the nitrous or marine acids from any substance containing them4 ,by its affinity to water it deprives borax of it4 ,one measure of this air saturates two of alkaline air1 and with it forms the vitriolic ammoniac4 ,water imbibes between #cj and #dj times its bulk of this air1 and retains it when frozen4 ,water thus impregnated dissolves some metals1 and thereby yields inflammable air4 ,if this water be confined in a glass tube1 together with common air1 and be exposed to a long continued heat1 it forms real sulphur1 the dephlogisticated part of the common air being imbibed1 and forming real vitriolic acid1 which uniting with the phlogiston in the air1 forms the sulphur4 ,also this air mixed with atmospheric air will1 without heat1 imbibe some part of it1 and thereby become the common acid of vitriol2 so that water impregnated with vitriolic acid air1 commonly called sulphureous1 or phlogisticated acid of vitriol1 wants dephlogisticated air to make it the common acid of of vitriol4 ,this kind of air is imbibed by oils1 which thereby change their colour2 whale oil becoming red1 olive oil of an orange colour1 and spirit of turpentine of the colour of amber4 ,if this air be confined in a glass tube by mercury1 and the electric spark be taken in it1 a black tinge will be given to the glass contiguous to the spark1 and this black substance appears to be mercury super-phlogisticated2 since by exposure to air it becomes running mercury3 so that the vapour of mercury must be diffused through every part of this air1 to the distance of at least several feet from the surface of the mercury4 ,of ,fluor ,acid ,air4 ,fluor acid air is procured by dissolving the earthy substance called fluor in vitriolic acid4 ,this kind of air extinguishes a candle1 and1 like vitriolic acid air1 one measure of it saturates two of alkaline air4 ,it is peculiar to this kind of air to dissolve glass when it is hot4 ,it seems to consist of a peculiar acid vapour united to the stony substance of the fluor2 for water being admitted to it absorbs the acid vapour1 and the stony substance is deposited4 ,by this means it exhibits an amusing appearance1 whether water be admitted to a glass jar previously filled with that air1 or the bubbles of air be admitted1 as they are formed1 to a quantity of water resting on mercury4 ,,lecture ,x4 ,of ,alkaline ,air4 ,alkaline air is produced by means of heat from caustic volatile alkali1 and also from a mixture of sal-ammoniac and slaked lime1 in the proportion of about one-fourth of the former to three-fourths of the latter4 ,in this case the marine acid in the sal-ammoniac unites with the calcareous earth1 and the volatile alkali 7probably with the assistance of the water7 takes the form of air4 ,this species of air is heavier than inflammable air1 but lighter than any of the acid airs4 ,like them1 however1 it dissolves ice1 and deprives alum1 and some other saline substances1 of the water which they contain4 ,united with fixed air1 it makes the concrete volatile alkali2 with marine acid air1 the common sal-ammoniac2 and with water1 the caustic volatile alkali4 ,the electric spark1 or a red heat1 converts alkaline air into three times its bulk of inflammable air2 and the calces of metals are revived in alkaline1 as well as in inflammable air2 but there remains about one-fourth of its bulk of phlogisticated air4 ,these facts shew that alkaline air consists chiefly of phlogiston4 ,miscellaneous ,observations relating to ,air4 ,the nitrous acid may be exhibited in the form of air1 as well as the vitriolic1 the marine1 and the fluor acids4 ,but it cannot be confined even by mercury1 which it instantly dissolves4 ,it may1 however1 in some measure1 be confined in a dry glass vessel1 from which it will in a great measure expel the common air4 ,this nitrous acid air is that red vapour1 which is produced by the rapid solution of bismuth1 and some other metals in the nitrous acid4 ,but the vegetable acid cannot be exhibited in the form of air4 ,it is only capable of being converted into vapour1 like water3 and in the common temperature of our atmosphere1 returns to a state of fluidity4 ,different kinds of air which have no affinity to each other1 when once mixed together will not separate1 notwithstanding any difference of specific gravity4 ,such is the case of a mixture of inflammable and dephlogisticated air1 and even of inflammable and fixed air4 ,without this property also1 the phlogisticated air1 which constitutes the greatest part of our atmosphere1 being specifically lighter than dephlogisticated air1 of which the other part of it consists1 would separate from it1 and ascend into the higher regions of the atmosphere4 ,inflammable air1 however1 will not mix with acid or alkaline air4 ,different kinds of air are expanded differently by the same degrees of heat2 dephlogisticated air the least1 and alkaline air the most4 ,if any fluid1 as water1 spirit of wine1 or even mercury1 be heated in a porous earthen vessel1 surrounded by any kind of air1 the vapour of the fluid will pass through the vessel one way1 while the air passes the other2 and when the operation ceases1 with respect to the one1 it likewise ceases with respect to the other4 ,,lecture ,,xi4 ,of ,liquid ,substances2 ,,and ,,first ,,of ,,water4 ,having considered all the substances that are usually found in the form of air1 ,i come to those that are generally in a fluid form1 beginning with water1 which is the principal1 if not the only cause of fluidity to all the other substances that ,i shall place in this class4 ,pure water is a liquid substance1 transparent1 without colour1 taste1 or smell2 and with different degrees of heat and cold may be made to assume the three forms of a solid1 of a fluid1 and of air4 ,below #cb deg4 of ,fahrenheit it is ice1 and above #bab deg4 it is vapour2 so that in an atmosphere below #cb deg4 it never could have been known to be any thing else than a peculiar kind of stone1 and above #bab deg4 a peculiar species of air4 ,in passing from the state of a solid to that of a liquid1 water absorbs a great quantity of the principle1 or matter1 of heat1 which remains in it in a latent state2 and in passing from a state of fluid to that of vapour1 it absorbs much more2 and this heat is found when the processes are reversed4 ,it has been observed1 that when water becomes vapour1 it takes the form of small globules1 hollow within1 so as to be specifically lighter than air4 ,the degree of heat at which water is converted into vapour depends upon the pressure of the atmosphere2 so that in vacuo1 or on the top of a high mountain1 it boils with little heat2 and when compressed1 as in ,papin's digester1 or in the bottom of a deep pit1 it requires much heat4 ,in the former case the restoring of the pressure will instantly put a stop to the boiling1 and in the latter case the removing of the pressure will instantly convert the heated water into vapour4 ,the ease with which water is converted into vapour by heat1 has given a great power to mechanicians1 either by employing the natural pressure of the atmosphere1 when steam is condensed under a moveable pistern1 in an iron cylinder1 which was the principle of the old fire-engine1 or by employing the elastic power of steam to produce the same effect1 which is the principle of ,mr4 ,watt's steam engine4 ,water was long thought to be incompressible by any external force1 but ,mr4 ,canton has shewn that even the pressure of the atmosphere will condense it very sensibly4 ,we do not know any external force equal to that by which water is expanded when it is converted into ice1 or into vapour4 ,for though the particles of water approach nearer by cold1 yet when it crystallizes1 the particles arrange themselves in a particular manner1 with interstices between them2 so that1 on the whole1 it takes up more room than before4 ,water has an affinity to1 and combines with1 almost all natural substances1 aerial1 fluid1 or solid2 but most intimately with acids1 alkalies1 calcareous earth1 and that calx of iron which is called finery cinder1 from which the strongest heat will not expel it4 ,it has been supposed by some1 that by frequent distillation1 and also by agitation1 water may be converted into a kind of earth2 but this does not appear to be the case4 ,it has also of late been thought1 that water is resolvable into dephlogisticated and inflammable air2 but the experiments which have been alleged to prove this do not satisfy me2 so that1 for any thing that appeared till very lately1 water might be considered as a simple element4 ,by means of heat1 however1 it seems to be resolvable into such air as that of which the atmosphere consists1 viz4 dephlogisticated and phlogisticated1 only with a greater proportion of the former4 ,water1 with respect to specific gravity and temperature1 has generally been made the standard to all other substances2 its freezing and boiling points being the limits by means of which thermometers are graduated4 ,other substances have also been compared with water1 as a standard1 with respect to the capacity of receiving heat1 and retaining it in a latent state1 as will be shewn when we consider the subject of heat4 ,,lecture ,,xii4 ,of the ,nitrous ,acid4 ,under the head of liquids ,i shall consider acids and alkalis1 though some of them may be exhibited in the form of air1 and others in a solid form4 ,these two chemical principles are formed to unite with one another1 and then they constitute what is called a neutral salt4 ,both acids and alkalis are distinguishable by their taste4 ,another test1 and more accurate1 is1 that acids change the blue juices of vegetables red1 and alkalis turn the syrup of violets green4 ,acids are generally distinguished according to the three kingdoms to which they belong1 viz4 mineral1 vegetable1 and animal4 ,the mineral acids are three1 the nitrous1 the vitriolic1 and the marine4 ,the nitrous acid is formed by the union of the purest inflammable air1 or the purest nitrous air1 with dephlogisticated air4 ,but it is usually procured from nitre by means of the vitriolic acid1 which1 seizing its base1 expels the nitrous acid in a liquid form4 ,on this account this acid is said to be weaker than the vitriolic4 ,if the nitrous acid be made to pass through a red-hot earthen tube1 it will be decomposed1 and the greatest part of it be converted into dephlogisticated air4 ,like all other acids1 the nitrous acid has a strong affinity to water2 but it is not capable of so much concentration as the vitriolic4 ,it is generally of an orange or yellow colour2 but heat will expel this colour in the form of a red vapour1 which is the same acid in the form of air1 and loaded with phlogiston2 and therefore when it is colourless it is said to be dephlogisticated4 ,but the colourless vapour exposed to heat1 or to light1 will become coloured again2 and the liquid acid imbibing this coloured vapour1 becomes coloured as before4 ,this acid tinges the skin of a yellow colour1 which does not disappear till the epidermis be changed4 ,the nitrous acid unites with phlogiston1 alkalis1 metallic substances1 and calcareous earth4 ,by means of its affinity with phlogiston it occasions that rapid accension called detonation1 when any salt containing this acid1 especially nitre1 is applied to hot charcoal1 or when charcoal is put to hot nitre4 ,in fact1 the charcoal burns so rapidly by means of the dephlogisticated air supplied by the nitre4 ,a mixture of sulphur assists the accension of these substances1 and makes gunpowder1 in the explosion of which much nitrous or phlogisticated air is suddenly produced1 and expanded by the heat4 ,the application of this force1 both to useful and destructive purposes1 is well known4 ,if1 instead of nitre1 a salt made with dephlogisticated marine acid be made use of1 the explosion is more easily produced1 and is much more violent4 ,friction will do this as well as heat4 ,nitre also enters into the composition of pulvis fulminans1 viz4 three parts nitre1 two of dry alkali1 and one of sulphur4 ,this composition melts1 and yields a blue flame1 before it explodes4 ,by means of the affinity of the nitrous acid to oil1 another substance containing phlogiston1 it is capable of producing not only a great heat1 but even a sudden flame1 especially when mixed with a little vitriolic acid4 ,nitrous acid dissolves all metallic substances except gold and platina1 and in the solution nitrous air is produced4 ,the particular kinds of saline substances formed by the union of the nitrous acid with the several metals and earths may be seen in tables constructed for the purpose4 ,they are all deliquescent4 ,,lecture ,,xiii4 ,of the ,vitriolic ,acid4 ,the vitriolic acid1 so called because it was originally procured from vitriol1 is now generally procured from sulphur2 the dephlogisticated part of the air uniting with it in the act of burning4 ,that dephlogisticated air is essential to this acid is evident from the decomposition of it2 for if the vapour of it be made to pass through a red-hot earthen tube1 a great quantity of dephlogisticated air is procured4 ,this acid has a strong affinity to water1 with which it unites with much heat2 and it is capable of greater concentration1 or of being made specifically heavier1 than any other acid4 ,when pure1 it is entirely free from colour and smell1 owing1 probably1 to its being free from phlogiston1 which is inseparable from the nitrous or marine acids4 ,the vitriolic acid will dislodge the nitrous1 or marine1 or any other acid1 from their earthy or metallic bases2 from which property it is called the strongest of all the acids4 ,by means of the superior affinity of the vitriolic acid to earths1 and especially to terra ponderosa1 the smallest quantity of it in water may be discovered by a solution of this earth in the marine acid4 ,in this acid the terra ponderosa is held in perfect solution2 but with the vitriolic acid it forms a substance that is insoluble in water1 and therefore it instantly appears in the form of a white cloud4 ,perhaps chiefly from the strong affinity which this acid has with water1 pyrophorus1 consisting of a mixture of alum and several substances containing phlogiston1 takes fire spontaneously on exposure to the air4 ,it is commonly made of three parts of alum and one of brown sugar1 or of two parts alum1 one of salt of tartar1 and one of charcoal4 ,they must be heated till they have for some time emitted a vapour that burns with a blue flame4 ,the saline substances produced by the union of this acid with the several earths and metals1 are best exhibited in tables constructed for the purpose4 ,when united to three of the metals1 viz4 iron1 copper1 and zinc1 they are called vitriols1 green1 blue1 and white4 ,and all the substances which this acid unites with crystallize1 and do not deliquesce4 ,this acid unites with oil1 and the mixture is always black4 ,when any substance containing phlogiston is heated in the vitriolic acid1 another species of the acid1 called sulphureous1 is formed1 of a pungent smell4 ,in reality1 it is water impregnated with vitriolic acid air4 ,it makes1 however1 a distinct species of acid1 and is dislodged from its base by most of the others4 ,of the ,marine ,acid4 ,the marine acid is procured from common salt by the vitriolic acid1 which unites with its base1 the fossil alkali4 ,this acid is generally of a straw-colour2 but this is owing to an impregnation with some earthy matter1 most of which it readily dissolves1 especially the metallic ones4 ,it is less capable of concentration than the vitriolic or nitrous acids1 perhaps from a more intimate union of phlogiston with it4 ,no heat can extract from it any dephlogisticated air4 ,though this is denominated a weaker acid than the nitrous1 yet it will take silver1 lead1 or mercury1 from their union with the nitrous acid4 ,upon this principle1 a solution of these metals in the nitrous acid will readily discover whether any water contains the marine acid1 the latter uniting with the metal dissolved in the former1 and forming with it1 if it be silver1 a luna cornea2 which being a substance insoluble in water1 discovers itself by a cloudy appearance4 ,the union of the marine acid with earths forms salts that easily deliquesce1 but with the metals such as are capable of crystallization2 and so also is that formed by the union of this acid to terra ponderosa4 ,neither this acid nor the nitrous will dissolve gold or platina2 but a mixture of them1 called aqua regia1 will do it4 ,the marine acid has a strong affinity to dephlogisticated air1 and will take it from manganese and other substances2 and with this union it becomes a different acid1 called dephlogisticated marine acid1 being water impregnated with dephlogisticated marine acid air1 described above4 ,,lecture ,,xiv4 ,of the ,vegetable ,acids1 and others of a less perfect nature4 ,the principal of the vegetable acids are the acetous and the tartareous4 ,the acetous acid is the produce of a peculiar fermentation of vegetable substances1 succeeding the vinous1 in which ardent spirit it is procured1 and succeeded by the putrefactive1 in which volatile alkali is generated4 ,thus wine is converted into vinegar4 ,crude vinegar1 however1 contains some ingredient from the vegetable substances from which it was procured3 but distillation separates them1 and makes the vinegar colourless2 though some of the acid is lost in the process4 ,the acetous acid is concentrated by frost1 which does not affect the proper acid1 but only the water with which it is united4 ,it may likewise be concentrated by being first combined with alkalies1 earths1 or metals1 and then dislodged by a stronger acid1 or by mere heat4 ,thus the acetous acid1 combined with vegetable alkali1 forms a substance that is called the foliated earth of tartar2 and it may be expelled from it by the vitriolic acid4 ,when combined with copper it makes verdigris2 and from this union heat alone will expel it in a concentrated state4 ,the acetous acid thus concentrated is called radical vinegar4 ,still1 however1 it is weaker than any of the preceding mineral acids4 ,several vegetables1 as lemons1 sorrel1 and unripe fruit1 contain acids1 ready formed by nature1 mixed with some of the essential oil of the plants1 which gives them their peculiar flavours4 ,all these acids have peculiar properties2 but it is not necessary to note them in this very general view of the subject4 ,like vinegar1 these acids may be concentrated by frost1 and also by a combination with other substances1 and then expelled by a stronger acid4 ,the acid of tartar is very similar to that of vinegar4 ,tartar1 from which it is procured1 is a substance deposited on the inside of wine-casks1 though it is also found ready formed in several vegetables4 ,it consists of the vegetable alkali and this peculiar acid4 ,when refined from its impurities1 it is called crystals1 or cream of tartar4 ,the acid is procured by mixing the tartar with chalk1 or lime1 which imbibes the superfluous acid1 and this is expelled by the acid of vitriol4 ,or it may be procured by boiling the tartar with five or six times its weight of water1 and then putting the acid of vitriol to it4 ,this unites with the vegetable alkali1 and forms vitriolated tartar2 and the pure acid of tartar may be procured in crystals1 by evaporation and filtration1 equal in weight to half the cream of tartar4 ,this acid of tartar is more soluble in water than the cream of tartar4 ,this acid1 united to the mineral alkali1 makes ,rochelle salt4 ,every kind of wood1 when distilled1 or burned1 yields a peculiar acid2 and it is the vapour of this acid that is so offensive to the eyes in the smoke of wood4 ,a peculiar acid is obtained from most vegetable substances1 especially the farinaceous ones1 and from sugar1 by distillation with the nitrous acid4 ,this seizes upon the substance with which the acid was united1 and especially the phlogiston adhering to it1 and then the peculiar acid of sugar crystallizes4 ,thus with three parts of sugar1 and thirty of nitrous acid1 one part of the proper acid of sugar may be obtained4 ,by the same process an acid may be procured from camphor4 ,the bark of oak1 and some other vegetable substances1 especially nut-galls1 contain a substance which has obtained the name of the astringent principle2 the peculiar property of which is1 that it precipitates solutions of iron in the form of a black powder1 and in this manner ink is made4 ,but by solution in water and evaporation1 crystals1 which are a proper acid of galls1 may be obtained4 ,amber is a hard semitransparent substance1 chiefly found in ,prussia1 either dug out of the earth1 or thrown up by the sea4 ,it is chiefly remarkable for its electrical property2 but by distillation in close vessels there sublimes from it a concreted acid1 soluble in #bd times its weight of cold water4 ,amber seems to be of vegetable origin1 and to consist of an oil united to this peculiar acid4 ,the acids ,i shall mention next are of a mineral origin2 but being of a less perfect nature as acids1 ,i shall only just note them here4 ,borax is a substance chiefly found in a crystallized state in some lakes in the ,east ,indies4 ,it consists of the mineral alkali and a peculiar acid1 which may be separated1 and exhibited in white flakes1 by putting acid of vitriol to a solution of it in water4 ,this acid has been called sedative salt1 from its supposed uses in medicine4 ,it is an acid that requires fifty times its weight of water to dissolve it4 ,several other mineral substances1 as arsenic1 molybdena1 tungsten1 and wolfram1 in consequence of being treated as the preceding vegetables ones1 have been lately found to yield peculiar acids4 ,they are also produced in a concrete state1 and require a considerable proportion of water to make them liquid2 but as the water in which they are dissolved turns the juice of litmus red1 and as they also unite with alkalis1 they have all the necessary characteristics of acids4 ,,lecture ,,xv4 ,of the ,phosphoric ,acid4 ,the most important acid of animal origin1 though it has lately been found in some mineral substances1 is the phosphoric4 ,phosphorus itself is a remarkable substance1 much resembling sulphur1 but much more inflammable4 ,it has been procured chiefly1 till of late1 from urine1 but now more generally from bones1 by means of the vitriolic acid1 which unites with the calcareous earth of which bones consist1 and sets at liberty the phosphoric acid1 or the base of that acid1 with which it was naturally combined4 ,the acid thus procured1 mixed with charcoal1 and exposed to a strong heat1 makes phosphorus4 ,this substance burns with a lambent flame in the common temperature of our atmosphere1 but with a strong and vivid flame if it be exposed to the open air when moderately warm4 ,in burning it unites with the dephlogisticated air of the atmosphere1 and in this manner the purest phosphoric acid is produced4 ,this acid is also procured in great purity by means of the nitrous or vitriolic acids1 especially the former1 which readily combines with the phlogiston of the phosphorus1 and thus leaves the acid pure4 ,in this process phlogisticated air is produced4 ,this acid is perfectly colourless1 and when exposed to heat loses all its water1 and becomes a glassy substance1 not liable to be dissipated by fire1 and readily uniting with earths4 ,united to the mineral alkali1 it forms a neutral salt1 lately introduced into medicine4 ,united to the mineral and vegetable alkalis naturally contained in urine1 it has obtained the name of microcosmic salt1 frequently used as a flux for mineral substances with a blow-pipe4 ,besides the phosphoric1 there are other acids of an animal origin2 as that of milk1 that of sugar of milk1 that of the animal calculus1 and that of fat4 ,the acid of milk is the sour whey contained in butter-milk1 which1 by a tedious chemical process1 may be obtained pure from any foreign substance4 ,the sugar of milk is procured by evaporating the whey to dryness1 then dissolving it in water1 clarifying it with whites of eggs1 and evaporating it to the consistence of honey4 ,in this state white crystals of the acid of sugar of milk will be obtained4 ,by distilling these crystals with nitrous acid1 other crystals of the proper acid of sugar of milk will be obtained1 similar to those of the acid of sugar4 ,if the human calculus be distilled1 it yields a volatile alkali1 and something sublimes from it which has a sourish taste1 and therefore called the acid of the calculus4 ,it is probably some modification of the phosphoric acid4 ,animal fat yields an acid by distillation1 or by first combining it with quick-lime1 and then separating it by the vitriolic acid4 ,siliceous earth is corroded by this acid4 ,,lecture ,,xvi4 ,of ,alkalis4 ,the class of substances that seems particularly formed by nature to unite with acids1 and thereby form neutral salts1 are the alkalis4 ,they have all a peculiar acrid taste1 not easily defined4 ,they change the blue juices of vegetables green1 or purple1 and in common with acids have an affinity with water1 so as to be capable of being exhibited in a liquid form2 though when this water is expelled by heat1 some of them will assume a solid form4 ,alkalis are of two kinds2 the fixed1 which have no smell1 and the volatile which have a pungent one4 ,the fixed alkalis are of vegetable or mineral origin4 ,when in a solid form1 they both melt with a moderate heat1 and uniting with earthy substances1 make glass4 ,with an intense heat they are volatilized4 ,vegetable alkali is procured by burning plants1 and lixiviating the ashes2 a purer kind by the burning of tartar1 hence called salt of tartar2 but the purest of all is got by the deflagration of nitre2 the charcoal uniting with the acid as it assumes the form of dephlogisticated air1 and the alkali being left behind4 ,mineral alkali is found in ashes of sea-weed4 ,it is likewise the basis of sea-salt2 from which it is separated by several processes1 but especially by the calx of lead1 which has a stronger affinity with the marine acid with which it is found combined4 ,alkalis united with fixed air are said to be mild1 and when deprived of it caustic1 from their readiness to unite with1 and thereby corrode1 vegetable and animal substances4 ,to render them caustic1 they are deprived of their fixed air by quick-lime2 and in this state they unite with oils1 and make soap4 ,alkalis have a stronger affinity with acids than metals have with them2 so that they will precipitate them from their solutions in acid menstruums4 ,the vegetable fixed alkali has a strong attraction to water1 with which it will become saturated in the common state of our atmosphere1 when it is said to deliquesce2 and having the appearance of oil1 the salt of tartar is thus said to become oil of tartar per deliquium4 ,on the other hand1 the mineral1 or fossil alkali1 is apt to lose its water in a dry atmosphere1 and then it is said to effloresce4 ,in this state it is often found on old walls4 ,volatile alkali is procured by burning animal substances2 in ,egypt 7from whence1 as contained in sal ammoniac1 we till of late imported it7 from camel's dung2 but now from bones1 by distillation4 ,to the liquor thus procured they add vitriolic acid1 or substances which contain it4 ,this acid unites with the alkali1 and common salt being put to it1 a double affinity takes place4 ,the vitriolic acid uniting with the mineral alkali of the salt1 makes ,glauber salt1 and the marine acid uniting with the volatile alkali1 makes sal ammoniac4 ,slaked lime added to this1 unites with the marine acid of the ammoniac1 and sets loose the volatile alkali in the form of alkaline air1 which combining with water1 makes the liquid caustic volatile alkali4 ,if chalk 7containing calcareous earth united with fixed air7 be mixed with the sal ammoniac1 heat will make the calcareous earth unite with the marine acid1 while the fixed air of the chalk will unite with the volatile alkali1 and assume a solid form1 being the sal volatile of the apothecaries4 ,,lecture ,,xvii4 ,of ,liquid ,inflammable ,substances4 ,of liquid inflammable substances the principal is spirit of wine1 sometimes called ardent spirit1 and1 when highly rectified1 alcohol4 ,it is obtained from vegetable substances by their going through the vinous fermentation4 ,it is considerably lighter than water1 colourless1 and transparent1 has a peculiar smell and taste1 and the property of inebriating4 ,ardent spirit seems to consist of a peculiar combination of phlogiston and water2 for when the vapour of it is made to pass through a red-hot earthen tube1 it is resolved into water and inflammable air4 ,it is highly inflammable1 and burns without smoke1 or leaving any residuum2 and in the act of burning its phlogiston so unites with dephlogisticated air as to make fixed air4 ,ardent spirit mixes readily with water in all proportions1 and also with essential oils1 and balsams or resins1 which are the same thing inspissated4 ,by its affinity with essential oils1 ardent spirit extracts them froth aromatic plants2 and these liquors have obtained the name of tinctures4 ,when the tinctures are distilled1 the more volatile parts of the essential oils1 which come over in distillation1 have acquired the name of waters2 as ,lavender water1 ,rosemary water1 c4 and what remains in the still is called the extract of the plant4 ,if the tinctures be diluted with much water1 the resinous part of the plant will be obtained pure1 and separated from the extractive part1 which will remain dissolved in the water1 while the resin separates from it4 ,spirit of wine will not dissolve the gummy parts of vegetables2 and by this means the gummy substances may be separated from their solutions in water1 the spirit uniting with the water only4 ,on the other hand1 if resins be dissolved in spirit of wine1 the affusion of water will separate them4 ,by means of the affinity of spirit of wine with water1 it will seize upon the water in which several salts are dissolved1 and thus produce an instant crystallization of them4 ,salt of tartar has a greater affinity to water than spirit of wine1 and by extracting water from it1 will assist in concentrating it2 but the best method of rendering spirit wine free from water is distillation1 the ardent spirit rising before the water4 ,spirit of wine mixed with the vitriolic and other mineral acids1 renders them milder1 and thereby more proper for certain medicinal uses4 ,this is called dulcifying them4 ,spirit of wine is a powerful antiseptic1 and is therefore of use to preserve vegetable and animal substances from putrefaction4 ,of ,a,ether4 ,if spirit of wine be distilled with almost any of the acids1 the produce is a liquor which has obtained the name of ,a,ether1 from its extreme lightness and volatility1 being much lighter1 and more volatile1 than any other fluid that we are acquainted with4 ,it is highly inflammable1 but the burning of it is accompanied with smoke1 and some soot2 and on this account it is a medium between spirit of wine and oil1 the acid having taken from the spirit of wine part of the water that was essential to it1 at the same time that it communicated something of its acid peculiarly modified2 since aethers have different properties according to the acids by which they are made2 as the vitriolic1 the nitrous1 the marine1 and the acetous4 ,no aether1 however1 can be made from the marine acid till it has been in some measure dephlogisticated2 from which it may be inferred1 that dephlogisticated air is necessary to the composition of aether4 ,vitriolic aether is the most common1 in consequence of the process by which it is made being the easiest4 ,a,ether does not mix with water in all proportions1 like spirit of wine1 but ten parts of water will take up one of aether4 ,it easily mixes with all oils4 ,it is something remarkable1 that though aether will not dissolve gold1 it will take from aqua regia the gold that has been previously dissolved in it4 ,by the quick evaporation of aether a considerable degree of cold may be procured2 and on this principle it has sometimes been applied to relieve the head-ach and other pains4 ,,lecture ,,xviii4 ,of ,oil4 ,oil is a liquid inflammable substance1 of great tenacity1 disposed to pour in a stream rather than in drops4 ,it is little1 if at all1 soluble in water4 ,it burns with smoke and soot1 and leaves a residuum of a coaly substance4 ,it consists of acid and water combined with phlogiston4 ,all oil is the produce of the vegetable or animal kingdom1 no proper mineral substance containing any of it4 ,by distillation oil is in part decomposed1 and by this means the thicker kinds of oil are rendered thinner and more volatile1 the acid1 to which their consistence is chiefly owing1 being lost in the process4 ,by repeated distillation it is supposed that all oils may be brought almost to the state of aether1 and even of ardent spirit4 ,acids act powerfully upon oils1 but very differently1 according to the nature of each4 ,alkalies also combine with oils1 and the less thin and volatile they are1 the more easily are they soluble in alkalies4 ,the union of alkali and oil makes soap4 ,all oil dissolves sulphur1 and with it makes what is called a balsam4 ,oils also dissolve metallic substances1 but most sensibly copper and lead4 ,united with the calx of lead1 it is used in painting4 ,oil not readily mixing with water1 it will diffuse itself over its surface1 and1 notwithstanding its tenacity1 it will do this very rapidly1 and to a great extent2 and then it has the extraordinary effect of preventing the action of the wind upon the water1 so as to prevent the forming of waves4 ,if a quantity of oil and water be put into a glass vessel and swung1 the surface of the water below the oil will be seen to change with respect to the vessel1 but not that of the oil4 ,if spirit of wine be put upon them1 that will be at rest1 and both the lower fluids in motion4 ,vegetable oil is of two kinds1 the soft1 or mild1 which has little or no taste or smell1 and the essential oil1 which is thin1 and retains the smell and taste of the plant from which it was extracted4 ,mild or sweet oil is expressed from the grains or kernels of vegetables1 and requires a considerable degree of heat to convert it into vapour1 in which state alone it is capable of being inflamed4 ,essential oil is volatile in the heat of boiling water1 and is generally obtained by means of distillation from the most odoriferous sorts of plants2 but is sometimes found in their vesicles1 as in the rind of an orange4 ,the strong taste of this kind of oil arises from the disengaged acid which abounds in it2 and by this means it is soluble in spirit of wine1 which sweet oil is not2 but it loses much of this property by repeated distillations4 ,by long exposure to the air it loses its more volatile parts1 and thereby approaches to the nature of a resin4 ,this volatile odoriferous principle has been called the spiritus rector of the plant4 ,the essential oils of different plants differ much in their specific gravity1 and also in the manner by which they are affected by cold1 some being heavier and others lighter than water1 and some being more difficultly1 and others more easily1 congealed4 ,though the differences with respect to weight and consistency in these oils is probably owing to the state of the acid that is combined with them1 these two properties are wholly independent of each other2 some essential oils being very thin and yet heavy1 and others thick and yet light4 ,essential oils are used in perfumes1 and also in medicine1 acting powerfully the nervous system4 ,essential oils are very apt to be adulterated4 ,if it be with sweet oil1 it may be discovered by evaporation on white paper1 or by a solution in spirit of wine1 which will not act upon the sweet oil4 ,if spirit of wine be mixed with it1 it will be discovered by a milky appearance upon putting water to it1 which uniting with the spirit1 will leave the oil much divided4 ,if oil of turpentine1 which is the cheapest of essential oils1 be mixed with any of the more valuable kinds1 it will be discovered by evaporation2 a strong smell of turpentine being left on the paper1 or cloth1 upon which the evaporation was made4 ,animal oil1 like the vegetable1 is of two kinds2 the first butter1 or fat1 which is easily congealed1 owing to the quantity of acid that is intimately combined with it4 ,it resembles the sweet oil of vegetables in having no smell or taste4 ,the other kind of animal oil is extracted by distillation from the flesh1 the tendons1 the bones1 and horns1 c4 of animals4 ,it differs essentially from the other kind of animal oil1 by containing an alkali instead of an acid4 ,by repeated distillation it becomes highly attenuated and volatile2 and in this state it is called the oil of ,dippel1 the discoverer of it4 ,all oil exposed to much heat is in part decomposed1 and acquires a disagreeable smell2 and in this state it is said to be empyreumatic3 but this property is lost by repeated distillations4 ,besides the vegetable and animal oils above described1 there is a fossil oil called bitumen1 the several kinds of which differ much in colour and consistence2 the most liquid is called petroleum1 from being found in the cavities of rocks1 and the more solid kinds are amber1 jet1 asphaltum1 and pit-coal4 ,when distilled1 the principal component parts of all these substances are an oil and an acid4 ,but all fossil oil is probably of vegetable or animal origin1 from masses of vegetables or animals long buried in the earth4 ,their differences from resins and other oily matters are probably owing to time2 the combinations of mineral acids and oils so nearly resembling bitumens1 the principal difference being their insolubility in spirit of wine4 ,that the most solid of these1 as amber1 has been formerly in a liquid state1 is evident1 from insects and other substances being frequently found in them2 and pit-coal has been often found with both the internal texture and external appearance of wood2 so that strata of pit-coal have probably been beds of peat in some former state of the earth4 ,,lecture ,,xix4 ,of ,solid ,substances4 ,all solid substances are capable of becoming fluid by heat1 and most of them may thereby be reduced into a state of vapour1 or air2 and in passing from a fluid into a solid state their component parts assume a particular mode of arrangement1 called crystallization1 which differs according to the nature of the substance2 so that all solids1 especially if they be suffered to concrete slowly1 may be called crystals4 ,exclusive of salts1 which have been considered already1 as formed by the union of acids and alkalis1 solids in general have obtained the names of earths1 or stones1 which differ only in their texture2 and they are distinguished into those that are metallizable1 or those that are not2 the former being called ores1 and the latter simply earths2 the principal of which are the calcareous1 siliceous1 argillaceous1 magnesia1 terra ponderosa1 and a few others which have been discovered lately1 but have not been much examined4 ,of ,calcareous ,earth4 ,calcareous earth is found in the shells of fishes1 the bones of animals1 chalk1 lime-stone1 marble1 and gypsum3 but all calcareous earth is supposed to be of animal origin2 and beds of chalk1 lime-stone1 or marble1 are thought to have been beds of shells formed in the sea1 in some pristine state of the earth4 ,the calcareous earth which is found in shells1 lime-stone1 and marble1 is combined with fixed air1 discovered by effervescing with acids4 ,to obtain it perfectly pure1 the earth must be pounded and washed with water1 in order to free it from any saline substance which may be contained in it1 then dissolved in distilled vinegar1 and precipitated by mild alkalies4 ,lime-stone exposed to heat loses about half its weight1 in fixed air and water1 and the remainder1 called quick-lime1 attracts water very powerfully1 and their union is attended with much heat1 after which it dissolves into a fine powder called slaked lime4 ,if it be left exposed to the atmosphere1 it will of itself1 by gradually imbibing moisture1 fall into the state of powder4 ,water dissolves about one seven hundredth part of its weight of quick-lime1 and is then called lime-water4 ,exposed to the air1 a crust will be formed on its surface1 which is found to consist of calcareous earth and fixed air4 ,lime and water mixed with sand make mortar1 by which means different stones may be made to cohere as one mass1 which is the most valuable use of this kind of earth4 ,calcareous earth1 united with vitriolic acid1 makes gypsum2 and this substance pounded and exposed to heat1 parts with its water1 and is then called plaister of ,paris4 ,in this state1 by imbibing water again1 it becomes a firm substance1 and thus is useful in making moulds1 c4 ,the earth of animal bones is calcareous united to the phosphoric acid4 ,of ,siliceous ,earth4 ,siliceous earth seems to be formed by nature from chalk1 perhaps by the introduction of some unknown acid1 which the vitriolic acid is not able to dislodge4 ,it abounds in most substances which are hard enough to strike fire with steel1 as flint1 rock crystal1 and most precious stones4 ,it is not acted upon by any acid except the fluor and phosphoric1 but especially the former3 but it is soluble in alkalies2 and being then dissolved in water1 makes liquor silicum1 from which the purest siliceous earth may be precipitated by acids4 ,for this purpose about four times the weight of alkali must be made use of4 ,with about equal weights of alkali and siliceous sand is made glass1 of so great use in admitting light and excluding the weather from our houses1 as well as for making various useful utensils4 ,to make glass perfectly colourless1 and at the same time more dense1 commonly called flint glass1 manufacturers use a certain proportion of calx of lead and manganese4 ,siliceous earth is not affected by the strongest heat1 except by means of a burning lens1 or dephlogisticated air4 ,,lecture ,,xx4 ,of ,argillaceous ,earth4 ,argillaceous earth is found in clay1 schistus1 or slate1 and in mica2 but the purest is that which is precipitated from a solution of alum by alkalies2 for alum consists of the union of vitriolic acid and argillaceous earth4 ,this species of earth is ductile with water2 it then hardens and contracts by heat1 so as to be of the greatest use in forming bricks1 or stones of any required form or size4 ,by means of the property of clay to contract in the fire1 ,mr4 ,wedgwood has constructed an excellent thermometer to measure the degrees of extreme heat4 ,the ductility of clay seems to depend upon some acid1 probably the vitriolic1 adhering to it2 for it loses that property when it is burned into a brick1 but recovers it when it has been again dissolved in an acid4 ,of ,terra ,ponderosa4 ,terra ponderosa1 or marmor metallicum1 is generally found in two states1 viz4 united to vitriolic acid1 when it is called calk1 or to fixed air1 when it is called terra ponderosa aerata4 ,to obtain it pure from its union with the vitriolic acid1 it must be melted with about twice its weight of fixed alkali2 which unites with the acid1 and forming a saline substance1 may be washed out of it4 ,in this state it contains water1 and therefore1 when exposed to heat1 will yield fixed air2 whereas the terra ponderosa aerata will not yield fixed air by heat only1 but when steam is made to pass over it when red hot4 ,this proves that water is essential to the composition of fixed air4 ,this stone is distinguishable by its great specific gravity1 being four times as heavy as water2 but though in this it resembles an ore1 it has not been found to be metallizable4 ,of ,magnesia4 ,this species of earth is found in steatites1 or soap rock1 ,spanish chalk1 asbestus1 and ,muscovy talck2 but the purest is got by dissolving ,epsom salts 7which consists of this earth united to the vitriolic acid7 and precipitating it by a mild alkali4 ,in this state it becomes united to fixed air1 which may be expelled by heat4 ,it is then calcined1 or caustic1 but differs from quick-lime by not being soluble in water4 ,asbestus1 which contains much of this kind of earth1 is remarkable for not being destructible by heat1 though it is sometimes found in flexible fibres1 so as to be capable of being woven into cloth4 ,muscovy talck is remarkable for the thin and transparent flakes into which it is divisible1 and thereby capable of various uses4 ,there are some other distinct species of earth1 particularly one brought from ,botany ,bay1 and another called ,stontiate1 from the place where it was found in ,scotland2 but they have not as yet been much examined4 ,all stones formed by nature are compounded1 and to distinguish them from one another1 and ascertain the parts of which they consist1 is the subject of lithology1 a very extensive branch of knowledge4 ,all the simple earths are nearly1 if not absolutely1 infusible2 but when they are mixed they may all be fused4 ,,lecture ,,xxi4 ,of ,ores4 ,metallizable earths1 commonly called ores1 when united to phlogiston1 make the metals1 distinguishable for their specific gravity1 their opacity1 shining appearance1 and fusibility4 ,all the proper metals are malleable1 and those which are not so are called semi-metals4 ,the metals again are subdivided into the perfect and imperfect4 ,the former1 which are gold1 silver1 and platina1 suffer no change by fusion1 or the longest continued heat3 whereas heat calcines or dissipates the phlogiston of the imperfect metals1 which are mercury1 lead1 copper1 iron1 and tin1 so that they return to the state of earth2 and this earth is always heavier than the metal1 though of less specific gravity1 having received an addition of weight from water or air3 but these earths1 or ores1 being exposed to heat in contact with substances containing phlogiston1 again become metals1 and are then said to be revived4 ,the semi-metals are bismuth1 zinc1 nickel1 regulus of arsenic1 of cobalt1 of antimony1 of manganese1 of wolfram1 and of molybdena4 ,all metallic substances are crystallizable1 and each in a peculiar form1 which is discovered by leaving a hole in the bottom of the crucible in which they are melted1 and drawing out the stopper1 when the mass is beginning to lose its fluidity4 ,some of the metals will not unite to others when hot1 and others of them will2 and such as will unite with others are called solders4 ,thus tin is a solder for lead1 and brass1 gold1 or silver1 for iron4 ,ores are never found in regular strata1 like the different kinds of earth2 but in places which have formerly been cavities1 running in all directions1 with respect to the regular strata1 and commonly called veins4 ,many of the ores in their natural state are said to be mineralized with arsenic or sulphur1 those substances being intimately united with the metallic earths4 ,in order to convert the ores into metals1 some of them are first reduced to powder1 to wash out the earthy or saline particles4 ,they are then kept in a red heat1 which the workmen call roasting1 in order to drive away the arsenic1 or sulphur1 which are volatile2 and in the last place they are fused in contact with charcoal1 or other substances containing phlogiston2 and to promote the fusion1 lime-stone is frequently mixed with them4 ,when the operation is completed1 the unmetallic parts are converted into glass1 or scoria1 which lies on the surface1 whereas the metal is found at the bottom4 ,to discover the quantity of metal in a small piece of ore is called assaying4 ,when metals are fused together1 the specific gravity1 fusibility1 and other properties are changed1 and in such a manner as could not be discovered from the properties of the constituent parts4 ,of ,gold4 ,gold is the heaviest of all metallic bodies except platina4 ,it appears yellow or reddish by reflected light1 but green or blue by transmitted light1 when it is reduced to thin plates4 ,though gold undergoes no change in a common furnace1 or burning lens1 it may1 in part1 at least1 be calcined by the electric shock4 ,gold has the greatest ductility1 and in wires of equal diameters1 it has the greatest tenacity1 of all the metals4 ,one grain of it may be made to cover #ef square inches2 some gold leaf being less than a #bjj1jjjth part of an inch thick2 and when it is made to cover a silver wire1 the gold upon it may not be more than one twelfth part of the thickness of the gold leaf4 ,this metal is soluble in aqua regia2 and being precipitated by a volatile alkali1 makes a powder called aurum fulminans1 which is one fourth heavier than the gold1 and explodes with great violence in a heat something greater than that of boiling water4 ,tin precipitates gold in the form of a purple powder1 called the powder of ,cassius1 from the inventor of it1 and is used in enamels1 or the glassy coating which is given to metals by heat4 ,gold unites with most of the metals1 especially with mercury1 and these mixtures are called amalgams4 ,in gilding1 the amalgam is applied to the surface of the metal to be gilded1 and the mercury is driven off by heat1 leaving the gold attached to the surface4 ,gold mixed with iron1 makes it harder1 for the purpose of cutting instruments4 ,to separate gold from the imperfect metals1 such as copper1 c4 it is mixed with lead1 and then exposed to a strong heat1 which calcines the lead1 and with it the imperfect metals1 leaving the gold pure4 ,this process is called cupellation1 from being performed in a small crucible called a cupell4 ,when the gold is mixed with silver1 three parts more of silver are put to it1 and then the silver is dissolved by nitrous acid1 leaving the gold pure4 ,this process is called quartation1 from the gold being one fourth part of the mass4 ,the fineness of gold is generally estimated by dividing the gold into twenty-four parts1 called carats4 ,the phrase twenty-three carats fine means that the mass contains twenty-three parts out of twenty-four of pure gold1 the remainder being alloy1 of some baser metal4 ,the fineness of gold may in some measure be discovered by the colour it leaves upon a touch-stone1 or fine-grained basaltes4 ,gold is generally found nearly pure1 but mixed with earth1 or diffused in fine grains through stones4 ,,lecture ,,xxii4 ,of ,silver4 ,silver is the whitest of all the metals1 very ductile1 but less so than gold2 the thinnest leaves of it being one third thicker than those of gold4 ,it is not calcined in the heat of a common furnace1 but partially so by repeated fusion1 or a strong burning lens4 ,sulphureous fumes unite with silver1 and tinge it black4 ,the nitrous acid dissolves it1 and will hold more than half its weight of it in solution4 ,when fully saturated1 this solution deposits crystals1 which are called lunar nitre1 or nitre of silver4 ,when these crystals are melted1 and the water they contain driven off1 a black substance1 called lapis infernalis1 or lunar caustic1 is formed4 ,this is used as a cautery in surgery4 ,a strong heat will decompose this lunar nitre1 and recover the silver4 ,though the nitrous acid dissolves silver the most readily1 the marine acid will deprive the nitrous of it1 and form a substance called luna cornea1 because1 when it is melted and cold1 it becomes a transparent mass something resembling horn4 ,from this luna cornea the purest silver may be obtained4 ,the vitriolic acid will likewise deprive the nitrous of the silver contained in it1 and form a white powder1 not easily soluble in water4 ,a fulminating silver may be made by the following process3 the silver must first be dissolved in pale nitrous acid1 then precipitated by lime-water1 dried1 and exposed to the air three days4 ,it must then be washed in caustic volatile alkali1 after which the fluid must be decanted1 and the black powder left to dry in the air4 ,the slightest friction will cause this powder to fulminate4 ,it is said1 that even a drop of water falling upon it will produce this effect2 so that it ought to be made only in very small quantities1 and managed with the greatest caution4 ,most of the metals precipitate silver4 ,that by mercury may be made to assume the form of a tree1 called arbor ,dianae4 ,silver is found native in ,peru2 and the ores frequently contain sulphur1 or arsenic1 or both4 ,of ,platina4 ,platina is a metal lately discovered in the gold mines of ,mexico1 where it is found in small particles1 never exceeding the size of a pea1 mixed with ferruginous sand and quartz4 ,the strongest fire will not melt these grains1 though it will make them cohere2 but they may be melted by a burning lens1 or a blow-pipe supplied with dephlogisticated air4 ,pure platina is the heaviest body in nature1 its specific gravity exceeding twenty-two4 ,it is very malleable1 though considerably harder than gold or silver1 and has the property of welding in common with iron4 ,this metal is not affected by exposure to the air1 or by any simple acid1 though concentrated and hot2 but it is dissolved by dephlogisticated marine acid1 and by aqua regia1 in which a little nitrous air is procured4 ,the solution is brown1 and when diluted yellow4 ,this liquor is very corrosive1 and tinges animal substances of a blackish brown colour4 ,platina is precipitated from a solution in aqua regia by sal-ammoniac1 as gold is by martial vitriol4 ,iron is precipitated from this solution by the ,prussian alkali4 ,also most of the metals precipitate platina1 but not in its metallic state4 ,arsenic facilitates the solution of platina2 and by melting it with equal parts of arsenic and vegetable alkali1 and then reducing the mass to a powder1 it may be made to take any form2 and a strong heat will dissipate the arsenic and the alkali1 leaving the platina in the shape required1 not fusible by any heat in a common furnace4 ,platina does not readily combine with gold or silver1 and it resists the action of mercury as much as iron2 but it mixes well with lead1 making it less ductile1 and even brittle1 according to the proportion of the platina4 ,with copper it forms a compound which takes a beautiful polish1 not liable to tarnish1 and is therefore used with advantage for mirrors of reflecting telescopes4 ,it unites easily with tin1 and also with bismuth1 antimony1 and zinc4 ,,lecture ,,xxiii4 ,of ,mercury4 ,mercury is the most fusible of all the metals1 not becoming solid but in #dj deg4 below #j in ,fahrenheit's thermometer4 ,it is then malleable4 ,it is heavier than any other metal except gold or platina4 ,it is volatile in a temperature much lower than that of boiling water1 and in vacuo in the common temperature of the atmosphere2 and at six hundred it boils4 ,in a degree of heat in which it would rise easily in vapour1 mercury imbibes pure air1 and becomes a red calx1 called precipitate per se4 ,at a greater degree of heat it parts with that air1 and is running mercury again4 ,mercury is not perceptibly altered by exposure to the air4 ,mercury is acted upon by the vitriolic acid when hot4 ,in this process vitriolic acid air is procured1 and the mercury is converted into a white substance1 which being dipped in water becomes yellow1 called turbith mineral1 one third heavier than the mercury from which it was made4 ,by heat this substance parts with its pure air1 and becomes running mercury2 but if the process be made in a clean earthen vessel1 there will remain a portion of red calx1 which cannot be reduced by any degree of heat1 except in contact with some substance containing phlogiston4 ,if this be done with a burning lens1 in inflammable air1 much of the air will be absorbed4 ,mercury is dissolved most readily in the nitrous acid1 when the purest nitrous air is procured2 and there remains a substance which is first yellow1 and by continuance red1 called red precipitate4 ,in a greater degree of heat the dephlogisticated air will be recovered1 and the mercury be revived2 but the substance yields nitrous air after it becomes solid1 and till it changes from yellow to red4 ,the precipitates of mercury from acids by means of alkalies possess the property of exploding1 when they are exposed to a gradual heat in an iron spoon1 after having been triturated with one sixth of their weight of the flowers of sulphur4 ,the residuum consists of a violet-coloured powder1 which1 by sublimation1 is converted into cinnabar4 ,it seems1 therefore1 as if the sulphur combined suddenly with the mercury1 and expelled the dephlogisticated air in an elastic state4 ,the marine acid seizes upon mercury dissolved in nitrous acid1 and if the acid be dephlogisticated1 the precipitate is corrosive sublimate2 but with common marine acid1 it is called calomel1 or mercurius dulcis4 ,this preparation is generally made in the dry way1 by triturating equal parts of mercury1 common salt and vitriol1 and exposing the whole to a moderate heat2 when the corrosive sublimate rises1 and adheres to the upper part of the glass vessel in which the process is made4 ,mercury combines readily with sulphur by trituration1 and with it forms a black powder called ,ethiops mineral4 ,a more intimate combination of mercury and sulphur is made by means of fire4 ,this is called cinnabar1 about one third of which is sulphur4 ,vermillion is cinnabar reduced to powder4 ,mercury readily unites with oil1 and with it forms a deep black or blue compound1 used in medicine4 ,it readily combines with most of the metals1 and when it is used in a sufficient quantity to make them soft1 the mixture is called an amalgam4 ,it combines most readily with gold1 silver1 lead1 tin1 bismuth1 and zinc4 ,looking-glasses are covered on the back with an amalgam of mercury and tin4 ,when mercury is united with lead or other metals1 it is rendered less brilliant and less fluid2 but agitation in pure air converts the impure metal into a calx1 together with much of the mercury1 in the form of a black powder4 ,heat recovers the pure air1 and the mercury1 leaving the calx of the impure metal4 ,much mercury is found native in a slaty kind of earth1 or in masses of clay or stone2 but the greatest quantity is found combined with sulphur in native cinnabar4 ,,lecture ,,xxiv4 ,of ,lead4 ,lead is a metal of a bluish tinge1 of no great tenacity1 but very considerable specific gravity1 being heavier than silver4 ,it melts long before it is red hot1 and is then calcined1 if it be in contact with respirable air4 ,when boiling it emits fumes1 and calcines very rapidly4 ,it may be granulated by being poured into a wooden box1 and agitated4 ,during congelation it is brittle1 so that the parts will separate by the stroke of a hammer2 and by this means the form of its crystals may be discovered4 ,in the progress of calcination it first becomes a dusky grey powder1 then yellow1 when it is called massicot2 then1 by imbibing pure air1 it becomes red1 and is called minium1 or red lead4 ,in a greater degree of heat it becomes massicot again1 having parted with its pure air4 ,if the heat be too great1 and applied rapidly1 it becomes a flaky substance1 called litharge2 and with more heat it becomes a glass1 which readily unites with metallic calces and earths1 and is a principal ingredient in the manufacture of flint glass1 giving it its peculiar density and refractive power4 ,though lead soon tarnishes1 the imperfect calx thus made does not separate from the rest of the metal1 and therefore protects it from any farther action of the air1 by which means it is very useful for the covering of houses1 and other similar purposes4 ,all acids act upon lead1 and form with it different saline substances4 ,white-lead consists of its union with vinegar and pure air4 ,also dissolved in vinegar1 and crystallized1 it becomes sugar of lead1 which1 like all the other preparations of this metal1 is a deadly poison4 ,oils dissolve the calces of lead1 which1 by this means1 is the basis of paints1 plaisters1 c4 ,by means of heat litharge decomposes common salt1 the lead uniting with the marine acid1 and forming a yellow substance1 used in painting1 and by this means the fossil alkali is separated4 ,lead unites with most metals1 though not with iron4 ,two parts of lead and one of tin make a solder1 which melts with less heat than either of the metals separately2 but a composition of eight parts of bismuth1 five of lead1 and three of tin1 makes a metal which melts in boiling water4 ,this metal will be dissolved by water if it contain any saline matter1 and the drinking of it occasions a peculiar kind of cholic4 ,lead is sometimes found native1 but generally minerally mineralized with sulphur or arsenic1 and often mixed with a small quantity of silver4 ,of ,copper4 ,copper is a metal of a reddish or brownish colour1 considerably sonorous1 and very malleable4 ,at a heat far below ignition1 the surface1 of copper becomes covered with a range of prismatic colours1 the commencement of its calcination2 and with more heat a black scale is formed1 which easily separates from the metal1 and in a strong heat it melts1 and burns with a bluish green flame4 ,copper rusts by exposure to the air2 but the partially-calcined surface adheres to the metal1 as in the case of lead1 and thus preserves it from farther corrosion4 ,copper dissolved in the vitriolic acid forms crystals of a blot colour1 called blue copperas4 ,from this solution it is precipitated by iron1 which by this means becomes coated with copper4 ,the nitrous acid dissolves copper with most rapidity1 producing nitrous air4 ,if the solution be distilled1 almost all the acid will be retained in the residuum1 which is white2 but more heat will expel the acid1 chiefly in the form of dephlogisticated air1 and the remainder will be a black substance1 consisting of the pure calx of copper4 ,the vegetable acids dissolve copper as well as the mineral ones1 which makes the use of this metal for culinary purposes in some cases dangerous4 ,to prevent this they give it a coat of tin4 ,the solution of copper in the vegetable acid is called verdigris4 ,alkalies dissolve copper as well as acids4 ,with the volatile alkali a blue liquor is formed1 but in some cases it becomes colourless4 ,all the circumstances of this change of colour have not yet been examined4 ,both oil and sulphur will dissolve copper1 and with the latter it forms a blackish grey compound1 used by dyers4 ,copper readily unites with melted tin1 at a temperature much lower than that which is necessary to melt the copper2 by which means copper vessels are easily covered with a coating of tin4 ,a mixture of copper and tin1 called bronze1 the specific gravity of which is greater than that of the medium of the two metals1 is used in casting statues1 cannon1 and bells2 and in a certain proportion this mixture is excellent for the purpose of mirrors of reflecting telescopes1 receiving a fine polish1 and not being apt to tarnish4 ,copper and arsenic make a brittle compound called tombach2 and with zinc it makes the useful compound commonly called brass1 in which zinc is about one third of its weight4 ,copper is sometimes found native2 but commonly mixed with sulphur1 in ores of a red1 green1 or blue colour4 ,copper being an earlier discovery than that of iron1 was formerly used for weapons and the shoeing of horses2 and the ancients had a method1 with which we are not well acquainted1 of giving it a considerable degree of hardness1 so that a sword made of it might have a pretty good edge4 ,,lecture ,,xxv4 ,of ,iron4 ,iron is a metal of a bluish colour1 of the greatest hardness1 the most variable in its properties1 and the most useful of all the metals2 so that without it it is hardly possible for any people to make great advances in arts and civilization4 ,this metal readily parts with its phlogiston1 so as to be very subject to calcine1 or rust1 by exposure to the air4 ,the same is evident by the colours which appear on its surface when exposed to heat1 and also when it is struck with flint2 the particles that fly from it being iron partially calcined4 ,in consequence of its readily parting with its phlogiston1 it is capable of burning1 like wood or other fuel1 in pure air4 ,iron and platina have the property of welding when very hot1 so that two pieces may be joined without any solder4 ,when iron is heated in contact with steam1 part of the water takes the place of the phlogiston1 while the rest unites with it1 and makes inflammable air4 ,by this means the iron acquires one third more weight1 and becomes what is called finery cinder4 ,this substance1 heated in inflammable air1 imbibes it1 parts with its water1 and becomes perfect iron again4 ,if the iron be heated in pure air1 it also imbibes the water1 of which that air chiefly consists1 and also a portion of the peculiar element of the pure air4 ,the solution of iron in spirit of vitriol produces green copperas2 which being calcined1 becomes a red substance1 called colcothar4 ,the precipitate of iron1 by an infusion of galls1 is the colouring matter in ink1 which is kept suspended by means of gum4 ,the precipitate from the same solution by phlogisticated alkali1 is ,prussian blue4 ,water saturated with fixed air dissolves iron1 and makes a pleasant chalybeat4 ,the calx of iron gives a green colour to glass4 ,iron readily combines with sulphur4 ,when they are found combined by nature1 the substance is called pyrites4 ,the union of phosphoric acid with iron makes it brittle when cold1 commonly called cold short2 and the union of arsenic makes it brittle when hot1 thence called red short4 ,iron unites with gold1 silver1 and platina1 and plunged in a white heat into mercury1 it becomes coated with it2 and if the process be frequently repeated1 it will become brittle1 which shews that there is some mutual action between them4 ,iron readily unites with tin2 and by dipping thin plates of iron into melted tin1 they get a complete coating of it1 and make the tinned plates in common use4 ,when crude iron comes from the smelting furnace it is brittle2 and when it is white within1 it is extremely hard2 but when it has a black grain1 owing to its having more phlogiston1 it is softer1 and may be filed and bored4 ,cast iron becomes malleable by being exposed to a blast of air when nearly melting2 the consequence of which is a discharge of inflammable air1 and the separation of a liquid substance1 which1 when concreted1 is called finery cinder4 ,the iron generally loses one fourth of its weight in the process4 ,crude iron contains much plumbago1 and the access of pure air probably assists in discharging it1 by converting it into air1 chiefly inflammable4 ,malleable iron1 exposed to a red heat in contact with charcoal1 called cementation1 converts it into steel1 which has the properties of becoming much harder than iron1 and very elastic1 by being first made very hot1 and then suddenly cooled1 by plunging it in cold water4 ,by first making it very hard1 and then giving different degrees of heat1 and cooling it in those different degrees1 it is capable of a great variety of tempers1 proper for different uses4 ,of the degrees of heat workmen judge by the change of colour on its surface4 ,steel1 like crude iron1 is capable of being melted without losing its properties4 ,it is then called cast steel1 and is of a more uniform texture4 ,iron acquires some little weight by being converted into steel2 and when dissolved in acid1 it yields more plumbago4 ,steel has something less specific gravity than iron4 ,if the cementation be continued too long1 the steel acquires a darkish fracture1 it is more fusible1 and incapable of welding4 ,steel heated in contact with earthy matters1 is reduced to iron4 ,iron is the only substance capable of magnetism2 and hardened steel alone is capable of retaining magnetism4 ,the loadstone is an ore of iron4 ,,lecture ,,xxvi4 ,of ,tin4 ,tin is a metal of a slightly yellowish cast1 though harder than lead1 very malleable1 but of no great tenacity2 so that wires cannot be made of it4 ,it easily extends under the hammer1 and plates of it1 called tinfoil1 are made only one thousandth part of an inch thick1 and might be made as thin again4 ,tin has less specific gravity than any other metal4 ,it melts long before ignition1 at #daj of ,fahrenheit1 and by the continuance of heat is slowly converted into a white powder1 which is the chief ingredient in putty1 used in polishing1 c4 ,like lead1 it is brittle when heated little short of fusion1 and may be reduced into grains by agitation as it passes from a fluid to a solid state4 ,the calx of tin resists fusion more than that of any other metal1 which makes it useful in making an opaque white enamel4 ,tin loses its bright surface when exposed to the air1 but is not properly subject to rust2 so that it is useful in protecting iron and other metals from the effects of the atmosphere4 ,concentrated vitriolic acid1 assisted by heat1 dissolves half its weight of tin1 and yields vitriolic acid air4 ,with more water it yields inflammable air4 ,during the solution the phlogiston of the tin uniting with the acid1 forms sulphur1 which makes it turbid4 ,by long standing1 or the addition of water1 the calx of tin is precipitated from the solution4 ,the nitrous acid dissolves tin very rapidly without heat1 and yields but little nitrous air4 ,with marine acid this metal yields inflammable air4 ,with aqua regia it assumes the form of a gelatinous substance used by dyers to heighten the colour of some red tinctures1 so as to produce a bright scarlet in dying wool4 ,a transparent liquor1 which emits very copious fumes1 called1 from the inventor1 the smoking liquor of ,libavius1 is made by distilling equal parts of amalgam of tin and mercury with corrosive sublimate1 triturated together4 ,a colourless liquor comes over first1 and then a thick white fume1 which condenses into the transparent liquor above mentioned4 ,mr4 ,adet has shewn1 that this liquor bears the same relation to the common solution of tin1 that corrosive sublimate does to calomel1 and has given an ingenious solution of many of its properties4 ,tin detonates with nitre2 and if the crystals made by the solution of copper in the nitrous acid be inclosed in tinfoil1 nitrous fumes will be emitted1 and the whole will become red hot4 ,also if five times its weight of sulphur be added to melted tin1 a black brittle compound1 which readily takes fire1 will be formed4 ,another combination of tin1 sulphur1 and mercury1 makes a light yellow substance called aurum musivum used in painting4 ,tin is the principal ingredient in the composition of pewter1 the other ingredients being lead1 zinc1 bismuth1 and copper2 each pewterer having his peculiar receipt4 ,it is also used in coating copper and iron plates1 and in silvering looking-glasses1 besides being cast into a variety of forms1 when it is called block tin4 ,tin is sometimes found native1 but is generally mineralized with sulphur and arsenic4 ,the latter is thought to be always contained in tin1 and to be the cause of the crackling noise made by bending plates of it4 ,of the ,semi-metals4 ,bismuth is a semi-metal of a yellowish or reddish cast1 but little subject to change in the air2 harder than lead1 but easily broken1 and reducible to powder4 ,when broken it exhibits large shining facets1 in a variety of positions4 ,thin pieces of it are considerably sonorous4 ,bismuth melts at about #dfj deg4 of ,fahrenheit4 ,with more heat it ignites1 and burns with a slight blue flame1 while a yellowish calx1 called flowers of bismuth1 is produced4 ,with more heat it becomes a greenish glass4 ,in a strong heat1 and in close vessels1 this metal sublimes4 ,vitriolic acid1 even concentrated and boiling1 has but little effect upon bismuth2 but the nitrous acid acts upon it with the greatest rapidity and violence1 producing much nitrous air1 mixed with phlogisticated nitrous vapour4 ,from the solution of bismuth in this acid1 a white substance1 called magistery of bismuth1 is precipitated by the affusion of water4 ,this has been used as a paint for the skin but has been thought to injure it4 ,the marine acid does not readily act upon bismuth2 but when concentrated1 it forms with it a saline combination1 which does not easily crystallize1 but may be sublimed in the form of a soft fusible salt1 called butter of bismuth4 ,bismuth unites with most metallic substances1 and in general renders them more fusible4 ,when calcined with the imperfect metals1 it unites with them1 and has the same effect as lead in cupellation4 ,bismuth is used in the composition of pewter1 in printers' types1 and other metallic mixtures4 ,this metal is sometimes found native1 but more commonly mineralized with sulphur4 ,,lecture ,,xxvii4 ,of ,nickel4 ,nickel is a semi-metal of a reddish cast1 of great hardness1 and always magnetical2 on which account it is supposed to contain iron1 though chemists have not yet been able to separate them4 ,the purest nickel was so infusible as not to run into a mass in the strongest heat of a smith's forge2 but then it was in some degree malleable4 ,concentrated acid of vitriol only corrodes nickel4 ,alkalies precipitate it from its solution in the nitrous acid1 and dissolve the precipitate4 ,it readily unites with sulphur4 ,nickel is found either native or mineralized with several other metals1 especially with copper1 when it is called kupfer nickel1 or false copper1 being of a reddish or copper colour4 ,this semi-metal has not yet been applied to any use4 ,of ,arsenic4 ,what is commonly called arsenic is the calx of a semi-metal called the regulus of arsenic4 ,it is a white and brittle substance1 expelled from the ores of several metals by heat4 ,it is then refined by a second sublimation1 and melted into the masses in which it is commonly sold4 ,this calx is soluble in about eighty times its weight of cold water1 or in fifteen times its weight of boiling water4 ,it acts in many respects like an acid1 as it decomposes nitre by distillation1 when the nitrous acid flies off1 and the arsenical salt of ,macquer remains behind4 ,when the calx of arsenic is distilled with sulphur1 the vitriolic acid flies off1 and a substance of a yellow colour1 called orpiment1 is produced4 ,this appears to consist of sulphur and the regulus of arsenic2 part of the sulphur receiving pure air from the calx1 to which it communicates phlogiston2 and thus the sulphur becomes converted into vitriolic acid1 while the arsenical calx is reduced1 and combines with the rest of the sulphur4 ,the combination of sulphur and arsenic1 by melting them together1 is of a red colour1 known by the name of realgal1 or realgar4 ,it is less volatile than orpiment4 ,the solution of fixed alkali dissolves the calx of arsenic1 and by means of heat a brown tenacious mass is produced1 and having also a disagreeable smell1 it is called liver of arsenic4 ,the regulus of arsenic is of a yellow colour1 subject to tarnish or grow black1 by exposure to the air1 very brittle1 and of a laminated texture4 ,in close vessels it wholly sublimes1 but burns with a small flame in pure air4 ,vitriolic acid has little action upon this semi-metal1 except when hot2 but the nitrous acid acts readily upon it1 and likewise dissolves the calx1 as does boiling marine acid1 though it affects it very little when cold4 ,most of the metals unite with the regulus of arsenic4 ,dephlogisticated marine acid converts the calx of arsenic into arsenical acid by giving it pure air4 ,the acid of arsenic acts more or less upon all metals1 but the phenomena do not appear to be of much importance4 ,the calx of acid is used in a variety of the arts1 especially in the manufactory of glass4 ,orpiment and realgar are used as pigments4 ,some attempts have been made to introduce it into medicine1 but being dangerous1 the experiments should be made with caution4 ,of ,cobalt4 ,cobalt is a semi-metal of a grey or steel colour1 of a close-grained fracture1 more difficult of fusion than copper1 not easily calcined4 ,it soon tarnishes in the air1 but water has no effect upon it4 ,cobalt1 dissolved in aqua regia1 makes an excellent sympathetic ink1 appearing green when held to the fire1 and disappearing when cold1 unless it has been heated too much1 when it burns the paper4 ,the calx of cobalt is of a deep blue colour1 which1 when fused1 makes the blue glass called smalt4 ,the ore of cobalt1 called zaffre1 is found in several parts of ,europe1 but chiefly in ,saxony4 ,as it is commonly sold1 it contains twice or thrice its weight of powder of flints4 ,the smalt is usually composed of one part of calcined cobalt1 fused with two parts of powder of flint and one of pot-ash4 ,the chief use of cobalt is for making smalt2 but the powder and the blue-stone used by laundresses is a preparation made by the ,dutch of a coarse kind of smalt4 ,of ,zinc4 ,zinc is a semi-metal of a bluish cast1 brighter than lead1 and so far malleable as not to be broken by a hammer1 though it cannot be much extended4 ,when broken by bending1 it appears to consist of cubical grains4 ,if it be heated nearly to melting1 it will be sufficiently brittle to be pulverized4 ,it melts long before ignition1 and when it is red hot1 it burns with a dazzling white flame1 and is calcined with such rapidity1 that its calx flies up in the form of white flowers1 called flowers of zinc1 or philosophical wool4 ,in a stronger heat they become a clear yellow glass4 ,heated in close vessels1 this metal rises without decomposition1 being the most volatile of all the metals except the regulus of arsenic4 ,zinc dissolved in diluted vitriolic acid1 yields much inflammable air1 and has a residuum1 which appears to be plumbago1 and the liquor forms crystals1 called white copperas4 ,this metals also yields inflammable air when dissolved in the marine acid4 ,dissolved in the nitrous acid1 it yields dephlogisticated nitrous air1 with very little proper nitrous air4 ,the ore of zinc1 called calamine1 is generally of a white colour2 and the chief use of it is to unite it with copper1 with which it makes brass and other gold-coloured mixtures of metals4 ,the calx and the salts of this metal are occasionally used in medicine4 ,,lecture ,,xxviii4 ,of ,antimony4 ,the regulus of antimony is of a silvery white colour1 of a scaly texture1 very brittle1 and melts soon after ignition4 ,by continuance of heat it calcines in white fumes1 called argentine flowers of antimony1 which melt into a hyacinthine glass4 ,in close vessels it rises without decomposition4 ,its calx is soluble in water1 like that of arsenic4 ,this metal tarnishes1 but does not properly rust1 by exposure to the air4 ,this metal is soluble in aqua regia4 ,it detonates with nitre1 and what remains of equal parts of nitre and regulus of antimony after detonation1 in a hot crucible1 is called diaphoretic antimony4 ,the water used in this preparation contains a portion of the calx suspended by the alkali1 and being precipitated by an acid1 is called ceruse of antimony4 ,when regulus of antimony is pulverized and mixed with twice its weight of corrosive sublimate 7which is attended with heat7 and then distilled with a gentle fire1 a thick fluid comes over1 which is congealed in the receiver1 or in the neck of the retort1 and is called butter of antimony4 ,the residuum consists of revived mercury1 with some regulus and calx of antimony4 ,when this butter of antimony is thrown into pure water1 there is a white precipitate1 called powder of algaroth1 a violent emetic4 ,nitrous acid dissolves the butter of antimony2 and when an equal weight of nitrous acid has been three times distilled to dryness from butter of antimony1 the residuum1 after ignition1 is called bezoar mineral1 and seems to be little more than a calx of the metal4 ,crude antimony1 which has been much used in the experiments of alchemists1 is a combination of sulphur and regulus of antimony4 ,heat melts it1 and finally converts it into glass1 of a dark red colour1 called liver of antimony4 ,if antimony be melted or boiled with a fixed alkali1 a precipitate is made by cooling1 called kermes mineral1 formerly used in medicine4 ,the antimonial preparations that are now most in use are antimonial wine and tartar emetic4 ,the wine is made by infusing pulverized glass of antimony in ,spanish wine some days1 and filtering the clear fluid through paper4 ,the emetic tartar1 or antimonial tartar1 is a saline substance1 composed of acid of tartar1 vegetable alkali1 and antimony partially calcined4 ,the preparation may be seen in the ,dispensaries4 ,the regulus of antimony is used in the form of pills1 which purge more or less in proportion to the acid they meet with2 and as they undergo little or no change in passing through the body1 they are called perpetual pills4 ,of ,manganese4 ,manganese is a hard1 black mineral1 very ponderous1 and the regulus of it is a semi-metal of a dull white colour when broken1 but soon grows dark by exposure to the air4 ,it is hard and brittle1 though not pulverizable1 rough in its fracture1 and of very difficult fusion4 ,its calces are white when imperfect1 but black1 or dark green1 when perfect4 ,the white calx is soluble in acids4 ,when broken in pieces1 it falls into powder by a spontaneous calcination1 and this powder is magnetical1 though the mass was not possessed of that property4 ,the black calx of manganese is altogether insoluble in acids4 ,it contains much dephlogisticated air4 ,the calx of manganese is used in making glass2 the glass destroying the colour of that of the other materials1 and thereby making the whole mass transparent4 ,this semi-metal mixes with most of the metals in fusion1 but not with mercury4 ,there is another ore of manganese1 called black woad1 which inflames spontaneously when mixed with oil4 ,of ,wolfram4 ,wolfram is a mineral of a brownish or black colour1 found in the tin mines of ,cornwall1 of a radiated or foliated texture1 shining almost like a metal4 ,it contains much of the calx of manganese1 and iron2 but when the substance is pulverized1 these are easily dissolved1 and the calx of wolfram is found to be yellow4 ,this calx turns blue by exposure to light2 and an hundred grains of it heated with charcoal will yield sixty grains of a peculiar metal1 in small particles1 which1 when broken1 look like steel4 ,it is soluble in the vitriolic or marine acids1 and reduced to a yellow calx by nitrous acid or aqua regia4 ,of ,molybdena4 ,molybdena is a substance which much resembles plumbago2 but its texture is scaly1 and not easily pulverized1 on account of a degree of flexibility which its laminae possess4 ,with extreme heat1 and mixed with charcoal1 it yields small particles of a metal that is grey1 brittle1 and extremely infusible2 and uniting with several of the metals1 it forms with them brittle or friable compounds4 ,by heat it is converted into a white calx4 ,of ,solid ,combustible ,substances4 ,there yet remains a class of solid substances1 of the combustible kind1 but most of them have been already considered under the form of the fluids1 from which they are originally formed1 as bitumen1 pit-coal1 and amber2 or under the principal ingredients of which they are composed1 as sulphur and plumbago4 ,there only remains to be mentioned the diamond1 which is of a nature quite different from that of the other precious stones1 the principal ingredient in which is siliceous earth1 which renders them not liable to be much affected by heat4 ,on the contrary1 the diamond is a combustible substance2 for in a degree of heat somewhat greater than that which will melt silver1 it burns with a slight flame1 diminishes common air1 and leaves a soot behind4 ,also1 if diamond powder be triturated with vitriolic acid1 it turns it black1 which is another proof of its containing phlogiston4 ,the diamond is valued on account of its extreme hardness1 the exquisite polish it is capable of1 and its extraordinary refractive power2 for light falling on its interior surface with an angle of incidence greater than #bd-a_/b will be wholly reflected1 whereas in glass it requires an angle of #da degrees4 ,,lecture ,,xxix4 ,of the ,doctrine of ,phlogiston and the ,composition of ,water4 ,it was supposed to be a great discovery of ,mr4 ,stahl1 that all inflammable substances1 as well as metals1 contain a principle1 or substance1 to which he gave the name of phlogiston1 and that the addition or deprivation of this substance makes some of the most remarkable changes in bodies1 especially that the union of a metallic calx and this substance makes a metal2 and that combustion consists in the separation of phlogiston from the substances that contain it4 ,that it is the same principle1 or substance1 that enters into all inflammable substances1 and metals1 is evident1 from its being disengaged from any of them1 and entering into the composition of any of the others4 ,thus the phlogiston of charcoal or inflammable air becomes the phlogiston of any of the metals1 when the calx is heated in contact with either of them4 ,on the contrary1 ,mr4 ,lavoisier and most of the ,french chemists1 are of opinion1 that there is no such principle1 or substance1 as phlogiston2 that metals and other inflammable bodies are simple substances1 which have an affinity to pure air2 and that combustion consists not in the separation of any thing from the inflammable substance1 but in the union of pure air with it4 ,they moreover say1 that water is not1 as has been commonly supposed1 a simple substance1 but that it consists of two elements1 viz4 pure air1 or oxygene1 and another1 to which they give the name of hydrogene1 which1 with the principle of heat1 called by them calorique1 is inflammable air4 ,the principal fact adduced by them to prove that metals do not lose any thing when they become calces1 but only gain something1 is1 that mercury becomes a calx1 called precipitate per se1 by imbibing pure air1 and that it becomes running mercury again by parting with it4 ,this is acknowledged3 but it is almost the only case of any calx being revived without the help of some known phlogistic substance2 and in this particular case it is not absurd to suppose1 that the mercury1 in becoming precipitate per se1 may retain all its phlogiston1 as well as imbibe pure air1 and therefore be revived by simply parting with that air4 ,in many other cases the same metal1 in different states1 contains more or less phlogiston1 as cast iron1 malleable iron1 and steel4 ,also there is a calx of mercury made by the acid of vitriol1 which cannot be revived without the help of inflammable air1 or some other substance supposed to contain phlogiston3 and that the inflammable air is really imbibed in these processes1 is evident1 from its wholly disappearing1 and nothing being left in the vessel in which the process is made beside the metal that is revived by it4 ,if precipitate per se be revived in inflammable air1 the air will be imbibed1 so that running mercury may contain more or less phlogiston4 ,the antiphlogistians also say1 that the diminution of atmospherical air by the burning of phosphorus is a proof of their theory2 the pure air being imbibed by that substance1 and nothing emitted from it4 ,but there is the same proof of phosphorus containing phlogiston1 that there is of dry flesh containing it2 since the produce of the solution of it in nitrous acid1 and its effect upon the acid1 are the same1 viz4 the production of phlogisticated air1 and the phlogistication of the acid4 ,their proof that water is decomposed1 is1 that in sending steam over hot iron1 inflammable air 7which they suppose to be one constituent part of it7 is procured2 while the other part1 viz4 the oxygene1 unites with the iron1 and adds to its weight4 ,but it is replied1 that the inflammable air may be well supposed to be the phlogiston of the iron1 united to part of the water1 as its base1 while the remainder of the water is imbibed by the calx2 and that it is mere water1 and not pure air1 or oxygene1 that is retained in the iron1 is evident1 from nothing but pure water being recovered when this calx of iron is revived in inflammable air1 in which case the inflammable air wholly disappears1 taking the place of the water1 by which it had been expelled4 ,in answer to this it is said1 that the pure air expelled from the calx uniting with the inflammable air in the vessel1 recomposes the water found after this process4 ,but in every other case in which any substance containing pure air is heated in inflammable air1 though the inflammable air be in part imbibed1 some fixed air is produced1 and this fixed air is composed of the pure air in the substance and part of the inflammable air in the vessel4 ,thus1 if minium1 which contains pure air1 and massicot1 which contains none1 be heated in inflammable air1 in both the cases lead will be revived by the absorption of inflammable air2 but in the former case only1 and not in the latter1 will fixed air be produced4 ,the calx of iron1 therefore1 having the same effect with massicot1 when treated in the same manner1 appears to contain no more pure air than massicot does4 ,besides this explanation of the facts on which the new theory is founded1 which shews it to be unnecessary1 the old hypothesis being sufficient for the purpose1 some facts are alledged1 as inconsistent with the new doctrine4 ,if the calx of iron made by water1 and charcoal made by the greatest degree of heat1 be mixed together1 a great quantity of inflammable air will be produced2 though1 according to the new theory1 neither of these substances contained any water1 which they maintain to be the only origin of it4 ,but this fact is easily explained upon the doctrine of phlogiston2 the water in this calx uniting with the phlogiston of the charcoal1 and then forming inflammable air2 and it is the same kind of inflammable air that is made from charcoal and water4 ,also the union of inflammable and pure air1 when they are fired together by means of the electric spark1 produces not pure water1 as1 according to the new theory1 it ought to do1 but nitrous acid4 ,to this it has been objected1 that the acid thus produced came from the decomposition of phlogisticated air1 a small portion of which was at first contained in the mixture of the two kinds of air4 ,but when every particle of phlogisticated air is excluded1 the strongest acid is procured4 ,they find1 indeed1 that by the slow burning of inflammable air in pure air1 they get pure water4 ,but then it appears1 that whenever this is the case1 there is a production of phlogisticated air1 which contains the necessary element of nitrous acid2 and this is always the case when there is a little surplus of the inflammable air that is fired along with the pure air1 as the acid is always procured when there is a redundancy of pure air4 ,that much water should be procured by the decomposition of these kinds of air1 is easily accounted for1 by supposing that water1 or steam1 is the basis of these1 as well as of all other kinds of air4 ,since air something better than that of the atmosphere is constantly produced from water by converting it into vapour1 and also by removing the pressure of the atmosphere1 and these processes do not appear to have any limits2 it seems probable1 that water united to the principle of heat2 constitutes atmospherical air2 and if so1 it must consist of the elements of both dephlogisticated and phlogisticated air2 which is a supposition very different from that of the ,french chemists4 ,,lecture ,,xxx4 ,of ,heat4 ,heat is an affection of bodies well known by the sensation that it excites4 ,it is produced by friction or compression1 as by the striking of flint against steel1 and the hammering of iron1 by the reflection or refraction of light1 and by the combustion of inflammable substances4 ,it has been long disputed1 whether the cause of heat be properly a substance1 or some particular affection of the particles that compose the substance that is heated4 ,but be it a substance1 or a principle of any other kind1 it is capable of being transferred from one body to another1 and the communication of it is attended with the following circumstances4 ,all substances are expanded by heat1 but some in a greater degree than others2 as metals more than earthy substances1 and charcoal more than wood4 ,also some receive and transmit heat through their substance more readily than others2 metals more so than earths1 and of the metals1 copper more readily than iron4 ,instruments contrived to ascertain the expansion of substances by heat1 are called pyrometers1 and are of various constructions4 ,as a standard to measure the degrees of heat1 mercury is in general preferable to any other substance1 on account of its readily receiving1 and communicating1 heat through its whole mass4 ,thermometers1 therefore1 or instruments to measure the degrees of heat1 are generally constructed of it1 though1 as it is subject to become solid in a great degree of cold1 ardent spirit1 which will not freeze at all1 is more proper in that particular case4 ,the graduation of thermometers is arbitrary4 ,in that of ,fahrenheit1 which is chiefly used in ,england1 the freezing point of water is #cb deg41 and the boiling point #bab deg4 ,in that of ,reaumur1 which is chiefly used abroad1 the freezing point of water is #j1 and the boiling point #hj4 ,to measure the degrees of heat above ignition1 ,mr4 ,wedgwood has happily contrived to use pieces of clay1 which contract in the fire2 and he has also been able to find the coincidence of the degrees in mercurial thermometers with those of his own4 ,to measure the degrees of heat and cold during a person's absence1 ,lord ,george ,cavendish contrived an instrument1 in which a small bason received the mercury1 that was raised higher than the place for which it was regulated by heat or cold1 without a power of returning4 ,but ,mr4 ,six has lately hit upon a better method1 viz4 introducing into the tube of his thermometer a small piece of iron1 which is raised by the ascent of the mercury1 and prevented from descending by a small spring2 but which may be brought back to its former place by a magnet acting through the glass4 ,heat1 like light1 is propagated in right lines2 and what is more remarkable1 cold observes the same laws4 ,for if the substance emitting heat without light1 as iron below ignition1 be placed in the focus of a burning mirror1 a thermometer in the focus of a similar mirror1 placed parallel to it1 though at a considerable distance1 will be heated by it1 and if a piece of ice be placed there1 the mercury will fall4 ,heat assists the solvent power of almost all menstrua2 so that many substances will unite in a certain degree of heat1 which will form no union at all without it1 as dephlogisticated and inflammable air4 ,if substances be of the same kind1 they will receive heat from one another1 in proportion to their masses4 ,thus1 if a quantity of water heated to #dj deg4 be mixed with another equal quantity of water heated to #bj deg41 the whole mass will be heated to #cj deg4 ,but if the substances be of different kinds1 they will receive heat from each other in different proportions1 according to their capacity 7as it is called7 of receiving heat4 ,thus1 if a pint of mercury of the temperature of #acf be mixed with a pint of water of the temperature of #ej1 the temperature of the two after mixture will not be a medium between those two numbers1 viz4 #ic1 but #gf2 consequently the mercury was cooled #fj deg41 while the water was heated only #bf2 so that #bf degrees of heat in water correspond to #fj in mercury4 ,but mercury is about #ac times specifically heavier than water1 so that an equal weight of mercury would contain only one thirtieth part of this heat2 and dividing #bf by #ac1 the quotient is #b4 ,if weight1 therefore1 be considered1 the heat discovered by water should be reckoned as #b instead of #fj2 and consequently when water receives #b degrees of heat1 an equal weight of mercury will receive #fj deg42 and dividing both the numbers by #b1 if the heat of water be #a1 that of the mercury will be #cj4 ,or since they receive equal degrees of heat1 whether they discover it or not 7and the less they discover1 the more they retain in a latent state7 a pound of mercury contains no more than one thirtieth part of the heat actually existing in a pound of water of the same temperature4 ,water1 therefore1 is said to have a greater capacity for receiving and retaining heat1 without discovering it1 than mercury1 in the proportion of #cj to #a1 if weight be considered1 or of #fj to #bf1 that is of #cj to #ac2 if bulk be the standard1 though1 according to some1 it is as #c to #b4 ,the capacity of receiving heat in the substance is greatest in a state of vapour1 and least in that of a solid2 so that when ice is converted into water1 heat is absorbed1 and more still when it is converted into vapour2 and on the contrary1 when vapour is converted into water1 it gives out the heat which it had imbibed1 and when it becomes ice it gives out still more4 ,if equal quantities of ice and water be exposed to heat at the temperature of #cb deg41 the ice will only become water1 without receiving any additional sensible heat2 but an equal quantity of water in the same situation would be raised to #agh deg41 so that #adf degrees of heat will be imbibed1 and remain in latent in the water1 in consequence of its passing from a state of ice3 and heat communicated by a given weight of vapour will raise an equal weight of a nonevaporable substance1 of the same capacity with water1 #idc degrees2 so that much more heat is latent in steam1 than in the water from which it was formed4 ,this doctrine of latent heat explains a great variety of phaenomena in nature2 as that of cooling bodies by evaporation1 the vapour of water1 or any other fluid substance1 absorbing and carrying off the heat they had before4 ,water1 perfectly at rest1 will fall considerably below the freezing point1 and yet continue fluid3 but on the slightest agitation1 the congelation of the whole1 or part of it1 takes place instantly1 and if the whole be not solid1 it will instantly rise to #cb deg41 the freezing point4 ,from whatever cause1 some motion seems necessary to the commencement of congelation1 at least in a moderate temperature2 but whenever any part of the water becomes solid1 it gives out some of the heat it had before1 and that heat which was before latent becoming sensible1 and being diffused through the whole mass1 raises its temperature4 ,on the same principle1 when water heated higher than the boiling point in a digester is suddenly permitted to escape in the form of steam1 the remainder is instantly reduced to the common boiling point1 the heat above that point being carried off in a latent state by the steam4 ,had it not been for this wise provision in nature1 the whole of any quantity of water would1 in all cases of freezing1 have become solid at once2 and also the whole of any quantity that was heated to the point of boiling1 would have been converted into steam at once2 circumstances which would have been extremely inconvenient1 and often fatal4 ,this doctrine also explains the effect of freezing mixtures1 as that of salt and snow4 ,these solid substances1 on being mixed1 become fluid1 and that fluid absorbing much heat1 deprives all the neighbouring bodies of part of what they had4 ,but if the temperature at which the mixture is made be as low as that to which this mixture would have brought it1 it has no effect1 and in a lower temperature this new fluid would become solid2 for that mixture has only a certain determinate capacity for heat1 and if the neighbouring bodies have less heat1 they will take from it4 ,it has been observed1 that the comparative heat of bodies containing phlogiston is increased by calcination or combustion2 so that the calx of iron has a greater capacity for heat1 and therefore contains more latent heat1 than the metal4 ,in general it is not found1 that the same substances have their capacity for receiving heat increased by an increase of temperature2 but this is said to be the case with a mixture of ardent spirit and water1 and also that of spirit of vitriol and water4 ,since all substances contain a greater or less quantity of heat1 and in consequence of being deprived of it become colder and colder1 it is a question of some curiosity to determine the extent to which this can go1 or at what degree in the scale of a thermometer any substance would be absolutely cold1 or deprived of all heat2 and an attempt has been made to solve this problem in the following manner4 ,comparing the capacity of water with that of ice1 by means of a third substance1 viz4 mercury1 it has been found1 that if that of ice be #i deg41 that of water is #aj deg42 so that water in becoming ice gives out one tenth part of its whole quantity of heat4 ,but it has been shown1 that ice in becoming water absorbs #adf degrees of heat4 ,this1 therefore1 being one tenth part of the whole heat of water1 it must have contained #adfj degrees2 so that taking #cb degrees1 which is the freezing point1 from that number1 the point of absolute cold will be #adbf below #j of ,fahrenheit's scale4 ,by a computation1 made by means of the heat of inflammable and dephlogisticated air1 at the temperature of #ej1 ,dr4 ,crawford finds1 that it contains nearly #aeej degrees of heat2 so that the point of absolute cold will be #aejj below #j4 ,but more experiments are wanted to solve this curious problem to entire satisfaction4 ,,lecture ,,xxxi4 ,of ,animal ,heat4 ,since all animals1 and especially those that have red blood1 are much hotter than the medium in which they live1 the source of this heat has become the subject of much investigation2 and as the most probable theory is that of ,dr4 ,crawford1 ,i shall give a short detail of the reasons on which it is founded4 ,having1 with the most scrupulous attention1 ascertained the latent1 or1 as he calls it1 the absolute heat of blood1 and also that of the aliments of which it is composed1 he finds that it contains more than could have been derived from them4 ,also finding that the absolute heat of arterial blood exceeds that of venous blood1 in the proportion of #aa-a_/b to #aj1 he concludes that it derives its heat from the air respired in the lungs1 and that it parts with this latent heat1 so that it becomes sensible1 in the course of its circulation1 in which it becomes loaded with phlogiston1 which it communicates to the air in the lungs4 ,that this heat is furnished by the air1 he proves1 by finding1 that that which we inspire contains more heat than that which we expire1 or than the aqueous humor which we expire along with it1 in a very considerable proportion2 so that if the heat contained in the pure air did not become latent in the blood1 it would raise its temperature higher than that of red-hot iron4 ,and again1 if the venous blood1 in being converted into arterial blood1 did not receive a supply of latent heat from the air1 its temperature would fall from #if to #ajd below #j in ,fahrenheit's thermometer4 ,that the heat procured by combustion has the same source1 viz4 the dephlogisticated air that is decomposed in the process1 is generally allowed2 and ,dr4 ,crawford finds1 that when equal portions of air are altered by the respiration of a ,guinea pig1 or by the burning of charcoal1 the quantity of heat communicated by the two processes is nearly equal4 ,the following facts are also alleged in favour of his theory4 ,whereas animals which have much red blood1 and respire much1 have the power of keeping themselves in a temperature considerably higher than that of the surrounding atmosphere1 other animals1 as frogs and serpents1 are nearly of the same temperature with it2 and those animals which have the largest respiratory organs1 as birds1 are the warmest2 also the degree of heat is in some measure proportionable to the quantity of air that is respired in a given time1 as in violent exercise4 ,it has been observed1 that animals in a medium hotter than the blood have a power of preserving themselves in the same temperature4 ,in this case the heat is probably carried off by perspiration1 while the blood ceases to receive1 or give out1 any heat2 and ,dr4 ,crawford finds1 that when an animal is placed in a warm medium the colour of the venous blood approaches nearer to that of the arterial than when it is placed in a colder medium2 and also1 that it phlogisticates the air less than in the former case2 so that in these circumstances respiration has not the same effect that it has in a colder temperature1 in giving the body an additional quantity of heat2 which is an excellent provision in nature1 as the heat is not wanted1 but1 on the contrary1 would prove inconvenient4 ,,lecture ,,xxxii4 ,of ,light4 ,another most important agent in nature1 and one that has a near connexion with heat1 is light1 being emitted by all bodies in a state of ignition1 and especially by the sun1 the great source of light and of heat to this habitable world4 ,whether light consists of particles of matter 7which is most probable7 or be the undulation of a peculiar fluid1 filling all space1 it is emitted from all luminous bodies in right lines4 ,falling upon other bodies1 part of the light is reflected at an angle equal to that of its incidence1 though not by impinging on the reflecting surface1 but by a power acting at a small distance from it4 ,but another part of the light enters the body1 and is refracted or bent towards1 or from1 the perpendicular to the surface of the new medium1 if the incidence be oblique to it4 ,in general1 rays of light falling obliquely on any medium are bent as if they were attracted by it1 when it has a greater density1 or contains more of the inflammable principle1 than the medium through which it was transmitted to it4 ,more of the rays are reflected when they fall upon a body with a small degree of obliquity to its surface1 and more of them are transmitted1 or enter the body1 when their incidence is nearer to a perpendicular4 ,the velocity with which light is emitted or reflected is the same1 and so great that it passes from the sun to the earth in about eight minutes and twelve seconds4 ,rays of light emitted or reflected from a body entering the pupil of the eye1 are so refracted by the humours of it1 as to be united at the surface of the retina1 and so make images of the objects1 by means of which they are visible to us2 and the magnifying power of telescopes or microscopes depends upon contriving1 by means of reflections or refractions1 that pencils of rays issuing from every point of any object shall first diverge1 and then converge1 as they would have done from a much larger object1 or from one placed much nearer to the eye4 ,when a beam of light is bent out of its course by refraction1 all the rays of which it consists are not equally refracted1 but some of them more and others less2 and the colour which they are disposed to exhibit is connected invariably with the degree of their refrangibility2 the red-coloured rays being the least1 and the violet the most refrangible1 and the rest being more or less so in proportion to their nearness to these1 which are the extremes1 in the following order1 violet1 indigo1 blue1 green1 yellow1 orange1 red4 ,these colours1 when separated as much possible1 are still contiguous2 and all the shades of each colour have likewise their separate and invariable degrees of refrangibility4 ,when separated as distinctly as possible1 they divide the whole space between them exactly as a musical chord is divided in order to found the several notes and half notes of an octave4 ,these differently-coloured rays of light are also separated in passing through the transparent medium of air and water1 in consequence of which the sky appears blue and the sea green1 these rays being returned1 while the red ones proceed to a greater distance4 ,by this means also objects at the bottom of the sea appear to divers red1 and so do all objects enlightened by an evening sun4 ,the mixture of all the differently-coloured rays1 in the proportions in which they cover the coloured image above mentioned1 makes a white1 and the absence of all light is blackness4 ,by means of the different refrangibility of light1 the colours of the rainbow may be explained4 ,the distance to which the differently-coloured rays are separated from each other is not in proportion to the mean refractive power of the medium1 but depends upon the peculiar constitution of the substance by which they are refracted4 ,the dispersing power of glass1 into the composition of which lead enters1 is great in proportion to the mean refraction2 and it is proportionally little in that glass in which there is much alkaline salt4 ,the construction of achromatic telescopes depends upon this principle4 ,not only have different rays of light these different properties with respect to bodies1 so as to be more or less refracted1 or dispersed1 by them1 but different sides of the same rays seem to have different properties1 for they are differently affected on entering a piece of island crystal4 ,with the same degree of incidence2 part of the pencil of rays1 consisting of all the colours1 proceeds in one direction1 and the rest in a different one2 so that objects seen through a piece of this substance appear double4 ,at the surface of all bodies rays of light are promiscuously reflected1 or transmitted4 ,but if the next surface be very near to it1 the rays of one colour chiefly are reflected1 and the rest transmitted1 and these places occur alternately for rays of each of the colours in passing from the thinnest to the thickest parts of the medium2 so that several series1 or orders1 of colours will be visible on the surface of the same thin transparent body4 ,on this principle coloured rings appear between a plane and a convex lens1 in a little oil on the surface of water1 and in bubbles made with soap and water4 ,when rays of light pass near to any body1 so as to come within the sphere of its attraction and repulsion1 an inflection takes place2 all the kinds of rays being bent towards1 or from1 the body1 and these powers affecting some rays more than others1 they are by this means also separated from each other1 so that coloured streaks appear both within the shadow1 and the outside of it1 the red rays being inflected at the greatest distance from the body4 ,part of the light which enters bodies is retained within them1 and proceeds no farther2 but so loosely in some kinds of bodies1 that a small degree of heat is sufficient to expel it again1 so as to make the body visible in the dark3 but the more heat is applied1 the sooner is all the light expelled4 ,this is a strong argument for the materiality of light4 ,bolognian phosphorus is a substance which has this property2 but a composition made by ,mr4 ,canton1 of calcined oyster-shells and sulphur1 in a much greater degree4 ,however1 white paper1 and most substances1 except the metals1 are possessed of this property in a small degree4 ,some bodies1 especially phosphorus1 and animal substances tending to putrefaction1 emit light without being sensibly hot4 ,the colours of vegetables1 and likewise their taste and smell1 depend upon light4 ,it is also by means of light falling on the leaves and other green parts of plants1 that they emit dephlogisticated air1 which preserves the atmosphere fit for respiration4 ,it is light that imparts colour to the skins of men1 by means of the fluid immediately under them4 ,this is the cause of tanning1 of the copper colour of the ,north ,americans1 and the black of the ,negroes4 ,light also gives colour to several other substances1 especially the solutions of mercury in acids4 ,,lecture ,,xxxiii4 ,of ,magnetism4 ,magnetism is a property peculiar to iron1 or some ores of it4 ,the earth itself1 owing probably to the iron ores contained in it1 has the same property4 ,but though all iron is acted upon by magnetism1 steel only is capable of having the power communicated to it4 ,every magnet has two poles1 denominated north and south1 each of which attracts the other1 and repels that of the same kind with itself4 ,if a magnet be cut into two parts1 between the two poles1 it will make two magnets1 the parts that were contiguous becoming opposite poles4 ,though the poles of a magnet are denominated north and south1 they do not constantly1 and in all parts of the earth1 point due north or south1 but in most places to the east or west of them1 and with a considerable variation in a course of time4 ,also a magnet exactly balanced at its center will have a declination from an horizontal position of about #gj degrees4 ,the former is called the variation1 and the latter the dipping of the magnetic needle4 ,a straight bar of iron which has been long fixed in a vertical position1 will become a magnet1 the lower end becoming a north pole1 and the upper end a south one2 for if it be suspended horizontally1 the lower end will point towards the north1 and the upper end towards the south4 ,also any bar of iron1 not magnetical1 held in a vertical position1 will become a temporary magnet1 the lower end becoming a north pole1 and the upper end a south one2 and a few strokes of a hammer will fix the poles for a short time1 though the position of the ends be changed4 ,magnetism may likewise be given to a bar of iron by placing it firmly in the position of the dipping-needle1 and rubbing it hard one way with a polished steel instrument4 ,iron will also become magnetical by ignition and quenching it in water in the position of the dipping-needle4 ,magnetism acts1 without any diminution of its force1 through any medium2 and iron not magnetical will have that power while it is in connexion with a magnet1 or rather the power of the magnet is extended through the iron4 ,steel filings gently thrown upon a magnet1 adhere to it in a curious manner2 and the filings1 acquiring magnetism by the contact1 adhere together1 and form a number of small magnets1 which arrange themselves according to the attraction of the poles of the original magnet4 ,this experiment is made to the most advantage upon a piece of pasteboard1 or paper1 placed over the magnet4 ,magnetism is communicated by the friction1 or the near position1 of a magnet to a piece of steel of a size less than it4 ,for this reason a combination of magnetical bars will have a greater effect than a single one2 and in the following manner1 beginning without any magnetism at all1 the greatest quantity may be procured4 ,six bars of steel may be rendered slightly magnetical by fixing each of them successively to an upright poker1 and stroking it several times from the bottom to the top with the lower end of an old pair of tongs4 ,if then four of these bars be joined1 the magnetism of the remaining two will be much increased by a proper method of rubbing with them2 and by changing their places1 joining the strongest1 and acting upon the weakest1 they may all be made as magnetical as they are capable of being4 ,the strength of a natural magnet may be increased by covering its polar extremities with steel4 ,this is called the arming of the loadstone4 ,to account for the variation of the needle1 ,dr4 ,halley supposed the earth to consist of two parts1 an external shell and an internal nucleus1 detached1 and having a revolution distinct from it2 and that the action of the poles of the shell and of the nucleus would explain all the varieties in the position of the needle4 ,but others think that the cause of the magnetism of the earth is not within1 but without itself4 ,one reason for this opinion is1 that a magnet is liable to be affected by a strong aurora borealis2 and another is1 that the variation of the needle proceeds in such manner as supposes that the motion of the nucleus must be quicker than that of the shell of the earth2 whereas1 since it is most natural to suppose that motion was communicated to the nucleus by the shell1 it would be slower4 ,some idea of the quantity and the progress of the variation of the needle may be formed from the following facts4--,at the ,cape of ,good ,hope1 when it was discovered by the ,portuguese1 in #adhf1 there was no variation1 the needle there pointing due north2 in #afbb it was about #b degrees westward1 in #afge it was #h deg4 ,w4 in #agjj about #aa deg4 ,w4 in #agef about #ah deg4 ,w4 and in #aggd about #ba-a_/b deg4 ,w4 ,in ,london1 in #aehj1 the variation was #aa degrees #ae seconds ,e42 in #afbb it was #f deg4 ,e4 in #afcd it was #d deg4 #e min4 ,e4 in #afeg it was nothing at all2 in #afgb it was #b deg4 #cj min4 ,w4 in #afib it was #f deg4 ,w4 in #agec it was about #af ,w4 and at present it is about #ba ,w4 ,the longitude may in some places be found by the variation of the needle2 and ,mr4 ,churchman1 of ,america1 having given much attention to the subject1 comparing the observations of others1 and many of his own1 thinks that he has found a method of determining the longitude to a great degree of certainty1 in most cases1 by this means4 ,he says there are two magnetic poles of the earth1 one to the north and the other to the south1 at different distances from the poles of the earth1 and revolving in different times2 and from the combined influence of these two poles he deduces rules for the position of the needle in all places of the earth1 and at all times1 past1 present1 or to come4 ,the north magnetic pole1 he says1 makes a complete revolution in #dbf years1 #gg days1 #i hours1 and the south pole in about #edei years4 ,in the beginning of the year #aggg the north magnetic pole was in #gf deg4 #d min4 north latitude2 and in longitude from ,greenwich #adj deg4 east2 and the south was in #gb deg4 south latitude1 and #adj deg4 east from ,greenwich4 ,,lecture ,,xxxiv4 ,of ,electricity4 ,electricity is a property belonging to1 or capable of being communicated to1 all substances whatever2 and whereas by some of them it is transmitted with great ease1 and by others with much difficulty1 they have been divided into two classes1 and denominated conductors or non-conductors of electricity4 ,also the latter receiving this power by friction1 and other means1 are termed electrics1 and the former non-electrics4 ,metals of all kinds1 and water1 are conductors1 though in very different degrees2 so also is charcoal4 ,all other substances1 and also a perfect vacuum1 are non-conductors of electricity4 ,but many of these substances1 when they are made very hot1 as glass1 resin1 baked wood1 and perhaps all the rest on which the experiment can be made in this state1 are conductors4 ,it is the property of all kinds of electrics1 when they are rubbed by bodies different from themselves1 to attract light substances of all kinds1 to exhibit an appearance of light1 attended with a particular sound1 on the approach of any conductor2 and if the nostrils are presented1 they are affected with a smell like that of phosphorus4 ,this attraction is most easily explained by supposing that electricity is produced by a fluid exceedingly elastic1 or repulsive of itself1 and attracted by all other substances4 ,an electric exhibiting the appearances above mentioned1 is said to be excited1 and some of them1 particularly the tourmaline1 are excited by heating and cooling1 as well as by friction4 ,it appears1 however1 that excitation consists in the mere transferring of electricity from one substance to another1 and that the great source of electricity is in the earth4 ,on this account it is necessary to the considerable excitation of any electric1 that the substance against which it is rubbed 7hence termed the rubber7 have a communication with the earth1 by means of conductors2 for if the rubber be insulated1 that is cut off from all communication with the earth by means of electrics1 the friction has but little effect4 ,when insulated bodies have been attracted by1 and brought into contact with1 an excited electric1 they begin to be repelled by it1 and also to repel one another2 nor will they be attracted again till they have been brought into contact with some conductor communicating with the earth2 but after this they will be attracted as at first4 ,if conductors be insulated1 electric powers may be communicated to them by the approach of excited electrics1 or the contact of other electrified bodies4 ,they will then attract light bodies1 and give sparks1 c4 like the excited electrics themselves4 ,when electricity is strongly communicated to insulated animal bodies1 the pulse is quickened1 and perspiration increased2 and if they receive1 or part with1 their electricity on a sudden1 a painful sensation is felt at the place of communication4 ,but what is more extraordinary1 is1 that the influence of the brain and nerves upon the muscles seems to be of an electric nature4 ,this is one of the last and most important of all philosophical discoveries4 ,i shall1 therefore1 give the result of all the observations that have hitherto been made on the subject1 in a series of propositions1 drawn up by an intelligent friend1 who has given much more attention to it than ,i have done4 #a4 ,the nerve of the limb of an animal being laid bare1 and surrounded with a piece of sheet lead1 or of tinfoil1 if a communication be formed between the nerve thus armed and any of the neighbouring muscles1 by means of a piece of zinc1 strong contractions will be produced in the limb4 #b4 ,if a portion of the nerve which has been laid bare be armed as above1 contractions will be produced as powerfully1 by forming the communication between the armed and bare part of the nerve1 as between the armed part and muscle4 #c4 ,a similar effect is produced by arming a nerve and simply touching the armed part of the nerve with the metallic conductor4 #d4 ,contractions will take place if a muscle be armed1 and a communication be formed by means of the conductor between it and a neighbouring nerve4 ,the same effect will be produced if the communication be formed between the armed muscle and another muscle1 which is contiguous to it4 #e4 ,contractions may be produced in the limb of an animal by bringing the pieces of metal into contact with each other at some distance from the limb1 provided the latter make part of a line of communication between the two metallic conductors4 ,the experiment which proves this is made in the following manner4 ,the amputated limb of an animal being placed upon a table1 let the operator hold with one hand the principal nerve1 previously laid bare1 and in the other let him hold a piece of zinc2 let a small plate of lead or silver be then laid upon the table1 at some distance from the limb1 and a communication be formed1 by means of water1 between the limb and the part of the table where the metal is lying4 ,if the operator touch the piece of silver with the zinc1 contractions will be produced in the limb the moment that the metals come into contact with each other4 ,the same effect will be produced if the two pieces of metal be previously placed in contact1 and the operator touch one of them with his finger4 ,this fact was discovered by ,mr4 ,william ,cruikshank4 #f4 ,contractions can be produced in the amputated leg of a frog1 by putting it into water1 and bringing the two metals into contact with each other at a small distance from the limb4 #g4 ,the influence which has passed through1 and excited contractions in1 one limb1 may be made to pass through1 and excite contractions in1 another limb4 ,in performing this experiment it is necessary to attend to the following circumstances3 let two amputated limbs of a frog be taken2 let one of them be laid upon a table1 and its foot be folded in a piece of silver2 let a person lift up the nerve of this limb with a silver probe1 and another person hold in his hand a piece of zinc1 with which he is to touch the silver including the foot2 let the person holding the zinc in one hand catch with the other the nerve of the second limb1 and he who touches the nerve of the first limb is to hold in his other hand the foot of the second2 let the zinc now be applied to the silver including the foot of the first limb1 and contractions will immediately be excited in both limbs4 #h4 ,the heart is the only involuntary muscle in which contractions can be excited by these experiments4 #i4 ,contractions are produced more strongly1 the farther the coating is placed from the origin of the nerve4 #aj4 ,animals which were almost dead have been found to be considerably revived by exciting this influence4 #aa4 ,when these experiments are repeated upon an animal that has been killed by opium1 or by the electric shock1 very slight contractions are produced2 and no contractions whatever will take place in an animal that has been killed by corrosive sublimate1 or that has been starved to death4 #ab4 ,zinc appears to be the best exciter when applied to gold1 silver1 molybdena1 steel1 or copper4 ,the latter metals1 however1 excite but feeble contractions when applied to each other4 ,next to zinc1 in contact with these metals1 tin and lead1 and silver and lead1 appear to be the most powerful exciters4 ,at least two kinds of fishes1 the torpedo and the electrical eel1 have a voluntary power of giving so strong a shock to the water in which they swim1 as to affect fishes and other animals which come near them2 and by a conducing communication between different parts of these fishes1 an electric shock may be given exactly like that of the ,leyden phial1 which will be described hereafter2 and if the communication be interrupted1 a flash of electric light will be perceived4 ,the growth of vegetables is also quickened by electricity4 ,,lecture ,,xxxv4 ,the same ,subject continued4 ,no electric can be excited without producing electric appearances in the body with which it is excited1 provided that body be insulated2 for this insulated rubber will attract light bodies1 give sparks1 and make a snapping noise1 upon the approach of a conductor1 as well as the excited electric4 ,if an insulated conductor be pointed1 or if a pointed conductor1 communicating with the earth1 be held pretty near it1 little or no electric appearance will be exhibited1 only a light will appear at each of the points during the act of excitation1 and a current of air will be sensible from off them both4 ,the effect of pointed bodies is best explained on the supposition of the electric matter in one body repelling that in another2 and consequently the electricity belonging to a body with a large surface making a greater resistance to the entrance of foreign electricity than that belonging to a smaller4 ,these two electricities1 viz4 that of the excited electric1 and that of the rubber1 though similar to1 are the reverse of1 one another4 ,a body attracted by the one will be repelled by the other1 and they will attract1 and in all respects act upon1 one another more sensibly than upon other bodies2 so that two pieces of glass or silk possessed of contrary electricities will cohere firmly together1 and require a considerable force to separate them4 ,these two electricities having been first discovered by producing one of them from glass1 and the other from amber1 sealing-wax1 sulphur1 rosin1 c4 first obtained the names of vitreous and resinous electricity2 and it being afterwards imagined that one of them was a redundancy1 and the other a deficiency1 of a supposed electric fluid1 the former has obtained the name of positive1 and the latter that of negative1 electricity2 and these terms are now principally in use4 ,positive and negative electricity may be distinguished from each other by the manner in which they appear at the points of bodies4 ,from a pointed body electrified positively1 there issues a stream of light1 divided into denser streams1 at the extremities2 whereas1 when the point is electrified negatively1 the light is more minutely divided1 and diffused equally4 ,the former of these is called a brush1 and the latter a star4 ,if a conductor not insulated be brought within the atmosphere 7that is the sphere of action7 of any electrified body1 it acquires the electricity opposite to that of the electrified body1 and the nearer it is brought1 the stronger opposite electricity does it acquire1 till the one receive a spark from the other1 and then the electricity of both will be discharged4 ,the electric substance which separates the two conductors possessing these two opposite kinds of electricity1 is said to be charged4 ,plates of glass are the most convenient for this purpose1 and the thinner the plate the greater is the charge it is capable of holding4 ,the conductors contiguous to each side of the glass are called their coating4 ,agreeably to the above-mentioned general principle1 it is necessary that one side of the charged glass have a communication with the rubber1 while the other receives the electricity from the conductor1 or with the conductor1 while the other receives from the rubber4 ,it follows also1 that the two sides of the plate thus charged are always possessed of the two opposite electricities2 that side which communicates with the excited electric having the electricity of the electric1 and that which communicates with the rubber1 that of the rubber4 ,there is1 consequently1 a very eager attraction between these two electricities with which the different sides of the plate are charged1 and when a proper communication is made by means of conductors1 a flash of electric light1 attended with a report 7which is greater or less in proportion to the quantity of electricity communicated to them1 and the goodness of the conductors7 is perceived between them1 and the electricity of both sides is thereby discharged4 ,the substance of the glass itself in1 or upon1 which these electricities exist1 is impervious to electricity1 and does not permit them to unite2 but if they be very strong1 and the plate of glass very thin1 they will force a passage through the glass4 ,this1 however1 always breaks the glass1 and renders it incapable of another charge4 ,the flash of light1 together with the explosion between the two opposite sides of a charged electric1 is generally called the electric shock1 on account of the disagreeable sensation it gives any animal whose body is made use of to form the communication been them4 ,the electric shock is always found to perform the circuit from one side of the charged glass to the other by the shortest passage through the best conductors4 ,common communicated electricity also observes the same rule in its transmission from one body to another4 ,it has not been found1 that the electric shock takes up any sensible space of time in being transmitted to the greatest distances4 ,the electric shock1 as also the common electric spark1 displaces the air through which it passes2 and if its passage from conductor to conductor be interrupted by non-conductors of a moderate thickness1 it will rend and tear them in its passage1 in such a manner as to exhibit the appearance of a sudden expansion of the air about the center of the shock4 ,if the electric circuit be interrupted1 the electric matter1 during the discharge1 will pass to any other body that lies near its path1 and instantly return4 ,this may be called the lateral explosion4 ,the effect of this lateral explosion through a brass chain1 when the quantity of electricity is very great1 will be the discolouring and partial burning of the paper on which it lies4 ,if a great quantity of electricity be accumulated1 as in a battery1 the explosion will pass over the surfaces of imperfect conductors without entering them1 and the effect will be a strong concussion of the substance4 ,also the electric matter thus accumulated and condensed will1 by its repulsion1 form concentric circles1 which will appear by melting the surface of a flat piece of metal on which the explosion is received4 ,if an electric shock1 or strong spark1 be made to pass through1 or over1 the belly of a muscle1 it forces it to contract1 as in a convulsion4 ,if a strong shock be sent through a small animal body1 it will often deprive it instantly of life4 ,when the electric shock is very strong1 it will give polarity to magnetic needles1 and sometimes it reverses their poles4 ,great shocks1 by which animals are killed1 are said to hasten putrefaction4 ,electricity and lightning are in all respects the same thing2 since every effect of lightning may be imitated by electricity1 and every experiment in electricity may be made with lightning1 brought down from the clouds by means of insulated pointed rods of metal4 ,,lecture ,,xxxvi4 ,the same ,subject continued4 ,three curious and important instruments1 which are among the latest improvements in electricity1 deserve a particular explanation1 and in all of them the effect depends upon the general principles mentioned above1 viz4 that bodies placed within the influence1 or1 as it is usually termed1 within the atmosphere1 of an electrified body1 are affected by a contrary electricity1 and that these two electricities mutually attract each other4 ,these instruments are the electrophorus1 the condenser of electricity1 and the doubler of it4 ,the electrophorus consists of an insulated conducting plate applied to an insulated electric4 ,if the latter have any electricity communicated to it1 for example the negative1 the positive electricity of the former will be attracted by it1 and consequently the plate will be capable of receiving electricity from any body communicating with the earth2 being1 in this situation1 capable of containing more electricity than its natural quantity4 ,consequently1 when it is removed from the lower plate1 and the whole of its electricity equally diffused through it1 it will appear to have a redundance1 and therefore will give a spark to any body communicating with the earth4 ,being then replaced upon the electric1 and touched by any body communicating with the earth1 it will be again affected as before1 and give a spark on being raised2 and this process may be continued at pleasure1 the electrophorus supplying the place of any other electrical machine4 ,if the conducting plate of the electrophorus be applied to a piece of dry wood1 marble1 or any other substance through which electricity can pass but very slowly1 or if the insulated conducting plate be covered with a piece of thin silk1 which will make some resistance to the passage of electricity1 and it be then applied to another plate communicating with the earth2 and if1 in either of these cases1 a body with a large surface possessed of a weak electricity be applied to the conducting plate1 the weak electricity not being able to overcome the obstruction presented to it1 so as to be communicated to the other plate1 will affect it with the contrary electricity1 and this reacting on the first plate1 will condense its electricity on that part of the plate to which it is contiguous2 in consequence of which its capacity of receiving electricity will be increased2 so that on the separation of the two plates1 that electricity which was before condensed1 being equally diffused through the whole plate1 will have a greater intensity than it had before1 attracting light bodies1 or even giving a spark1 when the body from which it received its electricity was incapable of it4 ,for though it contained a great quantity of electricity1 it was diffused through so large a space that its intensity was very small4 ,this instrument is therefore called a condenser of electricity4 ,if an insulated plate of metal possessing the smallest degree of electricity be presented very near to another plate communicating with the earth1 it will affect this plate with the opposite electricity2 and this being1 in the same manner1 applied to a third plate1 will put it into the same state with the first4 ,if then these two plates be joined1 and the first plate be presented to either of them1 its own electricity being attracted by that of the plate presented1 that of the other will be drawn into it1 so that its quantity will be doubled4 ,the same process being repeated1 will again double the electricity of this plate1 till1 from being quite insensible to the most exquisite electrometer1 it will become very conspicuous1 or even give sparks4 ,this instrument is therefore called a doubler of electricity1 of excellent use in ascertaining the quality of atmospherical electricity when ever so small4 ,if this instrument be so constructed that these three plates can be successively presented to one another by the revolution of one of them on an axis1 it is called the revolving doubler2 and in this form it is most convenient for use4 ,,the ,,end4 ,transcriber's ,note3 ,details of corrections ,position ,original ,correction ,lecture ,i1 first paragraph limestone lime-stone ,lecture ,i1 last paragraph attraction attraction1 ,lecture ,,iii1 first paragraph viz viz4 ,lecture ,,iii1 last paragraph #a4 #a ,lecture ,,xvii1 penultimate paragraph dissoved dissolved ,lecture ,,xix1 ,of ,calcareous ,earth hundreth hundredth ,lecture ,,xxvi1 ,of ,semi-metals ignates ignites ,lecture ,,xxviii1 first paragraph animony antimony