,libr>ies47 ,a ,,brief ,,acc\nt ,,( ,,radio-,,activity ,,by ,,francis ,p4 ,,v5able1 ,,ph4,d41 ,d4,,sc41 ,,ll4,d4 ,,pr(essor ,,( ,,*emi/ry1 ,,univ]sity ,,( ,,nor? ,,c>ol9a ,,au?or ,,( ,a ,,%ort ,,hi/ory ,,( ,,*emi/ry1 ,,p]iodic ,,law1 ,,etc4 ,d4 ,c4 ,,hea? ,,co41 ,,publi%]s ,,bo/on ,,new ,,york ,,*icago ,,copyright1 #aiag1 ,,by ,d4 ,c4 ,,hea? ,,co4 ,,ia#g ,,preface ,i h ga!r$ ! mat]ial = ?is little book because ,i h f\nd x a necess>y fill+ out ( ! c\rse = my class 9 g5]al *emi/ry4 ,su* a c\rse deal+ ) ! composition & /ructure ( matt] is left unf9i%$ & 9 ! air1 z x 71 unless ! m>vell\s facts & d$uctions f ! /udy ( radio-activity are pres5t$ & discuss$4 ,! usual page or two giv5 9 ! pres5t text-books are too cond5s$ 9 _! treatm5t to af=d any intellig5t grasp ( ! subject1 s ,i h put 9 book =m ! lectures :i* ,i h hi!rto felt =c$ to give4 ,p]haps ! book may prove useful also to busy m5 9 o!r bran*es ( sci5ce :o wi% to "k some?+ ( radio-activity & h scant leisure 9 :i* to read ! l>g] treatises4 ,x is ne$less to say t !re is no?+ orig9al 9 ! book unless x be 9 "p ! gr\p+ ( facts & ord] ( _! treatm5t4 ,i h made free use ( ! writ+s ( ,ru!r=d1 ,soddy1 & ,j4 ,j4 ,?omson1 & w\ld "h express my debt to !m--j a "p ( t indebt$ness :i* we all feel to ^! ma/]s4 ,i wi% also to ackn[l$ge my obligations to ,pr(essor ,b]tram ,b4 ,boltwood = 8 helpful sugge/ions 9 connection ) ?is "w4 ,,cont5ts ,,*apt] ,i ,,discov]y ,,( ,,radio-,,activity ,,page ,! beg9n+--,radio-active bodies--,an atomic prop]ty--,discov]y ( new radio-active bodies--,discov]y ( ,polonium--,discov]y ( ,radium--,o!r radio-active bodies f\nd #a ,,*apt] ,,ii ,,prop]ties ,,( ,,! ,,radiations ,ionization ( ,gases--,exp]im5tal confirmation--,application ( electric field--,size & nature ( ions--,photograph+ ! track ( ! ray--,action ( radiations on photographic plates--,dis*>ge ( electrifi$ bodies--,sc9tillations on phosphoresc5t bodies--,p5etrat+ p[]--,magnetic deflection--,?ree types ( rays--,alpha rays--,beta rays--,gamma rays--,measurem5t ( radiations--,id5tifications ( ! rays #g ,,*apt] ,,iii ,,*anges ,,9 ,,radio-,,active ,,bodies ,radio-activity a p]man5t prop]ty--,induc$ activity--,discov]y ( ,uranium ,x--,conclusions drawn--,se>* = new radio-active bodies--,me?ods ( inve/igation--,nature ( ! radiations--,life-p]iods--,equilibrium s]ies #ag ,,*apt] ,,iv ,,nature ,,( ,,! ,,alpha ,,p>ticle ,dis9tegrat+ ( ! elem5ts--,id5tification ( ! rays--,! alpha rays--,alpha rays consi/ ( solid p>ticles--,electrical *>ge--,helium =m$ f alpha p>ticles--,discov]y ( ,helium--,*>act]i/ics ( ,helium--,table ( con/ants #be ,,*apt] ,v ,,! ,,/ructure ,,( ,,! ,,atom ,prop]ties ( ,radium--,en]gy evolv$ by radium--,necessity = a dis9tegration !ory--,dis9tegration !ory--,con/itution ( ! atom--,ru!r=d's atom--,scatt]+ ( alpha p>ticles--,/opp+ p[] ( sub/ances #cb ,,*apt] ,,vi ,,radio-,,activity ,,& ,,*emical ,,!ory ,influ5ce ^u *emical !ory--,! p]iodic sy/em--,basis ( ! p]iodic sy/em--,influ5ce ( positive nucleus--,det]m9ation ( ! atomic numb]--,use ( ,x-ray spectra--,*anges caus$ by ray-emission--,atomic weight losses--,lead ! end product--,*anges ( position 9 ! p]iodic sy/em--,*anges f loss ( beta p>ticles--,isotopes--,radio-activity 9 nature--,radio-active products 9 ! e>?'s cru/--,pres5ce 9 air & soil wat]s--,cosmical radio-activity #da ,,index #ec ,a ,,brief ,,acc\nt ,,( ,,radio-,,activity ,,*apt] ,i ,,discov]y ,,( ,,radio-,,activity ,! object ( ?is brief treatise is to give a simple acc\nt ( ! developm5t ( our k ( radio-activity & its be>+ on *emical & physical sci5ce4 ,ma!matical processes w be omitt$1 z x is suffici5t to give ! assur$ results f calculations :i* are likely to be beyond ! tra9+ ( ! read]4 ,exp]im5tal evid5ce w be giv5 9 detail :]ev] x is fundam5tal & necess>y to a confid5t grasp ( "s ( ! m>vel\s d$uctions 9 ?is new bran* ( sci5ce4 ,!ories _c be avoid$1 b ! facts rema9 :ile !ories gr[ old & are disc>d$ = o!rs m 9 accord ) ! facts4 ,! ,beg9n+ ,z s (t5 happ5s 9 ! hi/ory ( sci5ce1 ! op5+ up ( ?is new field ) its fasc9at+ disclosures 0 due to an inve/igation und]tak5 = ano!r purpose b pa9/ak+ly c>ri$ out ) a m9d op5 to ! tru? :]ev] x might lead4 ,9 #ahie1 ,rntg5 mode/ly ann\nc$ 8 discov]y ( ! ,x rays4 ,?is attract$ imm$iate & int5se int]e/4 ,among ^? :o und]took to foll[ up ^! ph5om5a 0 ,becqu]el1 :o1 because ( ! app>5t connection ) phosphoresc5ce1 tri$ ! action ( a numb] ( phosphoresc5t sub/ances ^u ! photographic plate1 ! mo/ /rik+ *>act]i/ic ( ! ,x rays be+ _! effect ^u su* s5sitive plates4 ,9 ^! exp]im5ts he obta9$ no results until he tri$ salts ( uranium1 recall+ previ\s obs]vations ( 8 z to _! phosphoresc5ce4 ,di/9ct action 0 not$4 ,fur!rmore1 he prov$ t ?is _h no connection ) ! ph5om5on ( phosphoresc5ce1 z bo? uranic & uran\s salts 7 active & ! latt] %[ no phosphoresc5ce4 ,becqu]el ann\nc$ 8 discov]ies 9 #ahif & ?is 0 ! beg9n+ ( ! new sci5ce ( radio-activity4 ,radio-active bodies ,! rays giv5 (f by uranium & its salts 7 f\nd to diff] f ! ,x rays4 ,!y %[$ no appreciable v>iation 9 int5sity1 no previ\s exposure ( ! sub/ance to light 0 necess>y1 & nei!r *anges ( temp]ature nor any o!r physical or *emical ag5cy affect$ !m4 ,at fir/ uranium & its comp\nds 7 ! only kn[n s\rce ( ^! new radiations1 b _m o!r sub/ances 7 exam9$ & two ye>s lat] ?orium & its comp\nds 7 add$ to ! li/4 ,9 g5]al ! dis*>g+ action seem$ ab\t ! same4 ,o!r elem5ts & ord9>y sub/ances %[ a m9ute activity4 ,only potassium & rubidium h a great] activity ?an ?is1 & !irs is only ab\t "o-?\s&? t ( uranium4 ,an ,atomic ,prop]ty ,9 ! exam9ation ( uranium & ?orium comp\nds x 0 f\nd t ! activity 0 det]m9$ by ! uranium & ?orium pres5t2 x 0 proportto ! am\nt (ional ^! elem5ts pres5t & indep5d5t ( ! nature ( ! o!r elem5ts compos+ ! comp\nd4 ,! conclusion 01 !re=e1 t ! activity 0 an inh]5t prop]ty ( ! atoms ( uranium & ?orium1 t is1 an atomic prop]ty4 ,?is 0 a long /ep =w>d & introduc$ into sci5ce ! conception ( a new prop]ty ( matt]1 or at lea/ ( c]ta9 =ms ( matt]4 ,discov]y ( ,new ,radio-active ,bodies ,9 exam9+ a l>ge numb] ( m9]als conta9+ uranium & ?orium1 ,mme4 ,curie made ! important obs]vation t _m ( ^! 7 m active ?an ! elem5ts !mselves4 ,9 measur+ ! activity %e made use ( ! electrical me?od :i* w be describ$ lat]4 ,9 ! foll[+ table giv+ h] results = uranium m9]als ! numb]s "u i give ! maximum curr5t 9 amp]es4 ,!y s]ve simply = comp>ison4 i ,pit*bl5de f ,joa*im/hal #g4j #aj-aa ,clevite #a4d #aj-aa ,*alcolite #e4b #aj-aa ,autunite #b4g #aj-aa ,c>notite #f4b #aj-aa ,uranium #b4c #aj-aa ,uranium & potassium sulphate #j4g #aj-aa ,uranium & copp] phosphate #j4i #aj-aa ,! la/ ?ree are pure uranium & comp\nds ( t elem5t giv5 = comp>ison ) ! fir/ five1 :i* are naturally occurr+ m9]als4 ,! la/ comp\nd has ! same composition z *alcolite & is simply ! artificially prep>$ m9]al4 ,x has ! activity :i* w\ld be calculat$ f ! proportion ( uranium pres5t1 ! copp] & phosphoric acid contribut+ no activity4 ,s9ce ! activity is n dep5d5t ^u ! composition b ^u ! am\nt ( uranium pres5t1 ! activity 9 all ( ! m9]als %\ld be less ?an t ( uranium4 ,on ! contr>y1 x is sev]al times great]4 ,natural & artificial *alcolite also %[ a m>k$ diff]5ce 9 favor ( ! =m]4 ,! supposition 0 a natural "o1 !re=e1 t ^! m9]als conta9$ small quantities ( an elem5t1 or elem5ts1 undetect$ by ord9>y analysis & hav+ a mu* great] activity ?an uranium4 ,simil> results 7 obta9$ 9 ! exam9ation ( ?orium m9]als & ?orium salts4 ,discov]y ( ,polonium ,foll[+ up ?is supposition1 ,m4 & ,mme4 ,curie set !mselves ! task ( sep>at+ ?is unkn[n sub/ance4 ,/>t+ ) pit*bl5de1 a sy/ematic *emical exam9ation 0 made4 ,?is is an exce$+ly complex m9]al1 conta9+ _m elem5ts4 ,! processes 7 labori\s & dem&$ mu* "t & m9ute c>e4 ,!y ne$ n be describ$ "h4 ,x is suffici5t to say t along ) bismu? a v active sub/ance 0 sep>at$1 to :i* ,mme4 ,curie gave ! "n ( polonium = ,pol&1 h] native l&4 ,its complete isolation is v difficult & suffici5t quantities ( ! pure sub/ance h n be5 obta9$ to det]m9e its atomic weight & o!r prop]ties1 b "s ( ! l9es ( its spectrum h be5 det]m9$4 ,*emically x is v closely analog\s to bismu?4 ,discov]y ( ,radium ,9 a simil> mann] a b>ium precipitate 0 obta9$ f pit*bl5de :i* conta9$ a highly active sub/ance4 ,! pure *loride ( ?is body & b>ium c be prep>$ toge!r & !n sep>at$ by fractional cry/allization4 ,to ! new body ?us f\nd ! "n ( radium 0 giv54 ,x is simil> 9 *emical prop]ties to b>ium4 ,its atomic weight has be5 det]m9$ by sev]al c>eful inve/igators & is accept$ z #bbf4 ,its spectrum has be5 mapp$ & its g5]al prop]ties are kn[n4 ,x is a silv]y :ite1 oxidizable metal4 ,9 "o ton ( pit*bl5de ab\t #j4b gram ( radium is pres5t2 ?is is ab\t #ejjj times great] ?an ! am\nt ( polonium pres5t4 ,! activity ( ! products 0 dep5d$ ^u z ! guide 9 ^! sep>ations4 ,! radium f\nd is relatively enorm\sly m active ?an ! pit*bl5de or uranium4 ,o!r ,radio-active ,bodies ,f\nd ,9 ! above sep>ations use 0 made ( relation%ips to bismu? & b>ium4 ,simil>ly1 by tak+ advantage ( *emical relation%ip to ! iron gr\p ( elem5ts1 ano!r body 0 p>tially sep>at$ by ,debi]ne1 to :i* he gave ! "n act9ium4 ,boltwood discov]$ 9 uranium m9]als ! pres5ce ( a body :i* he nam$ ionium1 & :i* is s simil> to ?orium t x _c be sep>at$ f x4 ,x1 h[ev]1 f> exce$s ?orium 9 activity4 ,! lead :i* is pres5t 9 uranium & ?orium m9]als--app>5tly 9 fairly def9ite ratio to ! am\nt ( uranium & ?orium--is f\nd1 on sep>ation & purification1 to possess radio-active prop]ties4 ,?is activity is due to ! pres5ce ( a v small proportion ( an active con/itu5t call$ radio-lead1 :i* has *emical prop]ties id5tical ) ^? ( ord9>y lead4 ,! bulk ( ! lead obta9$ f radio-active m9]als diff]s 9 atomic weight f ord9>y lead & appe>s also to be diff]5t accord+ to :e!r its s\rce is a ?orium or a uranium m9]al4 ,a l>ge numb] ( o!r radio-active sub/ances h be5 sep>at$ & "s ( _! prop]ties det]m9$1 b ^! 7 f\nd by diff]5t means & w be not$ 9 _! prop] place4 ,!y numb] 9 all m ?an ?irty4 ,! s\rces or p>5ts ( ^! are ! orig9al uranium or ?orium1 & ! products =m regul> s]ies ) di/9ctive prop]ties = ea* memb]4 ,,*apt] ,,ii ,,prop]ties ,,( ,,! ,,radiations ,! activity ( ^! radio-active bodies consi/s 9 ! emission ( c]ta9 radiations :i* may be sep>at$ into rays & /udi$ ?r\gh ! ph5om5a :i* !y cause4 ,ionization ( ,gases ,"o ( ^! ph5om5a is ! p[] ( =m+ ions or c>ri]s ( electricity by ! passage ( ! rays ?r\gh a gas1 ?us ioniz+ ! gas4 ,! details ( an exp]im5t w s]ve to make ! mean+ ( ?is ionization cle>4 ,illu/ration3 ,,fig4 #a4--;,,ionization ,,( ,,gases4 ,:5 ?is app>atus is set up a m9ute curr5t w be obs]v$ )\t ! introduction ( any radio-active matt]4 ,?is1 z ,ru!r=d says1 has be5 f\nd due ma9ly to a slight natural radio-activity ( ! matt] compos+ ! plates4 ,if radio-active matt] is spread on plate ,a1 :i* is connect$ ) "o pole ( a gr\nd$ batt]y1 & if plate ,b is connect$ ) an electromet] :i* is also connect$ ) ! e>?1 a curr5t is caus$ :i* increases rapidly ) ! diff]5ce ( pot5tial betwe5 ! plates1 !n m sl[ly until a value is rea*$ t *anges only slightly ) a l>g] increase 9 ! voltage4 ,accord+ to ! !ory ( ionization1 ! radiation produces ions at a con/ant rate4 ,! ions c>ry+ a positive *>ge are attract$ to plate ,b1 :ile ^? negatively *>g$ are attract$ to plate ,a1 ?us caus+ a curr5t4 ,^! ions w recomb9e & neutralize _! *>ges if ! opportunity is giv54 ,! numb]1 !re=e1 increases to a po9t at :i* ! ions produc$ balance ! numb] recomb9+4 ,:5 an electric field is produc$ betwe5 ! plates1 ! velocity ( ! ions betwe5 ! plates is increas$ 9 proportion to ! /r5g? ( ! electric field4 ,9 a weak field ! ions travel s sl[ly t mo/ ( !m recomb9e on ! way & consequ5tly ! obs]v$ curr5t is v small4 ,on increas+ ! voltage ! spe$ ( ! ions is increas$1 few] recomb9e1 ! curr5t increases1 &1 :5 ! condition = recomb9ation is practically remov$1 x w h a maximum value4 ,?is maximum curr5t is call$ ! saturation curr5t & ! value ( ! pot5tial diff]5ce requir$ to give ?is maximum curr5t is call$ ! saturation ,p4,d4 or saturation voltage4 ,! picture1 !n1 is ?is4 ,! radiations sep>ate ! compon5ts ( ! gas into ions1 or c>ri]s ( electricity1 half ( :i* are *>g$ negatively & half positively4 ,9 ! electric field ^? negatively *>g$ seek ! positive plate & ^? positively *>g$ seek ! negative plate4 ,if "t is giv51 ^! ions meet & recomb9e1 _! *>ges are neutraliz$1 & !re is no curr5t4 ,exp]im5tal ,confirmation ,?is !ory ( ! ionization ( gases has be5 mo/ int]e/+ly confirm$ by direct exp]im5t4 ,= in/ance1 ! ions may =m nuclei = ! cond5sation ( wat]1 & 9 ?is way ! exi/5ce ( ! sep>ate ions 9 ! gas may be %[n & ! numb] pres5t actually c\nt$4 ,:5 air saturat$ ) wat] vapor is all[$ to exp& sudd5ly1 ! wat] pres5t =ms a mi/ ( small globules4 ,!re are always small du/ p>ticles 9 air & ar\nd ^! z nuclei ! drops are =m$4 ,^! drops w settle & ?us by repeat$ small expansions all du/ nuclei may be remov$ & no mi/ or cl\d w be =m$ by fur!r expansions4 ,if n[ ! radiation f a radio-active body be introduc$ into ! cond5sation vessel1 a new cl\d is produc$ 9 :i* ! wat] drops are f9] & m num]\s accord+ to ! int5sity ( ! rays4 ,on pass+ a /rong beam ( light ?r\gh ! cond5sation *amb]1 ! drops c readily be se54 ,^! drops =m on ! ions produc$ by ! radiation4 ,application ( ,electric ,field ,if ! cond5sation *amb] has two p>allel plates = ! application ( an electric field l t already describ$1 ! ions w be c>ri$ at once to ! electrodes & disappe>4 ,! rapidity ( ?is action dep5ds ^u ! /r5g? ( ! electric field & exp]im5t %[s t ! /rong] ! field ! small] ! numb] ( cond5sation drops =m$4 ,if !re is no electric field1 a cl\d c be produc$ "s "t aft] ! %utt+ (f ( ! s\rce ( radiation1 %[+ t "t is requir$ = ! recomb9ation ( ! ions4 ,size & ,nature ( ,ions ,if ! drops are c\nt$ 7!re be+ special me?ods = ?is7 & ! total curr5t c>ri$ accurately measur$1 !n ! *>ge c>ri$ by ea* ion may be calculat$4 ,?is has be5 det]m9$4 ,! mass ( an ion comp>$ ) ! mass ( ! molecules ( gas 9 :i* x 0 produc$ c also be approximately e/imat$4 ,9 ! /udy ( ^! ions ! view has be5 held t ! *>g$ ion attract$ to itself a clu/] ( molecules :i* surr\nd$ ! *>g$ nucleus & travel$ ) x4 ,x is r\ghly e/imat$ t ab\t ?irty molecules ( ! gas clu/] ar\nd ea* *>g$ ion4 ,photograph+ ! ,track ( ! ,ray ,utiliz+ ! fact t ^! ions ) _! clu/]s ( molecules =m nuclei = ! cond5sation ( wat] vapor1 ,c4 ,t4 ,r4 ,wilson has by in/antane\s photography be5 able to photograph ! track ( an ioniz+ ray ?r\gh air4 ,! numb] ( ! ions produc$1 & h5ce ! numb] ( drops1 is s great t ! trail is %[n z a cont9u\s l9e4 ,9 ! copy ( ?is photograph x w be se5 t at "s di/ance f its s\rce ! /raight trail is slightly b abruptly b5t4 ,ne> ! end ( its c\rse !re is ano!r abrupt & mu* %>p] b5d4 ,^! b5ds %[ :]e ! ioniz+ ray1 9 ?is case an alpha p>ticle1 has be5 deflect$ by m or less direct collision ) an atom4 ,^! collisions & ! f9al disappe>ance ( ! ray w be discuss$ lat]4 ,illu/ration3 ,,fig4 #b4--,,photograph ,,( ,,! ,,track ,,( ,,an ,,ioniz+ ,,ray4 ,action ( ,radiations on ,photographic ,plates ,tak+ up n[ o!r means ( exam9+ ^! radiations1 x is well to consid] _! action ^u a photographic or s5sitive plate4 ,x w be recall$ t ?is 0 ! me?od by :i* _! exi/5ce 0 orig9ally detect$4 ,to illu/rate ! me?od1 ! foll[+ acc\nt ( h[ "o su* photograph 0 tak5 may be giv54 ,! plate 0 wrapp$ 9 two ?icknesses ( black pap]4 ,! objects 7 plac$ ^u ?is & ! radio-active ore1 sep>at$ by a bo>d "o in* ?ick1 0 plac$ above4 ,! exposure la/$ five days4 ,! action is mu* less rapid & ! result n s cle>ly def9$ z 9 ! case ( photographs tak5 by ,x rays4 ,( c\rse1 ! removal ( ! bo>d & ! use ( m conc5trat$ prep>ations ( radium w\ld give quick] & bett] results4 ,! me?od1 h[ev]1 on acc\nt ( "t consum$ & lack ( def9ition is ill adapt$ to accurate "w4 ,illu/ration3 ,,fig4 #c--,,photograph ,,( ,,v>i\s ,,objects ,,tak5 ,,by ,,means ,,( ,,pit*bl5de ,dis*>ge ( ,electrifi$ ,bodies ,! radiations f radio-active bodies c dis*>ge bo? positively & negatively electrifi$ bodies by mak+ ! air surr\nd+ !m a conductor ( electricity4 ,to demon/rate ?is1 use is made ( an electroscope4 ,if ! h+$ leaf ( su* an in/rum5t be electrically *>g$ & a radio-active body be br\ght into its neighborhood1 ! electricity w be dis*>g$ & ! leaf return to its orig9al position4 ,! rapidity ( ?is dis*>ge is us$ to measure ! degree ( activity ( ! body giv+ (f ! radiation4 ,illu/ration3 ,,fig4 #d4--;,,gold-,,leaf ,,electroscope4 ,! gold-leaf ,l is atta*$ to a flat rod ,r & is insulat$ inside ! vessel by a piece ( amb] ,s support$ f ! rod ,p4 ,! sy/em is *>g$ by a b5t rod ,,cc' pass+ ?r\gh an ebonite /opp]4 ,aft] *>g+1 x is remov$ f contact ) ! gold-leaf sy/em4 ,! rods ,p & ,c & ! cyl9d] are !n connect$ ) ! e>?4 ,sc9tillations on ,phosphoresc5t ,bodies ,x 0 f\nd by ,crookes t a scre5 cov]$ ) phosphoresc5t z9c sulphide 0 brightly light$ up :5 expos$ to ! radiations4 ,?is is due to ! bomb>dm5t ( ! z9c sulphide by a type ( ray call$ ! alpha ray4 ,"u a magnify+ glass ?is light is se5 to be made up ( a numb] ( sc9tillat+ po9ts ( light & is n cont9u\s1 ea* sc9tillation be+ ( v %ort duration4 ,by prop] subdivision ( ! field "u ! l5s1 ! numb] ( sc9tillations c be c\nt$ ) close accuracy4 ,a simple =m ( app>atus call$ ! sp9?>iscope has be5 devis$ to %[ ^! sc9tillations4 ,a z9c sulphide scre5 is fix$ 9 "o end ( a small tube & a plate c>ry+ a trace ( radium is plac$ v close to x4 ,! sc9tillations c be obs]v$ ?r\gh an adju/able l5s at ! o!r end ( ! tube4 ,out] light %\ld be cut (f1 z 9 a d>k room4 ,! scre5 !n appe>s to be cov]$ ) brilliant fla%es ( light4 ,o!r phosphoresc5t sub/ances1 su* z b>ium plat9o-cyanide1 may be sub/itut$ = ! z9c sulphide1 b !y d n answ] s well4 ,p5etrat+ ,p[] ,by p5etrat+ p[] is meant ! p[] exhibit$ by ! rays ( pass+ ?r\gh solids ( diff]5t ?icknesses & gases ( v>i\s dep?s4 ,?is p[] v>ies ) diff]5t radiations & ) ! nature ( ! solid or gas4 ,= in/ance1 a %eet ( metallic foil may be us$ & ! effect ( alum9um w diff] f t ( gold & ! diff]5t rays v>y 9 p5etrat+ p[]4 ,9 ! case ( gases air w diff] f hydrog51 & x is notic$ t c]ta9 rays disappe> aft] p5etrat+ a %ort di/ance1 :ile o!rs c p5etrate fur!r be=e be+ lo/4 ,magnetic ,deflection ,if ! radiations are subject$ to ! action ( a /rong magnetic field1 x is f\nd t "p ( !m are mu* deflect$ 9 ! magnetic field & describe circul> orbits1 "p are only slightly deflect$ & 9 ! opposite direction f ! fir/1 & ! rema9+ rays are entirely unaffect$4 ,illu/ration3 ,,fig4 #e4--,,%[+ ,,magnetic ,,deflection ,,( alpha1 beta1 ,,& gamma ,,rays4 ,?ree ,types ( ,rays ,by ! use ( ^! me?ods ( inve/igation x is le>n$ t ! radiations consi/ ( ?ree types ( rays4 ,^! h be5 nam$ ! alpha1 beta1 & gamma rays1 respectively4 ,"s radio-active bodies emit all ?ree types1 "s two1 & "s only "o4 ,! di/+ui%+ *>act]i/ic ( ^! types ( rays may be summ$ up z foll[s3 ,alpha ,rays ,! alpha rays h a positive electrical *>ge & a comp>atively l[ p5etrat+ p[]4 ,!y are slightly deflect$ 9 /rong magnetic & electric fields4 ,!y h a great ioniz+ p[] & a velocity ab\t "o-fifte5? t ( light4 ,beta ,rays ,! beta rays are negatively *>g$ & h a great] p5etrat+ p[] ?an ! alpha rays4 ,!y %[ a /rong deflection 9 magnetic & electric fields1 h less ioniz+ p[] ?an ! alpha rays1 & a velocity ( ! same ord] z light4 ,gamma ,rays ,! gamma rays are v p5etrat+ & are n deflect$ 9 ! magnetic or electric fields4 ,!y h ! lea/ ioniz+ p[] & a v great velocity4 ,! p5etrat+ p[] ( ea* type is complex & v>ies ) ! s\rce1 s ! /atem5ts giv5 are b g5]alizations4 ,! alpha rays are project$ p>ticles :i* lose en]gy 9 p5etrat+ matt]4 ,z to ! p[] ( ioniz+ gases1 if t = ! alpha rays is tak5 z #aj1jjj1 !n ! beta rays w\ld be approximately #ajj & ! gamma rays #a4 ,measurem5t ( ,radiations ,! rays are exam9$ & measur$ 9 sev]al ways3 #a4 ,by _! action on ! s5sitive photographic plates4 ,! use ( ?is me?od is labori\s1 consumes "t1 & = comp>ative measurem5ts ( int5sity is unc]ta9 z to effect4 #b4 ,by electrical me?ods1 us+ electroscopes1 quadrant electromet]s1 etc4 ,^! are ! me?ods mo/ us$4 #c4 ,by exposure to magnetic & electric fields1 not+ ext5t & direction ( deflection4 #d4 ,by _! relative absorption by solids & gases4 #e4 ,by ! sc9tillations on a z9c sulphide scre54 ,id5tification ( ! ,rays ,! alpha rays h be5 id5tifi$ z simil> to ! s-call$ canal rays4 ,^! 7 fir/ obs]v$ 9 ! /udy ( ! ,x rays4 ,:5 an electrical dis*>ge is pass$ ?r\gh a vacuum tube ) a ca?ode hav+ holes 9 x1 lum9\s /reams pass ?r\gh ! holes t[>d ! side away f ! anode & ! g5]al direction ( ! /ream4 ,!y travel 9 /raight l9es & r5d] c]ta9 sub/ances phosphoresc5t4 ,^! rays are slightly deflect$ by a magnetic field & 9 an opposite direction f t tak5 by ! ca?ode rays 9 _! deflection4 ,! rays seem to be positive ions ) masses nev] less ?an t ( ! hydrog5 atom4 ,_! s\rce is unc]ta91 b !y may be d]iv$ f ! electrodes4 ,! beta rays are id5tical 9 type ) ! ca?ode rays & are negative electrons4 ,! gamma rays are analog\s to ! ,x rays & are ( ! ord] ( light4 ,!y are 9 g5]al consid]ably m p5etrat+ ?an ,x rays4 ,= example1 ! gamma rays s5t out by #cj milligrams ( radium c be detect$ by an electroscope aft] pass+ ?r\gh #cj c5timet]s ( iron1 a mu* great] ?ickness ?an c be p5etrat$ by ! ord9>y ,x rays4 ,,*apt] ,,iii ,,*anges ,,9 ,,radio-,,active ,,bodies ,is ,radio-activity a ,p]man5t ,prop]ty8 ,is ?is p[] ( emitt+ radiations a p]man5t prop]ty or is x lo/ ) ! passage ( "t8 ,! fir/ inve/igations ( ! activity ( uranium & ?orium %[$ no loss ( int5sity at ! end ( sev]al ye>s1 & radium also seem$ to %[ no decrease 9 its enorm\s activity4 ,polonium1 h[ev]1 0 f\nd to lose mo/ ( its activity 9 a ye>1 & lat] x appe>$ t "s radio-active sub/ances lo/ mo/ ( _! activity 9 ! c\rse ( a few m9utes or h\rs4 ,induc$ ,activity ,a ph5om5on call$ induc$ or second>y radio-activity 0 also obs]v$4 ,?us a metal plate or wire expos$ to ! action ( ?orium oxide = "s h\rs became itself active4 ,?is induc$ activity 0 n p]man5t b decreas$ to half its value 9 ab\t elev5 h\rs & practically disappe>$ )9 a week4 ,simil> ph5om5a 7 obs]v$ :5 radium 0 sub/itut$ = ?orium4 ,discov]y ( ,uranium ,x ,9 #aijj ,crookes precipitat$ a solution ( an active uranium salt ) ammonium c>bonate4 ,! precipitate 0 dissolv$ s f> z possible 9 an excess ( ! reag5t1 leav+ an insoluble residue4 ,?is residue 0 _m hundr$ times m active1 weight = weight1 ?an ! orig9al salt1 & ! solution conta9+ ! salt 0 practically inactive4 ,at ! end ( a ye> ! uranium salt _h rega9$ its activity :ile ! residue _h become inactive4 ,ano!r me?od ( obta9+ ! same result is to dissolve cry/alliz$ uranium nitrate 9 e!r4 ,two lay]s ( solution are =m$1 "o e!r & ! o!r wat] com+ f ! wat] ( cry/allization4 ,! aque\s lay] is active1 :ile ! wat] lay] is inactive4 ,simil>ly1 by add+ b>ium *loride solution to a solution ( a salt ( uranium & !n precipitat+ ! b>ium z sulphate1 ! activity is transf]r$ to ?is precipitate4 ,^! exp]im5ts give pro( ( ! =mation & sep>ation ( a radio-active body by ord9>y *emical op]ations4 ,s1 too1 9 ! case ( ?orium salts a sub/ance c be obta9$ by means ( ammonium hydroxide :i* is sev]al ?\s& times m active ?an an equal weight ( ! orig9al salt4 ,aft] /&+ a mon?1 ! sep>at$ mat]ial has lo/ its activity & ! ?orium salt has rega9$ x4 ,"h1 aga91 !re is ! =mation1 sep>ation1 & loss ( a radio-active body4 ,conclusions ,drawn ,n[1 ^! are ord9>y *emical processes = ! sep>ation ( di/9ct *emical individuals4 ,! results1 !re=e1 lead naturally to ! conclusions3 7#a7 x w\ld seem t uranium & ?orium are !mselves inactive & ! activity is due to "s o!r sub/ance =m$ by ^! elem5ts2 7#b7 ?is active sub/ance is produc$ by "s trans=mation 9 ^? elem5ts1 = on /&+ ! activity is rega9$4 ,?is latt] conclusion is />tl+1 = x indicates a *ange 9 ! atom :i*1 up to ! "t ( ?is discov]y1 0 deem$ un*angeable "u ! influ5ce ( su* physical & *emical *anges z 7 kn[n to u4 ,se>* = ,new ,radio-active ,bodies ,! se>* = new radio-active bodies & ! /udy ( _! *>act]i/ics has be5 sy/ematically & successfully c>ri$ on4 ,! bodies obta9$ 9 ! above exp]im5ts 7 nam$ uranium ,x & ?orium ,x1 respectively4 ,fur!r1 x became cle> f ! inve/igation ( uranium m9]als t radium1 polonium1 act9ium1 & ionium orig9at$ f uranium4 ,f ?orium m9]als a body 0 sep>at$ call$ meso?orium1 :i* 0 analog\s to radium4 ,bo? ?orium & radium 7 f\nd to give (f a radio-active gas4 ,! fir/ lo/ half ( its activity 9 less ?an "o m9ute4 ,! second 0 m /able & lo/ half ( its activity 9 ab\t f\r days4 ,! "n radium emanation 0 giv5 to ! latt] & x 0 f\nd *emically & physically to belong to ! class ( monatomic or noble gases1 su* z helium1 argon1 neon1 etc41 :i* _h be5 discov]$ by ,ramsay4 ,9 "s cases ! *emical action 0 det]m9$ & ^! new bodies 7 f\nd analog\s to well-kn[n elem5ts1 z radium to b>ium1 polonium to bismu?4 ,! physical prop]ties 7 inve/igat$ &1 :]e possible1 spectra 7 mapp$ & atomic weights det]m9$4 ,x is cle>1 !re=e1 t ^! bodies are elem5tal 9 "* & z su* are made up ( di/9ct1 simil> atoms1 j z ! commonly recogniz$ elem5ts are believ$ to be4 ,9 ?is way m ?an ?irty new elem5ts h be5 add$ to ! li/4 ,^! new elem5ts are call$ radio-active elem5ts1 b x is an op5 "q :e!r all atoms d n possess ?is prop]ty 9 great] or less degree4 ,c]ta9ly1 x is possess$ 9 v>y+ degree by f\r ( ! old elem5ts widely sep>at$ 9 ! ,p]iodic ,sy/em1 namely1 uranium1 ?orium1 rubidium1 & potassium4 ,! la/ two1 :ile feebly active !mselves1 d n =m any second>y radio-active sub/ance s f> z is kn[n4 ,only two ( ! elem5ts1 !n1 c def9itely be said to g ?r\gh ^! trans=mations4 ,x is j possible t radio-activity may be f\nd to be a common prop]ty ( all atoms & ( all matt]4 ,me?ods ( ,inve/igation ,x is important to "k h[ ^! new bodies 7 discov]$ & di/+ui%$ f "o ano!r4 ,two prop]ties are reli$ ^u4 ,"o is ! nature ( ! rays emitt$ & ! o!r is ! duration ( ! activity4 ,( c\rse1 k ( ! physical & *emical prop]ties is also ( great importance :5ev] obta9able4 ,nature ( ! ,radiations ,! nature ( ! radiation is a di/+ui%+ *>act]i/ic1 ?\gh simil>ity "h does n prove id5tity ( sub/ances4 ,"s emit alpha rays only1 "s emit beta rays1 "s emit two ( ! possible rays1 z = in/ance1 beta & gamma1 & "s emit all ?ree4 ,! rays may also diff] 9 ! velocity ) :i* !y are emitt$ by diff]5t radio-active sub/ances4 ,?us1 9 ! case ( "o sub/ance ! alpha rays may h a slightly great] or less p5etrat+ p[] ?an ^? emitt$ by "s o!r sub/ance1 & ?is may be true also ( ! o!r rays4 ,life ,p]iods ,! duration ( ! activity is call$ ! life p]iod4 ,?is is absolutely fix$ = ea* body & furni%es ! mo/ important mode ( diff]5tiat+ among !m4 ,x measures ! relative /ability & is ! "t :i* mu/ elapse be=e _! activity is lo/ & !y1 *ang+ into some?+ else1 entirely disappe>4 ,! measure usually adopt$ is ! half-value p]iod4 ,two hypo!ses are made use (3 #a4 ,t !re is a con/ant production ( fre% radio-active matt] by ! radio-active body4 #b4 ,t ! activity ( ! matt] s =m$ decreases accord+ to an expon5tial law ) ! "t f ! mom5t ( its =mation4 ,^! hypo!ses agree ) ! exp]im5tal results4 ,! decrease & rise ( activity1 = example1 ( uranium & uranium ,x1 & also ( ?orium & ?orium ,x1 h be5 measur$1 plott$1 & ! equations work$ out4 ,manife/ly1 a /ate ( equilibrium w be rea*$ :5 ! rate ( loss ( activity ( ! matt] already produc$ is balanc$ by ! activity ( ! new matt] produc$4 ,?is equilibrium & ! k ( ! rate ( decrease 9 g5]al w h little value if ?is rate1 l *emical *anges1 is subject to ! influ5ce ( *emical & physical conditions4 ,! rate ( decrease has be5 f\nd to be unalt]$ by any kn[n *emical or physical ag5cy4 ,= in/ance1 nei!r ! highe/ temp]atures applicable nor ! cold ( liquid air h any appreciable effect4 ,equilibrium ,s]ies ,9 ord] to measure ! dis9tegration ( a radio-active body 9 units ( "t s t ! rate may be comp>able ) t ( o!r radio-active bodies1 ! relation betwe5 ! am\nts "u consid]ation mu/ be a def9ite "o4 ,= ?is purpose equal weights ( ! bodies are n tak51 b use is made ( ! am\nts :i* are 9 equilibrium ) a fix$ am\nt ( ! p>5t sub/ance4 ,"o gram ( radium has be5 settl$ ^u z ! /&>d = t s]ies & a unit kn[n z ! curie has be5 adopt$ to express ! equilibrium quantity ( radium emanation4 ,?us1 a curie ( radium emanation 7or niton7 is ! weight 7or1 z ?is is a gas1 ! volume at /&>d pressure & temp]ature7 ( ! emanation 9 equilibrium ) "o gram ( radium4 ,?is1 by calculation & exp]im5t1 is f\nd to be #j4fc cubic millimet]4 ,:5 ?is am\nt has be5 produc$ by "o gram ( radium1 ! =mation & decay w exactly balance "o ano!r4 ,?is is1 !re=e1 "o curie ( emanation4 ,! measurem5t ( ! rate ( decay is difficult b c be c>ri$ out ) great accuracy1 ev5 d[n to seconds1 9 ! case ( c]ta9 %ort-liv$ bodies4 ,errors crept 9 at fir/ f ! failure to completely sep>ate ! sub/ances produc$ 9 ! s]ies1 & sometimes because ( ! simultane\s production ( two sub/ances4 ,z /at$1 ! decay foll[s an expon5tial law4 ,! "t requir$ = ! decay ( activity to half-value does n mean1 !re=e1 t !re w be total decay 9 twice t "t4 ,?us ! half-value p]iod = uranium ,x is ab\t #bb days4 ,! p]iod = complete decay is ab\t #afj days4 ,?is half-value p]iod corresponds to ! half-value recov]y p]iod ( uranium1 :i* is also #bb days4 ,^! 7 ! e>li] figures obta9$ = uranium ,x & !y illu/rate "s ( ! difficulties surr\nd+ su* det]m9ations4 ,x 0 f\nd lat] t ! body exam9$ z uranium ,x 0 really a con/ant mixture & ( c\rse ! decay & recov]y p]iods 7 also composite4 ,x requir$ lat] & v skilful "w to sep>ate !m into ! bodies indicat$ 9 ! dis9tegration s]ies4 ,! half-value p]iod = ?orium ,x is mu* %ort]1 namely1 a little ov] f\r days1 & ?is is also ! recov]y p]iod = ?orium ,x4 ,! plott$ decay & recov]y curves w int]sect at ?is po9t4 ,! consecutive dis9tegration s]ies1 ) ! half-value p]iods1 = ! uranium & ?orium s]ies z giv5 by ,soddy are se5 9 ! foll[+ tables4 ,!y are probably subject to "s *anges on fur!r & m accurate det]m9ation4 ,! nature ( ! rays emitt$ is also giv54 ,illu/ration3 ,uranium 7#h #aji ye>s7 #bch4e - alpha - alpha _/ ,uranium ,x 7#ce4e days7 7#bcj4e7 - betagamma - 7beta7 _/ _/ _/ ,ionium 7#e #ajd to #ajf ye>s7 7#bcj4e7 - alpha _/ ,radium 7#b1ejj ye>s7 #bbf4d - alpha _/ ,emanation 7#e4eg days7 7#bbb4d7 - alpha _/ ,radium ,a 7#d4c m9utes7 7#bah4d7 - alpha _/ ,radium ,b 7#ch4e m9utes7 7#bad4d7 - 7beta7 _/ ,radium ,c#a 7#bh4a m9utes7 7#bad4d7 - alpha - betagamma _/ ,radium ,c#b 7#a4i m9utes7 7#baj4d7 - betagamma _/ ,radium ,d 7#bd ye>s87 7#baj4d7 - 7beta7 _/ ,radium ,e 7#g4be days7 7#baj4d7 - betagamma _/ ,radium ,f 7,polonium #bjb days7 7#baj4d7 - alpha _/ ,radium ,g 7probably lead7 7#bjf4h7 ,act9ium 787 _/ ,radio-,act9ium 7#bh4a days7 - alpha - 7beta7 _/ ,act9ium ,x 7#ae days7 - alpha _/ ,emanation 7#e4f seconds7 - alpha _/ ,act9ium ,a 7#j4jjbi second7 - alpha _/ ,act9ium ,b 7#eb4a m9utes7 - 7beta7 _/ ,act9ium ,c#a 7#c4aj m9s47 - alpha _/ ,act9ium ,c#b 787 - alpha _/ ,act9ium ,d 7#g4d m9utes7 - betagamma _/ ,act9ium ,e 7unkn[n7 ,?orium 7#d #ajaj ye>s87 #bcb4d - alpha787 _/ ,meso?orium#a 7#g4i ye>s7 _/ ,meso?orium#b 7#h4i h\rs7 - betagamma _/ ,radio?orium 7#b4ia ye>s87 - alpha _/ ,?orium ,x 7#e4ce days7 - alpha _/ ,emanation 7#gf seconds7 - alpha _/ ,?orium ,a 7#j4bjc second7 - alpha _/ ,?orium ,b 7#ae4c h\rs7 - 7beta7 _/ ,?orium ,c#a 7#gi m9utes7 - alpha _/ ,?orium ,c#b 787 - alpha _/ ,?orium ,d 7#d4e m9utes7 - betagamma _/ ,?orium ,e 7unkn[n7 ,,fig4 #f4--;,,dis9tegration ,,s]ies ,,= ,,uranium1 ,,act9ium1 ,,& ,,?orium1 ,,z ,,giv5 ,,by ,,soddy4 ,,*apt] ,,iv ,,nature ,,( ,,! ,,alpha ,,p>ticle ,dis9tegration ( ! ,elem5ts ,! rem>kable dis9tegrations relat$ 9 ! la/ *apt]1 9 :i* ! heavie/ kn[n elem5t>y atom--t ( uranium 7at4 wt4 #bch7--;is by successive /ages *ang$ into o!rs ( l[] atomic weight1 af=d a clue to ! nature ( ! atom & to t goal ( ! *emi/1 ! f9al con/itution ( matt]4 ,! composite nature ( ! atom & "s sort ( int]relation ( ! elem5ts _h previ\sly be5 made app>5t f a /udy ( ! ,p]iodic ,sy/em & data ga!r$ /ill e>li]1 b all attempts at work+ out a s-call$ g5esis ( ! elem5ts _h prov$ vague & unsatisfactory4 ,id5tification ( ! ,rays ,to get an und]/&+ ( ! dis9tegration occurr+ 9 radio-active sub/ances1 ! nature ( ! rays produc$ mu/ be kn[n4 ,^! rays are ! cause ( ! activity & _! emission accompanies ! *anges or dis9tegration4 ,!y h = ! sake ( conv5i5ce be5 call$ ! alpha1 beta1 & gamma rays4 ,! gamma rays h be5 id5tifi$ ) ! ,x rays discov]$ by ,rntg5 & are a =m ( en]gy analog\s to light4 ,! beta rays are p>ticles ( negative electricity or electrons4 ,) ^!1 !n1 we h "s degree ( famili>ity4 ,b :at are ! alpha rays8 ,an answ] to ?is "q %\ld make cle>] ! "* ( ! *anges tak+ place1 & %\ld give "s insight into ! composition & me*anism ( ! atom4 ,! ,alpha ,rays ,x has already be5 /at$ t ^! alpha rays are simil> or analog\s to ! canal rays1 b ?is advances ! matt] v little1 z ! nature ( ^! canal rays has n be5 fully det]m9$4 ,! full id5tity ) !m1 if prov$1 %\ld h an important !oretical be>+4 ,alpha ,rays ,consi/ ( ,solid ,p>ticles ,9 ! fir/ place1 ^! alpha rays h be5 f\nd to be made up ( solid p>ticles1 t is1 ( :at we are accu/om$ to call matt]4 ,s9ce x has become m & m difficult to draw a cle> di/9ction betwe5 matt] & en]gy1 x w\ld p]haps be bett] to say t ^! p>ticles appe> to h "s ( ! prop]ties hi!rto attribut$ solely to matt]4 ,! be/ evid5ce t ^! p>ticles are ( atomic mass is furni%$ by _! deflection 9 electric & magnetic fields4 ,electrical ,*>ge ,x is n ( fir/ importance to discuss ?is or o!r pro(s ( ! mat]ial nature ( ^! p>ticles4 ,t !y c>ry a *>ge ( positive electricity is1 h[ev]1 a fact ( v great import4 ,! value ( ?is *>ge has be5 c>efully det]m9$ by a numb] ( inve/igators work+ ) diff]5t s\rces ( ! alpha p>ticles & has be5 f\nd to be #i4c #aj-aj electro/atic units 74#jjj1jjj1jjj1ic e4s474 ,f ! consid]ation ( ! *>ge ^u an electron previ\sly obta9$ by ,j4 ,j4 ,?omson & o!rs1 x 0 conclud$ t ! alpha p>ticle c>ri$ two unit positive *>ges2 ! fundam5tal unit *>ge1 !re=e1 is half ?is value1 or #d4fe #aj-aj e4s4 ,helium ,=m$ f ,alpha ,p>ticles ,to det]m9e ! nature ( ! alpha p>ticle a crucial exp]im5t 0 c>ri$ out by ,ru!r=d & ,royds1 :i* 0 describ$ z foll[s3 ,illu/ration3 ,,fig4 #g4--;,,app>atus ,,us$ ,,9 ,,exp]im5t ,,by ,,ru!r=d ,,& ,,royds4 ,a l>ge quantity ( radium emanation 0 compress$ into a f9e glass tube ,a1 ab\t #a4e cm4 long4 ,?is tube1 :i* 0 seal$ to a l>g] capill>y tube ,b1 0 suffici5tly ?9 to all[ ! alpha p>ticles f ! emanation & its products to pass ?r\gh1 b suffici5tly ?ick to )/& atmosph]ic pressure4 ,! ?ickness ( ! glass wall 0 9 mo/ cases less ?an 4#ja mm4 ,on introduc+ ! emanation into ! tube1 ! escape ( ! alpha p>ticles f ! emanation 0 cle>ly se5 by ! sc9tillations produc$ at "s di/ance on a z9c sulphide scre54 ,aft] ?is te/ ! glass tube ,a 0 surr\nd$ by a glass tube ,t & a small spectrum tube ,v atta*$ to x4 ,! tube ,t 0 exhau/$ to a *>coal vacuum4 ,by means ( ! m]cury column ,h1 ! gases 9 ! tube ,t c\ld at any "t be compress$ into ! spectrum tube ,v & ! nature ( ! gases :i* _h be5 produc$ det]m9$ spectroscopically4 ,x 0 f\nd t two days aft] ! introduction ( ! emanation into ,a ! spectrum %[$ ! yell[ l9e ( helium1 & aft] six days ! :ole helium spectrum 0 obs]v$4 ,9 ord] to be c]ta9 t ! helium1 com+ possibly f "s o!r s\rce1 _h n diffus$ ?r\gh ! ?9 walls ( ! tube ,a1 ! emanation 0 pump$ out & helium sub/itut$4 ,no trace ( helium c\ld be obs]v$ 9 ! vacuum tube aft] sev]al days1 %[+ t ! helium obs]v$ 9 ! fir/ exp]im5t mu/ h orig9at$ f ! alpha p>ticles :i* _h be5 propell$ ?r\gh ! ?9 glass tube into ! out] tube4 ,mo/ ( ! alpha p>ticles are propell$ ) su* =ce t !y p5etrate "s di/ance into ! walls ( ! out] tube & "s ( ^! gradually diffuse out into ! exhau/$ space4 ,! pres5ce ( helium 9 ! spectrum tube c be detect$ aft] a %ort] int]val if a ?9 cyl9d] ( lead is plac$ ov] ! emanation tube1 s9ce ! p>ticles fir$ into ! lead diffuse out m rapidly ?an f glass4 ,a /ill m def9ite pro( ( ! id5tity ( ! alpha p>ticle ) ! helium atom 0 obta9$ by remov+ ! out] glass tube ,t & plac+ a cyl9d] ( lead ov] ! emanation tube 9 ! op5 air4 ,helium 0 always detect$ 9 ! lead aft] x _h rema9$ sev]al h\rs ov] ! ?9 tube conta9+ a l>ge quantity ( ! emanation4 ,9 ord] to te/ = ! pres5ce ( helium 9 ! lead1 ! gases pres5t 7 releas$ by melt+ ! lead 9 a clos$ vessel4 ,!re c ?us be no d\bt t ! alpha p>ticle becomes a helium atom :5 its positive *>ge is neutraliz$4 ,?us ! *emi/ 0 af=d$ ! exp]i5ce ( ! build+ up ( at lea/ "o elem5t "u 8 obs]vation1 & bo? ! analysis & syn!sis ( matt] h be5 reveal$ ?r\gh ! discov]ies ( radio-activity4 ,discov]y ( ,helium ,x is ( int]e/ at ?is po9t to le>n some?+ ( ! hi/ory ( helium & its occurr5ce4 ,9 #ahfh !re 0 discov]$ by ,janss5 & ,locky] a bright yell[ l9e 9 ! spectrum ( ! sun's *romosph]e4 ,because ( its orig9 ! "n helium 0 giv5 to ! suppos$ new elem5t caus+ x4 ,lat] x 0 f\nd 9 ! spectra ( _m ( ! />s1 & because ( its pr$om9ance 9 "s ( ^! !y 7 call$ helium />s4 ,its exi/5ce on our planet 0 n detect$ = ne>ly ?irty ye>s4 ,9 #ahie1 9 connection ) ! discov]y ( argon 9 ! atmosph]e1 a se>* 0 made to see if ! latt] elem5t c\ld be obta9$ f m9]al s\rces4 ,9 analyz+ c]ta9 uranium m9]als ,hillebr& _h f\nd consid]able quantities ( a gas :i* he took to be a peculi> =m ( nitrog54 ,ramsay made a fur!r exam9ation ( ! gas com+ f ^! m9]als & ! spectroscope reveal$ ! yell[ l9e ( helium1 ?us at la/ prov+ ! pres5ce ( ?is elem5t on ! e>?4 ,x is kn[n n[ to be pres5t 9 ?orium m9]als1 9 ! wat]s ( radio-active wells1 & 9 m9ute am\nts 9 ! atmosph]e4 ,its occurr5ce 9 e case1 9 ! light ( ! exp]im5t describ$ above1 w\ld seem to be due to ! pres5ce ( radio-active *anges4 ,*>act]i/ics ( ,helium ,helium1 on acc\nt ( its *emical inactivity & physical prop]ties1 is class$ along ) argon1 neon1 krypton1 & x5on 9 ! z]o gr\p ( ! ,p]iodic ,sy/em1 & =ms ) !m ! monatomic1 in]t gases4 ,9 ?is class are n[ plac$ also ! ?ree radio-active gases1 emanat+ respectively f radium1 ?orium1 & act9ium4 ,^! are g5]ally kn[n z radium emanation1 ?orium emanation1 & act9ium emanation4 ,! fir/ m5tion$ 0 once call$ niton4 ,emanium 0 ! "n orig9ally propos$ by ,giesel = ! body n[ kn[n z act9ium4 ,! calculat$ rate ( production ( helium 9 ! s]ies 9 equilibrium ) "o gram ( radium is #aeh cubic millimet]s p] ye>4 ,?is corresponds q well ) ! exp]im5tal results4 ,table ( ,con/ants ,"s ( ! m important atomic & radio-active con/ants are giv5 9 ! foll[+ table4 ,!y are record$ "h to %[ h[ helpful ! /udy ( radio-activity has be5 9 work+ out ! composition ( matt]1 & to give "s idea ( ! magnitude ( ! numb]s & ! m9ut5ess ( ! quantities dealt )4 ,electric *>ge c>ri$ by ea* ,h atom 9 electrolysis #d4fe #aj-aj e4s4#a ,electric *>ge c>ri$ by ea* alpha p>ticle #i4c #aj-aj e4s4 ,numb] ( atoms 9 #a gram ( ,h #f4b #ajbc ,mass ( #a atom ( ,h #a4f #aj-bd gram ,numb] ( molecules p] cc4 ( any gas at /&>d pressure & temp]ature #b4gb #ajai ,numb] ( alpha p>ticles expell$ p] second p] gram ( radium itself #c4f #ajaj ,numb] ( alpha p>ticles expell$ p] second p] gram ( radium 9 equilibrium ) its products #ad4c #ajaj #a ,! expression #aj-aj means multiply+ by 4#jjj1jjj1jjj1a2 #ajaj means multiply+ by #aj1jjj1jjj1jjj4 ,,*apt] ,v ,,! ,,/ructure ,,( ,,! ,,atom ,prop]ties ( ,radium ,a /udy ( ! prop]ties ( radium w aid 9 ?r[+ light ^u ! "q z to ! build+ up ( ! atom4 ,fir/ to be consid]$ are ! usual prop]ties :i* di/+ui% an elem5t>y body4 ,metallic radium has be5 prep>$ by a me?od simil> to t us$ 9 ! prep>ation ( b>ium4 ,x is a pure :ite metal1 melt+ at #gjj1 & f> m volatile ?an b>ium4 ,x rapidly alt]s on exposure to ! air1 probably =m+ a nitride4 ,x en]getically decomposes wat] & ! product dissolves 9 ! wat]4 ,its atomic weight is #bbf4 ,radium =ms a s]ies ( salts analog\s 9 appe>ance & *emical action to ^? ( b>ium4 ,9 ! c\rse ( "t !y become color$1 especially if mix$ b>ium salts4 ,! radiations f radium produce m>k$ *emical effects 9 a numb] ( sub/ances4 ,c>bon dioxide is *ang$ into c>bon1 oxyg51 & c>bon monoxide1 & ! latt] is *ang$ into c>bon & oxyg54 ,ammonia is dissociat$ into nitrog5 & hydrog52 hydro*loric acid into *lor9e & hydrog54 ,oxyg5 is cond5s$ into ozone4 ,9 g5]al1 ! action ^u gases appe>s to be simil> to t ( ! sil5t electric dis*>ge4 ,wat] is decompos$ into hydrog5 & oxyg54 ,if moi/ radium *loride or a salt ( radium conta9+ wat] ( cry/allization is seal$ 9 a glass tube1 ! gradual accumulation ( hydrog5 & oxyg5 w bur/ ! tube4 ,! radiations rapidly decompose organic matt] ) ! evolution ( gases4 ,?us grease f /opcocks ( app>atus us$ ) radium or p>aff9 w give (f c>bon dioxide4 ,"u an int5se alpha radiation p>aff9 or vasel9e become h>d & infusible4 ,:ite phosphorus is *ang$ into r$4 ,! action ^u liv+ tissue is mo/ notewor?y1 z its possible use z a rem$ial ag5t is dep5d5t ^u ?is4 ,a small am\nt ( a radium salt enclos$ 9 a glass tube w cause a s]i\s burn on fle% expos$ to x4 ,x !re=e has to be h&l$ ) c>e & undue exposure to ! radiations mu/ be avoid$4 ,canc] sacs %rivel up & practically disappe> "u its action4 ,:e!r ! de/ruction ( :atev] causes ! canc] is complete is at lea/ op5 to s]i\s d\bt4 ,! coagulat+ effect ^u globul9 is int]e/+4 ,:5 two solutions ( globul9 f ox s]um are tak5 & acetic acid add$ to "o :ile ammonia is add$ to ! o!r1 ! opalesc5ce 9 drops ( ! =m] is rapidly dim9i%$ on exposure to radium1 %[+ a m complete solution1 :]eas ! latt] solution rapidly turns to a jelly & becomes opaque1 indicat+ a greatly decreas$ solubility4 ,en]gy ,evolv$ by ,radium ,! great] "p ( ! trem5d\s en]gy evolv$ by radium is due to ! emission ( ! alpha p>ticles1 & 9 comp>ison ! beta & gamma rays toge!r supply only a small fraction4 ,?is en]gy may be measur$ z heat4 ,x 0 fir/ obs]v$ t a radium comp\nd ma9ta9$ a temp]ature sev]al degrees high] ?an t ( ! air ar\nd x4 ,! rate ( heat production 0 lat] measur$ by means ( an ice calorimet] & also by not+ ! /r5g? ( ! curr5t requir$ to raise a comp>ison tube ( b>ium salt to ! same temp]ature4 ,bo? me?ods %[$ t ! heat produc$ 0 at ! rate ( ab\t #ace gram calories p] h\r4 ,z ! emission is cont9u\s1 "o gram ( radium w\ld !re=e emit ab\t #a1ahj1jjj gram calories 9 ! c\rse ( a ye>4 ,at ! end ( #bjjj ye>s x w\ld /ill emit #eij1jjj gram calories p] ye>4 ,su* a production ( en]gy s f> surpasses all exp]i5ce t x becomes almo/ inconceivable4 ,x is futile to speak ( x 9 t]ms ( ! heat evolv$ by ! combu/ion ( hydrog51 :i* is ! greate/ t c be produc$ by *emical means4 ,?is effect is unalt]$ at l[ temp]atures1 z has be5 te/$ by imm]s+ a tube conta9+ radium 9 liquid air4 ,x %\ld be /at$ t ^! measurem5ts 7 made aft] ! radium _h rea*$ an equilibrium ) its products2 t is1 aft] wait+ at lea/ a mon? aft] its prep>ation4 ,! evolution ( heat f radium & ! radio-active sub/ances is1 9 a s5se1 a second>y effect1 z x measures ! radiant en]gy trans=m$ into heat en]gy by ! active matt] itself & :atev] surr\nds x4 ,let u repeat1 !re=e1 t ! total am\nt ( en]gy p5t up 9 a s+le atom ( radium almo/ passes our p[]s ( conception4 ,necessity = a ,dis9tegration ,!ory ,! facts ga!r$ s f> ju/ify & necessitate a !ory :i* %all satisfactorily expla9 !m1 & s9ce ^! ph5om5a are n caus$ by nor subject to ! influ5ce ( ext]nal ag5cies1 !y mu/ ref] to *anges tak+ place )9 ! atom--9 o!r words1 a !ory ( dis9tegration4 ,9 ! ma91 ^! facts may be summ$ up z ! emission ( c]ta9 radiations f kn[n elem5tal matt]3 ! mat]ial alpha p>ticles ) positive *>ge1 ! beta p>ticles or negative electrons1 & ! gamma rays analog\s to ,x rays4 ,! emission ( ^! rays results 9 ! production ( great heat4 ,!n !re is ! law ( trans=mations by :i* :ole s]ies ( new elem5ts are g5]at$ f ! orig9al elem5t & ma9ta9 a con/ant equilibrium ( gr[? & decay 9 ! s]ies4 ,la/ly1 we h ! production ( helium f ! alpha p>ticles4 ,dis9tegration ,!ory ,9 explanation ( ^! ph5om5a1 ,ru!r=d (f]$ ! hypo!sis t ! atoms ( c]ta9 elem5ts 7 un/able & subject to dis9tegration4 ,! only elem5ts def9itely kn[n to come "u ?is description are ! two hav+ atoms ( ! greate/ kn[n mass1 ?orium 7#bcb7 & uranium 7#bch74 ,! atoms ( uranium1 = in/ance1 are suppos$ to be n p]man5t b un/able sy/ems4 ,accord+ to ! hypo!sis1 ab\t #a atom 9 e #ajah becomes un/able ea* second & breaks up ) a viol5t explosion = s small a mass ( matt]4 ,"o1 or possibly two alpha p>ticles are expell$ ) great velocity4 ,?is alpha p>ticle corresponds to an atom ( helium ) an atomic weight ( #d1 & its loss r$uces ! orig9al atomic weight to #bcd ) ! =mation ( a new elem5t1 hav+ *ang$ prop]ties correspond+ to ! new atomic weight4 ,?is new elem5t is uranium ,x#a4 ,^! new atoms are f> m un/able ?an ^? ( uranium1 & ! decomposition proce$s at a new rate ( #a 9 #ajg p] second4 ,s at a def9ite1 measurable rate ?is /epwise dis9tegration proce$s4 ,! explosions are n 9 all cases equally viol5t 9 go+ f elem5t to elem5t1 nor are ! results ! same4 ,sometimes alpha p>ticles alone are expell$1 sometimes beta1 or two ( !m toge!r1 z alpha & beta4 ,! new product may rema9 ) ! un*ang$ "p ( ! orig9al matt]4 ,?us !re w\ld be an accumulation ( x until its own decay balances its production1 result+ ev5tually 9 a /ate ( equilibrium4 ,con/itution ( ! ,atom ,9 ord] to expla9 ! electrical & optical prop]ties ( matt]1 ! hypo!sis 0 made t ! atom consi/$ ( positively & negatively electrifi$ p>ticles4 ,lat] x 0 %[n t negative electrons exi/ 9 all k9ds ( matt]4 ,v>i\s attempts 7 made to "w out a model ( su* an atom 9 :i* ^! p>ticles 7 held 9 equilibrium by electrical =ces4 ,! atom ( ,"l ,kelv9 consi/$ ( a uni=m sph]e ( positive electrification ?r\gh\t :i* a numb] ( negative electrons 7 di/ribut$1 & ,j4 ,j4 ,?omson has det]m9$ ! prop]ties ( ?is type z to ! numb] ( p>ticles1 _! arrangem5t & /ability4 ,ru!r=d's ,atom ,accord+ to ,ru!r=d1 ! atom ( uranium may be look$ ^u z consi/+ ( a c5tral *>ge ( positive electricity surr\nd$ by a numb] ( conc5tric r+s ( negative electrons 9 rapid motion4 ,! positively *>g$ c5tre is made up ( a complicat$ sy/em 9 movem5t1 consi/+ 9 "p ( *>g$ helium & hydrog5 atoms1 & practically ! :ole *>ge & mass ( ! atom is conc5trat$ at ! c5tre4 ,! c5tral sy/em ( ! atom is f "s unkn[n cause un/able1 & "o ( ! helium atoms escapes f ! c5tral mass z an alpha p>ticle4 ,!re are1 confess$ly1 difficulties connect$ ) ?is conception ( ! atom :i* ne$ n1 h[ev]1 be discuss$ "h4 ,mu* rema9s to be le>n$ z to ! me*anics ( ! atom1 & ! hypo!sis outl9$ above w probably h to be mat]ially alt]$ z k gr[s4 ,p]haps x may h to be entirely ab&on$ 9 favor ( "s m satisfactory solution4 ,until su* "t x at lea/ suffices z a m5tal picture ar\nd :i* ! kn[n facts gr\p !mselves4 ,9 ?is picture en]gy & matt] lose _! old-"t di/9ctness ( def9ition4 ,discrete subdivisions ( en]gy are recogniz$ :i* may be call$ *>g$ p>ticles )\t los+ _! significance4 ,"s ( ^! subdivisions *>g$ 9 a c]ta9 way or ) neutraliz$ *>ge exhibit ! prop]ties ( s-call$ matt]4 ,scatt]+ ( ,alpha ,p>ticles ,?is conception ( ! atom w\ld d\btless fail ( mu* support 7 x n = c]ta9 exp]im5tal facts :i* l5d great weight to x4 ,c]ta9 suppositions c be bas$ on ?is !ory ma!matically reason$ out & te/$ by exp]im5t4 ,pr$ictions ?us bas$ on ma!matical reason+ & aft]w>d confirm$ by exp]im5t give a v conv9c+ impression t tru? lies at ! bottom4 ,! fir/ ( ^! exp]im5tal pro(s comes "u ! head ( :at is kn[n z ! scatt]+ ( ! alpha p>ticles1 a ph5om5on :i*1 :5 fir/ obs]v$1 prov$ h>d to expla94 ,if an alpha p>ticle 9 its escape f ! p>5t atom %\ld come )9 ! influ5ce ( ! suppos$ out] electrical field ( "s o!r atom1 x %\ld be deflect$ f its c\rse &1 ! int5sity ( ! two *>ges be+ kn[n1 ! angle ( deflection c\ld be calculat$4 ,= in/ance1 if x came to :at might be call$ a head-on collision ) ! positive c5tral nucleus ( ano!r atom1 x w\ld recoil if x 7 itself ( less] mass1 or w\ld propel ! o!r =w>d if t 7 ! light]4 ,! exp]im5t is c>ri$ out by plac+ a ?9 metal foil ov] a radio-active body1 z radium ,c1 :i* expels alpha p>ticles ) a high velocity1 & c\nt+ ! numb] ( alpha p>ticles :i* are scatt]$ ?r\gh an angle great] ?an #ij & s recoil t[>d _! s\rce4 ,?is has be5 done by a numb] ( inve/igators & x has be5 f\nd t ! angle ( scatt]+ & ! numb] ( recoil p>ticles dep5d ^u ! atomic weight ( ! metal us$ z foil4 ,= example1 if gold is us$1 ! numb] ( recoil atoms is "o 9 some?+ less ?an #h1jjj4 ,tak+ ! atomic weight ( gold into consid]ation1 ,ru!r=d calculat$ ma!matically t ?is 0 ab\t ! numb] :i* %\ld be driv5 backw>d4 ,b he w5t fur!r & calculat$ also ! numb] :i* %\ld be return$ by alum9um1 :i* has an atomic weight ( only ab\t "o-sev5? t ( gold4 ,two inve/igators det]m9$ exp]im5tally ! numb] = alum9um & _! results agre$ ) ,ru!r=d's calculations4 ,! metals f alum9um to gold h be5 exam9$ 9 ?is way4 ,! numb] ( recoil p>ticles increases ) ! atomic weight ( ! metal4 ,comp>+ exp]im5t ) !ory1 ! c5tral *>ge 9 an atom corresponds to ab\t "o-half ! atomic weight multipli$ by ! *>ge on an electron1 or1 z x is express$1 #a_/b ,ae4 ,!re is only "o light] atom ?an helium1 namely1 hydrog51 :i* has a mass only "o-f\r? z great4 ,:5 alpha p>ticles are dis*>g$ into hydrog51 a few ( ! latt] atoms are f\nd to be propell$ to a di/ance f\r times z great z t rea*$ by ! alpha p>ticles4 ,/opp+ ,p[] ( ,sub/ances ,p>allel ) ! exp]im5ts m5tion$1 !re is :at is call$ ! /opp+ p[] ( sub/ances4 ,?is means ! dep? or ?ickness ( a sub/ance necess>y to put a /op to ! c\rse ( ! alpha p>ticles4 ,?is gives ! range ( ! alpha p>ticles 9 su* sub/ances & is connect$ 9 a simple way ) ! atomic weight1 t is1 x is aga9 fix$ by ! mass ( ! oppos+ atom4 ,?is /opp+ p[] ( an atom = an alpha p>ticle is approximately proportional to ! squ>e root ( its atomic weight4 ,consid]+ gases1 = in/ance1 if ! range 9 hydrog5 be #a1 !n ! range 9 oxyg51 ! atomic weight ( :i* is #af1 is only 7#a_/af7a_/b or #a_/d4 ,g5]ally 9 ! case ( metals ! weight ( matt] p] unit area requir$ to /op ! alpha p>ticle is f\nd to v>y accord+ to ! squ>e root ( ! atomic weight ( ! metal tak54 ,,*apt] ,,vi ,,radio-,,activity ,,& ,,*emical ,,!ory ,influ5ce ^u ,*emical ,!ory ,x c easily be se5 t ! revelations ( radio-activity mu/ h a f>-rea*+ effect ^u *emical !ory1 ?r[+ light ^u1 & s br++ ne>]1 ! solution ( "s ( ! problems :i* h be5 long discuss$ )\t arriv+ at any satisfactory solution4 ,! s-call$ electro-*emical nature ( ! elem5ts w c]ta9ly be made mu* cle>]4 ,! *anges 9 val5ce %\ld become intelligible & val5ce itself %\ld be expla9$4 ,a full] und]/&+ ( ! ionization ( electrolytes also becomes possible4 ,z ^! matt]s are debatable & ! details are /ill unsettl$1 x is sc>cely appropriate to give "h ! hypo!ses 9 detail or to ent] into any discussion ( !m4 ,b ! promise ( solution 9 accord ) ! facts is enc\rag+4 ,! ,p]iodic ,sy/em ,su* progress has be5 made1 h[ev]1 9 reg>d to a bett] und]/&+ ( ! ,p]iodic ,sy/em t ! new facts & _! int]pretation may well be giv54 ,no reliable clue to ! mean+ ( ?is sy/em & ! true relation%ip betwe5 ! elem5ts _h be5 f\nd up to ! "t :5 new light 0 ?r[n ^u x by ! discov]ies ( radio-activity4 ,! und]ly+ pr9ciple 0 unkn[n & ev5 ! /atem5t ( :at 0 sometimes errone\sly call$ ! ,p]iodic ,law 0 manife/ly incorrect & its t]ms 7 ignor$4 ,basis ( ! ,p]iodic ,sy/em ,! ord9>y /atem5t ( ! fundam5tal pr9ciple ( ! ,p]iodic ,sy/em has be5 t ! prop]ties ( ! elem5ts 7 p]iodic functions ( ! atomic weights1 & t :5 ! elem5ts 7 arrang$ 9 ! ord] ( _! atomic weights !y fell into a natural s]ies1 tak+ _! places 9 ! prop] relat$ gr\ps4 ,9 accept+ ?is1 ! int]pretation ( function 0 bo? unma!matical & vague1 & ! ord] ( ! atomic weights 0 n /rictly adh]$ to b unhesitat+ly ab&on$ to =ce ! gr\p relation%ip4 ,:]ev] consid]ation ( ! atomic weight w\ld h plac$ an elem5t out ( ! gr\p+ ) o!r elem5ts to :i* x 0 cle>ly relat$ 9 physical & *emical prop]ties1 ! guidance ( ^! prop]ties 0 accept$ & t ( ! atomic weights disreg>d$4 ,su* %ift+s are not$ 9 ! cases ( tellurium & iod9e2 cobalt & nickel2 argon & potassium4 ,x 0 mo/ helpful t1 foll[+ ! ord] ( atomic weights1 ! majority ( ! elem5ts fell naturally into _! places4 ,o!rwise ! g5]alization kn[n z ! ,p]iodic ,sy/em might h rema9$ = a long "t undiscov]$ & ! progress ( *emi/ry w\ld h be5 greatly ret>d$4 ,influ5ce ( ,positive ,nucleus ,x is evid5t t ! ord] ( ! elem5ts is det]m9$ by some?+ else ?an _! atomic weights4 ,f ! kn[n facts ( radio-activity x w\ld seem t ?is det]m9+ factor is ! positive nucleus4 ,& ?is nucleus also det]m9es ! mass or weight ( ! atom4 ,tak+ ! elem5ts 9 _! ord] 9 ! ,p]iodic ,s]ies & numb]+ ! positions held by !m 9 ?is s]ies z #a1 #b1 #c1 etc41 we get ! position numb] or :at is call$ ! atomic numb]4 ,?is designates ! ord] or position ( ! elem5t 9 ! s]ies4 ,we mu/ le>n t ?is numb] m>ks a position r ?an a s+le elem5t1 a /atem5t :i* w be expla9$ lat]4 ,det]m9ation ( ! ,atomic ,numb] ,s9ce ! atomic weight is unreliable z a means ( settl+ ! position ( an elem5t 9 ! s]ies & s fix+ its atomic numb]1 h[ is ?is numb] to be det]m9$8 ,( c\rse1 "o answ] to ?is "q is t we may rely ^u a consid]ation ( ! g5]al prop]ties1 z has be5 done 9 ! pa/4 ,=tunately1 o!r me?ods h be5 f\nd by :i* ?is may be confirm$4 ,= in/ance1 ! /opp+ & scatt]+ p[] ( ! elem5t = alpha p>ticles has be5 sugge/$ & successfully us$4 ,use ( ,x-,ray ,spectra ,a mo/ int]e/+ me?od is due to ,moseley's obs]vations ^u ! ,x-ray spectra ( ! v>i\s elem5ts4 ,x has be5 f\nd t cry/als1 su* z ^? ( qu>tz1 h ! p[] ( reflect+ & def9+ ! ,x rays4 ,! spectra giv5 by ^! rays c be photograph$ & ! wave l5g?s measur$4 ,^! ,x rays are emitt$ by v>i\s sub/ances "u bomb>dm5t by ! ca?ode rays 7negative electrons7 & h great int5sity & v m9ute wave l5g?s4 ,moseley made use ( v>i\s metals z anti-ca?odes = ! production ( ^! rays4 ,^! metals rang$ f calcium to z9c 9 ! ,p]iodic ,sy/em4 ,9 ea* case he obs]v$ t two *>act]i/ic types ( ,x rays ( def9ite int5sity & diff]5t wave l5g?s 7 emitt$4 ,f ! frequ5cy ( ^! waves !re is d$uc$ a simple relation connect$ ) a fundam5tal quantity :i* increases 9 units f "o elem5t to ! next4 ,?is is due to ! *>ge ( ! positive c5tral nucleus4 ,! numb] f\nd 9 ?is way is "o less ?an ! atomic numb]4 ,?us ! numb] = calcium is #ai in/ead ( #bj & t = z9c is #bi in/ead ( #cj4 ,s1 by add+ #a to ! numb] f\nd ! atomic numb] is obta9$4 ,! atomic weight c usually be foll[$ 9 fix+ ! atomic numb]1 b :]e d\bt exi/s ! me?od j giv5 c be resort$ to4 ,?us d\bt arises 9 ! case ( iron & nickel & cobalt4 ,?is w\ld be ! ord] accord+ to ! atomic weights4 ,! ,x-ray me?od gives ! ord] z iron1 cobalt1 & nickel1 & ?is is ! accept$ ord] 9 ! ,p]iodic ,sy/em4 ,*anges ,caus$ by ,ray ,emission ,on /udy+ ! prop]ties ( ! elem5ts 9 a trans=mation s]ies 9 connection ) ! ray emission :i* produc$ !m1 x 0 se5 t ^! prop]ties 7 det]m9$ 9 ea* case by ! nature ( ! ray emitt$ f ! prec$+ trans=mation product or p>5t elem5t4 ,atomic ,weight ,losses ,ea* alpha p>ticle emitt$ means a loss ( #d 9 ! atomic weight4 ,?is is ! mass ( a helium atom4 ,?us f uranium ) an atomic weight ( #bch to radium !re is a loss ( ?ree alpha p>ticles4 ,!re=e1 #ab mu/ be subtract$ f #bch1 leav+ #bbf1 :i* agrees closely ) ! atomic weight ( radium z actually det]m9$ by ! ord9>y me?ods4 ,uranium ,x#a1 !n1 w\ld h an atomic weight ( #bcd & t ( ionium w\ld be #bcj4 ,! o!r int]m$iate elem5ts1 ^: =mation is due to ! loss ( beta p>ticles only1 %[ no decrease 9 atomic weight4 ,lead ! ,end ,product ,f uranium to lead !re is a loss ( #h alpha p>ticles1 or #cb units 9 atomic weight4 ,?is w\ld give = ! f9al product an atomic weight ( #bjf4 ,! atomic weight ( lead is #bjg4ag4 ,x is n at all c]ta9 t ! f9al product ( ?is s]ies is ord9>y lead4 ,! facts are su* t !y w\ld lead "o to ?9k t x is n4 ,x is kn[n only t ! end product w\ld probably be "s elem5t closely resembl+ lead *emically & h5ce difficult or impossible to sep>ate f x4 ,sev]al accurate det]m9ations ( lead com+ f uranium m9]als1 :i* always c>ry ?is elem5t & 9 an approximately def9ite ratio to ! am\nt ( uranium pres5t1 %[ atomic weights ( #bjf4dj2 #bjf4cf2 & #bjf4ed4 ,ev5 ! mo/ rigid me?ods ( purification fail to *ange ^! results4 ,! lead 9 ^! m9]als might !re=e be consid]$ z com+ 9 ! ma9 f ! dis9tegration ( ! uranium atom &1 ?\gh *emically resembl+ lead1 z be+ 9 reality a diff]5t elem5t ) diff]5t atomic weight4 ,fur!rmore1 9 ! ?orium s]ies #f alpha p>ticles are lo/ be=e rea*+ ! end product1 :i* aga9 is p]haps ! *emical analogue ( lead4 ,! atomic weight "h %\ld be #bcb less #bd1 or #bjh4 ,det]m9ations ( ! atomic weight ( lead f ?orite1 a ?orium m9]al ne>ly free f uranium1 gave #bjh4d4 ,! end product ( ! act9ium s]ies is also an elem5t resembl+ lead1 b bo? ! beg9n+ & end+ ( ?is s]ies are /ill 9 obscurity4 ,*anges ( ,position 9 ! ,p]iodic ,sy/em ,! loss ( #d units 9 ! atomic weight ( an elem5t on ! expulsion ( an alpha p>ticle is accompani$ by a *ange ( *emical prop]ties :i* removes ! new elem5t two gr\ps t[>d ! positive side 9 ! ,p]iodic ,sy/em4 ,?us ionium is s closely relat$ to ?orium & s resembles x *emically t x is prop]ly class$ along ) ?orium z a quadrival5t elem5t 9 ! f\r? gr\p4 ,ionium expels an alpha p>ticle & becomes radium1 :i* is a bival5t elem5t resembl+ b>ium belong+ to ! second gr\p4 ,radium !n expels an alpha p>ticle & becomes ! gas1 radium emanation1 :i* is an analogue ( argon & belongs to ! z]o gr\p4 ,o!r in/ances might be cit$ :i* g to %[ t 9 all cases ! loss ( an alpha p>ticle makes a *ange ( two places t[>d ! left or positive side ( ! ,sy/em4 ,*anges f ,loss ( ,beta ,p>ticles ,! loss ( a beta p>ticle causes no *ange 9 ! atomic weight b does cause a %ift = ea* beta p>ticle ( "o gr\p t[>d ! "r or negative side ( ! ,sy/em4 ,two su* losses1 !n1 w c\nt]balance ! loss ( an alpha p>ticle & br+ ! new elem5t back to ! gr\p orig9ally occupi$ by its prog5itor4 ,?us uranium 9 ! six? gr\p loses an alpha p>ticle & ! product ,,ux#a falls 9 ! f\r? gr\p4 ,"o beta p>ticle is !n lo/ & ,,ux#b belong+ to ! fif? gr\p is =m$4 ,) ! loss ( "o m beta p>ticle ! new elem5t returns to ! six? gr\p f :i* ! trans=mation began4 ,! table on page #dh1 z adapt$ f ,soddy1 af=ds a g5]al view ( ^! *anges4 ,isotopes ,an exam9ation ( ! table w %[ a numb] ( diff]5t elem5ts fall+ 9 ! same position 9 a gr\p ( ! ,p]iodic ,sy/em irrespective ( _! atomic weights4 ,^! are *emically insep>able s f> z ! pres5t limitations ( *emical analysis are conc]n$4 ,ev5 ! spectra ( ^! elem5ts seem to be id5tical s f> z kn[n4 ,?is id5tity ext5ds to mo/ ( ! physical prop]ties1 b ?is dem&s mu* fur!r inve/igation4 ,= ?is new ph5om5on ,soddy has sugge/$ ! ^w isotope = ! elem5t & isotopic = ! prop]ty1 & ^! names h come into g5]al use4 ,illu/ration3 ,,radio-,,active ,,elem5ts ,,f ,,uranium ,,& ,,?orium ,,plac$ ,,9 ,,! ,,p]iodic ,,sy/ems ,adapt$ f ,soddy ,manife/ly1 we h come across a ph5om5on "h :i* q elim9ates ! atomic weight z a det]m9+ factor z to position 9 ! ,p]iodic or ,natural ,sy/em or ( ! elem5tal prop]ties 9 g5]al4 ,all ( ! prop]ties ( ! bodies :i* we call elem5ts1 & consequ5tly ( _! comp\nds & h5ce ( matt] 9 g5]al1 seem to dep5d ^u ! balance ma9ta9$ betwe5 ! *>ges ( negative & positive electricity :i*1 accord+ to ,ru!r=d's !ory1 g to make up ! atom4 ,x is evid5t t any /udy ( *emical ph5om5a & *emical !ory is q incomplete )\t a /udy ( radio-activity & ! trans=mations :i* x produces4 ,radio-activity 9 ,nature ,9 conclud+ ?is outl9e ( ! ma9 facts ( radio-activity1 x is ( int]e/ to discuss briefly ! pres5ce ( radio-active mat]ial on ?is planet & 9 ! />s4 ,facts en\gh h be5 ga!r$ to %[ ! probable univ]sality ( ?is ph5om5on ( radio-activity4 ,:e!r ?is means solely ! dis9tegration ( ! uranium & ?orium atoms1 or :e!r o!r elem5ts are also trans=m$ "u ! int5sity ( ! ag5cies at "w 9 ! univ]se1 is ( c\rse a "q z yet unsolv$4 ,radio-active ,products 9 ! ,e>?'s ,cru/ ,! pres5ce ( uranium & ?orium widely di/ribut$ ?r\gh\t ! cru/ ( ! e>? w\ld lead to ! conclusion t _! dis9tegration products w\ld be f\nd !re also4 ,v>i\s rocks ( igne\s orig9 h be5 exam9$ reveal+ f #d4gh #aj-ab to #j4ca #aj-ab grams ( radium p] gram ( ! rock4 ,aque\s rocks h %[n a less] am\nt1 rang+ f #b4ib #aj-ab to #j4hf #aj-ab grams4 ,z ! soil is =m$ by ! decomposition ( ^! rocks1 radium is pres5t 9 v>y+ am\nts 9 all k9ds ( soil4 ,pres5ce 9 ,air & ,soil ,wat]s ,z radium is trans=m$ into ! gase\s emanation1 ?is w escape :]ev] ! soil is n enclos$4 ,= in/ance1 a l>g] am\nt ( radio-activity is f\nd 9 ! soil ( caves & cell>s ?an 9 op5 soils4 ,if an iron pipe is sunk into a soil & ! air ( ! soil suck$ up into a l>ge electroscope1 ! latt] in/rum5t w %[ ! effect ( ! rays emitt$ & w measure ! degree ( activity4 ,also ! int]ior ( ! pipe w receive a deposit ( ! radio-active mat]ial & w %[ appreciable radio-activity aft] be+ remov$ f ! soil4 ,?is radium emanation is dissolv$ 9 ! soil wat]s1 wells1 spr+s1 & riv]s1 r5d]+ !m m or less radio-active1 & sometimes ! muddy deposit at ! bottom ( a spr+ %[s decid$ radio-activity4 ,! emanation also escapes into ! air s t _m obs]vations made 9 v>i\s places %[ t ! radium emanation is ev]y:]e pres5t 9 ! atmosph]e4 ,nei!r summ] nor w9t] seems to affect ?is emanation1 & x ext5ds c]ta9ly to a height ( two or ?ree miles4 ,ra91 fall+ ?r\gh ! air1 dissolves "s ( ! emanation1 s t x may be f\nd 9 fre%ly-fall5 ra9 wat] & also 9 fre%ly-fall5 sn[4 ,radio-active deposits are f\nd ^u electrically *>g$ wires expos$ ne> ! e>?'s surface4 ,z helium is ! result+ product ( ! alpha p>ticles emitt$ by ! emanation & o!r radio-active bodies1 x is f\nd 9 ! soil air1 soil wat]s1 & atmosph]e4 ,av]age measurem5ts ( ! radio-activity ( ! atmosph]e h l$ to ! calculation t ab\t "o gram ( radium p] squ>e kilomet] ( ! e>?'s surface is requisite to keep up ! supply ( ! emanation4 ,a numb] ( e/imates h be5 giv5 z to ! heat produc$ by ! radio-active trans=mations go+ on 9 ! mat]ial ( ?is planet4 ,actual data are sc>ce & m]e assumptions unsatisfactory1 s little t is wor? :ile c be d$uc$4 ,x is possible t ?is s\rce ( heat may h an appreciable effect ^u or s]ve to balance ! e>?'s rate ( cool+4 ,cosmical ,radio-activity ,meteorites ( iron com+ f o!r cele/ial bodies h n %[n ! pres5ce ( radium4 ,a]olites or /one meteorites h be5 f\nd to conta9 z mu* z simil> t]re/rial rock4 ,s9ce ! sun conta9s helium & "s />s %[ its pres5ce z pr$om9at+1 ?is sugge/s ! pres5ce ( radio-active matt] 9 ^! bodies4 ,9 addition1 ! spectral l9es ( uranium1 radium1 & ! radium emanation h be5 report$ z be+ f\nd 9 ! sun's spectrum & also 9 ! new />1 ,nova ,gem9orum #b4 ,^! obs]vations await fur!r inve/igation & confirmation4 ,s f> z ! sun's *romosph]e is conc]n$1 ! possible am\nt ( radium pres5t w\ld seem to be v small4 ,if ?is is true1 radio-active processes c\ld h little to d ) ! sun's heat4 ,! /atem5t is made by ,ru!r=d t indirect evid5ce obta9$ f ! /udy ( ! aurora sugge/s t ! sun emits rays simil> 9 type to ! alpha & beta rays4 ,su* rays w\ld be absorb$1 & ! gamma rays likewise1 9 pass+ ?r\gh ! e>?'s atmosph]e & s escape ord9>y obs]vation4 ,all ( ?is is b fur!r evid5ce ( ! unity ( matt] & ( =ces 9 ! univ]se4 ,,index ,act9ium1 discov]y (1 #f ,activity1 induc$1 #ag ,alpha p>ticles1 effect ( loss on ,atomic ,weight1 #de electrical *>ge (1 #bf =m helium1 #bg nature (1 #be p5etrat+ p[] (1 #ci position ( elem5t *ang$ by its loss1 #df recoil1 #ci scatt]+ (1 #ch solid1 #bf ,atom1 con/itution (1 #cf ,kelv9's1 #cg models (1 #cg ,ru!r=d's1 #cg ,atomic numb]1 det]m9ation (1 #dc ,becqu]el's exp]im5ts1 #b ,beta p>ticles1 *ange 9 position ( elem5t by loss (1 #dg ,*alcolite1 natural & artificial1 #d ,con/ants1 table (1 #ca ,curie unit1 #bb ,dis9tegration ( ! elem5t1 #be ,dis9tegration s]ies1 #bd ,dis9tegration !ory1 #ce ,electroscope1 #ab ,equilibrium s]ies1 #bb ,helium1 *>act]i/ics (1 #cj discov]y (1 #bi ,ionium1 discov]y (1 #f ,ionization1 application ( electric field to1 #aj exp]im5tal confirmation1 #i ,ionization ( gases1 #g !ory (1 #h ,ions1 size & nature (1 #aj ,isotopes1 #dg ,lead1 atomic weight v>ies ) s\rce1 #de radio-active1 #f ! end product1 #de ,life-p]iods ( radio-active bodies1 #ba ,p]iodic sy/em1 #da basis (1 #db ,polonium1 discov]y (1 #d ,positive nucleus1 influ5ce (1 #dc ,potassium1 radio-activity (1 #c ,radiations1 action on phosphoresc5t bodies1 #ac action on photographic plates1 #aa dis*>ge electrifi$ bodies1 #ab magnetic deflection (1 #ad measurem5ts (1 #ae p5etrat+ p[] (1 #ac1 #ae ,radio-active bodies1 elem5tal nature (1 #bj exam9ation (1 #bj life p]iods (1 #ba ,radio-activity1 an atomic prop]ty1 #c cosmical1 #ea influ5ce on *emical !ory1 #da products 9 atmosph]e1 #ea products 9 e>?'s cru/1 #ej products 9 soil wat]s1 #ej ,radium1 action on organic matt]1 etc41 #cc am\nt 9 pit*bl5de1 #e discov]y (1 #e emanation1 #bb en]gy evolv$ by1 #cd prop]ties (1 #e1 #cb ,rays1 alpha1 #ae1 #af1 #bf beta1 #ae1 #af gamma1 #ae1 #af id5tification (1 #af1 #be magnetic deflection (1 #ad photograph+ track (1 #aj types (1 #ad ,rubidium1 radio-activity (1 #c ,sp9?>iscope1 #ac ,/opp+ p[] ( sub/ances1 #ci ,?orium ,x1 discov]y (1 #ah1 #ba ,uranium atom1 dis9tegration (1 #cf ,uranium m9]als1 radio-activity (1 #c ,uranium ,x1 discov]y (1 #ag1 #ba1 #bc ,x-ray spectra1 #dd ,z9c sulphide scre51 #ac ,,transcrib]',s ,,notes #a4 ,passages 9 italics are surr\nd$ by und]scores4 #b4 ,images h be5 mov$ f ! middle ( a p>agraph to ! close/ p>agraph break4 #c4 ,! orig9al text includes c]ta9 ,greek alphabets4 ,= ?is text v]sion alpha1 beta1 gamma indicate fir/ ?ree lett]s ( ,greek alphabet respectively4 #d4 ,9 ?is v]sion1 ! numb] foll[+ c>at "* is to be int]pret$ z foll[s4 ,! expression #aj-b means multiply+ by #j4ja2 #ajaj means multiply+ by #aj1jjj1jjj1jjj4 #e4 ,9 ?is v]sion1 ! subscript$ text has be5 replac$ by an und]l9e "* foll[$ by ! same ) curly braces & 4 ,= example1 ,x#a indicates ,x ) subscript #a4 #f4 ,! fractions are indicat$ ) ! help ( =w>d "* _/4 ,= example1 #a_/d indicates "o-f\r?4 #g4 ,o!r ?an ! *anges li/$ above1 ! orig9al text has be5 reproduc$ z su*4