,alembic ,club ,repr9ts--,no4 #a4 ,,exp]im5ts ,,^u ,,magnesia ,,alba1 ,,quicklime1 ,,& ,,"s ,,o!r ,,alcal9e ,,sub/ances4 ,,by ,,joseph ,,black1 ,m4,d41 ,pr(essor ( ,*emi/ry 9 ! ,univ]sity ( ,ed9burgh1 #agff-agig4 7#agee47 ,ed9burgh3 ,,publi%$ ,,by ,,! ,,alembic ,,club4 ,ed9burgh ,ag5t3 ,,william ,f4 ,,clay1 #ah ,,teviot ,,place4 ,london ,ag5ts3 ,,simpk91 ,,m>%all1 ,,hamilton1 ,,k5t1 ,,co4 ,,ltd4 #ahih4 ,illu/ration3 ,insignia ,,preface4 ,black's ,pap] entitl$ ,exp]im5ts ^u ,magnesia ,alba1 ,quicklime1 & "s o!r ,alcal9e ,sub/ances 0 read 9 ,june #agee1 & 0 fir/ publi%$ 9 ,essays & ,obs]vations1 ,physical & ,lit]>y4 ,read be=e a ,society 9 ,ed9burgh1 & ,publi%$ by !m1 ,volume ,,ii41 ,ed9burgh1 #agef2 pp4 #aeg-bbe4 ,x 0 subsequ5tly repr9t$ sev]al times dur+ ! life ( ! au?or1 n only 9 lat] editions ( ^! ,essays1 b also 9 a sep>ate =m4 ,copies ( ! orig9al ,pap] are n[ v difficult to obta91 & ! lat] repr9ts h also become sc>ce4 ,! pres5t repr9t is a fai?ful copy ( ! ,pap] z x fir/ appe>$ 9 #agef1 ! spell+1 c41 ( ! orig9al hav+ be5 c>efully reproduc$4 ,! ,pap] con/itutes a highly important /ep 9 ! lay+ ( ! f\ndations ( *emi/ry z an exact sci5ce1 & furni%es a model ( c>efully plann$ exp]im5tal inve/igation1 & ( cle> reason+ ^u ! results ( exp]im5t4 ,x is nei!r s widely read by ! y\ng] *emi/s nor is x s readily accessible z x ought to be1 & ! object ( ! ,alembic ,club 9 issu+ x z ! fir/ volume ( a s]ies ( ,repr9ts ( hi/orically important contributions to ,*emi/ry1 is to place x )9 easy rea* ( e /ud5t ( ,*emi/ry & ( ! ,hi/ory ( ,*emi/ry4 ,! /ud5t's att5tion may be p>ticul>ly call$ to ,black's tacit adoption ( ! quantitative me?od 9 a l>ge numb] ( 8 exp]im5ts1 & to ! way 9 :i* he bases _m ( 8 conclusions ^u ! results obta9$ 9 ^! exp]im5ts4 ,ev5 yet x is v frequ5tly /at$ t ! introduction ( ! quantitative me?od into ,*emi/ry 7:i* did n by any means orig9ate ) ,black7 took place at a consid]ably lat] date4 ,l4 ,d4 ,,exp]im5ts ,,^u ,,magnesia ,,alba1 ,,quicklime1 ,,& ,,"s ,,o!r ,,alcal9e ,,sub/ances2 ,,by ,,joseph ,,black1 ,m4,d4#a ,,"p ,i4 ,h(fman1 9 "o ( 8 obs]vations1 gives ! hi/ory ( a p[d] call$ magnesia alba1 :i* _h long be5 us$ & e/eem$ z a mild & ta/eless purgative2 b ! me?od ( prep>+ x 0 n g5]ally kn[n be=e he made x public4#b ,x 0 orig9ally obta9$ f a liquor call$ ! "m ( nitre1 :i* is produc$ 9 ! foll[+ mann]3 ,salt-petre is sep>at$ f ! br9e :i* fir/ af=ds x1 or f ! wat] ) :i* x is wa%$ out ( nitr\s e>?s1 by ! process commonly us$ 9 cry/alliz+ salts4 ,9 ?is process ! br9e is gradually dim9i%$1 & at l5g? r$uc$ to a small quantity ( an unctu\s bitt] sal9e liquor1 af=d+ no m salt-petre by evaporation2 b1 if urg$ ) a brisk fire1 dry+ up into a confus$ mass :i* attracts wat] /rongly1 & becomes fluid aga9 :5 expos$ to ! op5 air4 ,to ?is liquor ! workm5 h giv5 ! "n ( ! "m ( nitre2 & ,h(fman1 f9d+ x compos$ ( ! magnesia unit$ to an acid1 obta9$ a sep>ation ( ^!1 ei!r by expos+ ! comp\nd to a /rong fire 9 :i* ! acid 0 dissipat$ & ! magnesia rema9$ beh9d1 or by ! addition ( an alkali :i* attract$ ! acid to itself3 & ?is la/ me?od he recomm5ds z ! be/4 ,he likewise makes an inquiry into ! nature & virtues ( ! p[d] ?us prep>$2 & obs]ves1 t x is an absorb5t e>? :i* jo9s readily ) all acids1 & mu/ necess>ily de/roy any acidity x meets 9 ! /oma*2 b t its purgative p[] is unc]ta91 = sometimes x has n ! lea/ effect ( t k9d4 ,z x is a m]e insipid e>?1 he rationally concludes x to be purgative only :5 conv]t$ into a sort ( neutral salt by an acid 9 ! /oma*1 & t its effect is !re=e proportional to ! quantity ( ?is acid4 ,al?o' magnesia appe>s f ?is hi/ory ( x to be a v innoc5t m$ic9e1 yet hav+ obs]v$1 t "s hypo*ondriacs :o us$ x frequ5tly1 7 subject to flatul5cies & spasms1 he seems to h suspect$ x ( "s noxi\s quality4 ,! circum/ances h[ev] :i* gave rise to 8 suspicion1 may v possibly h proce$$ f ! imprud5ce ( 8 pati5ts1 :o1 tru/+ too mu* to magnesia1 7:i* is prop]ly a palliative 9 t disease17 & neglect+ ! assi/ance ( o!r rem$ies1 all[$ _! disord] to increase ^u !m4 ,x may inde$ be all$g$1 t magnesia1 z a purgative1 is n ! mo/ eligible m$ic9e = su* con/itutions1 z !y agree be/ ) ^? t /r5g!n1 /imulate & w>m2 :i* ! sal9e purges commonly us$ are n obs]v$ to d4 ,b !re seems at lea/ to be no objection to its use :5 *ildr5 are tr\bl$ ) an acid 9 _! /oma*2 = g5tle purg+ 9 ?is case is v prop]1 & x is (t5 m conv5i5tly procur$ by means ( magnesia ?an ( any o!r m$ic9e1 on acc\nt ( its be+ intirely insipid4 ,! above-m5tion$ ,au?or obs]v+1 "s "t aft]1 t a bitt] sal9e liquor1 simil> to t obta9$ f ! br9e ( salt-petre1 0 likewise produc$ by ! evaporation ( ^? wat]s :i* conta9 common salt1 _h ! curiosity to try if ?is w\ld also yield a magnesia4 ,! exp]im5t succe$$3 & he ?us f\nd out ano!r process = obta9+ ?is p[d]1 & at ! same "t assur$ himself by exp]im5ts1 t ! product f bo? 0 exactly ! same4#c ,my curiosity l$ me "s "t ago to inquire m p>ticul>ly into ! nature ( magnesia1 & especially to comp>e its prop]ties ) ^? ( ! o!r absorb5t e>?s1 ( :i* !re pla9ly appe>$ to me to be v diff]5t k9ds1 al?o' commonly conf\nd$ toge!r "u "o "n4 ,i 0 inde$ l$ to ?is exam9ation ( ! absorb5t e>?s1 p>tly by ! hope ( discov]+ a new sort ( lime & lime-wat]1 :i* might possibly be a m p[]ful solv5t ( ! /one ?an t commonly us$2 b 0 disappo9t$ 9 my expectations4 ,i h _h no opportunity ( see+ ,h(fman's fir/ magnesia or ! liquor f :i* x is prep>$1 & h !re=e be5 oblig$ to make my exp]im5ts ^u ! second4 ,9 ord] to prep>e x1 ,i at fir/ employ$ ! bitt] sal9e liquor call$ bitt]n1 :i* rema9s 9 ! pans aft] ! evaporation ( sea wat]4 ,b z t liquor is n always easily procur$1 ,i aft]w>ds made use ( a salt call$ epsom-salt1 :i* is sep>at$ f ! bitt]n by cry/allization1 & is evid5tly compos$ ( magnesia & ! vitriolic acid4 ,!re is likewise a spuri\s k9d ( ,glaub] salt1 :i* yields pl5ty ( magnesia1 & seems to be no o!r ?an ! epsom salt ( sea wat] r$uc$ to cry/als ( a l>g] size4 ,& common salt also af=ds a small quantity ( ?is p[d]2 because be+ sep>at$ f ! bitt]n by "o ha/y cry/allization only1 x necess>ily conta9s a portion ( t liquor4 ,^? :o w\ld prep>e a magnesia f epsom-salt1 may use ! foll[+ process4 ,dissolve equal quantities ( epsom-salt1 & ( pe>l a%es sep>ately 9 a suffici5t quantity ( wat]2 purify ea* solution f its dregs1 & mix !m accurately toge!r by viol5t agitation3 !n make !m j to boil ov] a brisk fire4 ,add n[ to ! mixture ?ree or f\r times its quantity ( hot wat]2 aft] a little agitation1 all[ ! magnesia to settle to ! bottom1 & decant (f z mu* ( ! wat] z possible4 ,p\r on ! same quantity ( cold wat]2 &1 aft] settl+1 decant x (f 9 ! same mann]4 ,repeat ?is wa%+ ) ! cold wat] t5 or twelve times3 or ev5 (tn]1 if ! magnesia be requir$ p]fectly pure = *emical exp]im5ts4 ,:5 x is suffici5tly wa%$1 ! wat] may be /ra9$ & squeez$ f x 9 a l95 clo?2 = v little ( ! magnesia passes ?ro'4 ,! alkali 9 ! mixture unit+ ) ! acid1 sep>ates x f ! magnesia2 :i* n be+ ( itself soluble 9 wat]1 mu/ consequ5tly appe> imm$iately "u a solid =m4 ,b ! p[d] :i* ?us appe>s is n intirely magnesia2 "p ( x is ! neutral salt1 =m$ f ! union ( ! acid & alkali4 ,?is neutral salt is f\nd1 ^u exam9ation1 to agree 9 all respects ) vitriolat$ t>t>1 & requires a l>ge quantity ( hot wat] to dissolve x4 ,z mu* ( x is !re=e dissolv$ z ! wat] c take up2 ! re/ is disp]s$ ?ro' ! mixture 9 ! =m ( a p[d]4 ,h5ce ! necessity ( wa%+ ! magnesia ) s mu* tr\ble2 = ! fir/ affusion ( hot wat] is int5d$ to dissolve ! :ole ( ! salt1 & ! subsequ5t additions ( cold wat] to wa% away ?is solution4 ,! caution giv5 ( boil+ ! mixture is n unnecess>y2 if x be neglect$1 ! :ole ( ! magnesia is n accurately sep>at$ at once2 & by all[+ x to re/ = "s "t1 t p[d] concretes into m9ute gra9s1 :i*1 :5 view$ ) ! microscope1 appe> to be assemblages ( ne$les div]g+ f a po9t4 ,?is happ5s m especially :5 ! solutions ( ! epsom-salt & ( ! alkali are dilut$ ) too mu* wat] be=e !y are mix$ toge!r4 ,?us1 if a dram ( epsom-salt & ( salt ( t>t> be dissolv$ ea* 9 f\r ounces ( wat]1 & be mix$1 & !n all[$ to re/ ?ree or f\r days1 ! :ole ( ! magnesia w be =m$ into ^! gra9s4 ,or if we filtrate ! mixture soon aft] x is made1 & heat ! cle> liquor :i* passes ?ro'2 x w become turbid1 & deposite a magnesia4 ,i _h ! curiosity to satisfy myself ( ! purgative p[] ( magnesia1 & ( ,h(fman's op9ion conc]n+ x1 by ! foll[+ easy exp]im5t4 ,i made a neutral salt ( magnesia & di/ill$ v9eg>2 *oos+ ?is acid z be+1 l t 9 weak /oma*s1 ! product ( f]m5tation4 ,six drams ( ?is ,i dissolv$ 9 wat]1 & gave to a middle-ag$ man1 desir+ him to take x by degrees4 ,aft] hav+ tak5 ab\t a ?ird1 he desi/$1 & purg$ f\r times 9 an easy & g5tle mann]4 ,a woman ( a /rong con/itution got ! rema9d] z a brisk purgative1 & x op]at$ t5 times )\t caus+ any uneas9ess4 ,! ta/e ( ?is salt is n disagreeable1 & x appe>s to be r ( ! cool+ ?an ( ! acrid k9d4 ,hav+ ?us giv5 a %ort sket* ( ! hi/ory & m$ical virtues ( magnesia1 ,i n[ proce$ to an acc\nt ( its *emical prop]ties4 ,by my fir/ exp]im5ts1 ,i int5d$ to le>n :at sort ( neutral salts might be obta9$ by jo9+ x to ea* ( ! vulg> acids2 & ! result 0 z foll[s4 ,magnesia is quickly dissolv$ ) viol5t eff]vesc5ce1 or explosion ( air1 by ! acids ( vitriol1 nitre1 & ( common salt1 & by di/ill$ v9eg>2 ! neutral sal9e liquors !nce produc$ hav+ ea* _! peculi> prop]ties4 ,t :i* is made ) ! vitriolic acid1 may be cond5s$ into cry/als simil> 9 all respects to epsom-salt4 ,t :i* is made ) ! nitr\s is ( a yell[ col\r1 & yields sal9e cry/als1 :i* reta9 _! =m 9 a v dry air1 b melt 9 a moi/ "o4 ,t :i* is produc$ by means ( _s ( salt1 yields no cry/als2 & if evaporat$ to dryness1 soon melts aga9 :5 expos$ to ! air4 ,t :i* is obta9$ f ! union ( di/ill$ v9eg> ) magnesia1 af=ds no cry/als by evaporation1 b is cond5s$ into a sal9e mass1 :i*1 :ile w>m1 is extremely t\gh & viscid1 v mu* resembl+ a /rong glue bo? 9 col\r & consi/5ce1 & becomes brittle :5 cold4 ,by ^! exp]im5ts magnesia appe>s to be a sub/ance v diff]5t f ^? ( ! calc>i\s class2 "u :i* ,i w\ld be und]/ood to compreh5d all ^? t are conv]t$ into a p]fect quick-lime 9 a /rong fire1 su* z lime-/one1 m>ble1 *alk1 ^? sp>s & m>les :i* eff]vesce ) aqua =tis1 all animal %ells & ! bodies call$ li?ophyta4 ,all ( ^!1 by be+ jo9$ ) acids1 yield a set ( comp\nds :i* are v diff]5t f ^? we h j n[ describ$4 ,?us1 if a small quantity ( any calc>i\s matt] be r$uc$ to a f9e p[d] & ?r[n into _s ( vitriol1 x is attack$ by ?is acid ) a brisk eff]vesc5ce2 b little or no dissolution ensues4 ,x absorbs ! acid1 & rema9s unit$ ) x 9 ! =m ( a :ite p[d]1 at ! bottom ( ! vessel1 :ile ! liquor has h>dly any ta/e1 & %ews only a v light cl\d ^u ! addition ( alkali4#d ,! same :ite p[d] is also =m$ :5 _s ( vitriol is add$ to a calc>i\s e>? dissolv$ 9 any o!r acid2 ! vitriolic expell+ ! o!r acid1 & jo9+ itself to ! e>? by a /rong] attraction2 & ^u ?is acc\nt ! magnesia ( sea-wat] seems to be diff]5t f ei!r ( ^? describ$ by ,h(fman4 ,he says expressly1 t ! solutions ( ea* ( 8 p[d]s1 or1 :at is equival5t1 t ! liquors f :i* !y are obta9$1 =m$ a coagulum1 & deposit$ a :ite p[d]1 :5 he add$ ! vitriolic acid2#e :i* exp]im5t ,i h (t5 tri$ ) ! m>9e bitt]n1 b )\t success4 ,! coagulum ?us =m$ 9 ! "m ( nitre may be ow+ to a quantity ( quick-lime conta9$ 9 x2 = quick-lime is us$ 9 extract+ ! salt-petre f its matrix4 ,b x is m difficult to acc\nt = ! diff]5ce betwe5 ,h(fman's bitt]n & ours1 unless we w be satisfi$ to ref] x to ?is1 t he got 8 f ! wat]s ( salt spr+s1 :i* may possibly be diff]5t f ^? ( ! sea4 ,magnesia is n less rem>kably di/+ui%$ f ! calc>i\s e>?s1 by jo9+ x to ! nitr\s & vegetable acids1 ?an to ! vitriolic4 ,^? e>?s1 :5 comb9$ ) _s ( nitre1 _c be r$uc$ to a cry/all9e =m1 & if !y are dissolv$ 9 di/ill$ v9eg>1 ! mixture spontane\sly dries up into a friable salt4 ,hav+ ?us f\nd magnesia to diff] f ! common alkal9e e>?s1 ! object ( my next inquiry 0 its peculi> degree ( attraction = acids1 or :at 0 ! place due to x 9 ,mr4 ,ge(froy's table ( elective attractions4 ,?ree drams ( magnesia 9 f9e p[d]1 an ounce ( salt ammoniac1 & six ounces ( wat] 7 mix$ toge!r1 & dige/$ six days 9 a retort jo9$ to a receiv]4 ,dur+ ! :ole "t1 ! neck ( ! retort 0 po9t$ a little upw>ds1 & ! mo/ wat]y "p ( ! vap\r1 :i* 0 cond5s$ !re1 fell back into its body4 ,9 ! beg9n+ ( ! exp]im5t1 a volatile salt 0 !re=e collect$ 9 a dry =m 9 ! receiv]1 & aft]w>ds dissolv$ into _s4 ,:5 all 0 cool1 ,i f\nd 9 ! retort a sal9e liquor1 "s undissolv$ magnesia1 & "s salt ammoniac cry/alliz$4 ,! sal9e liquor 0 sep>at$ f ! o!r two1 & !n mix$ ) ! alkal9e _s4 ,a coagulum 0 imm$iately =m$1 & a magnesia precipitat$ f ! mixture4 ,! magnesia :i* _h rema9$ 9 ! retort1 :5 well wa%$ & dri$1 weigh$ two scruples & fifte5 gra9s4 ,we le>n by ! latt] "p ( ?is exp]im5t1 t ! attraction ( ! volatile alkali = acids is /rong] ?an t ( magnesia1 s9ce x sep>at$ ?is p[d] f ! acid to :i* x 0 jo9$4 ,b x also appe>s1 t a g5tle heat is capable ( ov]com+ ?is sup]iority ( attraction1 & ( gradually elevat+ ! alkali1 :ile x leaves ! less volatile acid ) ! magnesia4 ,dissolve a dram ( any calc>i\s sub/ance 9 ! acid ( nitre or ( common salt1 tak+ c>e t ! solution be r5d]$ p]fectly neutral1 or t no sup]flu\s acid be add$4 ,mix ) ?is solution a dram ( magnesia 9 f9e p[d]1 & dige/ x 9 ! heat ( boil+ wat] ab\t tw5ty f\r h\rs2 !n dilute ! mixture ) d\ble its quantity ( wat]1 & filtrate4 ,! greate/ "p ( ! e>? n[ left 9 ! filtre is calc>i\s1 & ! liquor :i* pass$ ?ro'1 if mix$ ) a dissolv$ alkali1 yields a :ite p[d]1 ! l>ge/ portion ( :i* is a true magnesia4 ,f ?is exp]im5t x appe>s1 t an acid quits a calc>i\s e>? to jo9 itself to magnesia2 b ! ex*ange be+ p]=m$ sl[ly1 "s ( ! magnesia is /ill undissolv$1 & "p ( ! calc>i\s e>? rema9s yet jo9$ to ! acid4 ,:5 a small quantity ( magnesia is ?r[n into a solution ( ! corrosive sublimate ( m]cury1 x soon sep>ates "p ( ! m]cury 9 ! =m ( a d>k r$ p[d]1 & is itself dissolv$4 ,imag9+ t ,i p]ceiv$ "s resemblance betwe5 ! prop]ties ( magnesia & ^? ( alkalis1 ,i 0 l$ to try :at *ange ?is sub/ance w\ld suff] f ! addition ( quick-lime1 :i* alt]s 9 su* a peculi> mann] ! alkal9e salts4 ,tw5ty sev5 gra9s ( magnesia 9 f9e p[d] 7 mix$ ) eighte5 ounces ( lime-wat] 9 a flask1 :i* 0 cork$ close & %ak5 frequ5tly = f\r days4 ,dur+ ?is "t1 ,i frequ5tly dipp'd into x little bits ( pap]1 :i* 7 col\r$ ) ! juice ( violets2 & ^! became gre5 z soon z !y t\*$ ! wat]1 until ! f\r? day1 :5 _! col\r did n seem to be alt]$4 ,! wat] be+ n[ p\r$ (f1 0 intirely insipid1 & agre$ 9 e *emical trial ) pure wat]4 ,! p[d]1 aft] be+ p]fectly well dri$1 weigh$ ?irty sev5 gra9s4 ,x did n dissolve intirely 9 _s ( vitriol2 b1 aft] a brisk eff]vesc5ce1 "p ( x subsid$ 9 ! same mann] z ! calc>i\s e>?s1 :5 mix$ ) ?is acid4 ,:5 ,i fir/ tri$ ?is exp]im5t1 ,i 0 at ! tr\ble ( dige/+ ! mixture 9 ! heat ( boil+ wat]1 & did n !n "k t x w\ld succe$ 9 ! heat ( ! air4 ,b ,dr4 ,al/on1 :o has oblig$ ! _w ) _m curi\s & useful discov]ies on ! subject ( quick-lime1 hav+ _h occasion to repeat x1 ,i le>n$ f him t heat is n necess>y2 & he has moreov] add$ an useful purpose to :i* ?is prop]ty ( magnesia may be appli$2 ,i mean ! sweet5+ ( wat] at sea1 ) :i* lime may h be5 mix$ to prev5t its putrefaction4 ,t "p ( ! dri$ p[d] :i* does n dissolve 9 _s ( vitriol1 consi/s ( ! lime sep>at$ f ! wat]4 ,quick-lime itself is also r5d]$ mild by magnesia1 if ^! two are well rubb$ toge!r & infus$ ) a small quantity ( wat]4 ,by ! foll[+ exp]im5ts1 ,i propos$ to "k :e!r ?is sub/ance c\ld be r$uc$ to a quick-lime4 ,an ounce ( magnesia 0 expos$ 9 a crucible = ab\t an h\r to su* a heat z is suffici5t to melt copp]4 ,:5 tak5 out1 x weigh$ ?ree drams & "o scruple1 or _h lo/ #g_/ab ( its =m] weight4 ,i repeat$1 ) ! magnesia prep>$ 9 ?is mann]1 mo/ ( ^? exp]im5ts ,i _h already made ^u x be=e calc9ation1 & ! result 0 z foll[s4 ,x dissolves 9 all ! acids1 & ) ^! composes salts exactly simil> to ^? describ$ 9 ! fir/ set ( exp]im5ts3 b :at is p>ticul>ly to be rem>k$1 x is dissolv$ )\t any ! lea/ degree ( eff]vesc5ce4 ,x sl[ly precipitates ! corrosive sublimate ( m]cury 9 ! =m ( a black p[d]4 ,x sep>ates ! volatile alkali 9 salt ammoniac f ! acid1 :5 x is mix$ ) a w>m solution ( t salt4 ,b x does n sep>ate an acid f a calc>i\s e>?1 nor does x induce ! lea/ *ange ^u lime-wat]4 ,la/ly1 :5 a dram ( x is dige/$ ) an ounce ( wat] 9 a bottle = "s h\rs1 x does n make any ! lea/ *ange 9 ! wat]4 ,! magnesia1 :5 dri$1 is f\nd to h ga9$ t5 gra9s2 b x nei!r eff]vesces ) acids1 nor does x s5sibly affect lime-wat]4 ,obs]v+ magnesia to lose su* a rem>kable proportion ( its weight 9 ! fire1 my next attempts 7 direct$ to ! inve/igation ( ?is volatile "p1 &1 among o!r exp]im5ts1 ! foll[+ seem$ to ?r[ "s light ^u x4 ,?ree ounces ( magnesia 7 di/ill$ 9 a glass retort & receiv]1 ! fire be+ gradually increas$ until ! magnesia 0 obscurely r$ hot4 ,:5 all 0 cool1 ,i f\nd only five drams ( a :iti% wat] 9 ! receiv]1 :i* _h a fa9t smell ( ! _s ( h>t%orn1 gave a gre5 col\r to ! juice ( violets1 & r5d]$ ! solutions ( corrosive sublimate & ( silv] v slightly turbid4 ,b x did n s5sibly eff]vesce ) acids4 ,! magnesia1 :5 tak5 out ( ! retort1 weigh$ an ounce1 ?ree drams1 & ?irty gra9s1 or _h lo/ m ?an ! half ( its weight4 ,x /ill eff]vesc$ pretty briskly ) acids1 ?o' n s /rongly z be=e ?is op]ation4 ,! fire %\ld h be5 rais$ "h to ! degree requisite = ! p]fect calc9ation ( magnesia4 ,b ev5 f ?is imp]fect exp]im5t1 x is evid5t1 t ( ! volatile p>ts conta9$ 9 t p[d]1 a small proportion only is wat]2 ! re/ _c1 x seems1 be reta9$ 9 vessels1 "u a visible =m4 ,*emi/s h (t5 obs]v$1 9 _! di/illations1 t "p ( a body has vani%$ f _! s5ses1 not)/&+ ! utmo/ c>e to reta9 x2 & !y h always f\nd1 ^u fur!r inquiry1 t subtile "p to be air1 :i* hav+ be5 imprison$ 9 ! body1 "u a solid =m1 0 set free & r5d]$ fluid & ela/ic by ! fire4 ,we may !re=e safely conclude1 t ! volatile matt]1 lo/ 9 ! calc9ation ( magnesia1 is mo/ly air2 & h5ce ! calc9$ magnesia does n emit air1 or make an eff]vesc5ce1 :5 mix$ ) acids4 ,! wat]1 f its prop]ties1 seems to conta9 a small portion ( volatile alkali1 :i* 0 probably =m$ f ! e>?1 air1 & wat]1 or f "s ( ^! comb9$ toge!r2 & p]haps also f a small quantity ( inflammable matt] :i* adh]$ accid5tally to ! magnesia4 ,:5ev] ,*emi/s meet ) ?is salt1 !y are incl9$ to ascribe its orig9 to "s animal1 or putrid vegetable1 sub/ance2 & ?is !y h always done1 :5 !y obta9$ x f ! calc>i\s e>?s1 all ( :i* af=d a small quantity ( x4 ,!re is1 h[ev]1 no d\bt t x c sometimes be produc$ indep5d5tly ( any su* mixture1 s9ce _m fre% vegetables & t>t> af=d a consid]able quantity ( x4 ,& h[ c x1 9 ! pres5t in/ance1 be suppos$1 t any animal or vegetable matt] adh]$ to ! magnesia1 :ile x 0 dissolv$ by an acid1 sep>at$ f ?is by an alkali1 & wa%$ ) s mu* wat]8 ,two drams ( magnesia 7 calc9$ 9 a crucible1 9 ! mann] describ$ above1 & ?us r$uc$ to two scruples & twelve gra9s4 ,?is calc9$ magnesia 0 dissolv$ 9 a suffici5t quantity ( _s ( vitriol1 & !n aga9 sep>at$ f ! acid by ! addition ( an alkali1 ( :i* a l>ge quantity is necess>y = ?is purpose4 ,! magnesia be+ v well wa%$ & dry$1 weigh$ "o dram & fifty gra9s4 ,x eff]vesc$ viol5tly1 or emitt$ a l>ge quantity ( air1 :5 ?r[n into acids1 =m$ a r$ p[d] :5 mix$ ) a solution ( sublimate1 sep>at$ ! calc>i\s e>?s f an acid1 & sweet5$ lime-wat]3 & _h ?us recov]$ all ^? prop]ties :i* x _h b j n[ lo/ by calc9ation3 nor _h x only recov]$ its orig9al prop]ties1 b acquir$ besides an addition ( weight ne>ly equal to :at _h be5 lo/ 9 ! fire2 &1 z x is f\nd to eff]vesce ) acids1 "p ( ! addition mu/ c]ta9ly be air4 ,?is air seems to h be5 furni%$ by ! alkali f :i* x 0 sep>at$ by ! acid2 = ,dr4 ,hales has cle>ly prov$1 t alkal9e salts conta9 a l>ge quantity ( fix$ air1 :i* !y emit 9 great abundance :5 jo9$ to a pure acid4 ,9 ! pres5t case1 ! alkali is really jo9$ to an acid1 b )\t any visible emission ( air2 & yet ! air is n reta9$ 9 x3 = ! neutral salt1 into :i* x is conv]t$1 is ! same 9 quantity1 & 9 e o!r respect1 z if ! acid employ$ _h n be5 previ\sly saturat$ ) magnesia1 b (f]$ to ! alkali 9 its pure /ate1 & _h driv5 ! air out ( x 9 _! conflict4 ,x seems !re=e evid5t1 t ! air 0 =c$ f ! alkali by ! acid1 & lodg$ itself 9 ! magnesia4 ,^! consid]ations l$ me to try a few exp]im5ts1 :]eby ,i might "k :at quantity ( air is expell$ f an alkali1 or f magnesia1 by acids4 ,two drams ( a pure fix$ alkal9e salt1 & an ounce ( wat]1 7 put into a ,flor5t9e flask1 :i*1 toge!r ) its cont5ts1 weigh$ two ounces & two drams4 ,"s oil ( vitriol dilut$ ) wat] 0 dropt 91 until ! salt 0 exactly saturat$2 :i* x 0 f\nd to be1 :5 two drams1 two scruples1 & ?ree gra9s ( ?is acid _h be5 add$4 ,! vial ) its cont5ts n[ weigh$ two ounces1 f\r drams1 & fifte5 gra9s4 ,"o scruple1 !re=e1 & eight gra9s 7 lo/ dur+ ! ebullition1 ( :i* a trifl+ portion may be wat]1 or some?+ ( ! same k9d4 ,! re/ is air4 ,! celebrat$ ,homb]g has attempt$ to e/imate ! quantity ( solid salt conta9$ 9 a det]m9$ portion ( ! sev]al acids4 ,he saturat$ equal quantities ( an alkali ) ea* ( !m2 &1 obs]v+ ! weight :i* ! alkali _h ga9$1 aft] be+ p]fectly dry$1 took ?is = ! quantity ( solid salt conta9$ 9 t %>e ( ! acid :i* p]=m$ ! saturation4 ,b we le>n f ! above exp]im5t1 t 8 e/imate 0 n accurate1 because ! alkali loses weight z well z ga9s x4 ,two drams ( magnesia1 treat$ exactly z ! alkali 9 ! la/ exp]im5t1 7 j dissolv$ by f\r drams1 "o scruple1 & sev5 gra9s ( ! same acid liquor1 & lo/ "o scruple & sixte5 gra9s by ! ebullition4 ,two drams ( magnesia 7 r$uc$1 by ! action ( a viol5t fire1 to two scruples & twelve gra9s1 ) :i* ! same process 0 repeat$1 z 9 ! two la/ exp]im5ts2 f\r drams1 "o scruple1 & two gra9s ( ! same acid 7 requir$ to compleat ! solution1 & no weight 0 lo/ 9 ! exp]im5t4 ,z 9 ! sep>ation ( ! volatile f ! fix$ p>ts ( bodies1 by means ( heat1 a small quantity ( ! latt] is g5]ally rais$ ) ! =m]2 s ! air & wat]1 orig9ally conta9$ 9 ! magnesia1 & aft]w>ds dissipat$ by ! fire1 seem to h c>ri$ (f a small "p ( ! fix$ e>? ( ?is sub/ance4 ,?is is probably ! reason1 :y calc9$ magnesia is saturat$ ) a quantity ( acid1 some:at less ?an :at is requir$ to dissolve x be=e calc9ation3 & ! same may be assign$ z "o cause :i* h9d]s u f re/or+ ! :ole ( its orig9al weight1 by solution & precipitation4 ,i took c>e to dilute ! vitriolic acid1 9 ord] to avoid ! heat & ebullition :i* x w\ld o!rwise h excit$ 9 ! wat]2 & ,i *ose a ,flor5t9e flask1 on acc\nt ( its lightness1 capacity1 & %ape1 :i* is peculi>ly adapt$ to ! exp]im5t2 = ! vap\rs rais$ by ! ebullition circulat$ = a %ort "t1 ?ro' ! wide cavity ( ! vial1 b 7 soon collect$ ^u its sides1 l dew1 & none ( !m seem$ to rea* ! neck1 :i* cont9u$ p]fectly dry to ! end ( ! exp]im5t4 ,we n[ p]ceive ! reason1 :y crude & calc9$ magnesia1 :i* diff] 9 _m respects f "o ano!r1 agree h[ev] 9 compos+ ! same k9d ( salt1 :5 dissolv$ 9 any p>ticul> acid2 = ! crude magnesia seems to diff] f ! calc9$ *iefly by conta9+ a consid]able quantity ( air1 :i* air is unavoidably dissipat$ & lo/ dur+ ! dissolution4 ,f our exp]im5ts1 x seems probable1 t ! increase ( weight :i* "s metals acquire1 by be+ fir/ dissolv$ 9 acids1 & !n sep>at$ f !m aga9 by alkalis1 proce$s f air furni%$ by ! alkalis4 ,& t 9 ! aurum fulm9ans1 :i* is prep>$ by ! same means1 ?is air adh]es to ! gold 9 su* a peculi> mann]1 t1 9 a mod]ate degree ( heat1 ! :ole ( x recov]s its ela/icity 9 ! same in/ant ( "t2 & ?us1 by ! viol5t %ock :i* x gives to ! air ar\nd1 produces ! l\d crack or fulm9ation ( ?is p[d]4 ,^? :o w imag9e ! explosion ( su* a m9ute portion ( fix$ air1 z c reside 9 ! aurum fulm9ans1 to be insuffici5t = ! excessive l\dness ( ! noise1 w consid]1 t x is n a l>ge quantity ( motion communicat$ to ! air1 b r a sm>t /roke :i* produces s\nd1 & t ! explosion ( b a few p>ticles ( fix$ air may be capable ( caus+ a l\d noise1 provid$ !y all recov] _! spr+ sudd5ly1 & 9 ! same in/ant4 ,! above exp]im5ts lead u also to conclude1 t volatile alkalis1 & ! common absorb5t e>?s1 :i* lose _! air by be+ jo9$ to acids1 b %ew evid5t signs ( _! hav+ recov]$ x1 :5 sep>at$ f !m by alkalis1 receiv$ x f ^! alkalis :i* lo/ x 9 ! in/ant ( _! jo9+ ) ! acid4 ,! foll[+ are a few exp]im5ts ^u ?ree ( ! absorb5t e>?s1 made 9 ord] to comp>e !m ) "o ano!r1 & ) magnesia4 ,suspect+ t magnesia might possibly be no o!r ?an a common calc>i\s e>?1 :i* _h *ang$ its nature1 by hav+ be5 previ\sly comb9$ ) an acid1 ,i saturat$ a small quantity ( *alk ) ! muriatic acid1 sep>at$ ! acid f x aga9 by means ( a fix$ alkali1 & c>efully wa%$ away ! :ole ( ! salt4 ,! *alk :5 dry$ 0 n f\nd to h suff]$ any alt]ation2 = x eff]vesc$ ) ! vitriolic acid1 b did n dissolve 9 x2 & :5 expos$ to a viol5t fire1 0 conv]t$ into a quick-lime1 9 all respects simil> to t obta9$ f common *alk4 ,9 ano!r exp]im5t ( ! same k9d1 ,i us$ ! vitriolic acid ) ! same ev5t4 ,any calc>i\s matt] r$uc$ to a f9e p[d]1 & ?r[n into a w>m solution ( alum1 imm$iately raises a brisk eff]vesc5ce4 ,b ! p[d] is n dissolv$2 x is r increas$ 9 bulk3 & if ! addition be repeat$ until x is no long] accompani$ ) eff]vesc5ce1 ! liquor loses all ta/e ( ! alum1 & yields only a v light cl\d ^u ! admixture ( an alkali4 ,f ?is exp]im5t we le>n1 t acids attract ! calc>i\s e>?s m /rongly ?an !y d ! e>? ( alum2 & z ! acid 9 ?is salt is exactly ! same ) ! vitriolic1 x composes ) ! calc>i\s e>? a neutral sub/ance1 :i* is v difficultly soluble 9 wat]1 & !re=e falls d[n to ! bottom ( ! vessel along ) ! e>? ( alum :i* is depriv$ ( its acid4 ,! light cl\d =m$ by ! alkali proce$s f ! m9ute portion ( ! calc>i\s comp\nd :i* saturates ! wat]4 ,! e>? ( animal bones1 :5 r$uc$ to a f9e p[d] & ?r[n into a dilut$ vitriolic acid1 gradually absorbs ! acid 9 ! same mann] z ! calc>i\s e>?s1 b )\t any rem>kable eff]vesc5ce4 ,:5 x is add$ to ! nitr\s or to ! muriatic acid1 x is sl[ly dissolv$4 ,! comp\nd liquor !nce produc$ is extremely acrid1 & /ill *anges ! col\r ( ! juice ( violets to a r$1 ev5 aft] x is fully saturat$ ) ! absorb5t4 ,di/ill$ v9eg> has little or no effect ^u ?is e>?2 = aft] a long dige/ion x /ill reta9s its s\r ta/e1 & gives only a light cl\d ^u ! addition ( an alkali4 ,by dropp+ a dissolv$ fix$ alkali into a w>m solution ( alum1 ,i obta9$ ! e>? ( ?is salt1 :i*1 aft] be+ well wa%$ & dri$1 0 f\nd to h ! foll[+ prop]ties4 ,x is dissolv$ 9 e acid b v sl[ly1 unless assi/$ by heat4 ,! sev]al solutions1 :5 ?or\ghly saturat$1 are all a/r+5t ) a slight degree ( an acid ta/e1 & !y also agree ) a solution ( alum 9 ?is1 t !y give a r$ col\r to ! infusion ( turnsol4 ,nei!r ?is e>?1 nor t ( animal bones1 c be conv]t$ into quick-lime by ! /ronge/ fire1 nor d !y suff] any *ange wor? notice4 ,bo? ( !m seem to attract acids b weakly1 & to alt] _! prop]ties less :5 unit$ to !m ?an ! o!r absorb5ts4 ,,"p ,,ii4 ,9 reflect+ aft]w>ds ^u ^! exp]im5ts1 an explication ( ! nature ( lime (f]$ itself1 :i* seem$ to acc\nt1 9 an easy mann]1 = mo/ ( ! prop]ties ( t sub/ance4 ,x is suffici5tly cle>1 t ! calc>i\s e>?s 9 _! native /ate1 & t ! alkalis & magnesia 9 _! ord9>y condition1 conta9 a l>ge quantity ( fix$ air1 & ?is air c]ta9ly adh]es to !m ) consid]able =ce1 s9ce a /rong fire is necess>y to sep>ate x f magnesia1 & ! /ronge/ is n suffici5t to expel x entirely f fix$ alkalis1 or take away _! p[] ( eff]vesc+ ) acid salts4 ,^! consid]ations l$ me to conclude1 t ! relations betwe5 fix$ air & alkal9e sub/ances 0 some:at simil> to ! relation betwe5 ^! & acids2 t z ! calc>i\s e>?s & alkalis attract acids /rongly & c be saturat$ ) !m1 s !y also attract fix$ air1 & are 9 _! ord9>y /ate saturat$ ) x3 & :5 we mix an acid ) an alkali or ) an absorb5t e>?1 t ! air is !n set at lib]ty1 & breaks out ) viol5ce2 because ! alkal9e body attracts x m weakly ?an x does ! acid1 & because ! acid & air _c bo? be jo9$ to ! same body at ! same "t4 ,i also imag9$1 t1 :5 ! calc>i\s e>?s are expos$ to ! action ( a viol5t fire1 & are !reby conv]t$ into quick-lime1 !y suff] no o!r *ange 9 _! composition ?an ! loss ( a small quantity ( wat] & ( _! fix$ air4 ,! rem>kable acrimony :i* we p]ceive 9 !m aft] ?is process1 0 n suppos$ to proce$ f any additional matt] receiv$ 9 ! fire1 b seem$ to be an ess5tial prop]ty ( ! pure e>?1 dep5d+ on an attraction = ^? sev]al sub/ances :i* x !n became capable ( corrod+ or dissolv+1 :i* attraction _h be5 ins5sible z long z ! air adh]$ to ! e>?1 b discov]$ itself ^u ! sep>ation4 ,?is supposition 0 f\nd$ ^u an obs]vation ( ! mo/ frequ5t consequ5ces ( comb9+ bodies 9 *emi/ry4 ,commonly :5 we jo9 two bodies toge!r1 _! acrimony or attraction = o!r sub/ances becomes imm$iately ei!r less p]ceivable or entirely ins5sible2 al?o' x 0 suffici5tly /rong & rem>kable be=e _! union1 & may be r5d]$ evid5t aga9 by disjo9+ !m4 ,a neutral salt1 :i* is compos$ ( an acid & alkali1 does n possess ! acrimony ( ei!r ( its con/itu5t p>ts4 ,x c easily be sep>at$ f wat]1 has little or no effect ^u metals1 is incapable ( be+ jo9$ to inflammable bodies1 & ( corrod+ & dissolv+ animals & vegetables2 s t ! attraction bo? ( ! acid & alkali = ^! sev]al sub/ances seems to be susp5d$ till !y are aga9 sep>at$ f "o ano!r4 ,crude lime 0 !re=e consid]$ z a peculi> acrid e>? r5d]$ mild by its union ) fix$ air3 & quick-lime z ! same e>?1 9 :i*1 by hav+ sep>at$ ! air1 we discov] t acrimony or attraction = wat]1 = animal1 vegetable1 & = inflammable sub/ances4 ,t ! calc>i\s e>?s really lose a l>ge quantity ( air :5 !y are burnt to quick-lime1 seems suffici5tly prov$ by an exp]im5t ( ,mr4 ,m>graaf1#f an exce$+ly accurate & judici\s ,*emi/4 ,he subject$ eight ounces ( o/eocolla to di/illation 9 an e>!n retort1 f9i%+ 8 process ) ! mo/ viol5t fire ( a rev]b]atory1 & caught 9 ! receiv] only two drams ( wat]1 :i* by its smell & prop]ties %ew$ itself to be slightly alkal9e4 ,he does n tell u ! weight ( ! o/eocolla rema9+ 9 ! retort1 & only says1 t x 0 conv]t$ into quick-lime2 b z no calc>i\s e>? c be conv]t$ into quick-lime1 or be> ! heat :i* he appli$ )\t los+ above a ?ird ( its weight1 we may safely conclude1 t ! loss 9 8 exp]im5t 0 proportional1 & proce$$ *iefly f ! dissipation ( fix$ air4 ,accord+ to our !ory1 ! relation ( ! calc>i\s e>? to air & wat] appe>$ to agree ) ! relation ( ! same e>? to ! vitriolic & vegetable acids4 ,z *alk = in/ance has a /rong] attraction = ! vitriolic ?an = ! vegetable acid1 & is dissolv$ ) m difficulty :5 comb9$ ) ! fir/1 ?an :5 jo9$ to ! second3 s x also attracts air m /rongly ?an wat]1 & is dissolv$ ) m difficulty :5 saturat$ ) air ?an :5 comp\nd$ ) wat] only4 ,a calc>i\s e>? depriv$ ( its air1 or 9 ! /ate ( quick-lime1 gre$ily absorbs a consid]able quantity ( wat]1 becomes soluble 9 t fluid1 & is !n said to be slak$2 b z soon z x meets ) fix$ air1 x is suppos$ to quit ! wat] & jo9 itself to ! air1 = :i* x has a sup]ior attraction1 & is !re=e re/or$ to its fir/ /ate ( mildness & insolubility 9 wat]4 ,:5 slak$ lime is mix$ ) wat]1 ! fix$ air 9 ! wat] is attract$ by ! lime1 & saturates a small portion ( x1 :i* !n becomes aga9 incapable ( dissolution1 b "p ( ! rema9+ slak$ lime is dissolv$ & composes lime-wat]4 ,if ?is fluid be expos$ to ! op5 air1 ! p>ticles ( quick-lime :i* are ne>e/ ! surface gradually attract ! p>ticles ( fix$ air :i* float 9 ! atmosph]e4 ,b at ! same "t t a p>ticle ( lime is ?us saturat$ ) air1 x is also re/or$ to its native /ate ( mildness & insolubility2 & z ! :ole ( ?is *ange mu/ happ5 at ! surface1 ! :ole ( ! lime is successively collect$ !re "u its orig9al =m ( an insipid calc>i\s e>?1 call$ ! cream or cru/s ( lime-wat]4 ,:5 quick-lime itself is expos$ to ! op5 air1 x absorbs ! p>ticles ( wat] & ( fix$ air :i* come )9 its sph]e ( attraction1 z x meets ) ! fir/ ( ^! 9 greate/ pl5ty1 ! greate/ "p ( x assumes ! =m ( slak$ lime2 ! re/ is re/or$ to its orig9al /ate2 & if x be expos$ = a suffici5t l5g? ( "t1 ! :ole ( x is gradually saturat$ ) air1 to :i* ! wat] z gradually yields its place4 ,we h already %[n by exp]im5t1 t magnesia alba is a comp\nd ( a peculi> e>? & fix$ air4 ,:5 ?is sub/ance is mix$ ) lime-wat]1 ! lime %ews a /rong] attraction = fix$ air ?an t ( ! e>? ( magnesia2 ! air leaves ?is p[d] to jo9 itself to ! lime4 ,& z nei!r ! lime :5 saturat$ ) air1 nor ! magnesia :5 depriv$ ( x1 are soluble 9 wat]1 ! lime-wat] becomes p]fectly pure & insipid1 ! lime :i* x conta9$ be+ mix$ ) ! magnesia4 ,b if ! magnesia be depriv$ ( air by calc9ation be=e x is mix$ ) ! lime-wat]1 ?is fluid suff]s no alt]ation4 ,if quick-lime be mix$ ) a dissolv$ alkali1 x likeways %ews an attraction = fix$ air sup]ior to t ( ! alkali4 ,x robs ?is salt ( its air1 & !reby becomes mild itself1 :ile ! alkali is consequ5tly r5d]$ m corrosive1 or discov]s its natural degree ( acrimony or /rong attraction = wat]1 & = bodies ( ! inflammable1 & ( ! animal & vegetable k9d2 :i* attraction 0 less p]ceivable z long z x 0 saturat$ ) air4 ,& ! volatile alkali :5 depriv$ ( its air1 besides ?is attraction = v>i\s bodies1 discov]s likeways its natural degree ( volatility1 :i* 0 =m]ly some:at repress$ by ! air adh]+ to x1 9 ! same mann] z x is repress$ by ! addition ( an acid4 ,?is acc\nt ( lime & alkalis recomm5d$ itself by its simplicity1 & by af=d+ an easy solution ( _m phnom5a1 b appe>$ ^u a ne>] view to be att5d$ ) consequ5ces t 7 s v new & extraord9>y1 z to r5d] suspici\s ! pr9ciples f :i* !y 7 drawn4 ,i resolv$ h[ev] to exam9e1 9 a p>ticul> mann]1 su* ( ^! consequ5ces z 7 ! mo/ unavoidable1 & f\nd ! greate/ numb] ( !m might be r$uc$ to ! foll[+ propositions3 ,i4 ,if we only sep>ate a quantity ( air f lime & alkalis1 :5 we r5d] !m cau/ic !y w be f\nd to lose "p ( _! weight 9 ! op]ation1 b w saturate ! same quantity ( acid z be=e1 & ! saturation w be p]=m$ )\t eff]vesc5ce4 ,,ii4 ,if quick-lime be no o!r ?an a calc>i\s e>? depriv$ ( its air1 & ^: attraction = fix$ air is /rong] ?an t ( alkalis1 x foll[s1 t1 by add+ to x a suffici5t quantity ( alkali saturat$ ) air1 ! lime w recov] ! :ole ( its air1 & be entirely re/or$ to its orig9al weight & condition3 & x also foll[s1 t ! e>? sep>at$ f lime-wat] by an alkali1 is ! lime :i* 0 dissolv$ 9 ! wat] n[ re/or$ to its orig9al mild & insoluble /ate4 ,,iii4 ,if x be suppos$ t slak$ lime does n conta9 any p>ts :i* are m firey1 active or subtile ?an o!rs1 & by :i* *iefly x communicates its virtues to wat]2 b t x is an uni=m comp\nd ( lime & wat]3 x foll[s1 t1 z "p ( x c be dissolv$ 9 wat]1 ! :ole ( x is also capable ( be+ dissolv$4 ,,iv4 ,if ! acrimony ( ! cau/ic alkali does n dep5d on any "p ( ! lime adh]+ to x1 a cau/ic or soap-ley w consequ5tly be f\nd to conta9 no lime1 unless ! quantity ( lime employ$ 9 mak+ x 7 great] ?an :at is j suffici5t to extract ! :ole air ( ! alkali2 = !n z mu* ( ! sup]flu\s quick-lime might possibly be dissolv$ by ! ley z w\ld be dissolv$ by pure wat]1 or ! ley w\ld conta9 z mu* lime z lime-wat] does4 ,v4 ,we h %ewn 9 ! =m] exp]im5ts1 t absorb5t e>?s lose _! air :5 !y are jo9$ to an acid2 b recov] x1 if sep>at$ aga9 f t acid1 by means ( an ord9>y alkali3 ! air pass+ f ! alkali to ! e>?1 at ! same "t t ! acid passes f ! e>? to ! alkali4 ,if ! cau/ic alkali !re=e be de/itute ( air1 x w sep>ate magnesia f an acid "u ! =m ( a magnesia free ( air1 or :i* w n eff]vesce ) acids2 & ! same cau/ic alkali w also sep>ate a calc>i\s e>? f acids "u ! =m ( a calc>i\s e>? de/itute ( air1 b saturat$ ) wat]1 or "u ! =m ( slak$ lime4 ,^! 7 all necess>y conclusions f ! above suppositions4 ,_m ( !m appe>$ too improbable to des]ve any fur!r att5tion3 "s h[ev]1 ,i f\nd ^u reflection1 7 already second$ by exp]i5ce4 ,?us ,h(fman has obs]v$1 t quick-lime does n eff]vesce ) _s ( vitriol2#g & x is well kn[n t ! cau/ic _s ( ur9e1 or ( salt ammoniac1 does n emit air1 :5 mix$ ) acids4 ,?is consid]ation excit$ my curiosity1 & det]m9$ me to inquire into ! tru? ( !m all by way ( exp]im5t4 ,i !re=e engag$ myself 9 a set ( trials2 ! hi/ory ( :i* is "h subjo9$4 ,"s new facts are likeways occasionally m5tion$2 & "h x w be prop] to in=m ! read]1 t ,i h nev] m5tion$ any )\t satisfy+ myself ( _! tru? by exp]im5t1 ?o' ,i h sometimes tak5 ! lib]ty to neglect describ+ ! exp]im5ts :5 !y seem$ suffici5tly obvi\s4 ,desir+ to "k h[ mu* ( an acid a calc>i\s e>? w absorb1 & :at quantity ( air is expell$ dur+ ! dissolution1 ,i saturat$ two drams ( *alk ) dilut$ _s ( salt1 & us$ ! ,flor5t9e flask1 z relat$ 9 a simil> exp]im5t ^u magnesia4 ,sev5 drams & "o gra9 ( ! acid f9i%$ ! dissolution1 & ! *alk lo/ two scruples & eight gra9s ( air4 ,?is exp]im5t 0 necess>y be=e ! foll[+1 by :i* ,i propos$ to inquire into ! tru? ( ! fir/ proposition s f> z x relates to quick-lime4 ,two drams ( *alk 7 conv]t$ into a p]fect quick-lime1 & lo/ two scruples & twelve gra9s 9 ! fire4 ,?is quick-lime 0 slak$ or r$uc$ to a milky liquor ) an ounce ( wat]1 & !n dissolv$ 9 ! same mann]1 & ) ! same acid1 z ! two drams ( *alk 9 ! prec$+ exp]im5t4 ,six drams1 two scruples & f\rte5 gra9s ( ! acid f9i%$ ! saturation )\t any s5sible eff]vesc5ce or loss ( weight4 ,x !re=e appe>s f ^! exp]im5ts1 t no air is sep>at$ f quick-lime by an acid1 & t *alk saturates ne>ly ! same quantity ( acid aft] x is conv]t$ into quick-lime z be=e4 ,) respect to ! second proposition1 ,i tri$ ! foll[+ exp]im5ts4 ,a piece ( p]fect quick-lime made f two drams ( *alk1 & :i* weigh$ "o dram & eight gra9s1 0 r$uc$ to a v f9e p[d]1 & ?r[n into a filtrat$ mixture ( an ounce ( a fix$ alkal9e salt & two ounces ( wat]4 ,aft] a slight dige/ion1 ! p[d] be+ well wa%$ & dri$1 weigh$ "o dram & fifty eight gra9s4 ,x 0 simil> 9 e trial to a f9e p[d] ( ord9>y *alk1 & 0 !re=e saturat$ ) air :i* mu/ h be5 furni%$ by ! alkali4 ,a dram ( pure salt ( t>t> 0 dissolv$ 9 f\rte5 p\nds ( lime-wat]1 & ! p[d] !reby precipitat$1 be+ c>efully collect$ & dri$1 weigh$ "o & fifty gra9s4 ,:5 expos$ to a viol5t fire1 x 0 conv]t$ into a true quick-lime1 & _h e o!r quality ( a calc>i\s e>?4 ,?is exp]im5t 0 repeat$ ) ! volatile alkali1 & also ) ! fossil or alkali ( sea-salt1 & exactly ) ! same ev5t4 ,! ?ird proposition _h less appe>ance ( probability ?an ! =ego+2 b1 z an accurate exp]im5t 0 ! only te/ ( its tru?1 ,i r$uc$ eight gra9s ( p]fect quick-lime made ( *alk1 to an exce$+ly subtile p[d]1 by slak+ x 9 two drams ( di/ill$ wat] boil+ hot1 & imm$iately ?rew ! mixture into eighte5 ounces ( di/ill$ wat] 9 a flask4 ,aft] %ak+ x1 a light s$im5t1 :i* float$ ?ro' ! liquor1 0 all[$ to subside & ?is1 :5 collect$ ) ! greate/ c>e1 & dry$1 weigh$1 z ne>ly z ,i c\ld guess1 "o ?ird ( a gra94 ,! wat] ta/$ /rongly ( ! lime1 _h all ! qualities ( lime-wat]1 & yield$ twelve gra9s ( precipitate1 ^u ! addition ( salt ( t>t>4 ,9 repeat+ ?is exp]im5t1 ! quantity ( s$im5t 0 sometimes less ?an ! above1 & sometimes am\nt$ to half a gra94 ,x consi/$ p>tly ( an e>? :i* eff]vesc$ viol5tly ) aqua =tis1 & p>tly ( an o*ry p[d]1 :i* w\ld n dissolve 9 t acid4 ,! o*ry p[d]1 z x usually appe>s 9 *alk to ! eye1 9 ! =m ( ve9s runn+ ?ro' its sub/ance1 mu/ be consid]$ only z an accid5tal or =eign admixture2 &1 ) respect to ! m9ute portion ( alkal9e e>? :i* compos$ ! rema9d] ( ! s$im5t1 x _c be suppos$ to h be5 orig9ally diff]5t f ! re/1 & incapable1 f its nature1 ( be+ conv]t$ into quick-lime1 or ( be+ dissolv$ 9 wat]2 x seems r to h consi/$ ( a small "p ( ! *alk 9 its mild /ate1 or saturat$ ) air1 :i* _h ei!r rema9$1 = want ( a suffici5t fire to drive x out entirely1 or _h be5 furni%$ by ! di/ill$ wat]4 ,i inde$ expect$ to see a mu* l>g] quantity ( s$im5t produc$ f ! lime1 on acc\nt ( ! air :i* wat] con/antly conta9s1 & ) a view to "k :e!r wat] reta9s its air :5 fully saturat$ ) lime1 a lime-wat] 0 made z /rong z possible2 f\r ounces ( :i* 7 plac$ "u ! receiv] ( an air-pump1 toge!r ) f\r ounces ( common wat] 9 a vial ( ! same size2 &1 ^u exhau/+ ! receiv]1 )\t heat+ ! vials1 ! air arose f ea* 9 ne>ly ! same quantity3 f :5ce x is evid5t1 t ! air1 :i* quick-lime attracts1 is ( a diff]5t k9d f t :i* is mix$ ) wat]4 ,& t x is also diff]5t f common ela/ic air1 is suffici5tly prov$ by daily exp]i5ce2 = lime-wat]1 :i* soon attracts air1 & =ms a cru/ :5 expos$ 9 op5 & %all[ vessels1 may be pres]v$1 = any "t1 9 bottles :i* are b slightly cork$1 or clos$ 9 su* a mann] z w\ld all[ free access to ela/ic air1 7 a vacuum =m$ 9 ! bottle4 ,quick-lime !re=e does n attract air :5 9 its mo/ ord9>y =m1 b is capable ( be+ jo9$ to "o p>ticul> species only1 :i* is disp]s$ ?ro' ! atmosph]e1 ei!r 9 ! %ape ( an exce$+ly subtile p[d]1 or m probably 9 t ( an ela/ic fluid4 ,to ?is ,i h giv5 ! "n ( fix$ air1 & p]haps v improp]ly2 b ,i ?\ght x bett] to use a ^w already famili> 9 philosophy1 ?an to inv5t a new "n1 be=e we be m fully acqua9t$ ) ! nature & prop]ties ( ?is sub/ance1 :i* w probably be ! subject ( my fur!r inquiry4 ,x is1 p]haps1 ne$less to m5tion "h1 t ! calc>i\s sub/ances us$ 9 mak+ ! above exp]im5ts %\ld be ( ! pure/ k9d1 & burnt ) ! utmo/ viol5ce ( heat1 if we w\ld be sure ( conv]t+ !m into p]fect quick-lime4 ,i !re=e made use ( *alk burnt 9 a small cov]$ crucible ) ! fi]ce/ fire ( a ,black-smi?'s =ge1 = half an h\r1 & f\nd x necess>y to employ1 = ?is purpose1 a crucible ( ! ,au/rian k9d1 :i* resemble black lead2 = if any calc>i\s sub/ance be heat$ to su* a degree 9 an ord9>y or ,hessian crucible1 ! :ole ( x is melt$ d[n1 toge!r ) "p ( ! vessel1 into glass4 ,i n[ prep>$ to inquire into ! prop]ties ( ! cau/ic alkali2 9 ord] to :i*1 ,i made a cau/ic or soap ley 9 ! foll[+ mann]4 ,tw5ty six ounces ( v /rong quick-lime made ( *alk1 7 slak$ or r$uc$ to a sort ( fluid pa/e1 ) elev5 p\nds ( boil+ wat]1 & !n mix$ 9 a glass vessel ) eighte5 ounces ( a pure fix$ alkal9e salt1 :i* _h be5 fir/ dissolv$ 9 two p\nds & a half ( wat]4 ,?is mixture 0 %ak5 frequ5tly = two h\rs1 :5 ! action ( ! lime ^u ! alkali 0 suppos$ to be ov]1 & no?+ rema9$ b to sep>ate !m aga9 f "o ano!r4 ,i !re=e add$ #ab p\nds ( wat]1 /irr$ up ! lime1 &1 aft] all[+ x to settle aga91 p\r$ (f z mu* ( ! cle> ley z possible4 ,! lime & alkali 7 mix$ toge!r "u ! =m ( a v ?ick milky liquor or fluid pa/e2 because !y are ?us kept 9 p]petual contact & equal mixture until !y h act$ suffici5tly ^u "o ano!r3 :]eas 9 ! common way ( us+ a l>g] quantity ( wat]1 ! lime lies = ! mo/ "p at bottom1 &1 ?o' /irr$ up ev] s (t51 _c ex]t its influ5ce s fully ^u ! alkali1 :i* is uni=mly diffus$ ?ro' e "p ( ! liquor4 ,! above ley 0 f\nd ^u trial to be saturat$ by acids )\t ! lea/ eff]vesc5ce or dim9ution ( weight4 ,x 0 n[ prop] to exam9e :e!r ! alkali suff]$ any loss 9 becom+ cau/ic1 :i* ,i propos$ to attempt by asc]ta9+ ! /r5g? ( ! ley1 or ! quantity ( salt :i* a giv5 portion ( x conta9$2 f :i* by computation "s imp]fect k might be obta9$ ( ! quantity ( cau/ic produc$ f ! eighte5 ounces ( mild salt4 ,i !re=e evaporat$ "s ( my ley1 b soon p]ceiv$ t no c]ta9 judgm5t c\ld be =m$ ( its /r5g? 9 ?is way1 because x always absorb$ a consid]able quantity ( air dur+ ! evaporation1 & ! dri$ salt made a pretty brisk eff]vesc5ce ) acids1 s t ! ley appe>$ /rong] ?an x really 02 & yet1 ^u proce$+ 9 ! e/imate f ?is rude & unfair trial1 x appe>$ t ! salt _h lo/ above a six? 9 becom+ cau/ic1 & ! quantity ( acid saturat$ by two drams ( x 0 to ! quantity ( acid saturat$ by two drams ( salt ( t>t>1 ne>ly z six to five4 ,^! exp]im5ts are !re=e agreeable to t "p ( ! second proposition :i* relates to ! cau/ic alkali4 ,^u f>!r exam9+ :at *anges ! alkali _h und]gone1 ,i f\nd t ! ley gave only an exce$+ fa9t milky hue to lime-wat]2 because ! cau/ic alkali wants t air by :i* salt ( t>t> precipitates ! lime4 ,:5 a few ounces ( x 7 expos$ 9 an op5 %all[ vessel = f\r & tw5ty h\rs1 x imbib$ a small quantity ( air1 & made a slight eff]vesc5ce ) acids4 ,aft] a =tnight's exposure 9 ! same mann]1 x became entirely mild1 eff]vesc$ z viol5tly ) acids1 & _h ! same effect ^u lime-wat] z a solution ( an ord9>y alkali4 ,x likeways agrees ) lime-wat] 9 ?is respect1 t x may be kept 9 close vessels1 or ev5 9 bottles :i* are b slightly cov]$1 = a consid]able "t1 )\t absorb+ a s5sible quantity ( air4 ,9 ord] to "k h[ mu* lime x conta9$1 ,i evaporat$ t5 ounces 9 a small silv] di% ov] a lamp1 & melt$ ! salt1 aft] hav+ dissipat$ ! wat]4#h ,! cau/ic ?us produc$ 0 dissolv$ aga9 9 a small quantity ( wat]1 & deposit$ a trifl+ portion ( s$im5t1 :i* ,i imag9$ at fir/ to be lime2 b f9d+ t x c\ld easily be dissolv$ 9 a little m wat]1 conclud$ x to be a vitriolat$ t>t>1 :i* always accompanies ! fix$ alkali ( vegetables4 ,i !n saturat$ ! solution ( ! cau/ic salt ) _s ( vitriol1 expect+ ?us to detect ! lime2 because t acid precipitates a calc>i\s e>? f its ord9>y solutions4 ,dur+ ! saturation1 a l>ge quantity ( :ite p[d] 0 =m$2 b ?is likeways turn$ out to be a vitriolat$ t>t>1 :i* _h appe>$ 9 ! =m ( a p[d]1 because !re 0 n en\gh ( wat] 9 ! mixture to dissolve x4 ,la/ly1 ,i expos$ a few ounces ( ! ley 9 an op5 %all[ vessel s long1 t ! alkali lo/ ! :ole ( its cau/icity1 & seem$ entirely re/or$ to ! /ate ( an ord9>y fix$ alkali2 b x did n h[ev] deposite a s+le atom ( lime4 ,& to assure myself t my cau/ic ley 0 n ( a s+ul> k9d1 ,i repeat$ ! same exp]im5ts ) an ord9>y soap-ley1 & ) "o made by mix+ "o "p ( a pure fix$ alkal9e salt ) ?ree p>ts ( common /one lime fre% slak$ & sift$2 nor c\ld ,i discov] any lime 9 ei!r4 ,! fir/ ( ^! conta9$ a small quantity ( brim/one1 & 0 f> f be+ p]fectly cau/ic1 = x made a pretty brisk eff]vesc5ce ) acids2 b ! la/ 0 s entirely depriv$ ( its air1 t x did n dim9i% 9 ! lea/ ! transp>5cy ( lime-wat]4 ,^! exp]im5ts seem !re=e to support ! f\r? proposition1 & to %ew t ! cau/ic alkali does n conta9 any lime4 ,z x seems probable1 f ! quickness & ease :]e) ! alkali 0 r5d]$ cau/ic1 t m lime _h be5 employ$ ?an :at 0 j suffici5t to extract ! :ole ( its air1 we are surpris$ to f9d t little or none ( ! sup]flu\s quick-lime 0 dissolv$ by ! wat]4 ,b ?is phnom5on w become less surpriz+1 by comp>+ x ) "s simil> in/ances 9 *emi/ry4 ,wat] may be made to deposite a salt1 by ! admixture ( a sub/ance :i* x attracts m /rongly ?an x does t salt2 su* z _s ( w9e2 & quick-lime itself may be sep>at$ f wat] ^u ! same pr9ciple2 = if t _s is add$ to an equal quantity ( lime-wat]1 ! mixture becomes turbid & deposites a s$im5t1 :i*1 :5 sep>at$ & dissolv$ aga9 9 di/ill$ wat]1 composes lime-wat]4 ,we may !re=e ref] ! above phnom5on1 ) respect to ! ley1 to ! same cause ) ^!1 & say1 t ! wat] did n dissolve ! lime1 because x already conta9$ a cau/ic alkali1 = :i* x has a sup]ior attraction4 ,i also r5d]$ ! volatile alkali cau/ic1 9 ord] to exam9e :at *ange x suff]$ 9 ! op]ation1 & obta9$ an exce$+ly volatile & acrid _s1 :i* nei!r eff]vesc$ ) acids1 nor alt]$ 9 ! lea/ ! transp>5cy ( lime-wat]2 &1 al?o' v /rong1 0 light] ?an wat]1 & float$ ^u x l _s ( w9e4 ,i next inquir$ into ! tru? ( ! fif? proposition1 9 ! foll[+ mann]4 ,two drams ( epsom-salt 7 dissolv$ 9 a small quantity ( wat]1 & ?r[n into two ounces ( ! cau/ic-ley2 ! mixture in/antly became ?ick1 l a decoction ( />* or b>ley1 by ! magnesia1 :i* 0 precipitat$4 ,i !n add$ _s ( vitriol by degrees1 until ! mixture became p]fectly cle>1 or ! :ole ( ! magnesia 0 aga9 dissolv$2 :i* happ5$ )\t any eff]vesc5ce or emission ( air4 ,half an ounce ( *alk 0 dissolv$ 9 _s ( salt1 ! quantity ( :i* 0 s adju/$1 t ! mixture 0 n acid 9 ! lea/ degree2 & ! solution 0 ?r[n into twelve ounces ( ! cau/ic ley2 :i* quantity ,i f\nd1 by exp]im5t1 to be suffici5t = precipitat+ almo/ ! :ole ( ! *alk4 ,i n[ filtrat$ ?is turbid liquor1 & laid ! p[d] rema9+ 9 ! pap] ^u a *alk-/one1 9 ord] to draw z mu* ( ! wat] f x z possible1 & !reby r$uce x to ! =m ( a m d5se & heavy p[d]1 t x might subside ! m p]fectly 9 ! foll[+ "p ( ! exp]im5t4 ,i !n mix$ x ) ab\t tw5ty ounces ( pure wat] 9 a flask1 &1 aft] all[+ ! p[d] to subside1 p\r$ (f ! wat]1 :i* _h all ! qualities ( lime-wat]4 ,& ,i successively conv]t$ eight wat]s m into lime-wat]1 sev5 ( ^! 9 ! same quantity1 & ) ! same managem5t1 z ! fir/4 ,! eigh? 0 likeways 9 ! same quantity2 b ,i all[$ x to rema9 ) ! *alk1 & %ook x frequ5tly1 = two days4 ,?is1 aft] be+ filtrat$1 =m$ a cream or cru/ ^u its surface :5 expos$ to ! air2 *ang$ ! col\r ( ! juice ( violets into gre52 sep>at$ an orange-col\r$ p[d] f a solution ( corrosive sublimate2 became turbid ^u ! addition ( an alkali2 0 entirely sweet5$ by magnesia2 & appe>$ s /rong to ! ta/e1 t ,i c\ld n h di/+ui%$ x f ord9>y lime-wat]4 ,& :5 ,i ?rew "s salt ammoniac into ! lime :i* rema9$1 ! vap\r ( ! volatile alkali imm$iately arose f ! mixture4 ,9 ?is exp]im5t !re=e ! air is fir/ driv5 out ( ! *alk by an acid1 & !n1 9 ord] to sep>ate ?is acid f x1 we add an alkali :i* has be5 previ\sly depriv$ ( its air2 by :i* means1 ! *alk itself is also obta9$ free ( air1 & 9 an acrid =m1 or 9 ! =m ( slak$ lime4 ,we h also sev]al processes = obta9+ ! volatile alkali 9 a cau/ic =m1 :i* seem to be only s _m me?ods ( obta9+ x 9 its pure /ate1 & free ( fix$ air4 ,! fir/ ( ^! is ! sep>ation ( ! alkali f an acid1 m]ely by heat2 an in/ance ( :i* we h f ,mr4 ,m>graaf4#i ,he prep>$ f ur9e an ammoniacal salt1 ! acid ( :i* is ! basis ( ! phosphorus1 & is ( su* a peculi> nature1 t x endures a r$ heat )\t be+ dissipat$4 ,sixte5 ounces ( ! neutral salt 7 subject$ by him to di/illation4 ,! acid rema9$ 9 ! retort1 & he f\nd 9 ! receiv] eight ounces ( an alkal9e _s1 :i*1 he tells u1 0 extremely volatile1 v mu* resembl+ ! _s ( salt ammoniac di/ill$ ) quick-lime2 & no cry/als 7 =m$ 9 x1 :5 expos$ to ! cold air4 ,a cau/ic volatile alkali may also be obta9$1 by mix+ salt ammoniac ) half its weight ( a cau/ic fix$ alkali1 or ( magnesia :i* has be5 previ\sly depriv$ ( its air by fire2 & !n submitt+ ^! mixtures to di/illation3 ,or m]ely by add+ any ord9>y volatile alkali to a prop] quantity ( a cau/ic ley2 = 9 ?is case ! air passes f ! volatile to ! fix$ alkali1 by a sup]ior attraction = ! la/1 &1 by a g5tle heat1 ! comp\nd yields a _s simil> to t prep>$ f salt ammoniac & quick-lime4 ,x is !re=e probable1 t1 _h we also a me?od ( sep>at+ ! fix$ alkali f an acid1 )\t1 at ! same "t1 saturat+ x ) air1 we %\ld !n obta9 x 9 a cau/ic =m2 b ,i am n acqua9t$ ) an in/ance ( ?is sep>ation 9 *emi/ry4 ,!re are two inde$ :i*1 at fir/ sight1 appe> to be ( ?is k9d2 ^! are ! sep>ation ( ! fix$ alkali f ! nitr\s acid by means ( inflam$ *>coal1 9 ! process = mak+ nitrum fixatum1 & ( ! same alkali1 f vegetable acids m]ely by heat2 b1 ^u exam9+ ! product ( ea* process1 we f9d ! alkali ei!r fully or ne>ly saturat$ ) air4 ,9 ! fir/1 ei!r ! *>coal or ! acid1 or bo? toge!r1 are almo/ :olly conv]t$ into air2 a "p ( :i* is probably jo9$ to ! alkali4 ,9 ! second1 ! acid is n prop]ly sep>at$1 b r de/roy$ by ! fire3 a consid]able portion ( x is conv]t$ into an inflammable sub/ance & we le>n f ,dr4 ,hales1 t ! bodies ( ?is class conta9 a l>ge quantity ( fix$ air4 ,:5 we consid] t ! attraction ( alkalis = fix$ air is weak] ?an t ( ! calc>i\s e>?s1 & reflect ^u ! effects ( heat 9 *emi/ry1 we are l$ to imag9e1 t alkalis might be entirely depriv$ ( _! air1 or r5d]$ p]fectly cau/ic1 by a fire some:at weak] ?an t :i* is suffici5t to produce ! same *ange ^u lime2 b ?is op9ion does n seem agreeable to exp]i5ce4 ,! alkalis d1 h[ev]1 acquire "s degree ( cau/icity 9 a /rong fire1 z appe>s f _! be+ m easily unit$ ) _s ( w9e aft] hav+ be5 kept 9 fusion = "s "t4 ,= t fluid1 :i* _c be t9ctur$ by a mild salt ( t>t>1 w soon take a v deep col\r f a few drops ( a /rong cau/ic ley4 ,! circum/ances :i* h9d] u f r5d]+ ^! salts p]fectly cau/ic by heat1 are _! prop5sity to dissipation 9 ! utmo/ viol5ce ( ! fire1 _! extreme acrimony1 & ! imp]fection ( our common vessels4 ,= be=e ! heat becomes v int5se1 ! alkalis ei!r evaporate1 or dissolve a "p ( ! crucibles 9 :i* !y are conta9$1 & (t5 escape ?ro' _! pores2 :i* happ5s1 especially z soon z !y h already acquir$ "s degree ( additional acrimony1 by ! loss ( "p ( _! air4 ,! fusion also1 :i* !y s readily und]go1 is well kn[n by ,*emi/s1 z a /rong ob/acle to ! sep>ation ( ! volatile f ! fix$ p>ts ( a comp\nd by fire2 accord+ly1 9 sev]al processes1 we are direct$ to add to ! fusible comp\nd "s por\s sub/ance :i* is incapable ( fusion1 & w reta9 ! :ole 9 a spongy =m1 !reby to facilitate ! dissipation ( ! volatile p>ts4 ,9 ord] to "k :e!r an alkali w\ld lose a "p ( its air1 & acquire a degree ( cau/icity1 :5 expos$1 ) ?is precaution1 to ! action ( a /rong fire1 ,i mix$ an ounce & a half ( salt ( t>t> ) ?ree ounces ( black-lead1 a sub/ance ( any ! mo/ un*angeable by *emical op]ations4 ,?is mixture ,i expos$1 = sev]al h\rs1 9 a cov]$ crucible1 to a fire some:at /rong] ?an :at is necess>y to keep salt ( t>t> 9 fusion4 ,:5 all[$ to cool1 ,i f\nd x /ill 9 ! =m ( a loose p[d]2 & tak+ out "o half1 ,i dilut$ x ) wat]1 & by filtration obta9$ a ley1 :i*1 :5 p\r$ into a solution ( :ite m>ble 9 aqua =tis1 precipitat$ ! m>ble "u ! =m ( a weak quick-lime3 = ! turbid mixture gave a gre5 col\r to ! juice ( violets1 & ?rew up a cru/ l t ( lime-wat]2 & ! precipitat$ p[d] collect$ & mix$ ) salt ammoniac imm$iately yield$ ! sc5t ( ! volatile alkali4 ,le/ x %\ld "h be suspect$1 t ! alkal9e qualities ( ?is mixture1 & ( ! precipitat$ m>ble1 7 n ow+ to a lime into :i* ! m>ble 0 conv]t$1 b to ! alkali itself :i* 0 add$1 x is prop] to obs]ve1 t ,i mix$ s small a proportion ( ! ley ) ! solution ( m>ble z made me sure1 f c]ta9 exp]im5ts1 t ! :ole ( ! alkali 0 sp5t 9 p]=m+ ! precipitation1 & 0 consequ5tly conv]t$ into a neutral salt by attract+ ! acid4 ,! prop]ties !re=e ( ! mixture c only be ref]r$ to a lime1 z is inde$ suffici5tly evid5t f ! cru/ :i* is peculi> to lime-wat]4 ,i 0 !re=e assur$ by ?is exp]im5t1 t an alkali does really lose a "p ( its air1 & acquire a degree ( cau/icity1 by ! prop] application ( heat2 b f9d+ by sev]al trials1 t ! degree ( cau/icity :i* x _h ?us acquir$ 0 b weak1 & t ! quick-lime produc$ 9 ?is exp]im5t 0 exhau/$ & r5d]$ mild by a small quantity ( wat]1 ,i expos$ ! crucible toge!r ) t half ( ! alkali :i* rema9$ 9 x to a /rong] fire1 9 ord] to expel a l>g] quantity ( air1 & r5d] x m rem>kably cau/ic2 b ! :ole ( x 0 dissipat$ by ! =ce ( ! heat1 & ! black lead1 :i* /ill reta9$ ! =m ( a loose & subtile p[d]1 yield$ little or no?+ to wat]4 ,we le>n !n f ! above exp]im5t ! reason :y ! alkali newly obta9$ f ! a%es ( vegetables is g5]ally ( ! m acrid k9ds ( t salt4 ,x nev] appe>s until ! subject be conv]t$ into a%es1 & is suppos$ to be =m$ by ! fire1 & to be ! result ( a p>ticul> comb9ation ( "s ( ! pr9ciples ( ! vegetable2 "o ( :i* pr9ciples is air1 :i* is conta9$ 9 l>ge quantity 9 all vegetable matt]s :atev]4 ,b z soon z ! smalle/ "p ( a vegetable is conv]t$ into a%es1 & an alkali is ?us =m$1 ?is salt necess>ily suff]s a calc9ation1 dur+ :i* x is kept 9 a spongy =m by ! a%es1 & %ews a v consid]able degree ( acrimony if imm$iately appli$ to ! body ( an animal b if ! a%es are = any "t expos$ to ! air1 or if we sep>ate ! alkali f !m by ! addition ( a l>ge quantity ( wat] & subsequ5t evaporation1 ! salt imbibes fix$ air f ! atmosph]e1 & becomes ne>ly saturat$ ) x3 ?o' ev5 9 ?is condition x is g5]ally m acrid ?an salt ( t>t>1 :5 ?is is prep>$ ) a g5tle heat4 ,borax has sometimes be5 ref]r$ to ! class ( alkalis1 on acc\nt ( "s resemblance x be>s to ^? salts3 b x has be5 demon/rat$ by accurate exp]im5ts1 t we %\ld r consid] x z a neutral salt2 t x is compos$ ( an alkali & ( a p>ticul> sal9e sub/ance call$ ! s$ative salt1 :i* adh]es to ! alkali 9 ! same mann] z an acid1 b c be sep>at$ by ! addition ( any acid :atev]1 ! add$ acid jo9+ itself to ! alkali 9 ! place ( ! s$ative salt4 ,z ?is conjunction ( an acid ) ! alkali ( borax happ5s )\t ! lea/ eff]vesc5ce1 our pr9ciples lay u "u a necessity ( all[+ t alkali to be p]fectly free ( air1 :i* mu/ proce$ f its be+ incapable ( union ) fix$ air & ) ! s$ative salt at ! same "t3 :5ce x foll[s1 t1 7 we to mix ! s$ative salt ) an alkali saturat$ ) air1 ! air w\ld imm$iately be expell$1 or ! two salts 9 jo9+ w\ld produce an eff]vesc5ce4 ,?is ,i f\nd to be really ! case ^u mak+ ! trial1 by mix+ a small quantity ( ! s$ative salt ) an equal quantity ( ea* ( ! ?ree alkalis1 rubb+ ! mixtures well 9 a mort>1 & add+ a little wat]4 ,x is h[ev] prop] 9 ?is place to obs]ve1 t1 if ! exp]im5ts be made 9 a diff]5t mann]1 !y are att5d$ ) a s+ul> circum/ance4 ,if a small quantity ( ! s$ative salt be ?r[n into a l>ge proportion ( a dissolv$ fix$ alkali1 ! s$ative salt gradually disappe>s1 & is unit$ to ! alkali )\t any eff]vesc5ce2 b if ! addition be repeat$ sev]al times1 x w at la/ be accompani$ ) a brisk eff]vesc5ce1 :i* w become m & m rem>kable1 until ! alkali be entirely saturat$ ) ! s$ative salt4 ,?is phnom5on may be expla9$ by consid]+ ! fix$ alkalis z n p]fectly saturat$ ) air3 & ! supposition w appe> v reasonable1 :5 we recollect1 t ^? salts are nev] produc$ )\t a consid]able degree ( heat1 :i* may easily be imag9$ to dissipate a small portion ( s volatile a body z air4 ,n[1 if a small quantity ( ! s$ative salt be ?r[n into an alkal9e liquor1 z x is v sl[ly dissolv$ by wat]1 its p>ticles are v gradually mix$ ) ! atoms ( ! alkali4 ,!y are mo/ /rongly attract$ by su* ( ^! atoms z are de/itute ( air1 & !re=e jo9 ) !m )\t produc+ an eff]vesc5ce2 or1 if !y expel a small quantity ( air f "s ( ! salt1 ?is air is at ! same "t absorb$ by su* ( ! contigu\s p>ticles z are de/itute ( x1 & no eff]vesc5ce appe>s until t "p ( ! alkali1 :i* 0 9 a cau/ic =m or de/itute ( air1 be ne>ly saturat$ ) ! s$ative salt4 ,b if1 on ! o!r h&1 a l>ge proportion ( ! s$ative salt be p]fectly & sudd5ly mix$ ) ! alkali1 ! :ole1 or a l>ge "p1 ( ! air is z sudd5ly expell$4 ,9 ! same mann] may we also expla9 a simil> phnom5on1 :i* (t5 pres5ts itself 9 saturat+ an alkali ) ! diff]5t acids3 ! eff]vesc5ce is less consid]able 9 ! fir/ additions ( acid1 & becomes m viol5t z ! mixture approa*es ! po9t ( saturation4 ,?is appe>s mo/ evid5tly 9 mak+ ! sal diureticus or reg5]at$ t>t>3 ,! p>ticles ( ! vegetable acid "h employ$ be+ always diffus$ ?ro' a l>ge quantity ( wat]1 are m gradually appli$ to ^? ( ! alkali1 & dur+ ! fir/ additions are *iefly unit$ to ^? t are free/ ( air4#aj ,t ! fix$ alkali1 9 its ord9>y /ate1 is seldom entirely saturat$ ) air1 seems to be confirm$ by ! foll[+ exp]im5t4 ,i expos$ a small quantity ( a pure vegetable fix$ alkali to ! air1 9 a broad & %all[ vessel1 = ! space ( two mon?s2 aft] :i* ,i f\nd a numb] ( solid cry/als1 :i* resembl$ a neutral salt s mu* z to reta9 _! =m pretty well 9 ! air1 & to produce a consid]able degree ( cold :5 dissolv$ 9 wat]4 ,_! ta/e 0 mu* mild] ?an t ( ord9>y salt ( t>t>2 & yet !y seem$ to be compos$ only ( ! alkali1 & ( a l>g] quantity ( air ?an is usually conta9$ 9 t salt1 & :i* _h be5 attract$ f ! atmosph]e3 = !y /ill jo9$ v readily ) any acid1 b ) a m viol5t eff]vesc5ce ?an ord9>y2 & !y c\ld n be mix$ ) ! smalle/ portion ( v9eg>1 or ( ! s$ative salt1 )\t emitt+ a s5sible quantity ( air4 ,z x n[ appe>$ t sev]al alkal9e sub/ances h an attraction = fix$ air1 ,i tri$ a few exp]im5ts to le>n ! relative /r5g? ( _! sev]al attractions4 ,tw5ty f\r gra9s ( magnesia 9 f9e p[d] 7 mix$ ) five ounces ( ! cau/ic ley 9 a small vial1 :i* 0 imm$iately cork$ & %ak5 frequ5tly = f\r h\rs4 ,! ley 0 !n p\r$ (f1 & ! magnesia wa%$ ) repeat$ affusions ( wat]1 & dri$4 ,x _h lo/ ab\t ! half ( its weight1 & :5 r$uc$ to a f9e p[d] 0 readily dissolv$ by acids ) an eff]vesc5ce :i* 0 h>dly p]ceivable3 ! alkali _h !re=e extract$ its air4 ,i also ?rew "s fre% magnesia into ! ley :i* _h be5 p\r$ (f1 & !reby r5d]$ x p]fectly mild & simil> to a solution ( salt ( t>t>2 s t x eff]vesc$ briskly ) acids4 ,) an ounce ( ! mild _s ( salt ammoniac1 ,i mix$ a dram ( magnesia 9 v f9e p[d] :i* _h be5 previ\sly depriv$ ( its air by fire2 & obs]v+ t ! magnesia _h a t5d5cy to concrete into a solid mass1 ,i %ook ! vial v frequ5tly4 ,aft] "s days ! p[d] 0 increas$ to m ?an d\ble its =m] bulk2 & :5 ! vial 0 op5$1 ! alkal9e _s emitt$ a mo/ intol]ably pung5t smell4 ,x likewise float$ ^u wat]1 b 0 n p]fectly cau/ic2 = x /ill yield$ "s air :5 mix$ ) acids1 & also r5d]$ lime-wat] turbid3 nei!r ( :i* w\ld probably h happ5$ if ,i _h us$ a great] quantity ( magnesia1 or _h all[$ ! mixture to rema9 a long] "t 9 ! vial4 ,i n[ wa%$ out ! :ole ( ! mixture into a b[l1 & dry$ ! magnesia until x lo/ all smell ( ! alkali4 ,x weigh$ a dram & fifty eight gra9s1 eff]vesc$ viol5tly ) acids1 & !re=e conta9$ a l>ge quantity ( air1 :i* _h be5 drawn f ! alkali by a /rong] attraction4 ,hav+ =m]ly %ewn1 t magnesia saturat$ ) air sep>ates an acid f a calc>i\s e>?1 :i* x is n able to d aft] be+ depriv$ ( its air by fire2 ,i n[ suspect$ t ! air 0 ! cause ( ?is sep>ation1 because ,i f\nd t x 0 jo9$ to ! calc>i\s e>? at ! same "t t ! acid 0 jo9$ to ! e>? ( magnesia2 & imag9$ t a pure calc>i\s e>? might possibly h a /rong] attraction = acids ?an a e>? ( magnesia4 ,i !re=e dissolv$ two drams ( magnesia 9 ! m>9e acid1 & ?us obta9$ a comp\nd ( an acid & ( ! pure e>? ( ?is sub/ance2 = ! air :i* 0 at fir/ atta*$ to x1 0 expell$ dur+ ! dissolution4 ,i !n add$ ?irty gra9s ( /rong quick-lime 9 exce$+ f9e p[d]1 %ook ! mixture well1 & filtrat$ x4 ,! p[d] rema9+ 9 ! pap]1 aft] be+ well wa%$1 0 f\nd to be a magnesia1 :i*1 z ,i expect$1 0 de/itute ( air2 = x 0 dissolv$ by ! vitriolic acid )\t eff]vesc5ce4 ,& ! filtrat$ liquor conta9$ ! lime unit$ to ! acid2 = ^u dropp+ _s ( vitriol into x1 a :ite p[d] 0 imm$iately =m$4 ,we mu/ !re=e ackn[l$ge a /rong] attraction betwe5 ! calc>i\s e>?s & acids ?an betwe5 ^! & magnesia3 b h[ does x !n happ51 t1 if magnesia saturat$ ) air be mix$ ) a comp\nd ( acid & calc>i\s e>?1 ^! two la/1 :i* attract "o ano!r ! mo/ /rongly1 d n rema9 unit$2 b ! acid is jo9$ to ! magnesia1 & ! calc>i\s e>? to ! air :i* x attracts mu* m weakly ?an x does ! acid8 ,is x because ! sum ( ! =ces :i* t5d to jo9 ! magnesia to ! acid & ! calc>i\s e>? to ! air1 is great] ?an ! sum ( ! =ces :i* t5d to jo9 ! calc>i\s e>? to ! acid1 & ! magnesia to ! air3 & because !re is a repulsion betwe5 ! acid & air1 & betwe5 ! two e>?s2 or !y are someh[ kept asund] 9 su* a mann] z h9d]s any ?ree ( !m f be+ unit$ toge!r8 ,! fir/ "p ( ?is supposition is fav\r$ by our exp]im5ts1 :i* seem to %ew a great] diff]5ce betwe5 ! =ces :]e) ! calc>i\s e>? & magnesia attract fix$ air1 ?an betwe5 ^? :i* dispose !m to unite ) ! acid4 ,! repulsions h[ev] h9t$ 9 ! second are p]haps m d\btful1 ?o' !y are sugge/$ 9 _m o!r in/ances ( decomposition2 b ! b\nds ( my pres5t purpose w n all[ me to ent] ^u ?is subject1 :i* is "o ( ! mo/ ext5sive 9 *emi/ry4 ,we meet also ) a difficulty ) respect to ! volatile alkali simil> to ! above4 ,?us a calc>i\s e>? t is pure or free ( air has a mu* /rong] attraction = acids ?an a pure volatile alkali1 z is evid5t :5 we mix quick-lime ) salt ammoniac2 = ! alkali is !n imm$iately deta*$ f ! acid3 & agreeably to ?is ,i f\nd1 ^u trial1 t a pure or cau/ic volatile alkali does n sep>ate a calc>i\s e>? f an acid4 ,yet1 if we mix a mild volatile alkali1 :i* is a comp\nd ( alkali & air1 ) a comp\nd ( acid & calc>i\s e>?1 ^! two la/1 :i* attract "o ano!r mo/ /rongly1 d n rema9 unit$2 b ! acid is jo9$ to ! alkali & ! e>? to ! air1 z happ5s 9 ! precipitation ( a calc>i\s e>? f an acid1 by means ( ! common or mild volatile alkali4 ,i rememb] likewise a p>allel in/ance ) reg>d to quick-silv]4 ,?is metal has an attraction = ! vitriolic acid1 & :5 jo9$ to x appe>s "u ! =m ( turbi? m9]al3 b ?is attraction is weak] ?an t ( ! fix$ alkali = ! same acid2 = if we mix a dissolv$ salt ( t>t> ) turbi? m9]al1 ! turbi? is conv]t$ into a br[n p[d]1 & ! alkali into vitriolat$ t>t>2 :i* *ange happ5s ! soon]1 if ! pure or cau/ic alkali is us$4 ,yet1 if to a comp\nd ( quick-silv] & ! nitr\s acid1 we add a comp\nd ( ! fix$ alkali & ! vitriolic acid1 or a vitriolat$ t>t>1 & dige/ ! mixture ) a /rong heat1 ! vitriolic acid does n rema9 ) ! alkali1 b is jo9$ to ! quick-silv] :i* x attracts m weakly1 compos+ ) x a turbi? m9]al2 :ile ! alkali is jo9$ to ! nitr\s acid :i* x likeways attracts m weakly ?an x does ! vitriolic1 & is conv]t$ into salt-petre4 ,f "s ( ! above exp]im5ts1 x appe>s1 t a few alt]ations may be made 9 ! column ( acids 9 ,mr4 ,ge(froy's table ( elective attractions1 & t a new column may be add$ to t table1 accord+ to ! foll[+ s*eme1 :]e ! alkal9e sub/ances are all consid]$ z 9 _! pure /ate & free ( fix$ air4 ,acids4 ,fix$ air4 ------------------------------ ----------------- ,fix$ alkali1 ,calc>i\s e>?4 ,calc>i\s e>?1 ,fix$ alkali4 ,volatile alkali & magnesia4 ,magnesia4 ,volatile alkali4 ---------------------- --------------- ,at ! foot ( ! fir/ column sev]al ( ! metals might foll[1 & aft] ^! ! e>? ( alum2 b z ,i don't "k :at numb] ( ! metals %\ld prec$e t e>?1 ,i h left x to be det]m9$ by fur!r exp]i5ce4 ,! volatile alkali & magnesia are plac$ 9 ! same l9e ( ?is column2 because _! =ce ( attraction seems pretty equal4 ,:5 we commit a mixture ( magnesia & salt ammoniac to di/illation1 ! alkali arises & leaves ! acid ) ! magnesia2 because ?is e>?1 by attract+ ! acid1 represses its volatility1 & x seems also to dim9i% ! cohesion ( ! acid & alkali1 & to r5d] !m sep>able by a g5tle heat4 ,if ! magnesia be saturat$ ) air1 ?is likewise1 on acc\nt ( its volatile nature & attraction = ! alkali1 is driv5 up along ) x1 & makes x appe> "u a mild =m1 & 9 ! same mann] d ! alkali & air arise f a mixture ( salt ammoniac & ( a crude calc>i\s e>?4 ,footnotes3 #a ,june #e4 #agee4 #b ,h(f4 ,op4 ,t4 iv4 p4 #dgi4 #c ,h(f4 ,op4 ,t4 iv4 p4 #ejj4 #d ,mr4 ,m>graaf has lately demon/rat$1 by a set ( curi\s & accurate exp]im5ts1 t ?is p[d] is ( ! nature1 & possesses ! prop]ties1 ( ! gypse\s or sel5itic sub/ances4 ,t su* sub/ances c be resolv$ into vitriolic acid & calc>i\s e>?1 & c be aga9 compos$ by jo9+ ^! two +r$i5ts toge!r4 ,mem4 de l',acad4 de ,b]l94 an4 #agej1 p4 #add4 #e ,h(f4 ,op4 ,t4 iv4 p4 #dhj #ejj4 #f ,mem4 de l',acad4 de ,b]l94 an4 #agdh1 p4 #eg4 #g ,h(f4 ,op4 ,t4 iv4 p4 #dhj4 #h ,?is evaporation 0 p]=m$ 9 a silv] di%1 on acc\nt ( ! acrimony ( ! salt2 :i* is s v great1 t1 hav+ once evaporat$ a "p ( ! same ley 9 a b[l ( ,engli% e>!n or /one w>e1 & melt$ ! cau/ic ) a g5tle heat1 x corrod$ & dissolv$ a "p ( ! b[l1 & left ! inside ( x pitt$ ) small holes4 #i ,mem4 de l',acad4 de ,b]l94 an4 #agdf1 p4 #hg4 #aj ,bo]h4 ,op]at4 ,*em4 process4 ,,lxxvi4 ,transcrib]s ,notes3 #a4 ,au?or's spell+ has be5 reta9$4 #b4 ,m9or punctuation issues h be5 correct$ )\t note4