,,the ,,story ,,of ,a ,,piece ,,of ,,coal ,,what ,,it ,,is1 ,,whence ,,it ,,comes1 ,,and ,,whither ,,it ,,goes ,,by ,,edward ,a4 ,,martin1 ,f4,g4,s4 #ahif ,,preface4 ,the knowledge of the marvels which a piece of coal possesses within itself1 and which in obedience to processes of man's invention it is always willing to exhibit to an observant enquirer1 is not so widespread1 perhaps1 as it should be1 and the aim of this little book1 this record of one page of geological history1 has been to bring together the principal facts and wonders connected with it into the focus of a few pages1 where1 side by side1 would be found the record of its vegetable and mineral history1 its discovery and early use1 its bearings on the great fog-problem1 its useful illuminating gas and oils1 the question of the possible exhaustion of ,british supplies1 and other important and interesting bearings of coal or its products4 ,in the whole realm of natural history1 in the widest sense of the term1 there is nothing which could be cited which has so benefited1 so interested1 ,i might almost say1 so excited mankind1 as have the wonderful discoveries of the various products distilled from gas-tar1 itself a distillate of coal4 ,coal touches the interests of the botanist1 the geologist1 and the physicist2 the chemist1 the sanitarian1 and the merchant4 ,in the little work now before the reader ,i have endeavoured to recount1 without going into unnecessary detail1 the wonderful story of a piece of coal4 ,e4,a4,m4 ,,thornton ,,heath1 ,february1 #ahif4 ,,contents4 ,i4 ,,the ,,origin ,,of ,,coal ,,and ,,the ,,plants ,,of ,,which ,,it ,,is ,,composed ,,ii4 ,a ,,general ,,view ,,of ,,the ,,coal-,,bearing ,,strata ,,iii4 ,,various ,,forms ,,of ,,coal ,,and ,,carbon ,,iv4 ,,the ,,coal-,,mine ,,and ,,its ,,dangers ,v4 ,,early ,,history--,,its ,,use ,,and ,,its ,,abuse ,,vi4 ,,how ,,gas ,,is ,,made--,,illuminating ,,oils ,,and ,,bye-,,products ,,vii4 ,,the ,,coal ,,supplies ,,of ,,the ,,world ,,viii4 ,,the ,,coal-,,tar ,,colours ,,chart ,,shewing ,,the ,,products ,,of ,,coal ,,general ,,index ,,list ,,of ,,illustrations4 ,,fig4 #a4 ,stigmaria #b4 ,annularia radiata #c4 ,rhacopteris inaequilatera #d4 ,frond of ,pecopteris #e4 ,pecopteris ,serlii #f4 ,sphenopteris affinis #g4 ,catamites ,suckowii #h4 ,calamocladus grandis #i4 ,asterophyllites foliosa #aj4 ,spenophyllum cuneifolium #aa4 ,cast of ,lepidodendron #ab4 ,lepidodendron longifolium #ac4 ,lepidodendron aculeatum #ad4 ,lepidostrobus #ae4 ,lycopodites #af4 ,stigmaria ficoides #ag4 ,section of ,stigmaria #ah4 ,sigillarian trunks in sandstone #ai4 ,productus #bj4 ,encrinite #ba4 ,encrinital limestone #bb4 ,various encrinites #bc4 ,cyathophyllum #bd4 ,archegosaurus minor #be4 ,psammodus porosus #bf4 ,orthoceras #bg4 ,fenestella retepora #bh4 ,goniatites #bi4 ,aviculopecten papyraceus #cj4 ,fragment of ,lepidodendron #ca4 ,engine-house at head of a ,coal-,pit #cb4 ,gas ,jet and ,davy ,lamp #cc4 ,part of a ,sigillarian trunk #cd4 ,inside a ,gas-holder #ce4 ,filling ,retorts by ,machinery #cf4 ,condensers #cg4 ,washers #ch4 ,purifiers ,,chapter ,i4 ,,the ,,origin ,,of ,,coal ,,and ,,the ,,plants ,,of ,,which ,,it ,,is ,,composed4 ,from the homely scuttle of coal at the side of the hearth to the gorgeously verdant vegetation of a forest of mammoth trees1 might have appeared a somewhat far cry in the eyes of those who lived some fifty years ago4 ,but there are few now who do not know what was the origin of the coal which they use so freely1 and which in obedience to their demand has been brought up more than a thousand feet from the bowels of the earth2 and1 although familiarity has in a sense bred contempt for that which a few shillings will always purchase1 in all probability a stray thought does occasionally cross one's mind1 giving birth to feelings of a more or less thankful nature that such a store of heat and light was long ago laid up in this earth of ours for our use1 when as yet man was not destined to put in an appearance for many1 many ages to come4 ,we can scarcely imagine the industrial condition of our country in the absence of so fortunate a supply of coal2 and the many good things which are obtained from it1 and the uses to which1 as we shall see1 it can be put1 do indeed demand recognition4 ,were our present forests uprooted and overthrown1 to be covered by sedimentary deposits such as those which cover our coal-seams1 the amount of coal which would be thereby formed for use in some future age1 would amount to a thickness of perhaps two or three inches at most1 and yet1 in one coal-field alone1 that of ,westphalia1 the #aag most important seams1 if placed one above the other in immediate succession1 would amount to no less than #bid feet of coal4 ,from this it is possible to form a faint idea of the enormous growths of vegetation required to form some of our representative coal beds4 ,but the coal is not found in one continuous bed4 ,these numerous seams of coal are interspersed between many thousands of feet of sedimentary deposits1 the whole of which form the coal-measures4 ,now1 each of these seams represents the growth of a forest1 and to explain the whole series it is necessary to suppose that between each deposit the land became overwhelmed by the waters of the sea or lake1 and after a long subaqueous period1 was again raised into dry land1 ready to become the birth-place of another forest1 which would again beget1 under similarly repeated conditions1 another seam of coal4 ,of the conditions necessary to bring these changes about we will speak later on1 but this instance is sufficient to show how inadequate the quantity of fuel would be1 were we dependent entirely on our own existing forest growths4 ,however1 we will leave for the present the fascinating pursuit of theorising as to the how and wherefore of these vast beds of coal1 relegating the geological part of the study of the carboniferous system to a future chapter1 where will be found some more detailed account of the position of the coal-seams in the strata which contain them4 ,at present the actual details of the coal itself will demand our attention4 ,coal is the mineral which has resulted1 after the lapse of thousands of thousands of years1 from the accumulations of vegetable material1 caused by the steady yearly shedding of leaves1 fronds and spores1 from forests which existed in an early age2 these accumulated where the trees grew that bore them1 and formed in the first place1 perhaps1 beds of peat2 the beds have since been subjected to an ever-increasing pressure of accumulating strata above them1 compressing the sheddings of a whole forest into a thickness in some cases of a few inches of coal1 and have been acted upon by the internal heat of the earth1 which has caused them to part1 to a varying degree1 with some of their component gases4 ,if we reason from analogy1 we are compelled to admit that the origin of coal is due to the accumulation of vegetation1 of which more scattered1 but more distinct1 representative specimens occur in the shales and clays above and below the coal-seams4 ,but we are also able to examine the texture itself of the various coals by submitting extremely thin slices to a strong light under the microscope1 and are thus enabled to decide whether the particular coal we are examining is formed of conifers1 horse-tails1 club-mosses1 or ferns1 or whether it consists simply of the accumulated sheddings of all1 or perhaps1 as in some instances1 of innumerable spores4 ,in this way the structure of coal can be accurately determined4 ,were we artificially to prepare a mass of vegetable substance1 and covering it up entirely1 subject it to great pressure1 so that but little of the volatile gases which would be formed could escape1 we might in the course of time produce something approaching coal1 but whether we obtained lignite1 jet1 common bituminous coal1 or anthracite1 would depend upon the possibilities of escape for the gases contained in the mass4 ,everybody has doubtless noticed that1 when a stagnant pool which contains a good deal of decaying vegetation is stirred1 bubbles of gas rise to the surface from the mud below4 ,this gas is known as marsh-gas1 or light carburetted hydrogen1 and gives rise to the ignis fatuus which hovers about marshy land1 and which is said to lure the weary traveller to his doom4 ,the vegetable mud is here undergoing rapid decomposition1 as there is nothing to stay its progress1 and no superposed load of strata confining its resulting products within itself4 ,the gases therefore escape1 and the breaking-up of the tissues of the vegetation goes on rapidly4 ,the chemical changes which have taken place in the beds of vegetation of the carboniferous epoch1 and which have transformed it into coal1 are even now but imperfectly understood4 ,all we know is that1 under certain circumstances1 one kind of coal is formed1 whilst under other conditions1 other kinds have resulted2 whilst in some cases the processes have resulted in the preparation of large quantities of mineral oils1 such as naphtha and petroleum4 ,oils are also artificially produced from the so-called waste-products of the gas-works1 but in some parts of the world the process of their manufacture has gone on naturally1 and a yearly increasing quantity is being utilised4 ,in ,england oil has been pumped up from the carboniferous strata of ,coalbrook ,dale1 whilst in ,sussex it has been found in smaller quantities1 where1 in all probability1 it has had its origin in the lignitic beds of the ,wealden strata4 ,immense quantities are used for fuel by the ,russian steamers on the ,caspian ,sea1 the ,baku petroleum wells being a most valuable possession4 ,in ,sicily1 ,persia1 and1 far more important1 in the ,united ,states1 mineral oils are found in great quantity4 ,in all probability coniferous trees1 similar to the living firs1 pines1 larches1 c41 gave rise for the most part to the mineral oils4 ,the class of living coniferae is well known for the various oils which it furnishes naturally1 and for others which its representatives yield on being subjected to distillation4 ,the gradually increasing amount of heat which we meet the deeper we go beneath the surface1 has been the cause of a slow and continuous distillation1 whilst the oil so distilled has found its way to the surface in the shape of mineral-oil springs1 or has accumulated in troughs in the strata1 ready for use1 to be drawn up when a well has been sunk into it4 ,the plants which have gone to make up the coal are not at once apparent to the naked eye4 ,we have to search among the shales and clays and sandstones which enclose the coal-seams1 and in these we find petrified specimens which enable us to build up in our mind pictures of the vegetable creation which formed the jungles and forests of these immensely remote ages1 and which1 densely packed together on the old forest floor of those days1 is now apparent to us as coal4 ,illustration3 ,fig4 #b4--;,annularia radiata4 ,carboniferous sandstone4 ,a very large proportion of the plants which have been found in the coal-bearing strata consists of numerous species of ferns1 the number of actual species which have been preserved for us in our ,english coal1 being double the number now existing in ,europe4 ,the greater part of these do not seem to have been very much larger than our own living ferns1 and1 indeed1 many of them bear a close resemblance to some of our own living species4 ,the impressions they have left on the shales of the coal-measures are most striking1 and point to a time when the sandy clay which imbedded them was borne by water in a very tranquil manner1 to be deposited where the ferns had grown1 enveloping them gradually1 and consolidating them into their mass of future shale4 ,in one species known as the neuropteris1 the nerves of the leaves are as clear and as apparent as in a newly-grown fern1 the name being derived from two ,greek words meaning nerve-fern4 ,it is interesting to consider the history of such a leaf1 throughout the ages that have elapsed since it was part of a living fern4 ,first it grew up as a new frond1 then gradually unfolded itself1 and developed into the perfect fern4 ,then it became cut off by the rising waters1 and buried beneath an accumulation of sediment1 and while momentous changes have gone on in connection with the surface of the earth1 it has lain dormant in its hiding-place exactly as we see it1 until now excavated1 with its contemporaneous vegetation1 to form fuel for our winter fires4 ,illustration3 ,,fig4 #c4--,rhacopteris inaequilatera4 ,carboniferous limestone4 ,although many of the ferns greatly resembled existing species1 yet there were others in these ancient days utterly unlike anything indigenous to ,england now4 ,there were undoubted tree-ferns1 similar to those which thrive now so luxuriously in the tropics1 and which throw out their graceful crowns of ferns at the head of a naked stem1 whilst on the bark are the marks at different levels of the points of attachment of former leaves4 ,these have left in their places cicatrices or scars1 showing the places from which they formerly grew4 ,amongst the tree-ferns found are megaphyton1 paloeopteris1 and caulopteris1 all of which have these marks upon them1 thus proving that at one time even tree-ferns had a habitat in ,england4 ,illustration3 ,fig4 #d4--;,frond of ,pecopteris4 ,coal-shale4 ,one form of tree-fern is known by the name of ,psaronius1 and this was peculiar in the possession of masses of aerial roots grouped round the stem4 ,some of the smaller species exhibit forms of leaves which are utterly unknown in the nomenclature of living ferns4 ,most have had names assigned to them in accordance with certain characteristics which they possess4 ,this was the more possible since the fossilised impressions had been retained in so distinct a manner4 ,here before us is a specimen in a shale of pecopteris1 as it is called1 7pekos1 a comb74 ,the leaf in some species is not altogether unlike the well-known living fern osmunda4 ,the position of the pinnules on both sides of the central stalk are seen in the fossil to be shaped something like a comb1 or a saw1 whilst up the centre of each pinnule the vein is as prominent and noticeable as if the fern were but yesterday waving gracefully in the air1 and but to-day imbedded in its shaly bed4 ,illustration3 ,,fig4 #e4--,pecopteris ,serlii4 ,coal-shale4 ,sphenopteris1 or wedge-fern1 is the name applied to another coal-fern2 glossopteris1 or tongue-leaf2 cyclopteris1 or round-leaf2 odonlopteris1 or tooth-leaf1 and many others1 show their chief characteristics in the names which they individually bear4 ,alethopteris appears to have been the common brake of the coal-period1 and in some respects resembles pecopteris4 ,illustration3 ,fig4 #f4--,sphenopteris ,affinis4 ,coal-shale4 ,in some species of ferns so exact are the representations which they have impressed on the shale which contains them1 that not only are the veins and nerves distinctly visible1 but even the fructification still remains in the shape of the marks left by the so-called seeds on the backs of the leaves4 ,something more than a passing look at the coal specimens in a good museum will well repay the time so spent4 ,what are known as septarian nodules1 or snake-stones1 are1 at certain places1 common in the carboniferous strata4 ,they are composed of layers of ironstone and sandstone which have segregated around some central object1 such as a fern-leaf or a shell4 ,when the leaf of a fern has been found to be the central object1 it has been noticed that the leaf can sometimes be separated from the stone in the form of a carbonaceous film4 ,experiments were made many years ago by ,m4 ,goppert to illustrate the process of fossilisation of ferns4 ,having placed some living ferns in a mass of clay and dried them1 he exposed them to a red heat1 and obtained thereby striking resemblances to fossil plants4 ,according to the degree of heat to which they were subjected1 the plants were found to be either brown1 a shining black1 or entirely lost4 ,in the last mentioned case1 only the impression remained1 but the carbonaceous matter had gone to stain the surrounding clay black1 thus indicating that the dark colour of the coal-shales is due to the carbon derived from the plants which they included4 ,another very prominent member of the vegetation of the coal period1 was that order of plants known as the ,calamites4 ,the generic distinctions between fossil and living ferns were so slight in many cases as to be almost indistinguishable4 ,this resemblance between the ancient and the modern is not found so apparent in other plants4 ,the ,calamites of the coal-measures bore indeed a very striking resemblance1 and were closely related1 to our modern horse-tails1 as the equiseta are popularly called2 but in some respects they differed considerably4 ,most people are acquainted with the horse-tail 7equisetum fluviatile7 of our marshes and ditches4 ,it is a somewhat graceful plant1 and stands erect with a jointed stem4 ,the foliage is arranged in whorls around the joints1 and1 unlike its fossil representatives1 its joints are protected by striated sheaths4 ,the stem of the largest living species rarely exceeds half-an-inch in diameter1 whilst that of the calamite attained a thickness of five inches4 ,but the great point which is noticeable in the fossil calamites and equisetites is that they grew to a far greater height than any similar plant now living1 sometimes being as much as eight feet high4 ,in the nature of their stems1 too1 they exhibited a more highly organised arrangement than their living representatives1 having1 according to ,dr ,williamson1 a fistular pith1 an exogenous woody stem1 and a thick smooth bark4 ,the bark having almost al ways disappeared has left the fluted stem known to us as the calamite4 ,the foliage consisted of whorls of long narrow leaves1 which differed only from the fern asterophyllites in the fact that they were single-nerved4 ,sir ,william ,dawson assigns the calamites to four sub-types3 calamite proper1 calamopitus1 calamodendron1 and eucalamodendron4 ,image3 ,,fig4 #g4--,root of ,catamites ,suckowii4 ,coal-shale4 ,image3 ,,fig #h4--;,calamocladus grandis4 ,carboniferous sandstone4 ,having used the word exogenous1 it might be as well to pay a little attention1 in passing1 to the nomenclature and broad classification of the various kinds of plants4 ,we shall then doubtless find it far easier thoroughly to understand the position in the scale of organisation to which the coal plants are referable4 ,illustration3 ,,fig4 #i4--;,asterophyllites foliosa4 ,coal-measures4 ,the plants which are lowest in organisation are known as ,cellular4 ,they are almost entirely composed of numerous cells built up one above the other1 and possess none of the higher forms of tissue and organisation which are met with elsewhere4 ,this division includes the lichens1 sea-weeds1 confervae 7green aquatic scum71 fungi 7mushrooms1 dry-rot71 c4 ,the division of ,vascular plants includes the far larger proportion of vegetation1 both living and fossil1 and these plants are built up of vessels and tissues of various shapes and character4 ,all plants are divided into 7#a7 ,cryptogams1 or ,flowerless1 such as mosses1 ferns1 equisetums1 and 7#b7 ,phanerogams1 or ,flowering4 ,flowering plants are again divided into those with naked seeds1 as the conifers and cycads 7gymnosperms71 and those whose seeds are enclosed in vessels1 or ovaries 7angiosperms74 ,angiosperms are again divided into the monocotyledons1 as the palms1 and dicotyledons1 which include most ,european trees4 ,thus3-- ---------------------------------------- --------------------------- 7,m4,a4 ,brongniart74 7,lindley74 ,,cellular ,cryptogams 7,flowerless7 ,fungi1 seaweeds1 ,thallogens lichens ,,vascular ,cryptogams 7,flowerless7 ,ferns1 equisetums1 ,acrogens mosses1 lycopodiums ,phanerogams 7,flowering7 ,gymnosperms 7having ,conifers and ,gymnogens naked seeds7 cycads ,two or more ,cotyledons ,angiosperms 7having enclosed seeds7 ,monocotyledons ,palms1 lilies1 ,endogens grasses ,dicotyledons ,most ,european ,exogens trees and shrubs ---------------------------------------- --------------------------- ,adolphe ,brongniart termed the coal era the ,age of ,acrogens1 because1 as we shall see1 of the great predominance in those times of vascular cryptogamic plants1 known in ,dr ,lindley's nomenclature as ,acrogens4 ,illustration3 ,,fig4 #aj4--,spenophyllum cuneifolium4 ,coal-shale4 ,two of these families have already been dealt with1 viz41 the ferns 7felices71 and the equisetums1 7calamites and equisetites71 and we now have to pass on to another family4 ,this is that which includes the fossil representatives of the ,lycopodiums1 or ,club-mosses1 and which goes to make up in some coals as much as two-thirds of the whole mass4 ,everyone is more or less familiar with some of the living ,lycopodiums1 those delicate little fern-like mosses which are to be found in many a home4 ,they are but lowly members of our ,british flora1 and it may seem somewhat astounding at first sight that their remote ancestors occupied so important a position in the forests of the ancient period of which we are speaking4 ,some two hundred living species are known1 most of them being confined to tropical climates4 ,they are as a rule1 low creeping plants1 although some few stand erect4 ,there is room for astonishment when we consider the fact that the fossil representatives of the family1 known as ,lepidodendra1 attained a height of no less than fifty feet1 and1 there is good ground for believing1 in many cases1 a far greater magnitude4 ,they consist of long straight stems1 or trunks which branch considerably near the top4 ,these stems are covered with scars or scales1 which have been caused by the separation of the petioles or leaf-stalks1 and this gives rise to the name which the genus bears4 ,the scars are arranged in a spiral manner the whole of the way up the stem1 and the stems often remain perfectly upright in the coal-mines1 and reach into the strata which have accumulated above the coal-seam4 ,illustration3 ,,fig4 #aa4--;,cast of lepidodendron in sandstone4 ,count ,sternberg remarked that we are unacquainted with any existing species of plant1 which like the ,lepidodendron1 preserves at all ages1 and throughout the whole extent of the trunk1 the scars formed by the attachment of the petioles1 or leaf-stalks1 or the markings of the leaves themselves4 ,the yucca1 dracaena1 and palm1 entirely shed their scales when they are dried up1 and there only remain circles1 or rings1 arranged round the trunk in different directions4 ,the flabelliform palms preserve their scales at the inferior extremity of the trunk only1 but lose them as they increase in age2 and the stem is entirely bare1 from the middle to the superior extremity4 ,in the ancient ,lepidodendron1 on the other hand1 the more ancient the scale of the leaf-stalk1 the more apparent it still remains4 ,portions of stems have been discovered which contain leaf-scars far larger than those referred to above1 and we deduce from these fragments the fact that those individuals which have been found whole1 are not by any means the largest of those which went to form so large a proportion of the ancient coal-forests4 ,the lepidodendra bore linear one-nerved leaves1 and the stems always branched dichotomously and possessed a central pith4 ,specimens variously named knorria1 lepidophloios1 halonia1 and ulodendron are all referable to this family4 ,illustration3 ,,fig4 #ab4--,lepidodendron longifolium4 ,coal-shale4 ,illustration3 ,,fig4 #ac4--,lepidodendron aculeatum in sandstone4 ,in some strata1 as for instance that of the ,shropshire coalfield1 quantities of elongated cylindrical bodies known as lepidostrobi have been found1 which1 it was early conjectured1 were the fruit of the giant club-mosses about which we have just been speaking4 ,their appearance can be called to mind by imagining the cylindrical fruit of the maize or ,indian corn to be reduced to some three or four inches in length4 ,the sporangia or cases which contained the microscopic spores or seeds were arranged around a central axis in a somewhat similar manner to that in which maize is found4 ,these bodies have since been found actually situated at the end of branches of lepidodendron1 thus placing their true nature beyond a doubt4 ,the fossil seeds 7spores7 do not appear to have exceeded in volume those of recent club-mosses1 and this although the actual trees themselves grew to a size very many times greater than the living species4 ,this minuteness of the seed-germs goes to explain the reason why1 as ,sir ,charles ,lyell remarked1 the same species of lepidodendra are so widely distributed in the coal measures of ,europe and ,america1 their spores being capable of an easy transportation by the wind4 ,illustration3 ,,fig4 #ad4--,lepidostrobus4 ,coal-shale4 ,one striking feature in connection with the fruit of the lepidodendron and other ancient representatives of the club-moss tribe1 is that the bituminous coals in many1 if not in most1 instances1 are made up almost entirely of their spores and spore-cases4 ,under a microscope1 a piece of such coal is seen to be thronged with the minute rounded bodies of the spores interlacing one another and forming almost the whole mass1 whilst larger than these1 and often indeed enclosing them1 are flattened bag-like bodies which are none other than the compressed sporangia which contained the former4 ,illustration3 ,,fig4 #ae4--,lycopodites4 ,coal sandstone4 ,now1 the little ,scottish or ,alpine club-moss which is so familiar1 produces its own little cones1 each with its series of outside scales or leaves2 these are attached to the bags or spore-cases1 which are crowded with spores4 ,although in miniature1 yet it produces its fruit in just the same way1 at the terminations of its little branches1 and the spores1 the actual germs of life1 when examined microscopically1 are scarcely distinguishable from those which are contained in certain bituminous coals4 ,and1 although ancient club-mosses have been found in a fossilised condition at least forty-nine feet high1 the spores are no larger than those of our miniature club-mosses of the present day4 ,the spores are more or less composed of pure bitumen1 and the bituminous nature of the coal depends largely on the presence or absence of these microscopic bodies in it4 ,the spores of the living club-mosses contain so much resinous matter that they are now largely used in the making of fireworks1 and upon the presence of this altered resinous matter in coal depends its capability of providing a good blazing coal4 ,at first sight it seems almost impossible that such a minute cause should result in the formation of huge masses of coal1 such an inconceivable number of spores being necessary to make even the smallest fragment of coal4 ,but if we look at the cloud of spores that can be shaken from a single spike of a club-moss1 then imagine this to be repeated a thousand times from each branch of a fairly tall tree1 and then finally picture a whole forest of such trees shedding in due season their copious showers of spores to earth1 we shall perhaps be less amazed than we were at first thought1 at the stupendous result wrought out by so minute an object4 ,another well-known form of carboniferous vegetation is that known as the ,sigillaria1 and1 connected with this form is one1 which was long familiar under the name of ,stigmaria1 but which has since been satisfactorily proved to have formed the branching root of the sigillaria4 ,the older geologists were in the habit of placing these plants among the tree-ferns1 principally on account of the cicatrices which were left at the junctions of the leaf-stalks with the stem1 after the former had fallen off4 ,no foliage had1 however1 been met with which was actually attached to the plants1 and hence1 when it was discovered that some of them had long attenuated leaves not at all like those possessed by ferns1 geologists were compelled to abandon this classification of them1 and even now no satisfactory reference to existing orders of them has been made1 owing to their anomalous structure4 ,the stems are fluted from base to stem1 although this is not so apparent near the base1 whilst the raised prominences which now form the cicatrices1 are arranged at regular distances within the vertical grooves4 ,when they have remained standing for some length of time1 and the strata have been allowed quietly to accumulate around the trunks1 they have escaped compression4 ,they were evidently1 to a great extent1 hollow like a reed1 so that in those trees which still remain vertical1 the interior has become filled up by a coat of sandstone1 whilst the bark has become transformed into an envelope of an inch1 or half an inch of coal4 ,but many are found lying in the strata in a horizontal plane4 ,these have been cast down and covered up by an ever-increasing load of strata1 so that the weight has1 in the course of time1 compressed the tree into simply the thickness of the double bark1 that is1 of the two opposite sides of the envelope which covered it when living4 ,sigillarae grew to a very great height without branching1 some specimens having measured from #fj to #gj feet long4 ,in accordance with their outside markings1 certain types are known as syringodendron1 favularia1 and clathraria4 ,diploxylon is a term applied to an interior stem referable to this family4 ,illustration3 ,,fig4 #af4--,stigmaria ficoides4 ,coal-shale4 ,but the most interesting point about the sigillariae is the root4 ,this was for a long time regarded as an entirely distinct individual1 and the older geologists explained it in their writings as a species of succulent aquatic plant1 giving it the name of stigmaria4 ,they realized the fact that it was almost universally found in those beds which occur immediately beneath the coal seams1 but for a long time it did not strike them that it might possibly be the root of a tree4 ,in an old edition of ,lyell's ,elements of ,geology1 utterly unlike existing editions in quality1 quantity1 or comprehensiveness1 after describing it as an extinct species of water-plant1 the author hazarded the conjecture that it might ultimately be found to have a connection with some other well-known plant or tree4 ,it was noticed that above the coal1 in the roof1 stigmariae were absent1 and that the stems of trees which occurred there1 had become flattened by the weight of the overlying strata4 ,the stigmariae on the other hand1 abounded in the underclay1 as it is called1 and were not in any way compressed but retained what appeared to be their natural shape and position4 ,hence to explain their appearance1 it was thought that they were water-plants1 ramifying the mud in every direction1 and finally becoming overwhelmed and covered by the mud itself4 ,on botanical grounds1 ,brongniart and ,lyell conjectured that they formed the roots of other trees1 and this became the more apparent as it came to be acknowledged that the underclays were really ancient soils4 ,all doubt was1 however1 finally dispelled by the discovery by ,mr ,binney1 of a sigillaria and a stigmaria in actual connection with each other1 in the ,lancashire coal-field4 ,stigmariae have since been found in the ,cape ,breton coal-field1 attached to ,lepidodendra1 about which we have already spoken1 and a similar discovery has since been made in the ,british coal-fields4 ,this1 therefore1 would seem to shew the affinity of the sigillaria to the lepidodendron1 and through it to the living lycopods1 or club-mosses4 ,some few species of stigmarian roots had been discovered1 and various specific names had been given to them before their actual nature was made out4 ,what for some time were thought to be long cylindrical leaves1 have now been found to be simply rootlets1 and in specimens where these have been removed1 the surface of the stigmaria has been noticed to be covered with large numbers of protuberant tubercles1 which have formed the bases of the rootlets4 ,there appears to have also been some special kind of arrangement in their growth1 since1 unlike the roots of most living plants1 the tubercles to which these rootlets were attached1 were arranged spirally around the main root4 ,each of these tubercles was pitted in the centre1 and into these the almost pointed ends of the rootlets fitted1 as by a ball and socket joint4 ,illustration3 ,,fig4 #ag--,section of stigmaria4 ,a single trunk of sigillaria in an erect forest presents an epitome of a coal-seam4 ,its roots represent the stigmaria underclay2 its bark the compact coal2 its woody axis1 the mineral charcoal2 its fallen leaves and fruits1 with remains of herbaceous plants growing in its shade1 mixed with a little earthy matter1 the layers of coarse coal4 ,the condition of the durable outer bark of erect trees1 concurs with the chemical theory of coal1 in showing the especial suitableness of this kind of tissue for the production of the purer compact coals4--7,dawson1 ,structures in ,coal47 ,there is yet one other family of plants which must be mentioned1 and which forms a very important portion of the constituent flora of the coal period4 ,this is the great family of the coniferae1 which although differing in many respects from the highly organised dicotyledons of the present day1 yet resembled them in some respects1 especially in the formation of an annual ring of woody growth4 ,the conifers are those trees which1 as the name would imply1 bear their fruit in the form of cones1 such as the fir1 larch1 cedar1 and others4 ,the order is one which is familiar to all1 not only on account of the cones they bear1 and their sheddings1 which in the autumn strew the ground with a soft carpet of long needle-like leaves1 but also because of the gum-like secretion of resin which is contained in their tissues4 ,only a few species have been found in the coal-beds1 and these1 on examination under the microscope1 have been discovered to be closely related to the araucarian division of pines1 rather than to any of our common firs4 ,the living species of this tree is a native of ,norfolk ,island1 in the ,pacific1 and here it attains a height of #bjj feet1 with a girth of #cj feet4 ,from the peculiar arrangement of the ducts in the elongated cellular tissue of the tree1 as seen under the microscope1 the fossil conifers1 which exhibit this structure1 have been placed in the same division4 ,the familiar fossil known to geologists as ,sternbergia has now been shown to be the cast of the central pith of these conifers1 amongst which may be mentioned cordaites1 araucarites1 and dadoxylon44 ,the central cores had become replaced with inorganic matter after the pith had shrunk and left the space empty4 ,this shrinkage of the pith is a process which takes place in many plants even when living1 and instances will at once occur1 in which the stems of various species of shrubs when broken open exhibit the remains of the shrunken pith1 in the shape of thin discs across the interval cavity4 ,we might reasonably expect that where we find the remains of fossil coniferous trees1 we should also meet with the cones or fruit which they bear4 ,and such is the case4 ,in some coal-districts fossil fruits1 named cardiocarpum and trigonocarpum1 have been found in great quantities1 and these have now been decided by botanists to be the fruits of certain conifers1 allied1 not to those which bear hard cones1 but to those which bear solitary fleshy fruits4 ,sir ,charles ,lyell referred them to a ,chinese genus of the yew tribe called salisburia4 ,dawson states that they are very similar to both taxus and salisburia44 ,they are abundant in some coal-measures1 and are contained1 not only in the coal itself1 but also in the sandstones and shales4 ,the under-clays appear to be devoid of them1 and this is1 of course1 exactly what might have been expected1 since the seeds would remain upon the soil until covered up by vegetable matter1 but would never form part of the clay soil itself4 ,in connection with the varieties which have been distinguished in the families of the conifers1 calamites1 and sigillariae1 ,sir ,william ,dawson makes the following observations3 ,i believe that there was a considerably wide range of organisation in cordaitinae as well as in calamites and sigillariae1 and that it will eventually be found that there were three lines of connection between the higher cryptogams 7flowerless7 and the phaenogams 7flowering71 one leading from the lycopodes by the sigillariae1 another leading by the cordaites1 and the third leading from the equisetums by the calamites4 ,still further back the characters1 afterwards separated in the club-mosses1 mare's-tails1 and ferns1 were united in the rhizocarps1 or1 as some prefer to call them1 the heterosporous filicinae4 ,in concluding this chapter dealing with the various kinds of plants which have been discovered as contributing to the formation of coal-measures1 it would be as well to say a word or two concerning the climate which must have been necessary to permit of the growth of such an abundance of vegetation4 ,it is at once admitted by all botanists that a moist1 humid1 and warm atmosphere was necessary to account for the existence of such an abundance of ferns4 ,the gorgeous waving tree-ferns which were doubtless an important feature of the landscape1 would have required a moist heat such as does not now exist in this country1 although not necessarily a tropical heat4 ,the magnificent giant lycopodiums cast into the shade all our living members of that class1 the largest of which perhaps are those that flourish in ,new ,zealand4 ,in ,new ,zealand1 too1 are found many species of ferns1 both those which are arborescent and those which are of more humble stature4 ,add to these the numerous conifers which are there found1 and we shall find that a forest in that country may represent to a certain extent the appearance presented by a forest of carboniferous vegetation4 ,the ferns1 lycopods1 and pines1 however1 which appear there1 it is but fair to add1 are mixed with other types allied to more recent forms of vegetation4 ,there are many reasons for believing that the amount of carbonic acid gas then existing in the atmosphere was larger than the quantity which we now find1 and ,professor ,tyndall has shown that the effect of this would be to prevent radiation of heat from the earth4 ,the resulting forms of vegetation would be such as would be comparable with those which are now reared in the green-house or conservatory in these latitudes4 ,the gas would1 in fact1 act as a glass roof1 extending over the whole world4 ,,chapter ,,ii4 ,a ,,general ,,view ,,of ,,the ,,coal-,,bearing ,,strata4 ,in considering the source whence coal is derived1 we must be careful to remember that coal itself is but a minor portion of the whole formation in which it occurs4 ,the presence of coal has indeed given the name to the formation1 the word carboniferous meaning coal-bearing1 but in taking a comprehensive view of the position which it occupies in the bowels of the earth1 it will be necessary to take into consideration the strata in which it is found1 and the conditions1 so far as are known1 under which these were deposited4 ,geologically speaking1 the ,carboniferous formation occurs near the close of that group of systems which have been classed as palaeozoic1 younger in point of age than the well known ,devonian and ,old ,red ,sandstone strata1 but older by far than the ,oolites1 the ,wealden1 or the ,cretaceous strata4 ,in ,south ,wales the coal-bearing strata have been estimated at between #aa1jjj and #ab1jjj feet1 yet amongst this enormous thickness of strata1 the whole of the various coal-seams1 if taken together1 probably does not amount to more than #abj feet4 ,this great disproportion between the total thickness and the thickness of coal itself shows itself in every coal-field that has been worked1 and when a single seam of coal is discovered attaining a thickness of #i or #aj feet1 it is so unusual a thing in ,great ,britain as to cause it to be known as the nine or ten-foot seam1 as the case may be4 ,although abroad many seams are found which are of greater thicknesses1 yet similarly the other portions of the formation are proportionately greater4 ,it is not possible therefore to realise completely the significance of the coal-beds themselves unless there is also a knowledge of the remaining constituents of the whole formation4 ,the strata found in the various coal-fields differ considerably amongst themselves in character4 ,there are1 however1 certain well-defined characteristics which find representation in most of the principal coal-fields1 whether ,british or ,european4 ,professor ,hull classifies these carboniferous beds as follows3-- ,,upper ,,carboniferous4 ,upper coal-measures4 ,reddish and purple sandstones1 red and grey clays and shales1 thin bands of coal1 ironstone and limestone1 with spirorbis and fish4 ,middle coal-measures4 ,yellow and gray sandstones1 blue and black clays and shales1 bands of coal and ironstone1 fossil plants1 bivalves and fish1 occasional marine bands4 ,,middle ,,carboniferous4 ,gannister beds or ,lower coal-measures4 ,millstone grit4 ,flagstone series in ,ireland4 ,yoredale beds4 ,upper shale series of ,ireland4 ,,lower ,,carboniferous4 ,mountain limestone4 ,limestone shale4 ,each of the three principal divisions has its representative in ,scotland1 ,belgium1 and ,ireland1 but1 unfortunately for the last-named country1 the whole of the upper coal-measures are there absent4 ,it is from these measures that almost all our commercial coals are obtained4 ,this list of beds might be further curtailed for all practical purposes of the geologist1 and the three great divisions of the system would thus stand3-- ,upper ,carboniferous1 or ,coal-measures proper4 ,millstone grit4 ,lower ,carboniferous1 or ,mountain limestone4 ,in short1 the formation consists of masses of sandstone1 shale1 limestone and coal1 these also enclosing clays and ironstones1 and1 in the limestone1 marbles and veins of the ores of lead1 zinc1 and antimony1 and occasionally silver4 ,illustration3 ,,fig4 #ah4--,sigillarian trunks in current-bedded sandstone4 ,st ,etienne4 ,as the most apparent of the rocks of the system are sandstone1 shale1 limestone1 and coal1 it will be necessary to consider how these were deposited in the waters of the carboniferous ages1 and this we can best do by considering the laws under which strata of a similar nature are now being deposited as sedimentary beds4 ,a great proportion consists of sandstone4 ,now sandstone is the result of sand which has been deposited in large quantities1 having become indurated or hardened by various processes brought to bear upon it4 ,it is necessary1 therefore1 first to ascertain whence came the sand1 and whether there are any peculiarities in its method of deposition which will explain its stratification4 ,it will be noticed at once that it bears a considerable amount of evidence of what is called current-bedding1 that is to say1 that the strata1 instead of being regularly deposited1 exhibit series of wedge-shaped masses1 which are constantly thinning out4 ,sand and quartz are of the same chemical composition1 and in all probability the sand of which every sandstone in existence is composed1 appeared on this earth in its first solid form in the shape of quartz4 ,now quartz is a comparatively heavy mineral1 so also1 therefore1 will sand be4 ,it is also very hard1 and in these two respects it differs entirely from another product of sedimentary deposition1 namely1 mud or clay1 with which we shall have presently to deal when coming to the shales4 ,since quartz is a hard mineral it necessarily follows that it will suffer1 without being greatly affected1 a far greater amount of wearing and knocking about when being transported by the agency of currents and rivers1 than will a softer substance1 such as clay4 ,an equal amount of this wearing action upon clay will reduce it to a fine impalpable silt4 ,the grains of sand1 however1 will still remain of an appreciable average size1 and where both sand and clay are being transported to the sea in one and the same stream1 the clay will be transported to long distances1 whilst the sand1 being heavier1 bulk for bulk1 and also consisting of grains larger in size than grains of clay1 will be rapidly deposited1 and form beds of sand4 ,of course1 if the current be a violent one1 the sand is transported1 not by being held in suspension1 but rather by being pushed along the bed of the river2 such an action will then tend to cause the sand to become powdered into still finer sand4 ,when a river enters the sea it soon loses its individuality2 it becomes merged in the body of the ocean1 where it loses its current1 and where therefore it has no power to keep in suspension the sediment which it had brought down from the higher lands4 ,when this is the case1 the sand borne in suspension is the first to be deposited1 and this accumulates in banks near the entrance of the river into the sea4 ,we will suppose1 for illustration1 that a small river has become charged with a supply of sand4 ,as it gradually approaches the sea1 and the current loses its force1 the sand is the more sluggishly carried along1 until finally it falls to the bottom1 and forms a layer of sand there4 ,this layer increases in thickness until it causes the depth of water above it to become comparatively shallow4 ,on the shallowing process taking place1 the current will still have a certain1 though slighter1 hold on the sand in suspension1 and will transport it yet a little further seaward1 when it will be thrown down1 at the edge of the bank or layer already formed1 thus tending to extend the bank1 and to shallow a wider space of river-bed4 ,as a result of this action1 strata would be formed1 shewing stratification diagonally as well as horizontally1 represented in section as a number of banks which had seemingly been thrown down one above the other1 ending in thin wedge-shaped terminations where the particular supply of sediment to which each owed its formation had failed4 ,the masses of sandstone which are found in the carboniferous formation1 exhibit in a large degree these wedge-shaped strata1 and we have therefore a clue at once1 both as to their propinquity to sea and land1 and also as to the manner in which they were formed4 ,illustration3 ,,fig4 #ai4--,productus4 ,coal-measures4 ,there is one thing more1 too1 about them4 ,just as1 in the case we were considering1 we could observe that the wedge-shaped strata always pointed away from the source of the material which formed them1 so we can similarly judge that in the carboniferous strata the same deduction holds good1 that the diagonally-pointing strata were formed in the same way1 and that their thinning out was simply owing to temporary failure of sediment1 made good1 however1 by a further deposition of strata when the next supply was borne down4 ,it is scarcely likely1 however1 that sand in a pure state was always carried down by the currents to the sea4 ,sometimes there would be some silt mixed with it4 ,just as in many parts large masses of almost pure sandstone have been formed1 so in other places shales1 or1 as they are popularly known by miners1 bind1 have been formed4 ,shales are formed from the clays which have been carried down by the rivers in the shape of silt1 but which have since become hardened1 and now split up easily into thin parallel layers4 ,the reader has no doubt often handled a piece of hard clay when fresh from the quarry1 and has remembered how that1 when he has been breaking it up1 in order1 perhaps1 to excavate a partially-hidden fossil1 it has readily split up in thin flakes or layers of shaly substance4 ,this exhibits1 on a small scale1 the chief peculiarity of the coal shales4 ,the formation of shales will now demand our attention4 ,when a river is carrying down with it a quantity of mud or clay1 it is transported as a fine1 dusty silt1 and when present in quantities1 gives the muddy tint to the water which is so noticeable4 ,we can very well see how that silt will be carried down in greater quantities than sand1 since nearly all rivers in some part of their course will travel through a clayey district1 and finely-divided clay1 being of a very light nature1 will be carried forward whenever a river passes over such a district4 ,and a very slight current being sufficient to carry it in a state of suspension1 it follows that it will have little opportunity of falling to the bottom1 until1 by some means or other1 the current1 which is the means of its conveyance1 becomes stopped or hindered considerably in its flow4 ,when the river enters a large body of water1 such as the ocean or a lake1 in losing its individuality1 it loses also the velocity of its current1 and the silt tends to sink down to the bottom4 ,but being less heavy than the sand1 about which we have previously spoken1 it does not sink all at once1 but partly with the impetus it has gained1 and partly on account of the very slight velocity which the current still retains1 even after having entered the sea1 it will be carried out some distance1 and will the more gradually sink to the bottom4 ,the deeper the water in which it falls the greater the possibility of its drifting farther still1 since in sinking1 it would fall1 not vertically1 but rather as the drops of rain in a shower when being driven before a gale of wind4 ,thus we should notice that clays and shales would exhibit a regularity and uniformity of deposition over a wide area4 ,currents and tides in the sea or lake would tend still further to retard deposition1 whilst any stoppages in the supply of silt which took place would give the former layer time to consolidate and harden1 and this would assist in giving it that bedded structure which is so noticeable in the shales1 and which causes it to split up into fine laminae4 ,this uniformity of structure in the shales over wide areas is a well ascertained characteristic of the coal-shales1 and we may therefore regard the method of their deposition as given here with a degree of certainty4 ,there is a class of deposit found among the coal-beds1 which is known as the underclay1 and this is the most regular of all as to the position in which it is found4 ,the underclays are found beneath every bed of coal4 ,warrant1 spavin1 and gannister are local names which are sometimes applied to it1 the last being a term used when the clay contains such a large proportion of silicious matter as to become almost like a hard flinty rock4 ,sometimes1 however1 it is a soft clay1 at others it is mixed with sand1 but whatever the composition of the underclays may be1 they always agree in being unstratified4 ,they also agree in this respect that the peculiar fossils known as stigmariae abound in them1 and in some cases to such an extent that the clay is one thickly-matted mass of the filamentous rootlets of these fossils4 ,we have seen how these gradually came to be recognised as the roots of trees which grew in this age1 and whose remains have subsequently become metamorphosed into coal1 and it is but one step farther to come to the conclusion that these underclays are the ancient soils in which the plants grew4 ,no sketch of the various beds which go to form the coal-measures would be complete which did not take into account the enormous beds of mountain limestone which form the basis of the whole system1 and which in thinner bands are intercalated amongst the upper portion of the system1 or the true coal-measures4 ,now1 limestones are not formed in the same way in which we have seen that sandstones and shales are formed4 ,the last two mentioned owe their origin to their deposition as sediment in seas1 estuaries or lakes1 but the masses of limestone which are found in the various geological formations owe their origin to causes other than that of sedimentary deposition4 ,in carboniferous times there lived numberless creatures which we know nowadays as encrinites4 ,these1 when growing1 were fixed to the bed of the ocean1 and extended upward in the shape of pliant stems composed of limestone joints or plates2 the stem of each encrinite then expanded at the top in the shape of a gorgeous and graceful starfish1 possessed of numberless and lengthy arms4 ,these encrinites grew in such profusion that after death1 when the plates of which their stems consisted1 became loosened and scattered over the bed of the sea1 they accumulated and formed solid beds of limestone4 ,besides the encrinites1 there were of course other creatures which were able to create the hard parts of their structures by withdrawing lime from the sea1 such as foraminifera1 shell-fish1 and especially corals1 so that all these assisted after death in the accumulation of beds of limestone where they had grown and lived4 ,illustration3 ,,fig4 #bj4--;,encrinite4 ,illustration3 ,,fig4 #ba4--;,encrinital limestone4 ,there is one peculiarity in connection with the habitats of the encrinites and corals which goes some distance in supplying us with a useful clue as to the conditions under which this portion of the carboniferous formation was formed4 ,these creatures find it a difficult matter1 as a rule1 to live and secrete their calcareous skeleton in any water but that which is clear1 and free from muddy or sandy sediment4 ,they are therefore not found1 generally speaking1 where the other deposits which we have considered1 are forming1 and1 as these are always found near the coasts1 it follows that the habitats of the creatures referred to must be far out at sea where no muddy sediments1 borne by rivers1 can reach them4 ,we can therefore safely come to the conclusion that the large masses of encrinital limestone1 which attain such an enormous thickness in some places1 especially in ,ireland1 have been formed far away from the land of the period2 we can at the same time draw the conclusion that if we find the encrinites broken and snapped asunder1 and the limestone deposits becoming impure through being mingled with a proportion of clayey or sandy deposits1 that we are approaching a coast-line where perhaps a river opened out1 and where it destroyed the growth of encrinites1 mixing with their dead remains the sedimentary dbris of the land4 ,illustration3 ,,fig4 #bb4--;,encrinites3 various4 ,mountain limestone4 ,we have lightly glanced at the circumstances attending the deposition of each of the principal rocks which form the beds amongst which coal is found1 and have now to deal with the formation of the coal itself4 ,we have already considered the various kinds of plants and trees which have been discovered as contributing their remains to the formation of coal1 and have now to attempt an explanation of how it came to be formed in so regular a manner over so wide an area4 ,each of the ,british coal-fields is fairly extensive4 ,the ,yorkshire and ,derbyshire coal-fields1 together with the ,lancashire coal-field1 with which they were at one time in geological connection1 give us an area of nearly #ajjj square miles1 and other ,british coal-fields show at least some hundreds of square miles4 ,and yet1 spread over them1 we find a series of beds of coal which in many cases extend throughout the whole area with apparent regularity4 ,if we take it1 as there seems every reason to believe was the case1 that almost all these coal-fields were not only being formed at the same time1 but were in most instances in continuation with one another1 this regularity of deposition of comparatively narrow beds of coal1 appears all the more remarkable4 ,the question at once suggests itself1 ,which of two things is probable8 ,are we to believe that all this vegetable matter was brought down by some mighty river and deposited in its delta1 or that the coal-plants grew just where we now find the coal8 ,formerly it was supposed that coal was formed out of dead leaves and trees1 the refuse of the vegetation of the land1 which had been carried down by rivers into the sea and deposited at their mouths1 in the same way that sand and mud1 as we have seen1 are swept down and deposited4 ,if this were so1 the extent of the deposits would require a river with an enormous embouchure1 and we should be scarcely warranted in believing that such peaceful conditions would there prevail as to allow of the layers of coal to be laid down with so little disturbance and with such regularity over these wide areas4 ,but the great objection to this theory is1 that not only do the remains still retain their perfection of structure1 but they are comparatively pure1--i4e41 unmixed with sedimentary depositions of clay or sand4 ,now1 rivers would not bring down the dead vegetation alone2 their usual burden of sediment would also be deposited at their mouths1 and thus dead plants1 sand1 and clay would be mixed up together in one black shaly or sandy mass1 a mixture which would be useless for purposes of combustion4 ,the only theory which explained all the recognised phenomena of the coal-measures was that the plants forming the coal actually grew where the coal was formed1 and where1 indeed1 we now find it4 ,when the plants and trees died1 their remains fell to the ground of the forest1 and these soon turned to a black1 pasty1 vegetable mass1 the layer thus formed being regularly increased year by year by the continual accumulation of fresh carbonaceous matter4 ,by this means a bed would be formed with regularity over a wide area2 the coal would be almost free from an admixture of sandy or clayey sediment1 and probably the rate of formation would be no more rapid in one part of the forest than another4 ,thus there would be everywhere uniformity of thickness4 ,the warm and humid atmosphere1 which it is probable then existed1 would not only have tended towards the production of an abnormal vegetation1 but would have assisted in the decaying and disintegrating processes which went on amongst the shed leaves and trees4 ,when at last it was announced as a patent fact that every bed of coal possessed its underclay1 and that trees had been discovered actually standing upon their own roots in the clay1 there was no room at all for doubt that the correct theory had been hit upon--viz41 that coal is now found just where the trees composing it had grown in the past4 ,but we have more than one coal-seam to account for4 ,we have to explain the existence of several layers of coal which have been formed over one another on the same spot at successive periods1 divided by other periods when shale and sandstones only have been formed4 ,a careful estimate of the ,lancashire coal-field has been made by ,professor ,hull for the ,geological ,survey4 ,of the #gjjj feet of carboniferous strata here found1 spread out over an area of #bag square miles1 there are on the average eighteen seams of coal4 ,this is only an instance of what is to be found elsewhere4 ,eighteen coal-seams6 what does this mean8 ,it means that1 during carboniferous times1 on no less than eighteen occasions1 separate and distinct forests have grown on this self-same spot1 and that between each of these occasions changes have taken place which have brought it beneath the waters of the ocean1 where the sandstones and shales have been formed which divide the coal-seams from each other4 ,we are met here by a wonderful demonstration of the instability of the surface of the earth1 and we have to do our best to show how the changes of level have been brought about1 which have allowed of this game of geological see-saw to take place between sea and land4 ,changes of level6 ,many a hard geological nut has only been overcome by the application of the principle of changes of level in the surface of the earth1 and in this we shall find a sure explanation of the phenomena of the coal-measures4 ,great changes of the level of the land are undoubtedly taking place even now on the earth's surface1 and in assuming that similar changes took place in carboniferous times1 we shall not be assuming the former existence of an agent with which we are now unfamiliar4 ,and when we consider the thicknesses of sandstone and shale which intervene beneath the coal-seams1 we can realise to a certain extent the vast lapses of years which must have taken place between the existence of each forest2 so that although now an individual passing up a coal-mine shaft may rapidly pass through the remains of one forest after another1 the rise of the strata above each forest-bed then was tremendously slow1 and the period between the growth of each forest must represent the passing away of countless ages4 ,perhaps it would not be too much to say that the strata between some of the coal-seams would represent a period not less than that between the formation of the few tertiary coals with which we are acquainted1 and a time which is still to us in the far-away future4 ,the actual seams of coal themselves will not yield much information1 from which it will be possible to judge of the contour of the landmasses at this ancient period4 ,of one thing we are sure1 namely1 that at the time each seam was formed1 the spot where it accumulated was dry land4 ,if1 therefore1 the seams which appear one above the other coincide fairly well as to their superficial extent1 we can conclude that each time the land was raised above the sea and the forest again grew1 the contour of the land was very similar4 ,this conclusion will be very useful to go upon1 since whatever decision may be come to as an explanation of one successive land-period and sea-period on the same spot1 will be applicable to the eighteen or more periods necessary for the completion of some of the coal-fields4 ,we will therefore look at one of the sandstone masses which occur between the coal-seams1 and learn what lessons these have to teach us4 ,in considering the formation of strata of sand in the seas around our river-mouths1 it was seen that1 owing to the greater weight of the particles of the sand over those of clay1 the former the more readily sank to the bottom1 and formed banks not very far away from the land4 ,it was seen1 too1 that each successive deposition of sand formed a wedge-shaped layer1 with the point of the wedge pointing away from the source of origin of the sediment1 and therefore of the current which conveyed the sediment4 ,therefore1 if in the coal-measure sandstones the layers were found with their wedges all pointing in one direction1 we should be able to judge that the currents were all from one direction1 and that1 therefore1 they were formed by a single river4 ,but this is just what we do not find1 for instead of it the direction of the wedge-shaped strata varies in almost every layer1 and the current-bedding has been brought about by currents travelling in every direction4 ,such diverse current-bedding could only result from the fact that the spot where the sand was laid down was subject to currents from every direction1 and the inference is that it was well within the sphere of influence of numerous streams and rivers1 which flowed from every direction4 ,the only condition of things which would explain this is that the sandstone was originally formed in a closed sea or large lake1 into which numerous rivers flowing from every direction poured their contents4 ,now1 in the sandstones1 the remains of numerous plants have been found1 but they do not present the perfect appearance that they do when found in the shales2 in fact they appear to have suffered a certain amount of damage through having drifted some distance4 ,this1 together with the fact that sandstones are not formed far out at sea1 justify the safe conclusion that the land could not have been far off4 ,wherever the current-bedding shows itself in this manner we may be sure we are examining a spot from which the land in every direction could not have been at a very great distance1 and also that1 since the heavy materials of which sandstone is composed could only be transported by being impelled along by currents at the bed of the sea1 and that in deep water such currents could not exist1 therefore we may safely decide that the sea into which the rivers fell was a comparatively shallow one4 ,although the present coal-fields of ,england are divided from one another by patches of other beds1 it is probable that some of them were formerly connected with others1 and a very wide sheet of coal on each occasion was laid down4 ,the question arises as to what was the extent of the inland sea or lake1 and did it include the area covered by the coal basins of ,scotland and ,ireland1 of ,france and ,belgium8 ,and if these1 why not those of ,america and other parts8 ,the deposition of the coal1 according to the theory here advanced1 may as well have been brought about in a series of large inland seas and lakes1 as by one large comprehensive sea1 and probably the former is the more satisfactory explanation of the two4 ,but the astonishing part of it is that the changes in the level of the land must have been taking place simultaneously over these large areas1 although1 of course1 while one quarter may have been depressed beneath the sea1 another may have been raised above it4 ,in connection with the question of the contour of the land during the existence of the large lakes or inland seas1 ,professor ,hull has prepared1 in his series of maps illustrative of the ,palaeo-,geography of the ,british ,islands1 a map showing on incontestible grounds the existence during the coal-ages of a great central barrier or ridge of high land stretching across from ,anglesea1 south of ,flint1 ,staffordshire1 and ,shropshire coal-fields1 to the eastern coast of ,norfolk4 ,he regards the ,british coal-measures as having been laid down in two1 or at most three1 areas of deposition--one south of this ridge1 the remainder to the north of it4 ,in regard to the extent of the former deposits of coal in ,ireland1 there is every probability that the sister island was just as favourably treated in this respect as ,great ,britain4 ,most unfortunately1 ,ireland has since suffered extreme denudation1 notably from the great convulsions of nature at the close of the very period of their deposition1 as well as in more recent times1 resulting in the removal of nearly all the valuable upper carboniferous beds1 and leaving only the few unimportant coal-beds to which reference has been made4 ,illustration3 ,,fig4 #bc4--;,cyathophyllum4 ,coral in encrinital limestone4 ,we are unable to believe in the continuity of our coal-beds with those of ,america1 for the great source of sediment in those times was a continent situated on the site of the ,atlantic ,ocean1 and it is owing to this extensive continent that the forms of flora found in the coal-beds in each country bear so close a resemblance to one another1 and also that the encrinital limestone which was formed in the purer depths of the ocean on the east1 became mixed with silt1 and formed masses of shaly impure limestone in the south-western parts of ,ireland4 ,it must be noted that1 although we may attribute to upheaval from beneath the fact that the bed of the sea became temporarily raised at each period into dry land1 the deposits of sand or shale would at the same time be tending to shallow the bed1 and this alone would assist the process of upheaval by bringing the land at least very near to the surface of the water4 ,each upheaval1 however1 could have been but a temporary arrest of the great movement of crust subsidence which was going on throughout the coal period1 so that1 at its close1 when the last coal forest grew upon the surface of the land1 there had disappeared1 in the case of ,south ,wales1 a thickness of #aa1jjj feet of material4 ,of the many remarkable things in connection with coal-beds1 not the least is the state of purity in which coal is found4 ,on the floor of each forest there would be many a streamlet or even small river which would wend its way to meet the not very distant sea1 and it is surprising at first that so little sediment found its way into the coal itself4 ,but this was cleverly explained by ,sir ,charles ,lyell1 who noticed1 on one of his visits to ,america1 that the water of the ,mississippi1 around the rank growths of cypress which form the cypress swamps at the mouths of that river1 was highly charged with sediment1 but that1 having passed through the close undergrowth of the swamps1 it issued in almost a pure state1 the sediment which it bore having been filtered out of it and precipitated4 ,this very satisfactorily explained how in some places carbonaceous matter might be deposited in a perfectly pure state1 whilst in others1 where sandstone or shale was actually forming1 it might be impregnated by coaly matter in such a way as to cause it to be stained black4 ,in times of flood sediment would be brought in1 even where pure coal had been forming1 and then we should have a thin parting of sandstone or shale1 which was formed when the flood was at its height4 ,or a slight sinking of the land might occur1 in which case also the formation of coal would temporarily cease1 and a parting of foreign matter would be formed1 which1 on further upheaval taking place1 would again give way to another forest growth4 ,some of the thicker beds have been found presenting this aspect1 such as the ,south ,staffordshire ten-yard coal1 which in some parts splits up into a dozen or so smaller beds1 with partings of sediment between them4 ,in the face of the stupendous movements which must have happened in order to bring about the successive growth of forests one above another on the same spot1 the question at once arises as to how these movements of the solid earth came about1 and what was the cause which operated in such a manner4 ,we can only judge that1 in some way or other1 heat1 or the withdrawal of heat1 has been the prime motive power4 ,we can perceive1 from what is now going on in some parts of the earth1 how great an influence it has had in shaping the land1 for volcanoes owe their activity to the hidden heat in the earth's interior1 and afford us an idea of the power of which heat is capable in the matter of building up and destroying continents4 ,no less certain is it that heat is the prime factor in those more gradual vertical movements of the land to which we have referred elsewhere1 but in regard to the exact manner in which it acts we are very much in the dark4 ,everybody knows that1 in the majority of instances1 material substances of all kinds expand under the influence of heat1 and contract when the source of heat is withdrawn4 ,if we can imagine movements in the quantity of heat contained in the solid crust1 the explanation is easy1 for if a certain tract of land receive an accession of heat beneath it1 it is certain that the principal effect will be an elevation of the land1 consequent on the expansion of its materials1 with a subsequent depression when the heat beneath the tract in question becomes gradually lessened4 ,should the heat be retained for a long period1 the strata would be so uplifted as to form an anticlinal1 or saddle-back1 and then1 should subsequent denudation take place1 more ancient strata would be brought to view4 ,it was thus in the instance of the tract bounded by the ,north and ,south ,downs1 which were formerly entirely covered by chalk1 and in the instance of the uprising of the carboniferous limestone between the coal-fields of ,lancashire1 ,staffordshire1 and ,derbyshire4 ,how the heat-waves act1 and the laws1 if any1 which they obey in their subterranean movements1 we are unable to judge4 ,from the properties which heat possesses we know that its presence or absence produces marked differences in the positions of the strata of the earth1 and from observations made in connection with the closing of some volcanoes1 and the opening up of fresh earth-vents1 we have gone a long way towards establishing the probability that there are even now slow and ponderous movements taking place in the heat stored in the earth's crust1 whose effects are appreciably communicated to the outside of the thin rind of solid earth upon which we live4 ,owing to the great igneous and volcanic activity at the close of the deposition of the carboniferous system of strata1 the coal-measures exhibit what are known as faults in abundance4 ,the mountain limestone1 where it outcrops at the surface1 is observed to be much jointed1 so much so that the work of quarrying the limestone is greatly assisted by the jointed structure of the rock4 ,faults differ from joints in that1 whilst the strata in the latter are still in relative position on each side of the joint1 they have in the former slipped out of place4 ,in such a case the continuation of a stratum on the opposite side of a fault will be found to be depressed1 perhaps a thousand feet or more4 ,it will be seen at once how that1 in sinking a new shaft into a coal-seam1 the possibility of an unknown fault has to be brought into consideration1 since the position of the seam may prove to have been depressed to such an extent as to cause it to be beyond workable depth4 ,many seams1 on the other hand1 which would have remained altogether out of reach of mining operations1 have been brought within workable depth by a series of step-faults1 this being a term applied to a series of parallel faults1 in none of which the amount of down-throw is great4 ,the amount of the down-throw1 or the slipping-down of the beds1 is measured1 vertically1 from the point of disappearance of a layer to an imaginary continuation of the same layer from where it again appears beyond the fault4 ,the plane of a fault is usually more or less inclined1 the amount of the inclination being known as the hade of the fault1 and it is a remarkable characteristic of faults that1 as a general rule1 they hade to the down-throw4 ,this will be more clearly understood when it is explained that1 by its action1 a seam of coal1 which is subject to numerous faults1 can never be pierced more than once by one and the same boring4 ,in mountainous districts1 however1 there are occasions when the hade is to the up-throw1 and this kind of fault is known as an inverted fault4 ,lines of faults extend sometimes for hundreds of miles4 ,the great ,pennine ,fault of ,england is #acj miles long1 and others extend for much greater distances4 ,the surfaces on both sides of a fault are often smooth and highly polished by the movement which has taken place in the strata4 ,they then show the phenomenon known as slicken-sides4 ,many faults have become filled with crystalline minerals in the form of veins of ore1 deposited by infiltrating waters percolating through the natural fissures4 ,in considering the formation and structure of the better-known coal-bearing beds of the carboniferous age1 we must not lose sight of the fact that important beds of coal also occur in strata of much more recent date4 ,there are important coal-beds in ,india of ,permian age4 ,there are coal-beds of ,liassic age in ,south ,hungary and in ,texas1 and of ,jurassic age in ,virginia1 as well as at ,brora in ,sutherlandshire2 there are coals of ,cretaceous age in ,moravia1 and valuable ,miocene ,tertiary coals in ,hungary and the ,austrian ,alps4 ,again1 older than the true carboniferous age1 are the ,silurian anthracites of ,co4 ,cavan1 and certain ,norwegian coals1 whilst in ,new ,south ,wales we are confronted with an assemblage of coal-bearing strata which extend apparently from the ,devonian into ,mesozoic times4 ,still1 the age we have considered more closely has an unrivalled right to the title1 coal appearing there not merely as an occasional bed1 but as a marked characteristic of the formation4 ,the types of animal life which are found in this formation are varied1 and although naturally enough they do not excel in number1 there are yet sufficient varieties to show probabilities of the existence of many with which we are unfamiliar4 ,the highest forms yet found1 show an advance as compared with those from earlier formations1 and exhibit amphibian characteristics intermediate between the two great classes of fishes and reptiles4 ,numerous specimens proper to the extinct order of labyrinthodontia have been arranged into at least a score of genera1 these having been drawn from the coal-measures of ,newcastle1 ,edinburgh1 ,kilkenny1 ,sarbruck1 ,bavaria1 ,pennsylvania1 and elsewhere4 ,the ,archegosaurus1 which we have figured1 and the ,anthracosaurus1 are forms which appear to have existed in great numbers in the swamps and lakes of the age4 ,the fish of the period belong almost entirely to the ancient orders of the ganoids and placoids4 ,of the ganoids1 the great megalichthys ,hibberti ranges throughout the whole of the system4 ,wonderful accumulations of fish remains are found at the base of the system1 in the bone-bed of the ,bristol coal-field1 as well as in a similar bed at ,armagh4 ,many fishes were armed with powerful conical teeth1 but the majority1 like the existing ,port ,jackson shark1 were possessed of massive palates1 suited in some cases for crushing1 and in others for cutting4 ,illustration3 ,,fig4 #bd4--;,archegosaurus minor4 ,coal-measures4 ,illustration3 ,,fig4 #be4--,psammodus porosus4 ,crushing palate of a fish4 ,illustration3 ,,fig4 #bf4--,orthoceras4 ,mountain limestone4 ,in the mountain limestone we see1 of course1 the predominance of marine types1 encrinital remains forming the greater proportion of the mass4 ,there are occasional plant remains which bear evidence of having drifted for some distance from the shore4 ,but next to the encrinites1 the corals are the most important and persistent4 ,corals of most beautiful forms and capable of giving polished marble-like sections1 are in abundance4 ,polyzoa are well represented1 of which the lace-coral 7fenestella7 and screw-coral 7archimedopora7 are instances4 ,cephalopoda are represented by the orthoceras1 sometimes five or six feet long1 and goniatites1 the forerunner of the familiar ammonite4 ,many species of brachiopods and lammellibranchs are met with4 ,lingula1 most persistent throughout all geological time1 is abundant in the coal-shales1 but not in the limestones4 ,aviculopecten is there abundant also4 ,in the mountain limestone the last of the trilobites 7,phillipsia7 is found4 ,illustration3 ,,fig4 #bg4--;,fenestella retipora4 ,mountain limestone4 ,illustration3 ,,fig4 #bh4--;,goniatites4 ,mountain limestone4 ,we have evidence of the existence in the forests of a variety of centipede1 specimens having been found in the erect stump of a hollow tree1 although the fossil is an extremely rare one4 ,the same may be said of the only two species of land-snail which have been found connected with the coal forests1 viz41 pupa vetusta and zonites priscus1 both discovered in the cliffs of ,nova ,scotia4 ,these are sufficient to demonstrate that the fauna of the period had already reached a high stage of development4 ,in the estuaries of the day1 masses of a species of freshwater mussel 7anthracosia7 were in existence1 and these have left their remains in the shape of extensive beds of shells4 ,they are familiar to the miner as mussel-binds1 and are as noticeable a feature of this long ago period1 as are the aggregations of mussels on every coast at the present day4 ,illustration3 ,,fig4 #bi4--;,aviculopecten papyraceus4 ,coal-shale4 ,,chapter ,,iii4 ,,various ,,forms ,,of ,,coal ,,and ,,carbon4 ,in considering the various forms and combinations into which coal enters1 it is necessary that we should obtain a clear conception of what the substance called carbon is1 and its nature and properties generally1 since this it is which forms such a large percentage of all kinds of coal1 and which indeed forms the actual basis of it4 ,in the shape of coke1 of course1 we have a fairly pure form of carbon1 and this being produced1 as we shall see presently1 by the driving off of the volatile or vaporous constituents of coal1 we are able to perceive by the residue how great a proportion of coal consists of carbon4 ,in fact1 the two have almost an identical meaning in the popular mind1 and the fact that the great masses of strata1 in which are contained our principal and most valuable seams of coal1 are termed carboniferous1 from the ,latin carbo1 coal1 and fero1 ,i bear1 tends to perpetuate the existence of the idea4 ,there is always a certain1 though slight1 quantity of carbon in the air1 and this remains fairly constant in the open country4 ,small though it may be in proportion to the quantity of pure air in which it is found1 it is yet sufficient to provide the carbon which is necessary to the growth of vegetable life4 ,just as some of the animals known popularly as the zoophytes1 which are attached during life to rocks beneath the sea1 are fed by means of currents of water which bring their food to them1 so the leaves1 which inhale carbon-food during the day through their under-surfaces1 are provided with it by means of the currents of air which are always circulating around them2 and while the fuel is being taken in beneath1 the heat and light are being received from above1 and the sun supplies the motive power to digestion4 ,it is assumed that it is1 within the knowledge of all that1 for the origin of the various seams and beds of coaly combinations which exist in the earth's crust1 we must look to the vegetable world4 ,if1 however1 we could go so far back in the world's history as the period when our incandescent orb had only just severed connection with a gradually-diminishing sun1 we should probably find the carbon there1 but locked up in the bonds of chemical affinities with other elements1 and existing therewith in a gaseous condition4 ,but1 as the solidifying process went on1 and as the vegetable world afterwards made its appearance1 the carbon became1 so to speak1 wrenched from its combinations1 and being absorbed by trees and plants1 finally became deposited amongst the ruins of a former vegetable world1 and is now presented to us in the form of coal4 ,we are able to trace the gradual changes through which the pasty mass of decaying vegetation passed1 in consequence of the fact that we have this material locked up in various stages of carbonisation1 in the strata beneath our feet4 ,these we propose to deal with individually1 in as unscientific and untechnical a manner as possible4 ,first of all1 when a mass of vegetable matter commences to decay1 it soon loses its colour4 ,there is no more noticeable proof of this1 than that when vitality is withdrawn from the leaves of autumn1 they at once commence to assume a rusty or an ashen colour4 ,let the leaves but fall to the ground1 and be exposed to the early frosts of ,october1 the damp mists and rains of ,november1 and the rapid change of colour is at once apparent4 ,trodden under foot1 they soon assume a dirty blackish hue1 and even when removed they leave a carbonaceous trace of themselves behind them1 where they had rested4 ,another proof of the rapid acquisition of their coaly hue is noticeable in the spring of the year4 ,when the trees have burst forth and the buds are rapidly opening1 the cases in which the buds of such trees as the horse-chestnut have been enclosed will be found cast off1 and strewing the path beneath4 ,moistened by the rains and the damp night-mists1 and trodden under foot1 these cases assume a jet black hue1 and are to all appearance like coal in the very first stages of formation4 ,but of course coal is not made up wholly and only of leaves4 ,the branches of trees1 twigs of all sizes1 and sometimes whole trunks of trees are found1 the last often remaining in their upright position1 and piercing the strata which have been formed above them4 ,at other times they lie horizontally on the bed of coal1 having been thrown down previously to the formation of the shale or sandstone1 which now rests upon them4 ,they are often petrified into solid sandstone themselves1 whilst leaving a rind of coal where formerly was the bark4 ,although the trunk of a tree looks so very different to the leaves which it bears upon its branches1 it is only naturally to be supposed that1 as they are both built up after the same manner from the juices of the earth and the nourishment in the atmosphere1 they would have a similar chemical composition4 ,one very palpable proof of the carbonaceous character of tree-trunks suggests itself4 ,take in your hand a few dead twigs or sticks from which the leaves have long since dropped2 pull away the dead parts of the ivy which has been creeping over the summer-house2 or clasp a gnarled old monster of the forest in your arms1 and you will quickly find your hand covered with a black smut1 which is nothing but the result of the first stage which the living plant has made1 in its progress towards its condition as dead coal4 ,but an easy1 though rough1 chemical proof of the constituents of wood1 can be made by placing a few pieces of wood in a medium-sized test-tube1 and holding it over a flame4 ,in a short time a certain quantity of steam will be driven off1 next the gaseous constituents of wood1 and finally nothing will be left but a few pieces of black brittle charcoal4 ,the process is of course the same in a fire-grate1 only that here more complete combustion of the wood takes place1 owing to its being intimately exposed to the action of the flames4 ,if we adopt the same experiment with some pieces of coal1 the action is similar1 only that in this case the quantity of gases given off is not so great1 coal containing a greater proportion of carbon than wood1 owing to the fact that1 during its long burial in the bowels of the earth1 it has been acted upon in such a way as to lose a great part of its volatile constituents4 ,from processes1 therefore1 which are to be seen going on around us1 it is easily possible to satisfy ourselves that vegetation will in the long run undergo such changes as will result in the formation of coal4 ,there are certain parts in most countries1 and particularly in ,ireland1 where masses of vegetation have undergone a still further stage in metamorphism1 namely1 in the well-known and famous peat-bogs4 ,ireland is par excellence the land of bogs1 some three millions of acres being said to be covered by them1 and they yield an almost inexhaustible supply of peat4 ,one of the peat-bogs near the ,shannon is between two and three miles in breadth and no less than fifty in length1 whilst its depth varies from #ac feet to as much as #dg feet4 ,peat-bogs have in no way ceased to be formed1 for at their surfaces the peat-moss grows afresh every year2 and rushes1 horse-tails1 and reeds of all descriptions grow and thrive each year upon the ruins of their ancestors4 ,the formation of such accumulations of decaying vegetation would only be possible where the physical conditions of the country allowed of an abundant rainfall1 and depressions in the surface of the land to retain the moisture4 ,where extensive deforesting operations have taken place1 peat-bogs have often been formed1 and many of those in existence in ,europe undoubtedly owe their formation to that destruction of forests which went on under the sway of the ,romans4 ,natural drainage would soon be obstructed by fallen trees1 and the formation of marsh-land would follow2 then with the growth of marsh-plants and their successive annual decay1 a peaty mass would collect1 which would quickly grow in thickness without let or hindrance4 ,in considering the existence of inland peat-bogs1 we must not lose sight of the fact that there are subterranean forest-beds on various parts of our coasts1 which also rest upon their own beds of peaty matter1 and very possibly1 when in the future they are covered up by marine deposits1 they will have fairly started on their way towards becoming coal4 ,peat-bogs do not wholly consist of peat1 and nothing else4 ,the trunks of such trees as the oak1 yew1 and fir1 are often found mingled with the remains of mosses and reeds1 and these often assume a decidedly coaly aspect4 ,from the famous ,bog of ,allen in ,ireland1 pieces of oak1 generally known as bog-oak1 which have been buried for generations in peat1 have been excavated4 ,these are as black as any coal can well be1 and are sufficiently hard to allow of their being used in the manufacture of brooches and other ornamental objects4 ,another use to which peat of some kinds has been put is in the manufacture of yarn1 the result being a material which is said to resemble brown worsted4 ,on digging a ditch to drain a part of a bog in ,maine1 ,u4,s41 in which peat to a depth of twenty feet had accumulated1 a substance similar to cannel coal itself was found4 ,as we shall see presently1 cannel coal is one of the earliest stages of true coal1 and the discovery proved that under certain conditions as to heat and pressure1 which in this case happened to be present1 the materials which form peat may also be metamorphosed into true coal4 ,darwin1 in his well-known ,voyage in the ,beagle gives a peculiarly interesting description of the condition of the peat-beds in the ,chonos ,archipelago1 off the ,chilian coast1 and of their mode of formation4 ,in these islands1 he says1 cryptogamic plants find a most congenial climate1 and within the forest the number of species and great abundance of mosses1 lichens1 and small ferns1 is quite extraordinary4 ,in ,tierra del ,fuego every level piece of land is invariably covered by a thick bed of peat4 ,in the ,chonos ,archipelago where the nature of the climate more closely approaches that of ,tierra del ,fuego1 every patch of level ground is covered by two species of plants 7,astelia pumila and ,donatia megellanica71 which by their joint decay compose a thick bed of elastic peat4 ,in ,tierra del ,fuego1 above the region of wood-land1 the former of these eminently sociable plants is the chief agent in the production of peat4 ,fresh leaves are always succeeding one to the other round the central tap-root2 the lower ones soon decay1 and in tracing a root downwards in the peat1 the leaves1 yet holding their places1 can be observed passing through every stage of decomposition1 till the whole becomes blended in one confused mass4 ,the ,astelia is assisted by a few other plants1--here and there a small creeping ,myrtus 7,m4 nummularia71 with a woody stem like our cranberry and with a sweet berry1--an ,empetrum 7,e4 rubrum71 like our heath1--a rush 7,juncus grandiflorus71 are nearly the only ones that grow on the swampy surface4 ,these plants1 though possessing a very close general resemblance to the ,english species of the same genera1 are different4 ,in the more level parts of the country the surface of the peat is broken up into little pools of water1 which stand at different heights1 and appear as if artificially excavated4 ,small streams of water1 flowing underground1 complete the disorganisation of the vegetable matter1 and consolidate the whole4 ,the climate of the southern part of ,america appears particularly favourable to the production of peat4 ,in the ,falkland ,islands almost every kind of plant1 even the coarse grass which covers the whole surface of the land1 becomes converted into this substance3 scarcely any situation checks its growth2 some of the beds are as much as twelve feet thick1 and the lower part becomes so solid when dry that it will hardly burn4 ,although every plant lends its aid1 yet in most parts the ,astelia is the most efficient4 ,it is rather a singular circumstance1 as being so very different from what occurs in ,europe1 that ,i nowhere saw moss forming by its decay any portion of the peat in ,south ,america4 ,with respect to the northern limit at which the climate allows of that peculiar kind of slow decomposition which is necessary for its production1 ,i believe that in ,chiloe 7lat4 #da to #db71 although there is much swampy ground1 no well characterised peat occurs2 but in the ,chonos ,islands1 three degrees farther southward1 we have seen that it is abundant4 ,on the eastern coast in ,la ,plata 7lat4 #ce7 ,i was told by a ,spanish resident1 who had visited ,ireland1 that he had often sought for this substance1 but had never been able to find any4 ,he showed me1 as the nearest approach to it which he had discovered1 a black peaty soil1 so penetrated with roots as to allow of an extremely slow and imperfect combustion4 ,the next stage in the making of coal is one in which the change has proceeded a long way from the starting-point4 ,lignite is the name which has been applied to a form of impure coal1 which sometimes goes under the name of brown coal4 ,it is not a true coal1 and is a very long way from that final stage to which it must attain ere it takes rank with the most valuable of earth's products4 ,from the very commencement1 an action has being going on which has caused the amount of the gaseous constituents to become less and less1 and which has consequently caused the carbon remaining behind to occupy an increasingly large proportion of the whole mass4 ,so1 when we arrive at the lignite stage1 we find that a considerable quantity of volatile matter has already been parted with1 and that the carbon1 which in ordinary living wood is about #ej per cent4 of the whole1 has already increased to about #fg per cent4 ,in most lignites there is1 as a rule1 a comparatively large proportion of sulphur1 and in such cases it is rendered useless as a domestic fuel4 ,it has been used as a fuel in various processes of manufacture1 and the lignite of the well-known ,bovey ,tracey beds has been utilised in this way at the neighbouring potteries4 ,as compared with true coal1 it is distinguished by the abundance of smoke which it produces and the choking sulphurous fumes which also accompany its combustion1 but it is largely used in ,germany as a useful source of paraffin and illuminating oils4 ,in ,silesia1 ,saxony1 and in the district about ,bonn1 large quantities of lignite are mined1 and used as fuel4 ,large stores of lignite are known to exist in the ,weald of the south-east of ,england1 and although the mining operations which were carried on at one time at ,heathfield1 ,bexhill1 and other places1 were failures so far as the actual discovery of true coal was concerned1 yet there can be no doubt as to the future value of the lignite in these parts1 when ,england's supplies of coal approach exhaustion1 and attention is turned to other directions for the future source of her gas and paraffin oils4 ,beside the ,bovey ,tracey lignitic beds to which we have above referred1 other tertiary clays are found to contain this early promise of coal4 ,the eocene beds of ,brighton are an important instance of a tertiary lignite1 the seam of surturbrand1 as it is locally called1 being a somewhat extensive deposit4 ,we have now closely approached to true coal1 and the next step which we shall take will be to consider the varieties in which the black mineral itself is found4 ,the principal of these varieties are as follows1 against each being placed the average proportion of pure carbon which it contains3-- ,splint or ,hard ,coal1 #hc per cent42 ,cannel1 ,candle or ,parrott ,coal1 #hd per cent42 ,cherry or ,soft ,coal1 #he per cent42 ,common ,bituminous1 or ,caking ,coal1 #hh per cent42 ,anthracite1 ,blind ,coal1 ,culm1 ,glance1 or ,stone ,coal1 from ,south ,wales1 #ic per cent4 ,as far as the gas-making properties of the first three are concerned1 the relative proportions of carbon and volatile products are much the same4 ,everybody knows a piece of cannel coal when it is seen1 how it appears almost to have been once in a molten condition1 and how it breaks with a conchoidal fracture1 as opposed to the cleavage of bituminous coal into thin layers2 and1 most apparent and most noticeable of all1 how it does not soil the hands after the manner of ordinary coal4 ,it is at times so dense and compact that it has been fashioned into ornaments1 and is capable of receiving a polish like jet4 ,from the large percentage of volatile products which it contains1 it is greatly used in gasworks4 ,caking coal and the varieties of coal which exist between it and anthracite1 are familiar to every householder2 the more it approaches the composition of the latter the more difficult it is to get it to burn1 but when at last fairly alight it gives out great heat1 and what is more important1 a less quantity of volatile constituents in the shape of gas1 smoke1 ammonia1 ash and sulphurous acid4 ,for this reason it has been proposed to compel consumers to adopt anthracite as the domestic coal by ,act of ,parliament4 ,certainly by this means the amount of impurities in the air might be appreciably lessened1 but as it would involve the reconstruction of some millions of fire-places1 and an increase in price in consequence of the general demand for it1 it is not likely that a government would be so rash as to attempt to pass such a measure2 even if passed1 it would probably soon become as dead and obsolete and impotent as those many laws with which our ancestors attempted1 first to arrest1 and then to curb the growth in the use of coal of any sort4 ,anthracite is not a homely coal4 ,if we use it alone it will not give us that bright and cheerful blaze which ,english-speaking people like to obtain from their fires4 ,it is a significant fact1 and one which proves that the various kinds of coal which are found are nothing but stages begotten by different degrees of disentanglement of the contained gases1 that where1 as in some parts1 a mass of basalt has come into contact with ordinary bituminous coal1 the coal has assumed the character of anthracite1 whilst the change has in some instances gone so far as to convert the anthracite into graphite4 ,the basalt1 which is one of the igneous rocks1 has been erupted into the coal-seam in a state of fusion1 and the heat contained in it has been sufficient to cause the disentanglement of the gases1 the extraction of which from the coal brings about the condition of anthracite and graphite4 ,the mention of graphite brings us to the next stage4 ,graphite1 plumbago1 or1 as it is more commonly called1 black-lead1 which1 we may say in passing1 has nothing of lead about it at all1 is best known in the shape of that very useful and cosmopolitan article1 the black-lead pencil4 ,this is even purer carbon than anthracite1 not more than #e per cent4 of ash and other impurities being present4 ,it is well-known by its grey metallic lustre2 the chemist uses it mixed with fire-clay to make his crucibles2 the engineer uses it1 finely powdered1 to lubricate his machinery2 the house-keeper uses it to black-lead her stoves to prevent them from rusting4 ,an imperfect graphite is found inside some of the hottest retorts from which gas is distilled1 and this is used as the negative element in zinc and carbon electricity-making cells1 whilst its use as the electrodes or carbons of the arc-lamp is becoming more and more widely adopted1 as installations of electric light become more general4 ,one great source of true graphite for many years was the famous mine at ,borrowdale1 in ,cumberland1 but this is now almost exhausted4 ,the vein lay between strata of slate1 and was from eight to nine feet thick4 ,as much as #ajj1jjj is said to have been realised from it in one year4 ,extensive supplies of graphite are found in rocks of the ,laurentian age in ,canada4 ,in this formation nothing which can undoubtedly be classed as organic has yet been discovered4 ,life at this early period must have found its home in low and humble forms1 and if the eozon of ,dawson1 which has been thought to represent the earliest type of life1 turns out after all not to be organic1 but only a deceptive appearance assumed by certain of the strata1 we at least know that it must have been in similarly humble forms that life1 if it existed at all1 did then exist4 ,we can scarcely1 therefore1 expect that the vegetable world had made any great advance in complexity of organism at this time1 otherwise the supplies of graphite or plumbago which are found in the formation1 would be attributed to dense forest growths1 acted upon1 after death1 in a similar manner to that which awaited the vegetation which1 ages after1 went to form beds of coal4 ,at present we know of no source of carbon except through the intervention and the chemical action of plants4 ,like iron1 carbon is seldom found on the earth except in combination4 ,if there were no growth of vegetation at this far-away period to give rise to these deposits of graphite1 we are compelled to ask ourselves whether1 perchance1 there did not then exist conditions of which we are not now cognisant on the earth1 and which allowed graphite to be formed without assistance from the vegetable kingdom4 ,at present1 however1 science is in the dark as to any other process of its formation1 and we are left to assume that the vegetable growth of the time was enormous in quantity1 although there is nothing to show the kind of vegetation1 whether humble mosses or tall forest trees1 which went to constitute the masses of graphite4 ,geologists will agree that this is no small assumption to make1 since1 if true1 it may show that there was an abundance of vegetation at a time when animal life was hidden in one or more very obscure forms1 one only of which has so far been detected1 and whose very identity is strongly doubted by nearly all competent judges4 ,at the same time there may have been an abundance of both animal and vegetable life at the time4 ,we must not forget that it is a well-ascertained fact that in later ages1 the minute seed-spores of forest trees were in such abundance as to form important seams of coal in the true carboniferous era1 the trees which gave birth to them being now classed amongst the humble cryptogams1 the ferns1 and club-mosses1 c4 ,the graphite of ,laurentian age may not improbably have been caused by deposits of minute portions of similar lowly specimens of vegetable life1 and if the eozon the dawn-animalcule1 does represent the animal life of the time1 life whose types were too minute to leave undoubted traces of their existence1 both animal life and vegetable life may be looked upon as existing side by side in extremely humble forms1 neither as yet having taken an undoubted step forward in advance of the other in respect to complexity of organism4 ,illustration3 ,,fig #cj4--,lepidodendron4 ,portion of ,sandstone stem after removal of bark of a giant club-moss ,there is but one more form of carbon with which we have to deal in running through the series4 ,we have seen that coal is not the summum bonum of the series4 ,other transformations take place after the stage of coal is reached1 which1 by the continued disentanglement of gases1 finally bring about the plumbago stage4 ,what the action is which transforms plumbago or some other form of carbon into the condition of a diamond cannot be stated4 ,diamond is the purest form of carbon found in nature4 ,it is a beautiful object1 alike from the results of its powers of refraction1 as also from the form into which its carbon has been crystallised4 ,how ,nature1 in her wonderful laboratory1 has precipitated the diamond1 with its wonderful powers of spectrum analysis1 we cannot say with certainty4 ,certain chemists have1 at a great expense1 produced crystals which1 in every respect1 stand the tests of true diamonds2 but the process of their production at a great expense has in no way diminished the value of the natural product4 ,the process by which artificial diamonds have been produced is so interesting1 and the subject may prove to be of so great importance1 that a few remarks upon the process may not be unacceptable4 ,the experiments of the great ,french chemist1 ,dumas1 and others1 satisfactorily proved the fact1 which has ever since been considered thoroughly established1 that the diamond is nothing but carbon crystallised in nearly a pure state1 and many chemists have since been engaged in the hitherto futile endeavour to turn ordinary carbon into the true diamond4 ,despretz at one time considered that he had discovered the process1 which consisted in his case of submitting a piece of charcoal to the action of an electric battery1 having in his mind the similar process of electrolysis1 by which water is divided up into the two gases1 hydrogen and oxygen4 ,he obtained a microscopic deposit on the poles of the battery1 which he pronounced to be diamond dust1 but which1 a long time after1 was proved to be nothing but graphite in a crystallised state4 ,this was1 however1 certainly a step in the right direction4 ,the honour of first accomplishing the task fell to ,mr ,hannay1 of ,glasgow1 who succeeded in producing very small but comparatively soft diamonds1 by heating lampblack under great pressure1 in company with one or two other ingredients4 ,the process was a costly one1 and beyond being a great scientific feat1 the discovery led to little result4 ,a young ,french chemist1 ,m4 ,henri ,moissau1 has since come to the front1 and the diamonds which he has produced have stood every test for the true diamond to which they could be subjected2 above all1 the density of the product is #c4e1 i4e41 that of the diamond1 that of graphite reaching #b only4 ,he recognised that in all diamonds which he had consumed--and he consumed some #aej worth in order to assure himself of the fact--there were always traces of iron in their composition4 ,he saw that iron in fusion1 like other metals1 always dissolves a certain quantity of carbon4 ,might it not be that molten iron1 cooling in the presence of carbon1 deep in volcanic depths where there was little scope for the iron to expand in assuming the solid form1 would exert such tremendous pressure upon the particles of carbon which it absorbed1 that these would assume the crystalline state8 ,he packed a cylinder of soft iron with the carbon of sugar1 and placed the whole in a crucible filled with molten iron1 which was raised to a temperature of #cjjj by means of an electric furnace4 ,the soft cylinder melted1 and dissolved a large portion of the carbon4 ,the crucible was thrown into water1 and a mass of solid iron was formed4 ,it was allowed further to cool in the open air1 but the expansion which the iron would have undergone on cooling1 was checked by the crucible which contained it4 ,the result was a tremendous pressure1 during which the carbon1 which was still dissolved1 was crystallised into minute diamonds4 ,these showed themselves as minute points which were easily separable from the mass by the action of acids4 ,thus the wonderful transformation from sugar to the diamond was accomplished4 ,it should be mentioned that iron1 silver1 and water1 alone possess the peculiar property of expanding when passing from the liquid to the solid state4 ,the diamonds so obtained were of both kinds4 ,the particles of white diamond resembled in every respect the true brilliant4 ,but there was also an appreciable quantity of the variety known as the black diamond4 ,these diamonds seem to approximate more closely to carbon as we are most familiar with it4 ,they are not considered as of such value as the transparent form1 but they are still of considerable commercial value4 ,the carbonado1 as this kind is called1 possesses so great a degree of hardness that by means of it it is possible to bore through the hardest rocks4 ,the diamond drill1 used for boring purposes1 is furnished around the outer edge of the cylinder of the boring bit1 as it is called1 with perhaps a dozen black diamonds1 together with another row of ,brazilian diamonds on the inside4 ,by the rotation of the boring tool the sharp edges of the diamonds cut their way through rocks of all degrees of hardness1 leaving a core of the rock cut through1 in the centre of the cylindrical drill4 ,it is found that the durability of the natural edge of the diamond is far greater than that of the edge caused by artificial cutting and trimming4 ,the cutting of a pane of glass by means of a ring set with an artificially-cut diamond1 cannot therefore be done without injuring to a slight extent the edge of the stone4 ,the diamond is the hardest of all known substances1 leaving a scratch on any substance across which it may be drawn4 ,yet it is one whose form can be changed1 and whose hardness can be completely destroyed1 by the simple process of combustion4 ,it can be deprived of its high lustre1 and of its power of breaking up by refraction the light of the sun into the various tints of the solar spectrum1 simply by heating it to a red heat1 and then plunging it into a jar of oxygen gas4 ,it immediately expands1 changes into a coky mass1 and burns away4 ,the product left behind is a mixture of carbon and oxygen1 in the proportions in which it is met with in carbonic-anhydride1 or1 carbonic acid gas deprived of its water4 ,this is indeed a strange transformation1 from the most valuable of all our precious stones to a compound which is the same in chemical constituents as the poisonous gas which we and all animals exhale4 ,but there is this to be said4 ,probably in the far-away days when the diamond began to be formed1 the tree or other vegetable product which was its far-removed ancestor abstracted carbonic acid gas from the atmosphere1 just as do our plants in the present day4 ,by this means it obtained the carbon wherewith to build up its tissues4 ,thus the combustion of the diamond into carbonic-anhydride now is1 after all1 only a return to the same compound out of which it was originally formed4 ,how it was formed is a secret3 probably the time occupied in the formation of the diamond may be counted by centuries1 but the time of its re-transformation into a mass of coky matter is but the work of seconds6 ,there is another form of carbon which was formerly of much greater importance than it is now1 and which1 although not a natural product1 is yet deserving of some notice here4 ,charcoal is the substance referred to4 ,in early days the word coal1 or1 as it was also spelt1 cole1 was applied to any substance which was used as fuel2 hence we have a reference in the ,bible to a fire of coals1 so translated when the meaning to be conveyed was probably not coal as we know it4 ,wood was formerly known as coal1 whilst charred wood received the name of charred-coal1 which was soon corrupted into charcoal4 ,the charcoal-burners of years gone by were a far more flourishing community than they are now4 ,when the old baronial halls and country-seats depended on them for the basis of their fuel1 and the log was a more frequent occupant of the fire-grate than now1 these occupiers of midforest were a people of some importance4 ,we must not overlook the fact that there is another form of charcoal1 namely1 animal charcoal or bone-black4 ,this can be obtained by heating bones to redness in closed iron vessels4 ,in the refining of raw sugar the discoloration of the syrup is brought about by filtering it through animal-charcoal2 by this means the syrup is rendered colourless4 ,when properly prepared1 charcoal exhibits very distinctly the rings of annual growth which may have characterised the wood from which it was formed4 ,it is very light in consequence of its porous nature1 and it is wonderfully indestructible4 ,but its greatest1 because it is its most useful property1 is undoubtedly the power which it has of absorbing great quantities of gas into itself4 ,it is in fact what may be termed an all-round purifier4 ,it is a deodoriser1 a disinfectant1 and a decoloriser4 ,it is an absorbent of bad odours1 and partially removes the smell from tainted meat4 ,it has been used when offensive manures have been spread over soils1 with the same object in view1 and its use for the purification of water is well known to all users of filters4 ,some idea of its power as a disinfectant may be gained by the fact that one volume of wood-charcoal will absorb no less than #ij volumes of ammonia1 #ce volumes of carbonic anhydride1 and #fe volumes of sulphurous anhydride4 ,other forms of carbon which are well-known are 7#a7 coke1 the residue left when coal has been subjected to a great heat in a closed retort1 but from which all the bye-products of coal have been allowed to escape2 7#b7 soot and lamp-black1 the former of which is useful as a manure in consequence of ammonia being present in it1 whilst the latter is a specially prepared soot1 and is used in the manufacture of ,indian ink and printers' ink4 ,,chapter ,,iv4 ,,the ,,coal-,,mine ,,and ,,its ,,dangers4 ,it is somewhat strange to think that where once existed the solitudes of an ancient carboniferous forest now is the site of a busy underground town4 ,for a town it really is4 ,the various roads and passages which are cut through the solid coal as excavation of a coal-mine proceeds1 represent to a stranger all the intricacies of a well-planned town4 ,nor is the extent of these underground towns a thing to be despised4 ,there is an old pit near ,newcastle which contains not less than fifty miles of passages4 ,other pits there are whose main thoroughfares in a direct line are not less than four or five miles in length1 and this1 it must be borne in mind1 is the result of excavation wrought by human hands and human labour4 ,so great an extent of passages necessarily requires some special means of keeping the air within it in a pure state1 such as will render it fit for the workers to breathe4 ,the further one would go from the main thoroughfare in such a mine1 the less likely one would be to find air of sufficient purity for the purpose4 ,it is as a consequence necessary to take some special steps to provide an efficient system of ventilation throughout the mine4 ,this is effectually done by two shafts1 called respectively the downcast and the upcast shaft4 ,a shaft is in reality a very deep well1 and may be circular1 rectangular or oval in form4 ,in order to keep out water which may be struck in passing through the various strata1 it is protected by plank or wood tubbing1 or the shaft is bricked over1 or sometimes even cast-iron segments are sunk4 ,in many shafts which1 owing to their great depth1 pass through strata of every degree of looseness or viscosity1 all three methods are utilised in turn4 ,in ,westphalia1 where coal is worked beneath strata of more recent geological age1 narrow shafts have been1 in many cases1 sunk by means of boring apparatus1 in preference to the usual process of excavation1 and the practice has since been adopted in ,south ,wales4 ,in ,england the usual form of the pit is circular1 but elliptical and rectangular pits are also in use4 ,on the ,continent polygonal-shaped shafts are not uncommon1 all of them1 of whatever shape1 being constructed with a view to resist the great pressure exerted by the rock around4 ,illustration3 ,,fig4 #ca4--;,engine-,house and ,buildings at head of a ,coal-,pit4 ,if there be one of these shafts at one end of the mine1 and another at a remote distance from it1 a movement of the air will at once begin1 and a rough kind of ventilation will ensue4 ,this is1 however1 quite insufficient to provide the necessary quantity of air for inhalation by the army of workers in the coal-mine1 for the current thus set up does not even provide sufficient force to remove the effete air and impurities which accumulate from hundreds of perspiring human bodies4 ,it is therefore necessary to introduce some artificial means1 by which a strong and regular current shall pass down one shaft1 through the mine in all its workings1 and out at the other shaft4 ,this is accomplished in various ways4 ,it took many years before those interested in mines came thoroughly to understand how properly to secure ventilation1 and in bygone days the system was so thoroughly bad that a tremendous amount of sickness prevailed amongst the miners1 owing to the poisonous effects of breathing the same air over and over again1 charged1 as it was1 with more or less of the gases given off by the coal itself4 ,now1 those miners who do so great a part in furnishing the means of warming our houses in winter1 have the best contrivances which can be devised to furnish them with an ever-flowing current of fresh air4 ,amongst the various mechanical appliances which have been used to ensure ventilation may be mentioned pumps1 fans1 and pneumatic screws4 ,there is1 as we have said1 a certain1 though slight1 movement of the air in the two columns which constitute the upcast and the downcast shafts1 but in order that a current may flow which shall be equal to the necessities of the miners1 some means are necessary1 by which this condition of almost equilibrium shall be considerably disturbed1 and a current created which shall sweep all foul gases before it4 ,one plan was to force fresh air into the downcast1 which should in a sense push the foetid air away by the upcast4 ,another was to exhaust the upcast1 and so draw the gases in the train of the exhausted air4 ,in other cases the plan was adopted of providing a continual falling of water down the downcast shaft4 ,these various plans have almost all given way to that which is the most serviceable of all1 namely1 the plan of having an immense furnace constantly burning in a specially-constructed chamber at the bottom of the upcast4 ,by this means the column of air above it becomes rarefied under the heat1 and ascends1 whilst the cooler air from the downcast rushes in and spreads itself in all directions whence the bad air has already been drawn4 ,on the other hand1 to so great a state of perfection have ventilating fans been brought1 that one was recently erected which would be capable of changing the air of ,westminster ,hall thirty times in one hour4 ,having procured a current of sufficient power1 it will be at once understood that1 if left to its own will1 it would take the nearest path which might lie between its entrance and its exit1 and1 in this way1 ventilating the principal street only1 would leave all the many off-shoots from it undisturbed4 ,it is consequently manipulated by means of barriers and tight-fitting doors1 in such a way that the current is bound in turn to traverse every portion of the mine4 ,a large number of boys1 known as trappers1 are employed in opening the doors to all comers1 and in carefully closing the doors immediately after they have passed1 in order that the current may not circulate through passages along which it is not intended that it should pass4 ,the greatest dangers which await the miners are those which result1 in the form of terrible explosions1 from the presence of inflammable gases in the mines4 ,the great walls of coal which bound the passages in mines are constantly exuding supplies of gas into the air4 ,when a bank of coal is brought down by an artificial explosion1 by dynamite1 by lime cartridges1 or by some other agency1 large quantities of gas are sometimes disengaged1 and not only is this highly detrimental to the health of the miners1 if not carried away by proper ventilation1 but it constitutes a constant danger which may at any time cause an explosion when a naked light is brought into contact with it4 ,fire-damp may be sometimes heard issuing from fiery seams with a peculiar hissing sound4 ,if the volume be great1 the gas forms what is called a blower1 and this often happens in the neighbourhood of a fault4 ,when coal is brought down in any large volume1 the blowers which commence may be exhausted in a few moments4 ,others1 however1 have been known to last for years1 this being the case at ,wallsend1 where the blower gave off #abj feet of gas per minute4 ,in such cases the gas is usually conveyed in pipes to a place where it can be burned in safety4 ,in the early days of coal-mining the explosions caused by this gas soon received the serious attention of the scientific men of the age4 ,in the ,philosophical ,transactions of the ,royal ,society we find a record of a gas explosion in #afgg4 ,the amusing part of such records was that the explosions were ascribed by the miners to supernatural agencies4 ,little attention seemed to have been paid to the fact1 which has since so thoroughly been established1 that the explosions were caused by accumulations of gas1 mixed in certain proportions with air4 ,as a consequence1 tallow candles with an exposed flame were freely used1 especially in ,britain4 ,these were placed in niches in the workings1 where they would give to the pitman the greatest amount of light4 ,previous to the introduction of the safety-lamp1 workings were tested before the men entered them1 by trying the candle4 ,owing to the specific gravity of fire-damp 74#eee7 being less than that of air1 it always finds a lodgement at the roofs of the workings1 so that1 to test the condition of the air1 it was necessary to steadily raise the candle to the roof at certain places in the passages1 and watch carefully the action of the flame4 ,the presence of fire-damp would be shown by the flame assuming a blue colour1 and by its elongation2 the presence of other gases could be detected by an experienced man by certain peculiarities in the tint of the flame4 ,this testing with the open flame has almost entirely ceased since the introduction of the perfected ,davy lamp4 ,the use of candles for illumination soon gave place in most of the large collieries to the introduction of small oil-lamps4 ,in the less fiery mines on the ,continent1 oil-lamps of the well-known ,etruscan pattern are still in use1 whilst small metal lamps1 which can conveniently be attached to the cap of the worker1 occasionally find favour in the shallower ,scotch mines4 ,these lamps are very useful in getting the coal from the thinner seams1 where progress has to be made on the hands and feet4 ,at the close of the last century1 as workings began to be carried deeper1 and coal was obtained from places more and more infested with fire-damp1 it soon came to be realised that the old methods of illumination would have to be replaced by others of a safer nature4 ,it is noteworthy that mere red heat is insufficient in itself to ignite fire-damp1 actual contact with flame being necessary for this purpose4 ,bearing this in mind1 ,spedding1 the discoverer of the fact1 invented what is known as the steel-mill for illuminating purposes4 ,in this a toothed wheel was made to play upon a piece of steel1 the sparks thus caused being sufficient to give a moderate amount of illumination4 ,it was found1 however1 that this method was not always trustworthy1 and lamps were introduced by ,humboldt in #agif1 and by ,clanny in #ahjf4 ,in these lamps the air which fed the flame was isolated from the air of the mine by having to bubble through a liquid4 ,many miners were not1 however1 provided with these lamps1 and the risks attending naked lights went on as merrily as ever4 ,in order to avoid explosions in mines which were known to give off large quantities of gas1 fiery pits as they are called1 ,sir ,humphrey ,davy in #ahae invented his safety lamp1 the principle of which can be stated in a few words4 ,if a piece of fine wire gauze be held over a gas-jet before it is lit1 and the gas be then turned on1 it can be lit above the gauze1 but the flame will not pass downwards towards the source of the gas2 at least1 not until the gauze has become over-heated4 ,the metallic gauze so rapidly conducts away the heat1 that the temperature of the gas beneath the gauze is unable to arrive at the point of ignition4 ,in the safety-lamp the little oil-lamp is placed in a circular funnel of fine gauze1 which prevents the flame from passing through it to any explosive gas that may be floating about outside1 but at the same time allows the rays of light to pass through readily4 ,sir ,humphrey ,davy1 in introducing his lamp1 cautioned the miners against exposing it to a rapid current of air1 which would operate in such a way as to force the flame through the gauze1 and also against allowing the gauze to become red-hot4 ,in order to minimise1 as far as possible1 the necessity of such caution the lamp has been considerably modified since first invented1 the speed of the ventilating currents not now allowing of the use of the simple ,davy lamp1 but the principle is the same4 ,during the progress of ,sir ,humphrey ,davy's experiments1 he found that when fire-damp was diluted with #he per cent4 of air1 and any less proportion1 it simply ignited without explosion4 ,with between #he per cent4 and #hi per cent4 of air1 fire-damp assumed its most explosive form1 but afterwards decreased in explosiveness1 until with #id-a_/d per cent4 of air it again simply ignited without explosion4 ,with between #aa and #ab per cent4 of fire-damp the mixture was most dangerous4 ,pure fire-damp itself1 therefore1 is not dangerous1 so that when a small quantity enters the gauze which surrounds the ,davy lamp1 it simply burns with its characteristic blue flame1 but at the same time gives the miner due notice of the danger which he was running4 ,illustration3 ,,fig4 #cb4--;,gas ,jet and ,davy ,lamp4 ,with the complicated improvements which have since been made in the ,davy lamp1 a state of almost absolute safety can be guaranteed1 but still from time to time explosions are reported4 ,of the cause of many we are absolutely ignorant1 but occasionally a light is thrown upon their origin by a paragraph appearing in a daily paper4 ,two men are charged before the magistrates with being in the possession of keys used exclusively for unlocking their miners' safety-lamps4 ,there is no defence4 ,these men know that they carry their lives in their hands1 yet will risk their own and those of hundreds of others1 in order that they may be able to light their pipes by means of their safety-lamps4 ,sometimes in an unexpected moment there is a great dislodgement of coal1 and a tremendous quantity of gas is set free1 which may be sufficient to foul the passages for some distance around4 ,the introduction or exposure of a naked light for even so much as a second is sufficient to cause explosion of the mass2 doors are blown down1 props and tubbing are charred up1 and the volume of smoke1 rushing up by the nearest shaft and overthrowing the engine-house and other structures at the mouth1 conveys its own sad message to those at the surface1 of the dreadful catastrophe that has happened below4 ,perhaps all that remains of some of the workers consists of charred and scorched bodies1 scarcely recognisable as human beings4 ,others escape with scorched arms or legs1 and singed hair1 to tell the terrible tale to those who were more fortunately absent2 to speak of their own sufferings when1 after having escaped the worst effects of the explosion1 they encountered the asphyxiating rush of the after-damp or choke-damp1 which had been caused by the combustion of the fire-damp4 ,choke-damp in very truth it is1 for it is principally composed of our old acquaintance carbonic acid gas 7carbon dioxide71 which is well known as a non-supporter of combustion and as an asphyxiator of animal life4 ,it seems a terrible thing that on occasions the workings and walls themselves of a coal-mine catch fire and burn incessantly4 ,yet such is the case4 ,years ago this happened in the case of an old colliery near ,dudley1 at the surface of which1 by means of the heat and steam thus afforded1 early potatoes for the ,london market1 we are told1 were grown2 and it was no unusual thing to see the smoke emerging from cracks and crevices in the rocks in the vicinity of the town4 ,from fire on the one hand1 we pass1 on the other1 to the danger which awaits miners from a sudden inrush of water4 ,during the great coal strike of #ahic1 certain mines became unworkable in consequence of the quantity of water which flooded the mines1 and which1 continually passing along the natural fractures in the earth's crust1 is always ready to find a storage reservoir in the workings of a coal-mine4 ,this is a difficulty which is always experienced in the sinking of shafts1 and the shutting off of water engages the best efforts of mining engineers4 ,added to these various dangers which exist in the coal-mine1 we must not omit to notice those accidents that are continually being caused by the falling-in of roofs or of walls1 from the falling of insecure timber1 or of what are known as coal-pipes or bell-moulds4 ,then1 again1 every man that enters the mine trusts his life to the cage by which he descends to his labour1 and shaft accidents are not infrequent4 ,the following table shows the number of deaths from colliery accidents for a period of ten years1 compiled by a ,government inspector1 and from this it will be seen that those resulting from falling roofs number considerably more than one-third of the whole4 ---------------------------------------- --------------------------- ,causes of ,death4 ,no4 of ,proportion ,deaths4 per cent4 ---------------------------------------- --------------------------- ,deaths resulting from fire-damp explosions #bjai #bj4cf ,deaths resulting from falling roofs and coals #ciec #ci4hg ,deaths resulting from shaft accidents #agaj #ag4bd ,deaths resulting from miscellaneous causes and above ground #bbcd #bb4ec ------------------------ #iiaf #ajj4jj ---------------------------------------- -------------------------- ,every reader of the daily papers is familiar with the harrowing accounts which are there given of coal-mine explosions4 ,this kind of accident is one1 which is1 above all1 associated in the public mind with the dangers of the coal-pit4 ,yet the accidents arising from this cause number but #bj per cent4 of those recorded1 and granted there be proper inspection1 and the use of naked lights be absolutely abolished1 this low percentage might still be considerably reduced4 ,a terrific explosion occurred at ,whitwick ,colliery1 ,leicestershire1 in #ahic1 when two lads were killed1 whilst a third was rescued after a very narrow escape4 ,the lads1 it is stated1 were working with naked lights1 when a sudden fall of coal released a quantity of gas1 and an immediate explosion was the natural result4 ,accidents had been so rare at this pit that it was regarded as particularly safe1 and it was alleged that the use of naked lights was not uncommon4 ,this is an instance of that large number of accidents which are undoubtedly preventable4 ,an interesting commentary on the careless manner in which miners risk their lives was shown in the discoveries made after an explosion at a colliery near ,wrexham in #ahhi4 ,near the scene of the explosion an unsecured safety lamp was found1 and the general opinion at the time was that the disaster was caused by the inexcusable carelessness of one of the twenty victims4 ,besides this1 when the clothing of the bodies recovered was searched1 the contents1 taken1 it should be noted1 with the pitmen into the mines1 consisted of pipes1 tobacco1 matches1 and even keys for unlocking the lamps4 ,it is a strange reflection on the manner in which this mine had been examined previous to the men entering upon their work1 that the under-looker1 but half an hour previously1 had reported the pit to be free from gas4 ,another instance of the same foolhardiness on the part of the miners is contained in the report issued in regard to an explosion which occurred at ,denny1 in ,stirlingshire1 on ,april #bfth1 #ahie4 ,by this accident thirteen men lost their lives1 and upon the bodies of eight of the number the following articles were found2 upon ,patrick ,carr1 tin matchbox half full of matches and a contrivance for opening lamps2 ,john ,comrie1 split nail for opening lamps2 ,peter ,conway1 seven matches and split key for opening lamps2 ,patrick ,dunton1 split nail for opening lamps2 ,john ,herron1 clay pipe and piece of tobacco2 ,henry ,m',govern1 tin matchbox half full of matches2 ,robert ,mitchell1 clay pipe and piece of tobacco2 ,john ,nicol1 wooden pipe1 piece of tobacco1 one match1 and box half full of matches4 ,the report stated that the immediate cause of the disaster was the ignition of fire-damp by naked light1 the conditions of temperature being such as to exclude the possibility of spontaneous combustion4 ,henry ,m',govern had previously been convicted of having a pipe in the mine4 ,with regard to the question of sufficient ventilation it continued3--,and we are therefore led1 on a consideration of the whole evidence1 to the conclusion that the accident cannot be attributed to the absence of ventilation1 which the mine owners were bound under the ,mines ,regulation ,act and the special rules to provide4 ,the report concluded as follows3-- ,on the whole matter we have to report that1 in our opinion1 the explosion at ,quarter ,pit on ,april #bfth1 #ahie1 resulting in the loss of thirteen lives1 was caused by the ignition of an accumulation or an outburst of gas coming in contact with a naked light1 'other than an open safety-lamp1' which had been unlawfully kindled by one of the miners who were killed4 ,in our opinion1 the intensity of the explosion was aggravated1 and its area extended1 by the ignition of coal-dust4 ,we have mentioned that accidents have frequently occurred from the falling of coal-pipes1 or1 as they are also called1 bell-moulds4 ,we must explain what is meant by this term4 ,they are simply what appear to be solid trunks of trees metamorphosed into coal4 ,if we go into a tropical forest we find that the woody fibre of dead trees almost invariably decays faster than the bark4 ,the result is that what may appear to be a sound tree is nothing but an empty cylinder of bark4 ,this appears to have been the case with many of the trees in coal-mines1 where they are seen to pierce the strata1 and around which the miners are excavating the coal4 ,as the coaly mass collected around the trunk when the coal was being formed1 the interior was undergoing a process of decomposition1 while the bark assumed the form of coal4 ,the hollow interior then became filled with the shale or sandstone which forms the roof of the coal1 and its sole support when the coal is removed from around it1 is the thin rind of carbonised bark4 ,when this falls to pieces1 or loses its cohesion1 the sandstone trunk falls of its own weight1 often causing the death of the man that works beneath it4 ,sir ,charles ,lyell mentions that in a colliery near ,newcastle1 no less than thirty sigillaria trees were standing in their natural position in an area of fifty yards square1 the interior in each case being sandstone1 which was surrounded by a bark of friable coal4 ,illustration3 ,fig4 #cc--,part of a trunk of ,sigillaria1 showing the thin outer carbonised bark1 with leaf-scars1 and the seal-like impressions where the bark is removed4 ,the last great danger to which we have here to make reference1 is the explosive action of a quantity of coal-dust in a dry condition4 ,it is only now commencing to be fully recognised that this is really a most dangerous explosive4 ,as we have seen1 large quantities of coal are formed almost exclusively of lepidodendron spores1 and such coal is productive of a great quantity of dust4 ,explosions which are always more or less attributable to the effects of coal-dust are generally considered1 in the official statistics1 to have been caused by fire-damp4 ,the ,act regulating mines in ,great ,britain is scarcely up to date in this respect4 ,there is a regulation which provides for the watering of all dry and dusty places within twenty yards from the spot where a shot is fired1 but the enforcement of this regulation in each and every pit necessarily devolves on the managers1 many of whom in the absence of an inspector leave the requirement a dead letter4 ,every improvement which results in the better ventilation of a coal-mine tends to leave the dust in a more dangerous condition4 ,the air1 as it descends the shaft and permeates the workings1 becomes more and more heated1 and licks up every particle of moisture it can touch4 ,thorough ventilation results in more greatly freeing a mine of the dangerous fire-damp1 but the remedy brings about another disease1 viz41 the drying-up of all moisture4 ,the dust is thus left in a dangerously inflammable condition1 acting like a train of gunpowder1 to be started1 it may be1 by the slightest breath of an explosion4 ,there is apparently little doubt that the presence of coal-dust in a dry state in a mine appreciably increases the liability of explosion in that mine4 ,so far as ,great ,britain is concerned1 a ,royal ,commission was appointed by ,lord ,rosebery's ,government to inquire into and investigate the facts referring to coal-dust4 ,generally speaking1 the conclusion arrived at was that fine coal-dust was inflammable under certain conditions4 ,there was considerable difference of opinion as to what these conditions were4 ,some were of opinion that coal-dust and air alone were of an explosive nature1 whilst others thought that alone they were not1 but that the addition of a small quantity of fire-damp rendered the mixture explosive4 ,an important conclusion was come to1 that1 with the combustion of coal-dust alone1 there was little or no concussion1 and that the flame was not of an explosive character4 ,coal-dust was1 however1 admittedly dangerous1 especially if in a dry condition4 ,the effects of an explosion of gas might be considerably extended by its presence1 and there seems every reason to believe that1 with a suitable admixture of air and a very small proportion of gas1 it forms a dangerous explosive4 ,legislation in the direction of the report of the ,commission is urgently needed4 ,we have seen elsewhere what it is in the dust which makes it dangerous1 how that1 for the most part1 it consists of the dust-like spores of the lepidodendron tree1 fine and impalpable as the spores on the backs of some of our living ferns1 and the fact that this consists of a large proportion of resin makes it the easily inflammable substance it is4 ,nothing but an incessant watering of the workings in such cases will render the dust innocuous4 ,the dust is extremely fine1 and is easily carried into every nook and crevice1 and when1 as at ,bridgend in #ahib1 it explodes1 it is driven up and out of the shaft1 enveloping everything temporarily in dust and darkness4 ,in some of the pits in ,south ,wales a system of fine sprays of water is in use1 by which the water is ejected from pin-holes pricked in a series of pipes which are carried through the workings4 ,a fine mist is thus caused where necessary1 which is carried forward by the force of the ventilating current4 ,a thorough system of inspection in coal-mines throughout the world is undoubtedly urgently called for1 in order to ensure the proper carrying out of the various regulations framed for their safety4 ,it is extremely unfortunate that so many of the accidents which happen are preventable1 if only men of knowledge and of scientific attainments filled the responsible positions of the overlookers4 ,,chapter ,v4 ,,early ,,history--,,its ,,use ,,and ,,its ,,abuse4 ,the extensive use of coal throughout the civilised world for purposes of heating and illumination1 and for the carrying on of manufactures and industries1 may be regarded as a well-marked characteristic of the age in which we live4 ,coal must have been in centuries past a familiar object to many generations4 ,people must have long been living in close proximity to its outcrops at the sides of the mountains and at the surface of the land1 yet without being acquainted with its practical value1 and it seems strange that so little use was made of it until about three centuries ago1 and that its use did not spread earlier and more quickly throughout civilised countries4 ,a mineral fuel is mentioned by ,theophrastus about #cjj ,b4,c41 from which it is inferred that thus early it was dug from some of the more shallow depths4 ,the ,britons before the time of the ,roman invasion are credited with some slight knowledge of its industrial value4 ,prehistoric excavations have been found in ,monmouthshire1 and at ,stanley1 in ,derbyshire1 and the flint axes there actually found imbedded in the layer of coal are reasonably held to indicate its excavation by neolithic or palaeolithic 7stone-age7 workmen4 ,the fact that coal cinders have been found on old ,roman walls in conjunction with ,roman tools and implements1 goes to prove that its use1 at least for heating purposes1 was known in ,england prior to the ,saxon invasion1 whilst some polygonal chambers in the six-foot seam near the river ,douglas1 in ,lancashire1 are supposed also to be ,roman4 ,the ,chinese were early acquainted with the existence of coal1 and knew of its industrial value to the extent of using it for the baking of porcelain4 ,the fact of its extensive existence in ,great ,britain1 and the valuable uses to which it might be put1 did not1 however1 meet with much notice until the ninth century1 when1 owing to the decrease of the forest-area1 and consequently of the supply of wood-charcoal therefrom1 it began to attract attention as affording an excellent substitute for charcoal4 ,the coal-miner was1 however1 still a creation of the future1 and even as peat is collected in ,ireland at the present day for fuel1 without the laborious process of mining for it1 so those people living in coal-bearing districts found their needs satisfied by the quantity of coal1 small as it was1 which appeared ready to hand on the sides of the carboniferous mountains4 ,till then1 and for a long time afterwards1 the principal source of fuel consisted of vast forests1 amidst which the charcoal-burners1 or colliers as they were even then called1 lived out their lonely existence in preparing charcoal and hewing wood1 for the fires of the baronial halls and stately castles then swarming throughout the land4 ,as the forests became used up1 recourse was had more and more to coal1 and in #abci the first charter dealing with and recognising the importance of the supplies was granted to the freemen of ,newcastle1 according them permission to dig for coals in the ,castle fields4 ,about the same time a coal-pit at ,preston1 ,haddingtonshire1 was granted to the monks of ,newbattle4 ,specimens of ,newcastle coal were sent to ,london1 but the city was loth to adopt its use1 objecting to the innovation as one prejudicial to the health of its citizens4 ,by the end of the #afth century1 two ships only were found sufficient to satisfy the demand for stone-coal in ,london4 ,this slow progress may1 perhaps1 have been partially owing to the difficulties which were placed in the way of its universal use4 ,great opposition was experienced by those who imported it into the metropolis1 and the increasing amount which was used by brewers and others about the year #acjj1 caused serious complaints to be made1 the effect of which was to induce ,parliament to obtain a proclamation from the ,king prohibiting its use1 and empowering the justices to inflict a fine on those who persisted in burning it4 ,the nuisance which coal has since proved itself1 in the pollution of the atmosphere and in the denuding of wide tracts of country of all vegetation1 was even thus early recognised1 and had the efforts which were then made to stamp out its use1 proved successful1 those who live now in the great cities might never have become acquainted with that species of black winter fog which at times hangs like a pall over them1 and transforms the brightness of day into a darkness little removed from that of night4 ,at the same time1 we must bear in mind that it is universally acknowledged that ,england owes her prosperity1 and her pre-eminence in commerce1 in great part1 to her happy possession of wide and valuable coal-fields1 and many authorities have not hesitated to say1 that1 in their opinion1 the length of time during which ,england will continue to hold her prominent position as an industrial nation is limited by the time during which her coal will last4 ,the attempt to prohibit the burning of coal was not1 however1 very successful1 for in the reign of ,edward ,,iii4 a license was again granted to the freemen of ,newcastle to dig for coals4 ,newcastle was thus the first town to become famous as the home of the coal-miner1 and the fame which it early acquired1 it has held unceasingly ever since4 ,other attempts at prohibition of the article were made at various times subsequently1 amongst them being one which was made in ,elizabeth's reign4 ,it was supposed that the health of the country squires1 who came to town to attend the session of ,parliament1 suffered considerably during their sojourn in ,london1 and1 to remedy this serious state of affairs1 the use of stone-coal during the time ,parliament was sitting was once more prohibited4 ,coal was1 however1 by this time beginning to be recognised as a most valuable and useful article of fuel1 and had taken a position in the industrial life of the country from which it was difficult to remove it4 ,rather than attempt to have arrested the growing use of coal1 ,parliament would have been better employed had it framed laws compelling the manufacturers and other large burners to consume their own smoke1 and instead of aiming at total prohibition1 have encouraged an intelligent and more economical use of it4 ,in spite of all prohibition its use rapidly spread1 and it was soon applied to the smelting of iron and to other purposes4 ,iron had been largely produced in the south of ,england from strata of the ,wealden formation1 during the existence of the great forest which at one time extended for miles throughout ,surrey and ,sussex4 ,the discovery of coal1 however1 and the opening up of many mines in the north1 gave an important impetus to the smelting of iron in those counties1 and as the forests of the ,weald became exhausted1 the iron trade gradually declined4 ,furnace after furnace became extinguished1 until in #ahji that at ,ashburnham1 which had lingered on for some years1 was compelled to bow to the inevitable fate which had overtaken the rest of the iron blast-furnaces4 ,in referring to this subject1 ,sir ,james ,picton says3--,ironstone of excellent quality is found in various parts of the county1 and was very early made use of4 ,even before the advent of the ,romans1 the ,forest of ,dean in the west1 and the ,forest of ,anderida1 in ,sussex1 in the east1 were the two principal sources from which the metal was derived1 and all through the mediaeval ages the manufacture was continued4 ,after the discovery of the art of smelting and casting iron in the sixteenth century1 the manufacture in ,sussex received a great impulse from the abundance of wood for fuel1 and from that time down to the middle of the last century it continued to flourish4 ,one of the largest furnaces was at ,lamberhurst1 on the borders of ,kent1 where the noble balustrade surrounding ,st ,paul's ,cathedral was cast at a cost of about #aa1jjj4 ,it is stated by the historian ,holinshed that the first cast-iron ordnance was manufactured at ,buxted4 ,two specialities in the iron trade belonged to ,sussex1 the manufacture of chimney-backs1 and cast-iron plates for grave-stones4 ,at the time when wood constituted the fuel the backs of fire-places were frequently ornamented with neat designs4 ,specimens1 both of the chimney-backs and of the monuments1 are occasionally met with4 ,these articles were exported from ,rye4 ,the iron manufacture1 of course1 met with considerable discouragement on the discovery of smelting with pit-coal1 and the rapid progress of iron works in ,staffordshire and the ,north1 but it lingered on until the great forest was cut down and the fuel exhausted4 ,in his interesting work1 ,sylvia1 published in #affa1 ,evelyn1 in speaking of the noxious vapours poured out into the air by the increasing number of coal fires1 writes1 ,this is that pernicious smoke which sullies all her glory1 superinducing a sooty crust or furr upon all that it lights1 spoiling movables1 tarnishing the plate1 gildings and furniture1 and corroding the very iron bars and hardest stones with those piercing and acrimonious spirits which accompany its sulphur1 and executing more in one year than the pure air of the country could effect in some hundreds4 ,the evils here mentioned are those which have grown and have become intensified a hundred-fold during the two centuries and a half which have since elapsed4 ,when the many efforts which were made to limit its use in the years prior to #afjj are remembered2 at which time1 we are informed1 two ships only were engaged in bringing coal to ,london1 it at once appears how paltry are the efforts made now to moderate these same baneful influences on our atmosphere1 at a time when the annual consumption of coal in the ,united ,kingdom has reached the enormous total of #aij millions of tons4 ,the various smoke-abatement associations which have started into existence during the last few years are doing a little1 although very little1 towards directing popular attention to the subject2 but there is an enormous task before them1 that of awakening every individual to an appreciation of the personal interest which he has in their success1 and to realise how much might at once be done if each were to do his share1 minute though it might be1 towards mitigating the evils of the present mode of coal-consumption4 ,probably very few householders ever realise what important factories their chimneys constitute1 in bringing about air pollution1 and the more they do away with the use of bituminous coal for fuel1 the nearer we shall be to the time when yellow fog will be a thing of the past4 ,a large proportion of smoke consists of particles of pure unconsumed carbon1 and this is accompanied in its passage up our chimneys by sulphurous acid1 begotten by the sulphur which is contained in the coal to the amount of about eight pounds in every thousand2 by sulphuretted hydrogen1 by hydro-carbons1 and by vapours of various kinds of oils1 small quantities of ammonia1 and other bodies not by any means contributing to a healthy condition of the atmosphere4 ,a good deal of the heavier carbon is deposited along the walls of chimneys in the form of soot1 together with a small percentage of sulphate of ammonia2 this is as a consequence very generally used for manure4 ,the remainder is poured out into the atmosphere1 there to undergo fresh changes1 and to become a fruitful cause of those thick black fogs with which town-dwellers are so familiar4 ,sulphuretted hydrogen 7,h#b,s7 is a gas well known to students of chemistry as a most powerful reagent1 its most characteristic external property being the extremely offensive odour which it possesses1 and which bears a strong resemblance to that of rotten eggs or decomposing fish4 ,it tarnishes silver work and picture frames very rapidly4 ,on combustion it changes to sulphurous acid 7,,so#b71 and this in turn has the power of taking up from the air another atom of oxygen1 forming sulphuric acid 7,,so#c water71 or1 as we more familiarly know it1 oil of vitriol4 ,yet the smoke itself1 including as it does all the many impurities which exist in coal1 is not only evil in itself1 but is evil in its influences4 ,dr ,siemens has said3--,it has been shown that the fine dust resulting from the imperfect combustion of coal was mainly instrumental in the formation of fog2 each particle of solid matter attracting to itself aqueous vapour4 ,these globules of fog were rendered particularly tenacious and disagreeable by the presence of tar vapour1 another result of imperfect combustion of raw fuel1 which might be turned to better account at the dyeworks4 ,the hurtful influence of smoke upon public health1 the great personal discomfort to which it gave rise1 and the vast expense it indirectly caused through the destruction of our monuments1 pictures1 furniture1 and apparel1 were now being recognised4 ,the most effectual remedy would result from a general recognition of the fact that wherever smoke was produced1 fuel was being consumed wastefully1 and that all our calorific effects1 from the largest furnace to the domestic fire1 could be realised as completely1 and more economically1 without allowing any of the fuel employed to reach the atmosphere unburnt4 ,this most desirable result might be effected by the use of gas for all heating purposes1 with or without the additional use of coke or anthracite4 ,the success of the so-called smoke-consuming stoves is greatly open to question1 whilst some of them have been reported upon by those appointed to inspect them as actually accentuating the incomplete combustion1 the abolition of which they were invented to bring about4 ,the smoke nuisance is one which cuts at the very basis of our business life4 ,the cloud which1 under certain atmospheric conditions1 rests like a pall over our great cities1 will not even permit at times of a single ray of sunshine permeating it4 ,no one knows whence it rises1 nor at what hour to expect it4 ,it is like a giant spectre which1 having lain dormant since the carboniferous age1 has been raised into life and being at the call of restless humanity2 it is now punishing us for our prodigal use of the wealth it left us1 by clasping us in its deadly arms1 cutting off our brilliant sunshine1 and necessitating the use in the daytime of artificial light2 inducing all kinds of bronchial and throat affections1 corroding telegraph and telephone wires1 and weathering away the masonry of public buildings4 ,the immense value to us of the coal-deposits which lie buried in such profusion in the earth beneath us1 can only be appreciated when we consider the many uses to which coal has been put4 ,we must remember1 as we watch the ever-extending railway ramifying the country in every direction1 that the first railway and the first locomotive ever built1 were those which were brought into being in #ahad by ,george ,stephenson1 for the purpose of the carriage of coals from the ,killingworth ,colliery4 ,to the importance of coal in our manufactures1 therefore1 we owe the subsequent development of steam locomotive power as the means of the introduction of passenger traffic1 and by the use of coal we are enabled to travel from one end of the country to the other in a space of time inconceivably small as compared with that occupied on the same journey in the old coaching days4 ,the increased rapidity with which our vessels cross the wide ocean we owe to the use of coal2 our mines are carried to greater depths owing to the power our pumping-engines obtain from coal in clearing the mines of water and in ensuring ventilation2 the enormous development of the iron trade only became possible with the increased blast power obtained from the consumption of coal1 and the very hulls and engines of our steamships are made of this iron2 our railroads and engines are mostly of iron1 and when we think of the extensive use of iron utensils in every walk in life1 we see how important becomes the power we possess of obtaining the necessary fuel to feed the smelting furnaces4 ,evaporation by the sun was at one time the sole means of obtaining salt from seawater2 now coal is used to boil the salt pans and to purify the brine from the salt-mines in the triassic strata of ,cheshire4 ,the extent to which gas is used for illuminating purposes reminds us of another important product obtained from coal4 ,paraffin oil and petroleum we obtain from coal1 whilst candles1 oils1 dyes1 lubricants1 and many other useful articles go to attest the importance of the underground stores of that mineral which has well and deservedly been termed the black diamond4 ,,chapter ,,vi4 ,,how ,,gas ,,is ,,made--,,illuminating ,,oils ,,and ,,bye-,,products4 ,accustomed as we are at the present day to see street after street of well-lighted thoroughfares1 brilliantly illuminated by gas-lamps maintained by public authority1 we can scarcely appreciate the fact that the use of gas is1 comparatively speaking1 of but recent growth1 and that1 like the use of coal itself1 it has not yet existed a century in public favour4 ,valuable as coal is in very many different ways1 perhaps next in value to its actual use as fuel1 ranks the use of the immediate product of its distillation--viz41 gas2 and although gas is in some respects waning before the march of the electric light in our day1 yet1 even as gas at no time has altogether superseded old-fashioned oil1 so we need not anticipate a time when gas in turn will be likely to be superseded by the electric light1 there being many uses to which the one may be put1 to which the latter would be altogether inapplicable2 for1 in the words of ,dr ,siemens1 assuming the cost of electric light to be practically the same as gas1 the preference for one or other would in each application be decided upon grounds of relative convenience1 but gas-lighting would hold its own as the poor man's friend4 ,gas is an institution of the utmost value to the artisan2 it requires hardly any attention1 is supplied upon regulated terms1 and gives1 with what should be a cheerful light1 a genial warmth1 which often saves the lighting of a fire4 ,the revolution which gas has made in the appearance of the streets1 where formerly the only illumination was that provided by each householder1 who1 according to his means1 hung out a more or less efficient lantern1 and consequently a more or less smoky one1 cannot fail also to have brought about a revolution in the social aspects of the streets1 and therefore is worthy to be ranked as a social reforming agent2 and some slight knowledge of the process of its manufacture1 such as it is here proposed to give1 should be in the possession of every educated individual4 ,yet the subjects which must be dealt with in this chapter are so numerous and of such general interest1 that we shall be unable to enter more than superficially into any one part of the whole1 but shall strive to give a clear and comprehensive view1 which shall satisfy the inquirer who is not a specialist4 ,the credit of the first attempt at utilising the gaseous product of coal for illumination appears to be due to ,murdock1 an engineer at ,redruth1 who1 in #agib1 introduced it into his house and offices1 and who1 ten years afterwards1 as the result of numerous experiments which he made with a view to its utilisation1 made a public display at ,birmingham on the occasion of the ,peace of ,amiens1 in #ahjb4 ,more than a century before1 however1 the gas obtained from coal had been experimented upon by a ,dr ,clayton1 who1 about #afij1 conceived the idea of heating coal until its gaseous constituents were forced out of it4 ,he described how he obtained steam first of all1 then a black oil1 and finally a spirit1 as our ancestors were wont to term the gas4 ,this1 to his surprise1 ignited on a light being applied to it1 and he considerably amused his friends with the wonders of this inflammatory spirit4 ,for a century afterwards it remained in its early condition1 a chemical wonder1 a thing to be amused with2 but it required the true genius and energy of ,murdock to show the great things of which it was capable4 ,london received its first instalment of gas in #ahjg1 and during the next few years its use became more and more extended1 houses and streets rapidly receiving supplies in quick succession4 ,it was not1 however1 till about the year #ahbj that its use throughout the country became at all general1 ,st ,james' ,park being gas-lit in the succeeding year4 ,this is not yet eighty years ago1 and amongst the many wonderful things which have sprung up during the present century1 perhaps we may place in the foremost rank for actual utility1 the gas extracted from coal1 conveyed as it is through miles upon miles of underground pipes into the very homes of the people1 and constituting now almost as much a necessity of a comfortable existence as water itself4 ,the use of gas thus rapidly extended for illuminating purposes1 and to a very great extent superseded the old-fashioned means of illumination4 ,illustration3 ,,fig4 #cd4--;,inside a ,gas-,holder4 ,the gas companies which sprang up were not slow to notice that1 seeing the gas was supplied by meter1 it was to their pecuniary advantage to give merely the prescribed illuminating power1 and to discourage the invention of economical burners1 in order that the consumption might reach a maximum4 ,the application of gas for heating purposes had not been encouraged1 and was still made difficult in consequence of the objectionable practice of reducing the pressure in the mains during daytime to the lowest possible point consistent with prevention of atmospheric indraught4 ,the introduction of an important rival into the field in the shape of the electric light has now given a powerful impetus to the invention and introduction of effective gas-lamps1 and amongst inventors of recent years no name is1 perhaps1 in this respect so well known as the name of ,sugg4 ,as long as gas retained almost the monopoly1 there was no incentive to the gas companies to produce an effective light cheaply2 but now that the question of the relative cheapness of gas and electricity is being actively discussed1 the gas companies1 true to the instinct of self-preservation1 seem determined to show what can be done when gas is consumed in a scientific manner4 ,in order to understand how best a burner should be constructed in order that the gas that is burnt should give the greatest possible amount of illumination1 let us consider for a moment the composition of the gas flame4 ,it consists of three parts1 7#a7 an interior dark space1 in which the elements of the gas are in an unconsumed state2 7#b7 an inner ring around the former1 whence the greatest amount of light is obtained1 and in which are numerous particles of carbon at a white heat1 each awaiting a supply of oxygen in order to bring about combustion2 and 7#c7 an outer ring of blue flame in which complete combustion has taken place1 and from which the largest amount of heat is evolved4 ,the second of these portions of the flame corresponds with the reducing flame of the blow-pipe1 since this part1 if turned upon an oxide1 will reduce it1 i4e41 abstract its oxygen from it4 ,this part also corresponds with the jet of the ,bunsen burner1 when the holes are closed by which otherwise air would mingle with the gas1 or with the flame from a gas-stove when the gas ignites beneath the proper igniting-jets1 and which gives consequently a white or yellow flame4 ,the third portion1 on the other hand1 corresponds with the oxidising flame of the blow-pipe1 since it gives up oxygen to bodies that are thirsting for it4 ,this also corresponds with the ordinary blue flame of the ,bunsen burner1 and with the blue flame of gas-stoves where heat1 and not light1 is required1 the blue flame in both cases being caused by the admixture of air with the gas4 ,thus1 in order that gas may give the best illumination1 we must increase the yellow or white space of carbon particles at a white heat1 and a burner that will do this1 and at the same time hold the balance so that unconsumed particles of carbon shall not escape in the way of smoke1 will give the most successful illuminating results4 ,with this end in view the addition of albo-carbon to a bulb in the gas-pipe has proved very successful1 and the incandescent gas-jet is constructed on exactly the same chemical principle4 ,the invention of burners which brought about this desirable end has doubtless not been without effect in acting as a powerful obstacle to the widespread introduction of the electric light4 ,without entering into details of the manufacture of gas1 it will be as well just to glance at the principal parts of the apparatus used4 ,the gasometer1 as it has erroneously been called1 is a familiar object to most people1 not only to sight but unfortunately also to the organs of smell4 ,it is in reality of course only the gas-holder1 in which the final product of distillation of the coal is stored1 and from which the gas immediately passes into the distributing mains4 ,the first1 and perhaps1 most important portion of the apparatus used in gas-making is the series of retorts into which the coal is placed1 and from which1 by the application of heat1 the various volatile products distil over4 ,these retorts are huge cast-iron vessels1 encased in strong brick-work1 usually five in a group1 and beneath which a large furnace is kept going until the process is complete4 ,each retort has an iron exit pipe affixed to it1 through which the gases generated by the furnace are carried off4 ,the exit pipes all empty themselves into what is known as the hydraulic main1 a long horizontal cylinder1 and in this the gas begins to deposit a portion of its impurities4 ,the immediate products of distillation are1 after steam and air1 gas1 tar1 ammoniacal liquor1 sulphur in various forms1 and coke1 the last being left behind in the retort4 ,in the hydraulic main some of the tar and ammoniacal liquor already begin to be deposited4 ,the gas passes on to the condenser1 which consists of a number of ,u-shaped pipes4 ,here the impurities are still further condensed out1 and are collected in the tar-pit whilst the gas proceeds1 still further lightened of its impurities4 ,it may be mentioned that the temperature of the gas in the condenser is reduced to about #fj ,f41 but below this some of the most valuable of the illuminants of coal-gas would commence to be deposited in liquid form1 and care has to be taken to prevent a greater lowering of temperature4 ,a mechanical contrivance known as the exhauster is next used1 by which the gas is1 amongst other things1 helped forward in its onward movement through the apparatus4 ,the gas then passes to the washers or scrubbers1 a series of tall towers1 from which water is allowed to fall as a fine spray1 and by means of which large quantities of ammonia1 sulphuretted hydrogen1 carbonic acid and oxide1 and cyanogen compounds1 are removed4 ,in the scrubber the water used in keeping the coke1 with which it is filled1 damp1 absorbs these compounds1 and the union of the ammonia with certain of them takes place1 resulting in the formation of carbonate of ammonia 7smelling salts71 sulphide and sulphocyanide of ammonia4 ,illustration3 ,,fig4 #ce4--;,filling ,retorts by ,machinery4 ,illustration3 ,,fig4 #cf4--;,,condensers4 ,hitherto the purification of the gas has been brought about by mechanical means1 but the gas now enters the purifier1 in which it undergoes a further cleansing1 but this time by chemical means4 ,illustration3 ,,fig4 #cg4 ,the agent used is either lime or hydrated oxide of iron1 and by their means the gas is robbed of its carbonic acid and the greater part of its sulphur compounds4 ,the process is then considered complete1 and the gas passes on into the water chamber over which the gas-holder is reared1 and in which it rises through the water1 forcing the huge cylinder upward according to the pressure it exerts4 ,the gas-holder is poised between a number of upright pillars by a series of chains and pulleys1 which allow of its easy ascent or descent according as the supply is greater or less than that drawn from it by the gas mains4 ,illustration3 ,,fig4 #ch4 ,when we see the process which is necessary in order to obtain pure gas1 we begin to appreciate to what an extent the atmosphere is fouled when many of the products of distillation1 which1 as far as the production of gas is concerned1 may be called impurities1 are allowed to escape free without let or hindrance4 ,in these days of strict sanitary inspection it seems strange that the air in the neighbourhood of gas-works is still allowed to become contaminated by the escape of impure compounds from the various portions of the gas-making apparatus4 ,go where one may1 the presence of these compounds is at once apparent to the nostrils within a none too limited area around them1 and yet their deleterious effects can be almost reduced to a minimum by the use of proper purifying agents1 and by a scientific oversight of the whole apparatus4 ,it certainly behoves all sanitary authorities to look well after any gas-works situated within their districts4 ,now let us see what these first five products of distillation actually are4 ,firstly1 house-gas4 ,everybody knows what house-gas is4 ,it cannot1 however1 be stated to be any one gas in particular1 since it is a mechanical mixture of at least three different gases1 and often contains small quantities of others4 ,a very large proportion consists of what is known as marsh-gas1 or light carburetted hydrogen4 ,this occurs occluded or locked up in the pores of the coal1 and often oozes out into the galleries of coal-mines1 where it is known as firedamp 7,german dampf1 vapour74 ,it is disengaged wherever vegetable matter has fallen and has become decayed4 ,if it were thence collected1 together with an admixture of ten times its volume of air1 a miniature coal-mine explosion could be produced by the introduction of a match into the mixture4 ,alone1 however1 it burns with a feebly luminous flame1 although to its presence our house-gas owes a great portion of its heating power4 ,marsh-gas is the first of the series of hydro-carbons known chemically as the paraffins1 and is an extremely light substance1 being little more than half the weight of an equal bulk of air4 ,it is composed of four atoms of hydrogen to one of carbon 7,,ch#d74 ,marsh-gas1 together with hydrogen and the monoxide of carbon1 the last of which burns with the dull blue flame often seen at the surface of fires1 particularly coke and charcoal fires1 form about #hg per cent4 of the whole volume of house-gas1 and are none of them anything but poor illuminants4 ,the illuminating power of house-gas depends on the presence therein of olefiant gas 7ethylene71 or1 as it is sometimes termed1 heavy carburetted hydrogen4 ,this is the first of the series of hydro-carbons known as the olefines1 and is composed of two atoms of carbon to every four atoms of hydrogen 7,c#b;,h#d74 ,others of the olefines are present in minute quantities4 ,these assist in increasing the illuminosity1 which is sometimes greatly enhanced1 too1 by the presence of a small quantity of benzene vapour4 ,these illuminants1 however1 constitute but about #f per cent4 of the whole4 ,added to these1 there are four other usual constituents which in no way increase the value of gas1 but which rather detract from it4 ,they are consequently as far as possible removed as impurities in the process of gas-making4 ,these are nitrogen1 carbonic acid gas1 and the destructive sulphur compounds1 sulphuretted hydrogen and carbon bisulphide vapour4 ,it is to the last two to which are to be attributed the injurious effects which the burning of gas has upon pictures1 books1 and also the tarnishing which metal fittings suffer where gas is burnt1 since they give rise to the formation of oil of vitriol 7sulphuric acid71 which is being incessantly poured into the air4 ,of course the amount so given off is little as compared with that which escapes from a coal fire1 but1 fortunately for the inmates of the room1 in this case the greater quantity goes up the chimney2 this1 however1 is but a method of postponing the evil day1 until the atmosphere becomes so laden with impurities that what proceeds at first up the chimney will finally again make its way back through the doors and windows4 ,a recent official report tells us that1 in the town1 of ,st ,helen's alone1 sufficient sulphur escapes annually into the atmosphere to finally produce #aaj1ehj tons of sulphuric acid1 and a computation has been made that every square mile of land in ,london is deluged annually with #ahj tons of the same vegetation-denuding acid4 ,it is a matter for wonder that any green thing continues to exist in such places at all4 ,the chief constituents of coal-gas are1 therefore1 briefly as follows3-- _/ 7#a7 ,hydrogen1 7#b7 ,marsh-gas 7carburetted hydrogen or fire-damp71 7#c7 ,carbon monoxide1 7#d7 ,olefiant gas 7ethylene1 or heavy carburetted hydrogen71 with other olefines1 _/ 7#e7 ,nitrogen1 7#f7 ,carbonic acid gas1 7#g7 ,sulphuretted hydrogen1 7#h7 ,carbon bisulphide 7vapour71 the last four being regarded as impurities1 which are removed as far as possible in the manufacture4 ,in the process of distillation of the coal1 we have seen that various other important substances are brought into existence4 ,the final residue of coke1 which is impregnated with the sulphur which has not been volatilised in the form of sulphurous gases1 we need scarcely more than mention here4 ,but the gas-tar and the ammoniacal liquor are two important products which demand something more than our casual attention4 ,at one time regarded by gas engineers as unfortunately necessary nuisances in the manufacture of gas1 they have both become so valuable on account of materials which can be obtained from them1 that they enable gas itself to be sold now at less than half its original price4 ,the waste of former generations is being utilised in this1 and an instance is recorded in which tar1 which was known to have been lying useless at the bottom of a canal for years1 has been purchased by a gas engineer for distilling purposes4 ,it has been estimated that about #eij1jjj tons of coal-tar are distilled annually4 ,tar in its primitive condition has been used1 as every one is aware1 for painting or tarring a variety of objects1 such as barges and palings1 in fact1 as a kind of protection to the object covered from the ravages of insects or worms1 or to prevent corrosion when applied to metal piers4 ,but it is worthy of a better purpose1 and is capable of yielding far more useful and interesting substances than even the most imaginative individual could have dreamed of fifty years ago4 ,in the process of distillation1 the tar1 after standing in tanks for some time1 in order that any ammoniacal liquor which may be present may rise to the surface and be drawn off1 is pumped into large stills1 where a moderate amount of heat is applied to it4 ,the result is that some of the more volatile products pass over and are collected in a receiver4 ,these first products are known as first light oils1 or crude coal-naphtha1 and to this naphtha all the numerous natural naphthas which have been discovered in various portions of the world1 and to which have been applied numerous local names1 bear a very close resemblance4 ,such an one1 for instance1 was that small but famous spring at ,biddings1 in ,derbyshire1 from which the late ,mr ,young--,paraffin ,young--obtained his well-known paraffin oil1 which gave the initial impetus to what has since developed into a trade of immense proportions in every quarter of the globe4 ,after a time the crude coal-naphtha ceases to flow over1 and the heat is increased4 ,the result is that a fresh series of products1 known as medium oils1 passes over1 and these oils are again collected and kept separate from the previous series4 ,these in turn cease to flow1 when1 by a further increase of heat1 what are known as the heavy oils finally pass over1 and when the last of these1 green grease1 as it is called1 distils over1 pitch alone is left in the still4 ,pitch is used to a large extent in the preparation of artificial asphalte1 and also of a fuel known as briquettes4 ,the products thus obtained at the various stages of the process are themselves subjected to further distillation1 and by the exercise of great care1 requiring the most delicate and accurate treatment1 a large variety of oils is obtained1 and these are retailed under many and various fanciful names4 ,one of the most important and best known products of the fractional distillation of crude coal-naphtha is that known as benzene1 or benzole1 7,c#f;,h#f74 ,this1 in its unrefined condition1 is a light spirit which distils over at a point somewhat below the boiling point of water1 but a delicate process of rectification is necessary to produce the pure spirit4 ,other products of the same light oils are toluene and xylene4 ,benzene of a certain quality is of course a very familiar and useful household supplement4 ,it is sometimes known and sold as benzene collas1 and is used for removing grease from clothing1 cleaning kid gloves1 c4 ,if pure it is in reality a most dangerous spirit1 being very inflammable2 it is also extremely volatile1 so much so that1 if an uncorked bottle be left in a warm room where there is a fire or other light near1 its vapour will probably ignite4 ,should the vapour become mixed with air before ignition1 it becomes a most dangerous explosive1 and it will thus be seen how necessary it is to handle the article in household use in a most cautious manner4 ,being highly volatile1 a considerable degree of cold is experienced if a drop be placed on the hand and allowed to evaporate4 ,benzene1 which is only a compound of carbon and hydrogen1 was first discovered by ,faraday in #ahbe2 it is now obtained in large quantities from coal-tar1 not so much for use as benzene2 is for its conversion1 in the first place1 by the action of nitric acid1 into nitro-benzole1 a liquid having an odour like the oil of bitter almonds1 and which is much used by perfumers under the name of essence de mirbane2 and1 in the second place1 for the production from this nitro-benzole of the far-famed aniline4 ,after the distillation of benzene from the crude coal-naphtha is completed1 the chief impurities in the residue are charred and deposited by the action of strong sulphuric acid4 ,by further distillation a lighter oil is given off1 often known as artificial turpentine oil1 which is used as a solvent for varnishes and lackers4 ,this is very familiar to the costermonger fraternity as the oil which is burned in the flaring lamps which illuminate the ,new ,cut or the ,elephant and ,castle on ,saturday and other market nights4 ,by distillation of the heavy oils1 carbolic acid and commercial anthracene are produced1 and by a treatment of the residue1 a white and crystalline substance known as naphthalin 7,c#aj;,h#h7 is finally obtained4 ,thus1 by the continued operation of the chemical process known as fractional distillation of the immediate products of coal-tar1 these various series of useful oils are prepared4 ,the treatment is much the same which has resulted in the production of paraffin oil1 to which we have previously referred1 and an account of the production of coal-oils would be very far from satisfactory1 which made no mention of the production of similar commodities by the direct distillation of shale4 ,oil-shales1 or bituminous shales1 exist in all parts of the world1 and may be regarded as mineral matter largely impregnated by the products of decaying vegetation4 ,they therefore greatly resemble some coals1 and really only differ therefrom in degree1 in the quantity of vegetable matter which they contain4 ,into the subject of the various native petroleums which have been found--for these rock-oils are better known as petroleums--in ,south ,america1 in ,burmah 7,rangoon ,oil71 at ,baku1 and the shores of the ,caspian1 or in the ,united ,states of ,america1 we need not enter1 except to note that in all probability the action of heat on underground bituminous strata of enormous extent has been the cause of their production1 just as on a smaller scale the action of artificial heat has forced the reluctant shale to give up its own burden of mineral oil4 ,however1 previous to #ahdg1 although native mineral oil had been for some years a recognised article of commerce1 the causes which gave rise to the oil-wells1 and the source1 probably a deep-seated one1 of the supply of oil1 does not appear to have been well known1 or at least was not enquired after4 ,but in that year ,mr ,young1 a chemist at ,manchester1 discovered that by distilling some petroleum1 which he obtained from a spring at ,riddings in ,derbyshire1 he was able to procure a light oil1 which he used for burning in lamps1 whilst the heavier product which he also obtained proved a most useful lubricant for machinery4 ,this naturally distilled oil was soon found to be similar to that oil which was noticed dripping from the roof of a coal-mine4 ,judging that the coal1 being under the influence of heat1 was the cause of the production of the oil1 ,mr ,young tested this conclusion by distilling the coal itself4 ,success attended his endeavour thus to procure the oil1 and indelibly ,young stamped his name upon the roll of famous men1 whose industrial inventions have done so much towards the accomplishment of the marvellous progress of the present century4 ,from the distillation he obtained the well-known ,young's ,paraffin ,oil1 and the astonishing developments of the process which have taken place since he obtained his patent in #ahej1 for the manufacture of oils and solid paraffin1 must have been a source of great satisfaction to him before his death1 which occurred in #ahhc4 ,cannel coal1 ,boghead or ,bathgate coal1 and bituminous shales of various qualities1 have all been requisitioned for the production of oils1 and from these various sources the crude naphthas1 which bear a variety of names according to some peculiarity in their origin1 or place of occurrence1 are obtained4 ,boghead coal1 also known as ,torebanehill mineral1 gives ,boghead naphtha1 while the crude naphtha obtained from shales is often quoted as shale-oil4 ,in chemical composition these naphthas are closely related to one another1 and by fractional distillation of them similar series of products are obtained as those we have already seen as obtained from the crude coal-naphtha of coal-tar4 ,in the direct distillation of cannel-coal for the production of paraffin1 it is necessary that the perpendicular tubes or retorts into which the coal is placed be heated only to a certain temperature1 which is considerably lower than that applied when the object is the production of coal-gas4 ,by this means nearly all the volatile matters pass over in the form of condensible vapours1 and the crude oils are at once formed1 from whence are obtained at different temperatures various volatile ethers1 benzene1 and artificial turpentine oil or petroleum spirit4 ,after these1 the well-known safety-burning paraffin oil follows1 but it is essential that the previous three volatile products be completely cleared first1 since1 mixed with air1 they form highly dangerous explosives4 ,to the fact that the operation is carried on in the manufactories with great care and accuracy can only be attributed the comparative rareness of explosions of the oil used in households4 ,after paraffin1 the heavy lubricating oils are next given off1 still increasing the temperature1 and1 the residue being in turn subjected to a very low temperature1 the white solid substance known as paraffin1 so much used for making candles1 is the result4 ,by a different treatment of the same residue is produced that wonderful salve for tender skins1 cuts1 and burns1 known popularly as vaseline4 ,probably no such widely-advertised remedial substance has so deserved its success as this universally-used waste product of petroleum4 ,we have noticed the fact that in order to procure safety-burning oils1 it is absolutely necessary that the more volatile portions be completely distilled over first4 ,by ,act of ,parliament a test is applied to all oils which are intended for purposes of illumination1 and the test used consists of what is known as the flashing-point4 ,many of the more volatile ethers1 which are highly inflammable1 are given off even at ordinary temperatures1 and the application of a light to the oil will cause the volatile portion to flash1 as it is called4 ,a safety-burning oil1 according to the ,act1 must not flash under #ajj ,fahrenheit open test1 and all those portions which flash at a less temperature must be volatilised off before the residue can be deemed a safe oil4 ,it seems probable that the flashing-point will sooner or later be raised4 ,one instance may be cited to show how necessary it is that the native mineral oils which have been discovered should have this effectual test applied to them4 ,when the oil-wells were first discovered in ,america1 the oil was obtained simply by a process of boring1 and the fountain of oil which was bored into at times was so prolific1 that it rushed out with a force which carried all obstacles before it1 and defied all control4 ,in one instance a column of oil shot into the air to a height of forty feet1 and defied all attempts to keep it under4 ,in order to prevent further accident1 all lights in the immediate neighbourhood were extinguished1 the nearest remaining being at a distance of four hundred feet4 ,but in this crude naphtha there was1 as usual1 a quantity of volatile spirit which was being given off even at the temperature of the surrounding atmosphere4 ,this soon became ignited1 and with an explosion the column of oil was suddenly converted into a roaring column of fire4 ,the owner of the property was thrown a distance of twenty feet by the explosion1 and soon afterwards died from the burns which he had received from it4 ,such an accident could not now1 however1 happen4 ,the tapping1 stopping1 and regulating of gushing wells can now be more effectually dealt with1 and in the process of refining2 the most inflammable portions are separated1 with a result that1 as no oil is used in the country which flashes under #ajj ,f4 open test1 and as our normal temperature is considerably less than this1 there is little to be feared in the way of explosion if the ,act be complied with4 ,when the results of ,mr ,young's labours became publicly known1 a number of companies were started with the object of working on the lines laid down in his patent1 and these not only in ,great ,britain but also in the ,united ,states1 whither quantities of cannel coal were shipped from ,england and other parts to feed the retorts4 ,in #ahfj1 according to the statistics furnished1 some seventy factories were established in the ,united ,states alone with the object of extracting oil from coal and other mineral sources1 such as bituminous shale1 etc4 ,when ,young's patent finally expired1 a still greater impetus was given to its production1 and the manufacture would probably have continued to develop were it not that attention had1 two years previously1 been forcibly turned to those discoveries of great stores of natural oil in existence beneath a comparatively thin crust of earth1 and which1 when bored into1 spouted out to tremendous heights4 ,the discovery of these oil-fountains checked for a time the development of the industry1 but with the great production there has apparently been a greatly increased demand for it1 and the ,british industry once again appears to thrive1 until even bituminous shales have been brought under requisition for their contribution to the national wealth4 ,were it not for the nuisance and difficulty experienced in the proper cleaning and trimming of lamps1 there seems no other reason why mineral oil should not in turn have superseded the use of gas1 even as gas had1 years before1 superseded the expensive animal and vegetable oils which had formerly been in use4 ,although this great development in the use of mineral oils has taken place only within the last thirty years1 it must not be thought that their use is altogether of modern invention4 ,that they were not altogether unknown in the fifth century before ,christ is a matter of certainty1 and at the time when the ,persian ,empire was at the zenith of its glory1 the fires in the temples of the fire-worshippers were undoubtedly kept fed by the natural petroleum which the districts around afforded4 ,it is thought by some that the legend which speaks of the fire which came down from heaven1 and which lit the altars of the ,zoroastrians1 may have had its origin in the discovery of a hitherto unknown petroleum spring4 ,more recently1 the remarks of ,marco ,polo in his account of his travels in ,a4,d4 #abfj and following years1 are particularly interesting as showing that1 even then1 the use of mineral oil for various purposes was not altogether unknown4 ,he says that on the north of ,armenia the ,greater is ,zorzania1 in the confines of which a fountain is found1 from which a liquor like oil flows1 and though unprofitable for the seasoning of meat1 yet is very fit for the supplying of lamps1 and to anoint other things2 and this natural oil flows constantly1 and that in plenty enough to lade camels4 ,from this we can infer that the nature of the oil was entirely unknown1 for it was a liquor like oil1 and was also1 strange to say1 unprofitable for the seasoning of meat6 ,in another place in ,armenia1 ,marco ,polo states that there was a fountain whence rises oil in such abundance that a hundred ships might be at once loaded with it4 ,it is not good for eating1 but very fit for fuel1 for anointing the camels in maladies of the skin1 and for other purposes2 for which reason people come from a great distance for it1 and nothing else is burned in all this country4 ,the remedial effects of the oil1 when used as an ointment1 were thus early recognised1 and the far-famed vaseline of the present day may be regarded as the lineal descendent1 so to speak1 of the crude medicinal agent to which ,marco ,polo refers4 ,the term asphalt has been applied to so many and various mixtures1 that one scarcely associates it with natural mineral pitch which is found in some parts of the world4 ,from time immemorial this compact1 bituminous1 resinous mineral has been discovered in masses on the shores of the ,dead ,sea1 which has in consequence received the well-known title of ,lake ,asphaltites4 ,like the naphthas and petroleums which have been noticed1 this has had its origin in the decomposition of vegetable matter1 and appears to be thrown up in a liquid form by the volcanic energies which1 are still believed to be active in the centre of the lake1 and which may be existent beneath a stratum1 or bed1 of oil-producing bitumen4 ,in connection with the formation of this substance1 the remarks of ,sir ,charles ,lyell1 the great geologist1 may well be quoted1 as showing the transformation of vegetable matter into petroleum1 and afterwards into solid-looking asphalt4 ,at ,trinidad is a lake of bitumen which is a mile and a half in circumference4 ,the ,orinoco has for ages been rolling down great quantities of woody and vegetable bodies into the surrounding sea1 where1 by the influence of currents and eddies1 they may be arrested1 and accumulated in particular places4 ,the frequent occurrence of earthquakes and other indications of volcanic action in those parts1 lend countenance to the opinion that these vegetable substances may have undergone1 by the agency of subterranean fire1 those transformations or chemical changes which produce petroleum2 and this may1 by the same causes1 be forced up to the surface1 where1 by exposure to the air1 it becomes inspissated1 and forms those different varieties of earth-pitch or asphaltum so abundant in the island4 ,it is interesting to note also that it was obtained1 at an ancient period1 from the oil-fountains of ,is1 and that it was put to considerable use in the embalming of the bodies of the ,egyptians4 ,it appears1 too1 to have been employed in the construction of the walls of ,babylon1 and thus from very early times these wonderful products and results of decayed vegetation have been brought into use for the service of man4 ,aniline has been previously referred 7p4 #ace7 to as having been prepared from nitro-benzole1 or essence de mirbane1 and its preparation1 by treating this substance with iron-filings and acetic acid1 was one of the early triumphs of the chemists who undertook the search after the unknown contained in gas-tar4 ,it had previously been obtained from oils distilled from bones4 ,the importance of the substance lies in the fact that1 by the action of various chemical reagents1 a series of colouring matters of very great richness are formed1 and these are the well-known aniline dyes4 ,as early as #ahcf1 it was discovered that aniline1 when heated with chloride of lime1 acquired a beautiful blue tint4 ,this discovery led to no immediate practical result1 and it was not until twenty-one years after that a further discovery was made1 which may indeed be said to have achieved a world-wide reputation4 ,it was found that1 by adding bichromate of potash to a solution of aniline and sulphuric acid1 a powder was obtained from which the dye was afterwards extracted1 which is known as mauve4 ,since that time dyes in all shades and colours have been obtained from the same source4 ,magenta was the next dye to make its appearance1 and in the fickle history of fashion1 probably no colours have had such extraordinary runs of popularity as those of mauve and magenta4 ,every conceivable colour was obtained in due course from the same source1 and chemists began to suspect that1 in the course of time1 the colouring matter of dyer's madder1 which was known as alizarin1 would also be obtained therefrom4 ,hitherto this had been obtained from the root of the madder-plant1 but by dint of careful and well-reasoned research1 it was obtained by ,dr ,groebe1 from a solid crystalline coal-tar product1 known as anthracene1 7,c#ab;,h#ad74 ,this artificial alizarin yields colours which are purer than those of natural madder1 and being derived from what was originally regarded as a waste product1 its cost of production is considerably cheaper4 ,we have endeavoured thus far to deal with 7#a7 gas1 and 7#b7 tar1 the two principal products in the distillation of coal4 ,we have yet to say a few words concerning the useful ammoniacal liquor1 and the final residue in the retorts1 i4e41 coke4 ,the ammoniacal liquor which has been passing over during distillation of the coal1 and which has been collecting in the hydraulic main and in other parts of the gas-making apparatus1 is set aside to be treated to a variety of chemical reactions1 in order to wrench from it its useful constituents4 ,amongst these1 of course1 ammonia stands in the first rank1 the others being comparatively unimportant4 ,in order to obtain this1 the liquor is first of all neutralised by being treated with a quantity of acid1 which converts the principal constituent of the liquor1 viz41 carbonate of ammonia 7smelling salts71 into either sulphate of ammonia1 or chloride of ammonia1 familiarly known as sal-ammoniac1 according as sulphuric acid or hydrochloric acid is the acid used4 ,thus carbonate of ammonia with sulphuric acid will give sulphate of ammonia1 but carbonate of ammonia with hydrochloric acid will give sal-ammoniac 7chloride of ammonia74 ,by a further treatment of these with lime1 or1 as it is chemically known1 oxide of calcium1 ammonia is set free1 whilst chloride of lime 7the well-known disinfectant71 or sulphate of lime 7gypsum1 or plaster of ,paris 71 is the result4 ,thus3 ,sulphate of ammonia lime plaster of ,paris ammonia4 or1 ,sal-ammoniac lime chloride of lime ammonia4 ,ammonia itself is a most powerful gas1 and acts rapidly upon the eyes4 ,it has a stimulating effect upon the nerves4 ,it is not a chemical element1 being composed of three parts of hydrogen by weight to one of nitrogen1 both of which elements alone are very harmless1 and1 the latter indeed1 very necessary to human life4 ,ammonia is fatal to life1 producing great irritation of the lungs4 ,it has also been called hartshorn1 being obtained by destructive distillation of horn and bone4 ,the name ammonia is said to have been derived from the fact that it was first obtained by the ,arabs near the temple of ,jupiter ,ammon1 in ,lybia1 ,north ,africa1 from the excrement of camels1 in the form of sal-ammoniac4 ,there are always traces of it in the atmosphere1 especially in the vicinity of large towns and manufactories where large quantities of coal are burned4 ,coke1 if properly prepared1 should consist of pure carbon4 ,good coal should yield as much as #hj per cent4 of coke1 but owing to the unsatisfactory manner of its production1 this proportion is seldom yielded1 whilst the coke which is familiar to householders1 being the residue left in the retorts after gas-making1 usually contains so large a proportion of sulphur as to make its combustion almost offensive4 ,no doubt the result of its unsatisfactory preparation has been that it has failed to make its way into households as it should have done1 but there is also another objection to its use1 namely1 the fact that1 owing to the quantity of oxygen required in its combustion1 it gives rise to feelings of suffocation where insufficient ventilation of the room is provided4 ,large quantities of coke are1 however1 consumed in the feeding of furnace fires1 and in the heating of boilers of locomotives1 as well as in metallurgical operations2 and in order to supply the demand1 large quantities of coal are coked1 a process by which the volatile products are completely combusted1 pure coke remaining behind4 ,this process is therefore the direct opposite to that of distillation1 by which the volatile products are carefully collected and re-distilled4 ,the sulphurous impurities which are always present in the coal1 and which are1 to a certain extent1 retained in coke made at the gas-works1 themselves have a value1 which in these utilitarian days is not long likely to escape the attention of capitalists4 ,in coal1 bands of bright shining iron pyrites are constantly seen1 even in the homely scuttle1 and when coal is washed1 as it is in some places1 the removal of the pyrites increases the value of the coal1 whilst it has a value of its own4 ,the conversion of the sulphur which escapes from our chimneys into sulphuretted hydrogen1 and then into sulphuric acid1 or oil of vitriol1 has already been referred to1 and we can only hope that in these days when every available source of wealth is being looked up1 and when there threatens to remain nothing which shall in the future be known as waste1 that the atmosphere will be spared being longer the receptacle for the unowned and execrated brimstone of millions of fires and furnaces4 ,,chapter ,,vii4 ,,the ,,coal ,,supplies ,,of ,,the ,,world4 ,as compared with some of the ,american coal-fields1 those of ,britain are but small1 both in extent and thickness4 ,they can be regarded as falling naturally into three principal areas4 ,the northern coal-field1 including those of ,fife1 ,stirling1 and ,ayr in ,scotland2 ,cumberland1 ,newcastle1 and ,durham in ,england2 ,tyrone in ,ireland4 ,the middle coal-field1 all geologically in union1 including those of ,yorkshire1 ,derbyshire1 ,shropshire1 ,staffordshire1 ,flint1 and ,denbigh4 ,the southern coal-field1 including ,south ,wales1 ,forest of ,dean1 ,bristol1 ,dover1 with an offshoot at ,leinster1 c41 and ,millstreet1 ,cork4 ,thus it will be seen that while ,england and ,scotland are1 in comparison with their extent of surface1 bountifully supplied with coal-areas1 in the sister island of ,ireland coal-producing areas are almost absent4 ,the isolated beds in ,cork and ,tipperary1 in ,tyrone and ,antrim1 are but the remnants left of what were formerly beds of coal extending the whole breadth and length of ,ireland4 ,such beds as there remain undoubtedly belong to the base of the coal-measures1 and observations all go to show that the surface suffered such extreme denudation subsequent to the growth of the coal-forests1 that the wealth which once lay there1 has been swept away from the surface which formerly boasted of it4 ,on the continent of ,europe the coal-fields1 though not occupying so large a proportion of the surface of the country as in ,england1 are very far from being slight or to be disregarded4 ,the extent of forest-lands still remaining in ,germany and ,austria are sufficing for the immediate needs of the districts where some of the best seams occur4 ,it is only where there is a dearth of handy fuel1 ready to be had1 perhaps1 by the simple felling of a few trees1 that man commences to dig into the earth for his fuel4 ,but although on the continent not yet occupying so prominent a position in public estimation as do coal-fields in ,great ,britain1 those of the former have one conspicuous characteristic1 viz41 the great thickness of some of the individual seams4 ,in the coal-field of ,midlothian the seams of coal vary from #b feet to #e feet in thickness4 ,one of them is known as the great seam1 and in spite of its name attains a thickness only of from #h to #aj feet thick4 ,there are altogether about thirty seams of coal4 ,when1 however1 we pass to the continent1 we find many instances1 such as that of the coal-field of ,central ,france1 in which the seams attain vast thicknesses1 many of them actually reaching #dj and #fj feet1 and sometimes even #hj feet4 ,one of the seams in the district of ,st4 ,etienne varies from #cj to #gj feet thick1 whilst the fifteen to eighteen workable seams give a thickness of #aab feet1 although the total area of the field is not great4 ,again1 in the remarkable basin of the ,sane-et-,loire1 although there are but ten beds of coal1 two of them run from #cj to #fj feet each1 whilst at ,creusot the main seam actually runs locally to a thickness varying between #dj and #acj feet4 ,the ,belgian coal-field stretches in the form of a narrow strip from #g to #i miles wide by about #ajj miles long1 and is divided into three principal basins4 ,in that stretching from ,lige to ,verviers there are eighty-three seams of coal1 none of which are less than #c feet thick4 ,in the basin of the ,sambre1 stretching from ,namur to ,charleroi1 there are seventy-three seams which are workable1 whilst in that between ,mons and ,thulin there are no less than one hundred and fifty-seven seams4 ,the measures here are so folded in zigzag fashion1 that in boring in the neighbourhood of ,mons to a depth of #cej yards vertical1 a single seam was passed through no less than six times4 ,germany1 on the west side of the ,rhine1 is exceptionally fortunate in the possession of the famous ,pfalz-,saarbrcken coal-field1 measuring about #fj miles long by #bj miles wide1 and covering about #age square miles4 ,much of the coal which lies deep in these coal-measures will always remain unattainable1 owing to the enormous thickness of the strata1 but a careful computation made of the coal which can be worked1 gives an estimate of no less than #bgej millions of tons4 ,there is a grand total of two hundred and forty-four seams1 although about half of them are unworkable4 ,beside other smaller coal-producing areas in ,germany1 the coal-fields of ,silesia in the southeastern corner of ,prussia are a possession unrivalled both on account of their extent and thickness4 ,it is stated that there exist #ccc feet of coal1 all the seams of which exceed #b-a_/b feet1 and that in the aggregate there is here1 within a workable depth1 the scarcely conceivable quantity of #ej1jjj million tons of coal4 ,the coal-field of ,upper ,silesia1 occupying an area about #bj miles long by #ae miles broad1 is estimated to contain some #aj1jjj feet of strata1 with #ccc feet of good coal4 ,this is about three times the thickness contained in the ,south ,wales coal-field1 in a similar thickness of coal-measures4 ,there are single seams up to #fj feet thick1 but much of the coal is covered by more recent rocks of ,new ,red and ,cretaceous age4 ,in ,lower ,silesia there are numerous seams #c-a_/b feet to #e feet thick1 but owing to their liability to change in character even in the same seam1 their value is inferior to the coals of ,upper ,silesia4 ,when ,british supplies are at length exhausted1 we may anticipate that some of the earliest coals to be imported1 should coal then be needed1 will reach ,britain from the upper waters of the ,oder4 ,the coal-field of ,westphalia has lately come into prominence in connection with the search which has been made for coal in ,kent and ,surrey1 the strata which are mined at ,dortmund being thought to be continuous from the ,bristol coal-field4 ,borings have been made through the chalk of the district north of the ,westphalian coal-field1 and these have shown the existence of further coal-measures4 ,the coal-field extends between ,essen and ,dortmund a distance of #cj miles east and west1 and exhibits a series of about one hundred and thirty seams1 with an aggregate of #cjj feet of coal4 ,it is estimated that this coal-field alone contains no less than #ci1bjj millions of tons of coal4 ,russia possesses supplies of coal whose influence has scarcely yet been felt1 owing to the sparseness of the population and the abundance of forest4 ,carboniferous rocks abut against the flanks of the ,ural ,mountains1 along the sides of which they extend for a length of about a thousand miles1 with inter-stratifications of coal4 ,their actual contents have not yet been gauged1 but there is every reason to believe that those coal-beds which have been seen are but samples of many others which will1 when properly worked1 satisfy the needs of a much larger population than the country now possesses4 ,like the lower coals of ,scotland1 the ,russian coals are found in the carboniferous limestone4 ,this may also be said of the coal-fields in the governments of ,tula and ,kaluga1 and of those important coal-bearing strata near the river ,donetz1 stretching to the northern corner of the ,sea of ,azov4 ,in the last-named1 the seams are spread over an area of #aa1jjj square miles1 in which there are forty-four workable seams containing #aad feet of coal4 ,the thickest of known ,russian coals occur at ,lithwinsk1 where three seams are worked1 each measuring #cj feet to #dj feet thick4 ,an extension of the ,upper ,silesian coal-field appears in ,russian ,poland4 ,this is of upper ,carboniferous age1 and contains an aggregate of #fj feet of coal4 ,at ,ostrau1 in ,upper ,silesia 7,austria71 there is a remarkable coal-field4 ,of its #cgj seams there are no less than #aag workable ones1 and these contain #cej feet of coal4 ,the coals here are very full of gas1 which even percolates to the cellars of houses in the town4 ,a bore hole which was sunk in #aheb to a depth of #aej feet1 gave off a stream of gas1 which ignited1 and burnt for many years with a flame some feet long4 ,the ,zwickau coal-field in ,saxony is one of the most important in ,europe4 ,it contains a remarkable seam of coal1 known as ,russokohle or soot-coal1 running at times #be feet thick4 ,it was separated by ,geinitz and others into four zones1 according to their vegetable contents1 viz43-- #a4 ,zone of ,ferns4 #b4 ,zone of ,annularia and ,calamites4 #c4 ,zone of ,sigillaria4 #d4 ,zone of ,sagenaria 7in ,silesia71 equivalent to the culm-measures of ,devonshire4 ,coals belonging to other than true ,carboniferous age are found in ,europe at ,steyerdorf on the ,danube1 where there are a few seams of good coal in strata of ,liassic age1 and in ,hungary and ,styria1 where there are tertiary coals which approach closely to those of true ,carboniferous age in composition and quality4 ,in ,spain there are a few small scattered basins4 ,coal is found overlying the carboniferous limestone of the ,cantabrian chain1 the seams being from #e feet to #h feet thick4 ,in the ,satero valley1 near ,sotillo1 is a single seam measuring from #fj feet to #ajj feet thick4 ,coal of ,neocomian age appears at ,montalban4 ,when we look outside the continent of ,europe1 we may well be astonished at the bountiful manner in which nature has laid out beds of coal upon these ancient surfaces of our globe4 ,professor ,rogers estimated that1 in the ,united ,states of ,america1 the coal-fields occupy an area of no less than #aif1hej square miles4 ,here1 again1 it is extremely probable that the coal-fields which remain1 in spite of their gigantic existing areas1 are but the remnants of one tremendous area of deposit1 bounded only on the east by the ,atlantic1 and on the west by a line running from the great lakes to the frontiers of ,mexico4 ,the whole area has been subjected to forces which have produced foldings and flexures in the ,carboniferous strata after deposition4 ,these undulations are greatest near the ,alleghanies1 and between these mountains and the ,atlantic1 whilst the flexures gradually dying out westward1 cause the strata there to remain fairly horizontal4 ,in the troughs of the foldings thus formed the coal-measures rest1 those portions which had been thrown up as anticlines having suffered loss by denudation4 ,where the foldings are greatest there the coal has been naturally most altered2 bituminous and caking-coals are characteristic of the broad flat areas west of the mountains1 whilst1 where the contortions are greatest1 the coal becomes a pure anthracite4 ,it must not be thought that in this huge area the coal is all uniformly good4 ,it varies greatly in quality1 and in some districts it occurs in such thin seams as to be worthless1 except as fuel for consumption by the actual coal-getters4 ,there are1 too1 areas of many square miles in extent1 where there are now no coals at all1 the formation having been denuded right down to the palaeozoic back-bone of the country4 ,amongst the actual coal-fields1 that of ,pennsylvania stands pre-eminent4 ,the anthracite here is in inexhaustible quantity1 its output exceeding that of the ordinary bituminous coal4 ,the great field of which this is a portion1 extends in an unbroken length for #hge miles ,n4,e4 and ,s4,w41 and includes the basins of ,ohio1 ,maryland1 ,virginia1 ,kentucky1 and ,tennessee4 ,the workable seams of anthracite about ,pottsville measure in the aggregate from #gj to #bjg feet4 ,some of the lower seams individually attain an exceptional thickness1 that at ,lehigh ,summit mine containing a seam1 or rather a bed1 of #cj feet of good coal4 ,a remarkable seam of coal has given the town of ,pittsburg its name4 ,this is #h feet thick at its outcrop near the town1 and although its thickness varies considerably1 ,professor ,rogers estimates that the sheet of coal measures superficially about #ad1jjj square miles4 ,what a forest there must have existed to produce so widespread a bed6 ,even as it is1 it has at a former epoch suffered great denudation1 if certain detached basins should be considered as indicating its former extent4 ,the principal seam in the anthracite district of central ,pennsylvania1 which extends for about #fej miles along the left bank of the ,susquehanna1 is known as the ,mammoth vein1 and is #bi-a_/b feet thick at ,wilkesbarre1 whilst at other places it attains to1 and even exceeds1 #fj feet4 ,on the west of the chain of mountains the foldings become gentler1 and the coal assumes an almost horizontal position4 ,in passing through ,ohio we find a saddle-back ridge or anticline of more ancient strata than the coal1 and in consequence of this1 we have a physical boundary placed upon the coal-fields on each side4 ,passing across this older ridge of denuded ,silurian and other rocks1 we reach the famous ,illinois and ,indiana coal-field1 whose coal-measures lie in a broad trough1 bounded on the west by the uprising of the carboniferous limestone of the upper ,mississippi4 ,this limestone formation appears here for the first time1 having been absent on the eastern side of the ,ohio anticline4 ,the area of the coal-field is estimated at #ea1jjj square miles4 ,in connection with the coal-fields of the ,united ,states1 it is interesting to notice that a wide area in ,texas1 estimated at #cjjj square miles1 produces a large amount of coal annually from strata of the ,liassic age4 ,another important area of production in eastern ,virginia contains coal referable to the ,jurassic age1 and is similar in fossil contents to the ,jurassic of ,whitby and ,brora4 ,the main seam in eastern ,virginia boasts a thickness of from #cj to #dj feet of good coal4 ,very serviceable lignites of ,cretaceous age are found on the ,pacific slope1 to which age those of ,vancouver's ,island and ,saskatchewan ,river are referable4 ,other coal-fields of less importance are found between ,lakes ,huron and ,erie1 where the measures cover an area of #ejjj square miles1 and also in ,rhode ,island4 ,in ,british ,north ,america we find extensive deposits of valuable coal-measures4 ,large developments occur in ,new ,brunswick and ,nova ,scotia4 ,at ,south ,joggins there is a thickness of #ad1gej feet of strata1 in which are found seventy-six coal-seams of #de feet in total thickness4 ,at ,picton there are six seams with a total of #hj feet of coal4 ,in the lower carboniferous group is found the peculiar asphaltic coal of the ,albert mine in ,new ,brunswick4 ,extensive deposits of lignite are met with both in the ,dominion and in the ,united ,states1 whilst true coal-measures flank both sides of the ,rocky ,mountains4 ,coal-seams are often encountered in the ,arctic archipelago4 ,the principal areas of deposit in ,south ,america are in ,brazil1 ,uruguay1 and ,peru4 ,the largest is the ,candiota coal-field1 in ,brazil1 where sections in the valley of the ,candiota ,river show five good seams with a total of #fe feet of coal4 ,it is1 however1 worked but little1 the principal workings being at ,san ,jeronimo on the ,jacahahay ,river4 ,in ,peru the true carboniferous coal-seams are found on the higher ground of the ,andes1 whilst coal of secondary age is found in considerable quantities on the rise towards the mountains4 ,at ,porton1 east of ,truxillo1 the same metamorphism which has changed the ridge of sandstone to a hard quartzite has also changed the ordinary bituminous coal into an anthracite1 which is here vertical in position4 ,the coals of ,peru usually rise to more than #aj1jjj feet above the sea1 and they are practically inaccessible4 ,cretaceous coals have been found at ,lota in ,chili1 and at ,sandy ,point1 ,straits of ,magellan4 ,turning to ,asia1 we find that coal has been worked from time to time at ,heraclea in ,asia ,minor4 ,lignites are met with at ,smyrna and ,lebanon4 ,the coal-fields of ,hindoostan are small but numerous1 being found in all parts of the peninsula4 ,there is an important coal-field at ,raniganj1 near the ,hooghly1 #adj miles north of ,calcutta4 ,it has an area of #ejj square miles4 ,in the ,raniganj district there are occasional seams #bj feet to #hj feet in thickness1 but the coals are of somewhat inferior quality4 ,the best quality amongst ,indian coals has come from a small coal-field of about #aa square miles in extent1 situated at ,kurhurbali on the ,east ,indian ,railway4 ,other coal-fields are found at ,jherria and on the ,sone ,river1 in ,bengal1 and at ,mopani on the ,nerbudda4 ,much is expected in future from the large coal-field of the ,wardha and ,chanda districts1 in the ,central ,provinces1 the coal of which may eventually prove to be of ,permian age4 ,the coal-deposits of ,china are undoubtedly of tremendous extent1 although from want of exploration it is difficult to form any satisfactory estimate of them4 ,near ,pekin there are beds of coal #ie feet thick1 which afford ample provision for the needs of the city4 ,in the mountainous districts of western ,china the area over which carboniferous strata are exposed has been estimated at #ajj1jjj square miles4 ,the coal-measures extend westward to the ,mongolian frontier1 where coal-seams #cj feet thick are known to lie in horizontal plane for #bjj miles4 ,most of the ,chinese coal-deposits are rendered of small value1 either owing to the mountainous nature of the valleys in which they outcrop1 or to their inaccessibility from the sea4 ,japan is not lacking in good supplies of coal4 ,a colliery is worked by the government on the island of ,takasima1 near ,nagasaki1 for the supply of coals for the use of the navy4 ,the ,british possession of ,labuan1 off the island of ,borneo1 is rich in a coal of tertiary age1 remarkable for the quantity of fossil resin which1 it contains4 ,coal is also found in ,sumatra1 and in the ,malayan ,archipelago4 ,in ,cape ,colony and ,natal the coal-bearing ,karoo beds are probably of ,new ,red age4 ,the coal is reported to be excellent in quantity4 ,in ,abyssinia lignites are frequently met with in the high lands of the interior4 ,coal is very extensively developed throughout ,australasia4 ,in ,new ,south ,wales1 coal-measures occur in large detached portions between #bi and #ce ,s4 latitude4 ,the ,newcastle district1 at the mouth of the ,hunter river1 is the chief seat of the coal trade1 and the seams are here found up to #cj feet thick4 ,coal-bearing strata are found at ,bowen ,river1 in ,queensland1 covering an area of #bd1jjj square miles1 whilst important mines of ,cretaceous age are worked at ,ipswich1 near ,brisbane4 ,in ,new ,zealand quantities of lignite1 described as a hydrous coal1 are found and utilised2 also an anhydrous coal which may prove to be either of ,cretaceous or ,jurassic age4 ,we have thus briefly sketched the supplies of coal1 so far as they are known1 which are to be found in various countries4 ,but ,england has of late years been concerned as to the possible failure of her home supplies in the not very distant future1 and the effects which such failure would be likely to produce on the commercial prosperity of the country4 ,great ,britain has long been the centre of the universe in the supply of the world's coal1 and as a matter of fact1 has been for many years raising considerably more than one half of the total amount of coal raised throughout the whole world4 ,there is1 as we have seen1 an abundance of coal elsewhere1 which will1 in the course of time1 compete with her when properly worked1 but ,britain seems to have early taken the lead in the production of coal1 and to have become the great universal coal distributor4 ,those who have misgivings as to what will happen when her coal is exhausted1 receive little comfort from the fact that in ,north ,america1 in ,prussia1 in ,china and elsewhere1 there are tremendous supplies of coal as yet untouched1 although a certain sense of relief is experienced when that fact becomes generally known4 ,if by the time of exhaustion of the home mines ,britain is still dependent upon coal for fuel1 which1 in this age of electricity1 scarcely seems probable1 her trade and commerce will feel with tremendous effect the blow which her prestige will experience when the first vessel1 laden with foreign coal1 weighs anchor in a ,british harbour4 ,in the great coal lock-out of #ahic1 when1 for the greater part of sixteen weeks scarcely a ton of coal reached the surface in some of her principal coal-fields1 it was rumoured1 falsely as it appeared1 that a collier from ,america had indeed reached those shores1 and the importance which attached to the supposed event was shown by the anxious references to it in the public press1 where the truth or otherwise of the alarm was actively discussed4 ,should such a thing at any time actually come to pass1 it will indeed be a retribution to those who have for years been squandering their inheritance in many a wasteful manner of coal-consumption4 ,thirty years ago1 when so much small coal was wasted and wantonly consumed in order to dispose of it in the easiest manner possible at the pitmouths1 and when only the best and largest coal was deemed to be of any value1 louder and louder did scientific men speak in protest against this great and increasing prodigality4 ,wild estimates were set on foot showing how that1 sooner or later1 there would be in ,britain no native supply of coal at all1 and finally a ,royal ,commission was appointed in #ahff1 to collect evidence and report upon the probable time during which the supplies of ,great ,britain would last4 ,this ,commission reported in #ahga1 and the outcome of it was that a period of twelve hundred and seventy-three years was assigned as the period during which the coal would last1 at the then-existing rate of consumption4 ,the quantity of workable coal within a depth of #djjj feet was estimated to be #ij1bjg millions of tons1 or1 including that at greater depths1 #adf1dhj millions of tons4 ,since that date1 however1 there has been a steady annual increase in the amount of coal consumed1 and subsequent estimates go to show that the supplies cannot last for more than #bej years1 or1 taking into consideration a possible decrease in consumption1 #cej years4 ,most of the coal-mines will1 indeed1 have been worked out in less than a hundred years hence1 and then1 perhaps1 the competition brought about by the demand for1 and the scarcity of1 coal from the remaining mines1 will have resulted in the dreaded importation of coal from abroad4 ,in referring to the outcome of the ,royal ,commission of #ahff1 although the ,commissioners fixed so comparatively short a period as the probable duration of the coal supplies1 it is but fair that it should be stated that other estimates have been made which have materially differed from their estimate4 ,whereas one estimate more than doubled that of the ,royal ,commission1 that of ,sir ,william ,armstrong in #ahfc gave it as #bab years1 and ,professor ,jevons1 speaking in #ahge concerning ,armstrong's estimate1 observed that the annual increase in the amount used1 which was allowed for in the estimate1 had so greatly itself increased1 that the #bab years must be considerably reduced4 ,one can scarcely thoroughly appreciate the enormous quantity of coal that is brought to the surface annually1 and the only wonder is that there are any supplies left at all4 ,the ,great ,pyramid which is said by ,herodotus to have been twenty years in building1 and which took #ajj1jjj men to build1 contains #c1cid1cjg cubic yards of stone4 ,the coal raised in #ahib would make a pyramid which would contain #aha1ejj1jjj cubic yards1 at the low estimate that one ton could be squeezed into one cubic yard4 ,the increase in the quantity of coal which has been raised in succeeding years can well be seen from the following facts4 ,in #ahbj there were raised in ,great ,britain about #bj millions of tons4 ,by #ahee this amount had increased to #fd-a_/b millions4 ,in #ahfe this again had increased to #ih millions1 whilst twenty years after1 viz41 in #ahhe1 this had increased to no less than #aei millions1 such were the giant strides which the increase in consumption made4 ,in the return for #ahib1 this amount had farther increased to #aha-a_/b millions of tons1 an advance in eight years of a quantity more than equal to the total raised in #ahbj1 and in #ahid the total reached #aii-a_/b millions2 this was produced by #gie1bdj persons1 employed in and about the mines4 ,,chapter ,,viii4 ,,the ,,coal-,,tar ,,colours4 ,in a former chapter some slight reference has been made to those bye-products of coal-tar which have proved so valuable in the production of the aniline dyes4 ,it is thought that the subject is of so interesting a nature as to deserve more notice than it was possible to bestow upon it in that place4 ,with abstruse chemical formulae and complex chemical equations it is proposed to have as little as possible to do1 but even the most unscientific treatment of the subject must occasionally necessitate a scientific method of elucidation4 ,the dyeing industry has been radically changed during the last half century by the introduction of what are known as the artificial dyes1 whilst the natural colouring matters which had previously been the sole basis of the industry1 and which had been obtained by very simple chemical methods from some of the constituents of the animal kingdom1 or which were found in a natural state in the vegetable kingdom1 have very largely given place to those which have been obtained from coal-tar1 a product of the mineralised vegetation of the carboniferous age4 ,the development and discovery of the aniline colouring matters were not1 of course1 possible until after the extensive adoption of house-gas for illuminating purposes1 and even then it was many years before the waste products from the gas-works came to have an appreciable value of their own4 ,this1 however1 came with the increased utilitarianism of the commerce of the present century1 but although aniline was first discovered in #ahbf by ,unverdorben1 in the materials produced by the dry distillation of indigo 7,portuguese1 anil1 indigo71 it was not until thirty years afterwards1 namely1 in #ahef1 that the discovery of the method of manufacture of the first aniline dye1 mauveine1 was announced1 the discovery being due to the persistent efforts of ,perkin1 to whom1 together with other chemists working in the same field1 is due the great advance which has been made in the chemical knowledge of the carbon1 hydrogen1 and oxygen compounds4 ,scientists appeared to work along two planes2 there were those who discovered certain chemical compounds in the resulting products of reactions in the treatment of existing vegetation1 and there were those who1 studying the wonderful constituents in coal-tar1 the product of a past age1 immediately set to work to find therein those compounds which their contemporaries had already discovered4 ,generally1 too1 with signal success4 ,the discovery of benzene in #ahbe by ,faraday was followed in the course of a few years by its discovery in coal-tar by ,hofmann4 ,toluene1 which was discovered in #ahcg by ,pelletier1 was recognised in the fractional distillation of crude naphtha by ,mansfield in #ahdh4 ,although the method of production of mauveine on a large scale was not accomplished until #ahef1 yet it had been noticed in #ahcd1 the actual year of its recognition as a constituent of coal-tar1 that1 when brought into contact with chloride of lime1 it gave brilliant colours1 but it required a considerable cheapening of the process of aniline manufacture before the dyes commenced to enter into competition with the old natural dyes4 ,the isolation of aniline from coal-tar is expensive1 in consequence of the small quantities in which it is there found1 but it was discovered by ,mitscherlich that by acting upon benzene1 one of the early distillates of coal-tar1 for the production of nitro-benzole1 a compound was produced from which aniline could be obtained in large quantities4 ,there were thus two methods of obtaining aniline from tar1 the experimental and the practical4 ,in producing nitrobenzole 7nitrobenzene71 chemically represented as 7,c#f;,h#e,,no#b71 the nitric acid used as the reagent with benzene1 is mixed with a quantity of sulphuric acid1 with the object of absorbing water which is formed during the reaction1 as this would tend to dilute the efficiency of the nitric acid4 ,the proportions are #ajj parts of purified benzene1 with a mixture of #aae parts of concentrated nitric acid 7,,hno#c7 and #afj parts of concentrated sulphuric acid4 ,the mixture is gradually introduced into the large cast-iron cylinder into which the benzene has been poured4 ,the outside of the cylinder is supplied with an arrangement by which fine jets of water can be made to play upon it in the early stages of the reaction which follows1 and at the end of from eight to ten hours the contents are allowed to run off into a storage reservoir4 ,here they arrange themselves into two layers1 the top of which consists of the nitrobenzene which has been produced1 together with some benzene which is still unacted upon4 ,the mixture is then freed from the latter by treatment with a current of steam4 ,nitrobenzene presents itself as a yellowish oily liquid1 with a peculiar taste as of bitter almonds4 ,it was formerly in great demand by perfumers1 but its poisonous properties render it a dangerous substance to deal with4 ,in practice a given quantity of benzene will yield about #aej per cent of nitrobenzene4 ,stated chemically1 the reaction is shown by the following equation3-- ,c#f;,h#f ,,hno#c ,c#f;,h#e,,no#b1 ,h#b,o 7,benzene7 7,nitric acid7 7,nitrobenzene7 7,water74 ,the water which is thus formed in the process1 by the freeing of one of the atoms of hydrogen in the benzene1 is absorbed by the sulphuric acid present1 although the latter takes no actual part in the reaction4 ,from the nitrobenzene thus obtained1 the aniline which is now used so extensively is prepared4 ,the component atoms of a molecule of aniline are shown in the formula ,c#f;,h#e,,nh#b4 ,it is also known as phenylamine or amido-benzole1 or commercially as aniline oil4 ,there are various methods of reducing nitrobenzene for aniline1 the object being to replace the oxygen of the former by an equivalent number of atoms of hydrogen4 ,the process generally used is that known as ,bchamp's1 with slight modifications4 ,equal volumes of nitrobenzene and acetic acid1 together with a quantity of iron-filings rather in excess of the weight of the nitrobenzene1 are placed in a capacious retort4 ,a brisk effervescence ensues1 and to moderate the increase of temperature which is caused by the reaction1 it is found necessary to cool the retort4 ,instead of acetic acid hydrochloric acid has been a good deal used1 with1 it is said1 certain advantageous results4 ,from #fj to #fe per cent4 of aniline on the quantity of nitrobenzene used1 is yielded by ,bchamp's process4 ,stated in a few words1 the above is the process adopted on all hands for the production of commercial aniline1 or aniline oil4 ,the details of the distillation and rectification of the oil are1 however1 as varied as they can well be1 no two manufacturers adopting the same process4 ,many of the aniline dyes depend entirely for their superiority1 on the quality of the oil used1 and for this reason it is subject to one or more processes of rectification4 ,this is performed by distilling1 the distillates at the various temperatures being separately collected4 ,when pure1 aniline is a colourless oily liquid1 but on exposure rapidly turns brown4 ,it has strong refracting powers and an agreeable aromatic smell4 ,it is very poisonous when taken internally2 its sulphate is1 however1 sometimes used medicinally4 ,it is by the action upon aniline of certain oxidising agents1 that the various colouring matters so well known as aniline dyes are obtained4 ,commercial aniline oil is not1 as we have seen1 the purest form of rectified aniline4 ,the aniline oils of commerce are very variable in character1 the principal constituents being pure aniline1 para- and meta-toluidine1 xylidines1 and cumidines4 ,they are best known to the colour manufacturer in four qualities-- 7a7 ,aniline oil for blue and black4 7b7 ,aniline oil for magenta4 7c7 ,aniline oil for safranine4 7d7 ,liquid toluidine4 ,from the first of these1 which is almost pure aniline1 aniline black is derived1 and a number of organic compounds which are further used for the production of dyes4 ,the hydrochloride of aniline is important and is known commercially as aniline salt4 ,the distillation and rectification of aniline oil is practised on a similar principle to the fractional distillation which we have noticed as being used for the distillation of the naphthas4 ,first1 light aniline oils pass over1 followed by others1 and finally by the heavy oils1 or aniline-tailings4 ,it is a matter of great necessity to those engaged in colour manufacture to apply that quality oil which is best for the production of the colour required4 ,this is not always an easy matter1 and there is great divergence of opinion and in practice on these points4 ,the so-called aniline colours are not all derived from aniline1 such colouring matters being in some cases derived from other coal-tar products1 such as benzene and toluene1 phenol1 naphthalene1 and anthracene1 and it is remarkable that although the earlier dyes were produced from the lighter and more easily distilled products of coal-tar1 yet now some of the heaviest and most stubborn of the distillates are brought under requisition for colouring matters1 those which not many years ago were regarded as fit only to be used as lubricants or to be regarded as waste4 ,it is scarcely necessary or advisable in a work of this kind to pursue the many chemical reactions1 which1 from the various acids and bases1 result ultimately in the many shades and gradations of colour which are to be seen in dress and other fabrics4 ,many of them1 beautiful in the extreme1 are the outcome of much careful and well-planned study1 and to print here the complicated chemical formulae which show the great changes taking place in compounds of complex molecules1 or to mention even the names of these many-syllabled compounds1 would be to destroy the purpose of this little book4 ,the ,rosanilines1 the ,indulines1 and ,safranines2 the ,oxazines1 the ,thionines3 the ,phenol and ,azo dyes are all substances which are of greater interest to the chemical students and to the colour manufacturer than to the ordinary reader4 ,many of the names of the bases of various dyes are unknown outside the chemical dyeworks1 although each and all have complicated2 reactions of their own4 ,in the reds are rosanilines1 toluidine xylidine1 c42 in the blues--phenyl-rosanilines1 diphenylamine1 toluidine1 aldehyde1 c42 violets--rosaniline1 mauve1 phenyl1 ethyl1 methyl1 c42 greens--iodine1 aniline1 leucaniline1 chrysotoluidine1 aldehyde1 toluidine1 methyl-anilinine1 c42 yellows and orange--leucaniline1 phenylamine1 c42 browns--chrysotoluidine1 c42 blacks--aniline1 toluidine1 c4 ,to take the rosanilines as an instance of the rest4 ,aniline red1 magenta1 azaleine1 rubine1 solferino1 fuchsine1 chryaline1 roseine1 erythrobenzine1 and others1 are colouring matters in this group which are salts of rosaniline1 and which are all recognised in commerce4 ,the base rosaniline is known chemically by the formula ,c#bj;,hl#i,n#c1 and is prepared by heating a mixture of magenta aniline1 toluidine1 and pseudotoluidine1 with arsenic acid and other oxidising agents4 ,it is important that water should be used in such quantities as to prevent the solution of arsenic acid from depositing crystals on cooling4 ,unless carefully crystallised rosaniline will contain a slight proportion of the arseniate1 and when articles of clothing are dyed with the salt1 it is likely to produce an inflammatory condition of skin1 when worn4 ,some years ago there was a great outcry against hose and other articles dyed with aniline dyes1 owing to the bad effects which were produced1 and this has no doubt proved very prejudicial to aniline dyes as a whole4 ,again1 the base known as mauve1 or mauveine1 has a composition shown by the formula ,c#bg;,h#bd,n#d4 ,it is produced from the sulphate of aniline by mixing it with a cold saturated solution of bichromate of potash1 and allowing the mixture to stand for ten or twelve hours4 ,a blue-black precipitate is then formed1 which1 after undergoing a process of purification1 is dissolved in alcohol and evaporated to dryness4 ,a metallic-looking powder is then obtained1 which constitutes this all-important base4 ,mauve forms with acids a series of well-defined salts and is capable of expelling ammonia from its combinations4 ,mauve was the first aniline dye which was produced on a large scale1 this being accomplished by ,perkin in #ahef4 ,the substance known as carbolic acid is so useful a product of a piece of coal that a description of the method of its production must necessarily have a place here4 ,it is one of the most powerful antiseptic agents with which we are acquainted1 and has strong anaesthetic qualities4 ,some useful dyes are also obtained from it4 ,it is obtained in quantities from coal-tar1 that portion of the distillate known as the light oils being its immediate source4 ,the tar oil is mixed with a solution of caustic soda1 and the mixture is violently agitated4 ,this results in the caustic soda dissolving out the carbolic acid1 whilst the undissolved oils collect upon the surface1 allowing the alkaline solution to be drawn from beneath4 ,the soda in the solution is then neutralised by the addition of a suitable quantity of sulphuric acid1 and the salt so formed sinks while the carbolic acid rises to the surface4 ,purification of the product is afterwards carried out by a process of fractional distillation4 ,there are various other methods of preparing carbolic acid4 ,carbolic acid is known chemically as ,c#f;,h#e7;,,ho74 ,when pure it appears as colourless needle-like crystals1 and is exceedingly poisonous4 ,it has been used with marked success in staying the course of disease1 such as cholera and cattle plague4 ,it is of a very volatile nature1 and its efficacy lies in its power of destroying germs as they float in the atmosphere4 ,modern science tells us that all diseases have their origin in certain germs which are everywhere present and which seek only a suitable nidus in which to propagate and flourish4 ,unlike mere deodorisers which simply remove noxious gases or odours2 unlike disinfectants which prevent the spread of infection1 carbolic acid strikes at the very root and origin of disease by oxidising and consuming the germs which breed it4 ,so powerful is it that one part in five thousand parts of flour paste1 blood1 c41 will for months prevent fermentation and putrefaction1 whilst a little of its vapour in the atmosphere will preserve meat1 as well as prevent it from becoming fly-blown4 ,although it has1 in certain impure states1 a slightly disagreeable odour1 this is never such as to be in any way harmful1 whilst on the other hand it is said to act as a tonic to those connected with its preparation and use4 ,the new artificial colouring matters which are continually being brought into the market1 testify to the fact that1 even with the many beautiful tints and hues which have been discovered1 finality and perfection have not yet been reached4 ,a good deal of popular prejudice has arisen against certain aniline dyes on account of their inferiority to many of the old dye-stuffs in respect to their fastness1 but in recent years the manufacture of many which were under this disadvantage of looseness of dye1 has entirely ceased1 whilst others have been introduced which are quite as fast1 and sometimes even faster than the natural dyes4 ,it is convenient to express the constituents of coal-tar1 and the distillates of those constituents1 in the form of a genealogical chart1 and thus1 by way of conclusion1 summarise the results which we have noticed4 ,,coal4 4--------------------------------------- -----------------4 ,water ,house-gas ,coal-tar ,ammoniacal ,coke liquor 4----------------------------------4 ,sulphur 7sulphurreted ,first ,second ,heavy ,anthracene ,pitch hydrogen3 light light oils 7green sulphurous oils oils 7creosote oils7 acid3 oil 7crude oils7 of vitriol7 4--------4 naphtha7 ,anthracene ,ammoniacal ,benzene ,alizarin or liquor toluene1 dyer's madder c4 ,sulphuric acid,carbonate of,hydrochloric ammonia acid 7smelling salts7 ,lime,sulphate of ,lime,chloride of ammonia ammonia 7sal ammoniac7 4--------4 4--------4 ,ammonia ,sulphate ,ammonia ,chloride of lime of lime4 7,plaster of ,paris7 4-----------------4 ,crude ,carbolic ,naphthalin ,creosote acid 4--------------------------------------- ------4 ,benzene,nitric ,acid ,toluene ,nylene ,artificial ,burning turpentine oils ,nitrobenzene ,iron filings oil 7solvent 7,essence de and acetic acid naphtha7 mirbane7 ,aniline,various reagents ,aniline dyes ,,index4 ,a4 ,accidents1 causes of mining ,age of ,acrogens ,alethopteris ,alizarin ,american coal-fields ,ammoniacal liquor ,aniline ,aniline dyes ,aniline oil1 commercial ,aniline salt ,aniline tailings ,anthracene ,anthracite ,artificial turpentine oil ,asphalt ,australian coals ,aviculopecten ,b4 ,bchamp's process ,benzene ,bind ,bitumen in ,trinidad ,blower a ,boghead coal ,bog-oak ,boring diamonds ,borrowdale graphite mine ,bovey ,tracey lignite ,british coal-fields ,british ,north-,american coal-measures ,briquettes ,c4 ,calamites1 extinct horsetails ,carbolic acid ,carboniferous formation1 the ,cardiocarpum1 fossil fruit ,carelessness of miners ,causes of earth-movements ,changes of level ,charcoal as a disinfectant ,chemistry of a gas-flame ,chinese coals ,clanny's safety-lamp ,clayton's experiments with gas ,clay1 regularity in deposition of ,club-mosses1 great height of fossil ,coal-dust1 danger from ,coal formed in large lakes or closed seas ,coal formation1 geological position of ,coal formed by escape of gases ,coal-mine1 the ,coal not the result of drifted vegetation ,coal-period1 climate of ,coal-pipes ,coal-plants1 classification of ,coal-seam1 each1 a forest growth ,coals of non-carboniferous age ,coal1 vegetable origin of ,coke ,cole ,condensers ,cones of ,lepidodendra ,conifers in coal-measures ,current-bedding in sandstone ,d4 ,davy-lamp ,dangers of benzene ,darwin on the ,chonos ,archipelago ,diamonds1 how made artificially ,disintegration of vegetable substances ,disproportion in relative thickness of coal and coal-measures ,e4 ,early use of coal ,effects of an explosion ,encrinital limestone ,equiseta ,essence de mirbane ,european coal-fields ,evelyn on the use of coal ,experiments illustrating fossilisation ,f4 ,filling retorts by machinery ,firedamp ,fire1 mines on ,first light oils ,first record of an explosion ,flashing-point of oil ,flooding of pits ,fog and smoke ,foraminifera ,fossil ferns ,fructification on fossil-ferns ,furnace1 ventilating ,g4 ,gas1 coal ,gasholder1 the ,gas1 house1 constituents of ,glossopteris ,graphite ,green ,grease ,h4 ,hannay1 of ,glasgow ,heavy oils ,humboldt's safety-lamp ,hydraulic ,main ,i4 ,impurities in house-gas ,indian coals ,insertion of rootlets of stigmaria ,insufficiency of modern forest growths ,ireland denuded of coal-beds ,iron1 supplies of ,l4 ,lepidodendra ,lepidostrobi ,lignite ,london lit by gas ,m4 ,mammoth trees ,marco ,polo ,marsh gas ,medium oils ,metamorphism of coal by igneous agency ,methods of ventilation ,mountain limestone ,murdock's use of gas ,mussel beds ,n4 ,napthalin ,neuropteris ,newcastle1 charters to ,nitro-benzole ,o4 ,objections to use of coal ,oils from coal and lignite ,oil-wells of ,america ,olefiant gas ,orthoceras ,p4 ,paraffins ,peat ,pecopteris ,pennsylvanian anthracite ,persian fire-worshippers ,pitch ,plumbago ,polyzoa ,prejudice against aniline dyes ,prohibitions of the use of coal ,proportions of explosive mixtures ,psaronius ,purifiers ,pyrites in coal ,q4 ,quantity of coal raised in ,great ,britain ,r4 ,reptiles of the coal-era ,resemblance of ,american and ,british coal-flora ,retorts ,roman use of coal ,rosanilines1 the ,royal ,commission of #ahff ,s4 ,sandstone1 how formed ,shales ,sigillaria ,south ,american coals ,spores of lepidodrendron ,spores1 resinous matter in ,spores1 inflammability of ,steel-mill ,sternbergia ,stigmaria ,subsidence throughout coal-era ,surturbrand at ,brighton ,sussex iron-works ,t4 ,tar ,testing pits by the candle ,texas coal ,toluene1 discovery of ,torbanehill mineral ,trappers ,u4 ,underclays ,uses to which coal is put ,v4 ,vaseline ,vegetation of the coal age ,ventilation of coal-pits ,w4 ,washers ,waste of fuel ,wealden lignite ,westphalian coal-field ,y4 ,young's ,paraffin ,oil ,z4 ,zoroastrians